KR20140069011A - 그라핀 나노리본의 용매계 제조 방법 - Google Patents
그라핀 나노리본의 용매계 제조 방법 Download PDFInfo
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- KR20140069011A KR20140069011A KR1020147007546A KR20147007546A KR20140069011A KR 20140069011 A KR20140069011 A KR 20140069011A KR 1020147007546 A KR1020147007546 A KR 1020147007546A KR 20147007546 A KR20147007546 A KR 20147007546A KR 20140069011 A KR20140069011 A KR 20140069011A
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- graphene nanoribbons
- gnr
- carbon nanotubes
- graphene
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
- C01B32/174—Derivatisation; Solubilisation; Dispersion in solvents
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- C01B32/178—Opening; Filling
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- C01B32/00—Carbon; Compounds thereof
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/56—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic condensed
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
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- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/06—Multi-walled nanotubes
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- C01B2204/00—Structure or properties of graphene
- C01B2204/06—Graphene nanoribbons
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
- Y10S977/846—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes internal modifications, e.g. filling, endohedral modifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11411222B2 (en) | 2018-01-26 | 2022-08-09 | Korea Advanced Institute Of Science And Technology | Conductive agent, slurry for forming electrode including same, electrode, and lithium secondary battery manufactured using same |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013040356A1 (en) | 2011-09-14 | 2013-03-21 | William Marsh Rice University | Solvent-based methods for production of graphene nanoribbons |
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| GB201408221D0 (en) | 2014-05-09 | 2014-06-25 | Univ Manchester | Functionalised graphene |
| JP6825781B2 (ja) * | 2014-06-12 | 2021-02-03 | センター ナショナル デ ラ レシェルシェ サイエンティフィック（シーエヌアールエス）Ｃｅｎｔｒｅ Ｎａｔｉｏｎａｌ Ｄｅ Ｌａ Ｒｅｃｈｅｒｃｈｅ Ｓｃｉｅｎｔｉｆｉｑｕｅ（Ｃｎｒｓ） | 剥離ナノカーボン材料の水性および有機懸濁液、その作製方法及びその使用 |
| US9840418B2 (en) | 2014-06-16 | 2017-12-12 | William Marsh Rice University | Production of graphene nanoplatelets by oxidative anhydrous acidic media |
| US10199646B2 (en) | 2014-07-30 | 2019-02-05 | StoreDot Ltd. | Anodes for lithium-ion devices |
| CN104212053A (zh) * | 2014-09-18 | 2014-12-17 | 福州大学 | 一种防水隔氧密封膜及其制备和应用 |
| US10299366B2 (en) | 2015-08-06 | 2019-05-21 | International Business Machines Corporation | Tamper detection circuits |
| EP3360180A4 (en) * | 2015-10-08 | 2019-06-12 | William Marsh Rice University | POROUS CARBON MATERIALS WITH HIGH SURFACES AS ELECTRODES |
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| US10096859B2 (en) | 2016-04-07 | 2018-10-09 | StoreDot Ltd. | Electrolytes with ionic liquid additives for lithium ion batteries |
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| US10183754B1 (en) * | 2017-12-20 | 2019-01-22 | The Florida International University Board Of Trustees | Three dimensional graphene foam reinforced composite coating and deicing systems therefrom |
| CN108383111A (zh) * | 2018-05-11 | 2018-08-10 | 深圳市本征方程石墨烯技术股份有限公司 | 一种石墨烯浆料及其制备方法 |
| JP6586197B1 (ja) | 2018-06-01 | 2019-10-02 | 東洋インキＳｃホールディングス株式会社 | カーボンナノチューブ、カーボンナノチューブ分散液およびその利用 |
| EP3597594A1 (en) * | 2018-07-17 | 2020-01-22 | Graphenano Medical Care, S.L. | Graphene product and therapeutic uses thereof |
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| RU2703635C1 (ru) * | 2018-12-28 | 2019-10-21 | федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный технический университет имени Н.Э. Баумана (национальный исследовательский университет)" (МГТУ им. Н.Э. Баумана) | Способ повышения прочности на разрыв композитного материала с помощью предварительной пропитки углеволокон |
| US10608463B1 (en) | 2019-01-23 | 2020-03-31 | StoreDot Ltd. | Direct charging of battery cell stacks |
| US11831012B2 (en) | 2019-04-25 | 2023-11-28 | StoreDot Ltd. | Passivated silicon-based anode material particles |
