RU2543210C2 - Твердая неорганическая композиция, способ ее получения и ее применение для снижения содержания диоксинов и тяжелых металлов в дымовых газах - Google Patents

Твердая неорганическая композиция, способ ее получения и ее применение для снижения содержания диоксинов и тяжелых металлов в дымовых газах Download PDF

Info

Publication number
RU2543210C2
RU2543210C2 RU2012104806/05A RU2012104806A RU2543210C2 RU 2543210 C2 RU2543210 C2 RU 2543210C2 RU 2012104806/05 A RU2012104806/05 A RU 2012104806/05A RU 2012104806 A RU2012104806 A RU 2012104806A RU 2543210 C2 RU2543210 C2 RU 2543210C2
Authority
RU
Russia
Prior art keywords
inorganic compound
halide
salt
content
composition
Prior art date
Application number
RU2012104806/05A
Other languages
English (en)
Russian (ru)
Other versions
RU2012104806A (ru
Inventor
Ален БРАССЁР
Жан-Поль ПИРАР
Ален Лоде
Original Assignee
С.А. Луаст Решерш Э Девелопмен
Университе Де Льеж
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by С.А. Луаст Решерш Э Девелопмен, Университе Де Льеж filed Critical С.А. Луаст Решерш Э Девелопмен
Publication of RU2012104806A publication Critical patent/RU2012104806A/ru
Application granted granted Critical
Publication of RU2543210C2 publication Critical patent/RU2543210C2/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/68—Halogens or halogen compounds
    • B01D53/70—Organic halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0288—Halides of compounds other than those provided for in B01J20/046
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28071—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/11—Clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/116—Molecular sieves other than zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/304—Linear dimensions, e.g. particle shape, diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/311—Porosity, e.g. pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/206—Organic halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
RU2012104806/05A 2009-07-13 2010-07-13 Твердая неорганическая композиция, способ ее получения и ее применение для снижения содержания диоксинов и тяжелых металлов в дымовых газах RU2543210C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
BE2009/0427 2009-07-13
BE200900427 2009-07-13
US33225410P 2010-05-07 2010-05-07
US61/332,254 2010-05-07
PCT/EP2010/060075 WO2011006898A1 (fr) 2009-07-13 2010-07-13 Composition solide minerale, son procede de preparation et son utilisation en abattement de dioxines et metaux lourds des gaz de fumees

Publications (2)

Publication Number Publication Date
RU2012104806A RU2012104806A (ru) 2013-09-27
RU2543210C2 true RU2543210C2 (ru) 2015-02-27

Family

ID=41719070

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2012104806/05A RU2543210C2 (ru) 2009-07-13 2010-07-13 Твердая неорганическая композиция, способ ее получения и ее применение для снижения содержания диоксинов и тяжелых металлов в дымовых газах

Country Status (17)

