RU2502756C2 - Перерабатываемые наполненные вулканизуемые галоидированные изоолефиновые эластомеры - Google Patents
Перерабатываемые наполненные вулканизуемые галоидированные изоолефиновые эластомеры Download PDFInfo
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- RU2502756C2 RU2502756C2 RU2010128685/05A RU2010128685A RU2502756C2 RU 2502756 C2 RU2502756 C2 RU 2502756C2 RU 2010128685/05 A RU2010128685/05 A RU 2010128685/05A RU 2010128685 A RU2010128685 A RU 2010128685A RU 2502756 C2 RU2502756 C2 RU 2502756C2
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- rubber
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- 238000009472 formulation Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229940083123 ganglion-blocking adreneregic sulfonium derivative Drugs 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 125000002887 hydroxy group Chemical class [H]O* 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- TUFJPPAQOXUHRI-KTKRTIGZSA-N n'-[(z)-octadec-9-enyl]propane-1,3-diamine Chemical compound CCCCCCCC\C=C/CCCCCCCCNCCCN TUFJPPAQOXUHRI-KTKRTIGZSA-N 0.000 description 1
- VFLWKHBYVIUAMP-UHFFFAOYSA-N n-methyl-n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCC VFLWKHBYVIUAMP-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 229910000273 nontronite Inorganic materials 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 125000002081 peroxide group Chemical group 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical class [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000548 poly(silane) polymer Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 150000005376 secondary alkyl halides Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000011064 split stream procedure Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- HOBBGWUQJYXTQU-UHFFFAOYSA-N sulfurodithioic O,O-acid Chemical class OS(O)(=S)=S HOBBGWUQJYXTQU-UHFFFAOYSA-N 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 150000007944 thiolates Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical group [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000012991 xanthate Chemical class 0.000 description 1
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0008—Compositions of the inner liner
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/957,204 US7906600B2 (en) | 2004-12-29 | 2007-12-14 | Processable filled, curable halogenated isoolefin elastomers |
| US11/957,204 | 2007-12-14 | ||
| PCT/US2008/082043 WO2009079102A1 (en) | 2007-12-14 | 2008-10-31 | Processable filled, curable halogenated isoolefin elastomers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2010128685A RU2010128685A (ru) | 2012-01-20 |
| RU2502756C2 true RU2502756C2 (ru) | 2013-12-27 |
Family
ID=40262199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2010128685/05A RU2502756C2 (ru) | 2007-12-14 | 2008-10-31 | Перерабатываемые наполненные вулканизуемые галоидированные изоолефиновые эластомеры |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7906600B2 (OSRAM) |
| EP (1) | EP2225113B1 (OSRAM) |
| JP (1) | JP5590726B2 (OSRAM) |
| CN (1) | CN101678713B (OSRAM) |
| AT (1) | ATE549182T1 (OSRAM) |
| CA (1) | CA2688501C (OSRAM) |
| RU (1) | RU2502756C2 (OSRAM) |
| WO (1) | WO2009079102A1 (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2759546C2 (ru) * | 2017-03-10 | 2021-11-15 | Эксонмобил Кемикэл Пейтентс Инк. | Привитые полимеры, предназначенные для диспергирования графена и графита |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2475713A1 (en) * | 2009-09-10 | 2012-07-18 | ExxonMobil Chemical Patents Inc. | Elastomeric copolymers, copolymer compositions, and their use in articles |
| US9475910B2 (en) * | 2009-10-26 | 2016-10-25 | Exxonmobil Chemical Patents Inc. | Elastomer nanocomposites with incorporated process oils |
| ES2525036T3 (es) * | 2012-04-12 | 2014-12-16 | Lanxess Elastomers B.V. | Composición de caucho curada con resol activado |
| JP2014218041A (ja) * | 2013-05-10 | 2014-11-20 | 住友ゴム工業株式会社 | 空気入りタイヤの加硫成形方法 |
| WO2017077044A1 (de) * | 2015-11-06 | 2017-05-11 | Arlanxeo Deutschland Gmbh | Nanokomposits enthaltend ein schichtsilikat und einen kautschuk |