| CN110316727B (zh) * | 2019-06-20 | 2021-06-15 | 宁波锋成纳米科技有限公司 | 双面不对称修饰石墨烯的制备方法 |
| CN112267060B (zh) * | 2020-10-17 | 2021-09-28 | 安徽军明机械制造有限公司 | 一种改善球磨铸铁组织性能的方法 |
| CN113388905B (zh) * | 2021-06-15 | 2022-07-05 | 广西大学 | 一种中空石墨烯纤维的自卷曲制备方法及其应用 |
| US20240343584A1 (en) * | 2021-11-03 | 2024-10-17 | The Penn State Research Foundation | Exfoliation and dispersion of carbon nanothreads |
| KR20240158223A (ko) * | 2021-12-23 | 2024-11-04 | 시코나 배터리 테크놀로지스 피티와이 엘티디 | 에지 기능화된 그래핀 열적 나노유체 |
| CN114735680B (zh) * | 2022-04-27 | 2023-07-25 | 北京化工大学 | 一种石墨烯纳米带及其制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001007694A1 (en) * | 1999-07-21 | 2001-02-01 | Hyperion Catalysis International, Inc. | Methods of oxidizing multiwalled carbon nanotubes |
| JP2008515654A (ja) | 2004-10-12 | 2008-05-15 | ナノシス・インク． | 導電性ポリマー及び半導体ナノワイヤに基づいてプラスチック電子部品を製造するための完全に集積化された有機層プロセス |
| JP5119451B2 (ja) * | 2006-07-07 | 2013-01-16 | 国立大学法人大阪大学 | カップ型ナノカーボンの製造方法およびカップ型ナノカーボン |
| US20080048152A1 (en) * | 2006-08-25 | 2008-02-28 | Jang Bor Z | Process for producing nano-scaled platelets and nanocompsites |
| US7745528B2 (en) * | 2006-10-06 | 2010-06-29 | The Trustees Of Princeton University | Functional graphene-rubber nanocomposites |
| US20100140792A1 (en) * | 2006-10-31 | 2010-06-10 | The Regents Of The University Of California | Graphite nanoplatelets for thermal and electrical applications |
| US8481421B2 (en) | 2007-07-25 | 2013-07-09 | California Institute Of Technology | Functional anchors connecting graphene-like carbon to metal |
| US20110104700A1 (en) * | 2008-05-30 | 2011-05-05 | Halloran Philip F | Molecular signature for fibrosis and atrophy |
| US9991391B2 (en) | 2008-07-25 | 2018-06-05 | The Board Of Trustees Of The Leland Stanford Junior University | Pristine and functionalized graphene materials |
| TW201012749A (en) | 2008-08-19 | 2010-04-01 | Univ Rice William M | Methods for preparation of graphene nanoribbons from carbon nanotubes and compositions, thin films and devices derived therefrom |
| US8501318B2 (en) * | 2008-09-03 | 2013-08-06 | Nanotek Instruments, Inc. | Dispersible and conductive nano graphene platelets |
| JP2010173874A (ja) * | 2009-01-28 | 2010-08-12 | Toray Ind Inc | カーボンナノチューブ凝集体を得る方法 |
| BRPI1016033A2 (pt) * | 2009-06-15 | 2016-05-10 | Univ Rice William M | nanofitas de grafeno preparadas a partir de nanotubos de carbono via exposição de metal alcalino. |
| US8652362B2 (en) | 2009-07-23 | 2014-02-18 | Nanotek Instruments, Inc. | Nano graphene-modified curing agents for thermoset resins |
| US8287699B2 (en) * | 2009-07-27 | 2012-10-16 | Nanotek Instruments, Inc. | Production of chemically functionalized nano graphene materials |
| US8226801B2 (en) | 2009-07-27 | 2012-07-24 | Nanotek Instruments, Inc. | Mass production of pristine nano graphene materials |
| WO2013040356A1 (en) | 2011-09-14 | 2013-03-21 | William Marsh Rice University | Solvent-based methods for production of graphene nanoribbons |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11411222B2 (en) | 2018-01-26 | 2022-08-09 | Korea Advanced Institute Of Science And Technology | Conductive agent, slurry for forming electrode including same, electrode, and lithium secondary battery manufactured using same |
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| CN103796766B (zh) | 2017-05-31 |
| TWI568669B (zh) | 2017-02-01 |
| AU2012308433A1 (en) | 2014-03-06 |
| RU2609915C2 (ru) | 2017-02-07 |
| US20170081441A1 (en) | 2017-03-23 |
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| US9493355B2 (en) | 2016-11-15 |
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| IL231029A0 (en) | 2014-03-31 |
| US20150057417A1 (en) | 2015-02-26 |
| WO2013040356A1 (en) | 2013-03-21 |
| EP2755776A1 (en) | 2014-07-23 |
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| PH12014500426A1 (en) | 2014-04-14 |
| TW201328969A (zh) | 2013-07-16 |
| EP2755776A4 (en) | 2015-10-28 |
| BR112014006025A2 (pt) | 2017-06-13 |
| SG2014014880A (en) | 2014-05-29 |
| CN103796766A (zh) | 2014-05-14 |
| IN2014DN02052A (enExample) | 2015-05-15 |
| CA2848400A1 (en) | 2013-03-21 |
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