Country Link
US (1) US20120134903A1 (enExample)
EP (1) EP2454007B1 (enExample)
JP (1) JP5722888B2 (enExample)
KR (1) KR20120085718A (enExample)
CN (1) CN102497921B (enExample)
AU (1) AU2010272573A1 (enExample)
BE (1) BE1019420A5 (enExample)
CA (1) CA2767282A1 (enExample)
FR (1) FR2949979A1 (enExample)
IL (1) IL217480A0 (enExample)
MX (1) MX2012000590A (enExample)
NZ (1) NZ598097A (enExample)
PL (1) PL2454007T3 (enExample)
RU (1) RU2543210C2 (enExample)
SG (1) SG177490A1 (enExample)
UA (1) UA108615C2 (enExample)
WO (1) WO2011006898A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102814180B (zh) * 2012-06-07 2017-12-22 盐城工学院 用于烟气中单质汞氧化凹凸棒土载体催化剂及其制备方法
US20130330257A1 (en) 2012-06-11 2013-12-12 Calgon Carbon Corporation Sorbents for removal of mercury
US9751043B1 (en) 2014-09-05 2017-09-05 Mississippi Lime Company Systems and method for removal of acid gas in a circulating dry scrubber
US10155227B2 (en) 2012-08-24 2018-12-18 Mississippi Lime Company Systems and method for removal of acid gas in a circulating dry scrubber
JP6461807B2 (ja) * 2012-11-13 2019-01-30 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライト材料の製造方法及び酸素含有物質のオレフィンへの転化方法におけるゼオライト材料の使用
US9963386B1 (en) 2013-03-04 2018-05-08 Mississippi Lime Company Method of manufacturing hydrated lime
US10221094B1 (en) 2013-03-04 2019-03-05 Mississippi Lime Company Method of manufacturing hydrated lime
US20140374655A1 (en) * 2013-06-19 2014-12-25 Calgon Carbon Corporation Methods for mitigating the leaching of heavy metals from activated carbon
CN103381337B (zh) * 2013-06-26 2016-01-20 广东电网公司电力科学研究院 一种用于湿法烟气脱汞的催化氧化添加剂及其制备方法
US10668480B1 (en) 2014-09-05 2020-06-02 Mississippi Lime Company Systems and method for removal of acid gas in a circulating dry scrubber
WO2017027230A1 (en) 2015-08-11 2017-02-16 Calgon Carbon Corporation Enhanced sorbent formulation for removal of mercury from flue gas
CN105435735A (zh) * 2015-11-19 2016-03-30 兰州坤仑环保科技有限公司 一种水体重金属离子凹凸棒吸附剂
CN105944554A (zh) * 2016-06-08 2016-09-21 黄立维 一种去除有害气体的方法及装置
US11148149B2 (en) 2017-12-29 2021-10-19 Mississippi Lime Company Hydrated lime with reduced resistivity and method of manufacture
US11365150B1 (en) 2018-07-18 2022-06-21 Mississippi Lime Company Lime hydrate with improved reactivity via additives
CN111389219B (zh) * 2020-03-27 2021-11-02 浙江浙能技术研究院有限公司 一种用于燃煤锅炉启停阶段的喷氨控制方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2035993C1 (ru) * 1993-09-30 1995-05-27 Александр Ефимович Горенбейн Способ получения сорбентов для очистки газов от ртути
DE19824237A1 (de) * 1998-05-29 1999-12-02 Walhalla Kalk Entwicklungs Und Reagentien für die Reinigung von Abgasen
RU2200053C1 (ru) * 2001-11-27 2003-03-10 Рынейский Вадим Анатольевич Установка для очистки дымовых газов
DE10228459A1 (de) * 2002-06-26 2004-01-15 Iko Minerals Gmbh Verfahren zur Herstellung eines silikatischen Adsorbermaterials
RU2352383C2 (ru) * 2004-03-15 2009-04-20 С.А.Луаст Решерш Э Девелопмен Способ улавливания тяжелых металлов из дымовых газов

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1481646A (fr) 1966-05-31 1967-05-19 Union Carbide Corp Compositions adsorbantes siliceuses et leur procédé de préparation
JPS4953591A (enExample) * 1972-09-29 1974-05-24
JPS59160534A (ja) * 1983-03-03 1984-09-11 Takeda Chem Ind Ltd 水銀蒸気吸着剤および水銀蒸気含有気体の処理方法
JPS5910343A (ja) * 1982-07-08 1984-01-19 Takeda Chem Ind Ltd 水銀蒸気吸着剤
ES8704428A1 (es) 1986-02-11 1987-04-16 Consejo Superior Investigacion Procedimiento de fabricacion de un adsorbente azufrado, util para retener vapores de metal, como mercurio.
JPH0659383B2 (ja) * 1987-12-11 1994-08-10 小野田セメント株式会社 複合乾燥剤
JPH09208336A (ja) * 1996-01-30 1997-08-12 Ootake Seramu Kk 塩基性多孔体及びその製造法
ES2136496B1 (es) 1996-06-18 2000-10-01 Consejo Superior Investigacion Procedimiento de sulfuracion de silicatos naturales para retener vapores de metales.
JP2000140627A (ja) * 1998-11-10 2000-05-23 Takuma Co Ltd ダイオキシン除去材、ダイオキシン除去方法、及び、ダイオキシン除去材の再生方法
JP3242902B2 (ja) * 1999-07-21 2001-12-25 クリン化成株式会社 ダイオキシン対策用ごみ袋
JP2001276606A (ja) 2000-03-31 2001-10-09 Hitachi Zosen Corp 排ガス中の有機系有害物除去用吸着剤および同有害物の除去方法
JP3790890B2 (ja) 2001-07-19 2006-06-28 日立造船株式会社 塩素化芳香族化合物の生成抑制剤および生成抑制方法
US8652235B2 (en) * 2004-08-30 2014-02-18 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
CA2600876C (en) * 2005-03-14 2011-10-11 Praxair Technology, Inc. Adsorbents for mercury removal from flue gas
JP2008537587A (ja) * 2005-03-17 2008-09-18 ノックス・ツー・インターナショナル・リミテッド 石炭の燃焼からの水銀放出の低減
US8906823B2 (en) * 2007-09-24 2014-12-09 Basf Corporation Pollutant emission control sorbents and methods of manufacture and use
PL2454006T3 (pl) * 2009-07-13 2016-04-29 Lhoist Rech Et Developpement Sa Mineralna kompozycja stała, sposób jej wytwarzania i jej zastosowanie do zmniejszania zawartości metali ciężkich w gazach spalinowych

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2035993C1 (ru) * 1993-09-30 1995-05-27 Александр Ефимович Горенбейн Способ получения сорбентов для очистки газов от ртути
DE19824237A1 (de) * 1998-05-29 1999-12-02 Walhalla Kalk Entwicklungs Und Reagentien für die Reinigung von Abgasen
RU2200053C1 (ru) * 2001-11-27 2003-03-10 Рынейский Вадим Анатольевич Установка для очистки дымовых газов
DE10228459A1 (de) * 2002-06-26 2004-01-15 Iko Minerals Gmbh Verfahren zur Herstellung eines silikatischen Adsorbermaterials
RU2352383C2 (ru) * 2004-03-15 2009-04-20 С.А.Луаст Решерш Э Девелопмен Способ улавливания тяжелых металлов из дымовых газов

Also Published As

Publication number Publication date
CN102497921B (zh) 2015-08-19
US20120134903A1 (en) 2012-05-31
UA108615C2 (uk) 2015-05-25
AU2010272573A1 (en) 2012-02-23
EP2454007B1 (fr) 2017-08-02
JP5722888B2 (ja) 2015-05-27
CA2767282A1 (fr) 2011-01-20
BE1019420A5 (fr) 2012-07-03
IL217480A0 (en) 2012-02-29
WO2011006898A1 (fr) 2011-01-20
RU2012104806A (ru) 2013-09-27
NZ598097A (en) 2013-08-30
CN102497921A (zh) 2012-06-13
FR2949979A1 (fr) 2011-03-18
PL2454007T3 (pl) 2018-01-31
KR20120085718A (ko) 2012-08-01
EP2454007A1 (fr) 2012-05-23
SG177490A1 (en) 2012-02-28
MX2012000590A (es) 2012-06-01
JP2012532754A (ja) 2012-12-20

Similar Documents

Publication Publication Date Title
RU2543210C2 (ru) Твердая неорганическая композиция, способ ее получения и ее применение для снижения содержания диоксинов и тяжелых металлов в дымовых газах
US11819821B2 (en) Methods for the treatment of flue gas streams using sorbent compositions with reduced auto-ignition properties
US11045764B2 (en) Methods for the treatment of a flue gas stream using catalytically-enhanced sorbent compositions
US8722571B2 (en) Process to prepare adsorbents from organic fertilizer and their applications for removal of acidic gases from wet air streams
JP5689878B2 (ja) 固体無機組成物、その作製方法および煙道ガス中の重金属を減少させるためのその使用
JP2007529305A (ja) 燃焼排ガス中の重金属を低減するための方法
RU2574541C2 (ru) Твердая минеральная композиция, способ ее получения и ее применение для снижения содержания тяжелых металлов в отходящем газе
KR20120062703A (ko) 연도 가스에서 중금속을 감소시키기 위한 고체 무기 조성물, 이의 제조방법 및 이의 용도
MX2012000589A (es) Composicion mineral solida, procedimiento de fabricacion y uso de la misma para reducir los metales pesados de los gases de combustion.

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20200714