| WO2019164567A1 (en) * | 2018-02-20 | 2019-08-29 | Exxonmobil Chemical Patents Inc. | Isobutylene-containing compositions and articles made thereof |
| CN111745848B (zh) * | 2020-06-17 | 2021-05-07 | 通力轮胎有限公司 | 一种纯溴化丁基橡胶气密层及其混炼方法与应用 |
| CN111662482B (zh) * | 2020-07-21 | 2022-07-26 | 华奇（中国）化工有限公司 | 一种硫化剂组合物、用于制备混炼胶的组合物、混炼胶及其制备方法、轮胎 |
| CN112852029B (zh) * | 2021-02-05 | 2022-09-06 | 中国科学院青岛生物能源与过程研究所 | 一种低压缩生热轮胎胎面基部胶复合材料及其制备方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004081106A1 (en) * | 2003-03-06 | 2004-09-23 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition having moderate cure state |
| RU2266932C2 (ru) * | 2000-05-11 | 2005-12-27 | Эксонмобил Кемикэл Пейтентс Инк. | Эластомерные смеси на изобутиленовой основе |
| WO2006002033A1 (en) * | 2004-06-15 | 2006-01-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions, air barriers, and processes for making the same |
| RU2004124689A (ru) * | 2003-08-14 | 2006-04-27 | ЛЕНКСЕСС Инк. (CA) | Полимерная композиция, способ ее получения, формованное изделие на ее основе и способ увеличения плотности сшивок галогенированного бутильного каучука |
| WO2006071959A1 (en) * | 2004-12-29 | 2006-07-06 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| RU2299221C2 (ru) * | 2000-10-18 | 2007-05-20 | Эксонмобил Кемикэл Пейтентс Инк. | Эластомерная композиция |
| US20070213444A1 (en) * | 2006-03-10 | 2007-09-13 | Weiqing Weng | Processable branched isoolefin-alkylstyrene elastomers |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5162445A (en) | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US5071913A (en) | 1987-12-11 | 1991-12-10 | Exxon Chemical Patents Inc. | Rubbery isoolefin polymers exhibiting improved processability |
| US6013727A (en) | 1988-05-27 | 2000-01-11 | Exxon Chemical Patents, Inc. | Thermoplastic blend containing engineering resin |
| US5063268A (en) | 1990-06-08 | 1991-11-05 | Exxon Chemical Patents Inc. | Composition for tire treads (E-235) |
| US5333662A (en) | 1990-07-18 | 1994-08-02 | Exxon Chemical Patents Inc. | Tire innerliner composition |
| BR9106745A (pt) | 1990-08-15 | 1993-07-06 | Exxon Chemical Patents Inc | Composicao de parede lateral de pneus e pneu vulcanizado |
| US5227426A (en) | 1990-12-27 | 1993-07-13 | Exxon Chemical Patents Inc. | Adhesives based on elastomeric copolymers having theromplastic polymer grafts |
| US5391625A (en) | 1993-03-19 | 1995-02-21 | Arjunan; Palanisamy | Compatibilized elastomer blends containing copolymers of isoolefins |
| CZ291645B6 (cs) | 1993-04-05 | 2003-04-16 | Exxon Chemical Patents Inc. | Pneumatiková vnitřní vložka a její použití |
| US5576372A (en) | 1993-04-05 | 1996-11-19 | Exxon Chemical Patents Inc. | Composite tire innerliners and inner tubes |
| US5576373A (en) | 1993-04-05 | 1996-11-19 | Exxon Chemical Patents Inc. | Composite tire innerliners and inner tubes |
| US5656694A (en) | 1995-05-03 | 1997-08-12 | Exxon Chemical Patents Inc. | Interpolymer cures of blends comprising halogenated isoolefin/para-alkylstyrene elastomers and unsaturated elastomers |
| US5973053A (en) | 1995-06-05 | 1999-10-26 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Composite clay material and method for producing the same, blend material and composite clay rubber using the same and production method thereof |
| JP3712736B2 (ja) | 1995-06-23 | 2005-11-02 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 乳化合成によって形成されたナノコンポジットポリマー |
| US5681899A (en) | 1995-07-17 | 1997-10-28 | Exxon Chemical Patents Inc. | Impact modifier for polyamides containing an elastomer and a halogenated isoolefin copolymer7 |
| JP3377159B2 (ja) | 1996-09-04 | 2003-02-17 | 株式会社豊田中央研究所 | 粘土複合ゴム材料の製造方法 |
| US6051653A (en) | 1996-09-20 | 2000-04-18 | Exxon Chemical Patents, Inc. | Metal salts of acrylic or methacrylic acid as curatives for compositions containing halogenated isomonoolefin-para-aklylstyrene copolymers |
| US5807629A (en) | 1996-11-15 | 1998-09-15 | Exxon Research And Engineering Company | Tactoidal elastomer nanocomposites |
| US6034164A (en) | 1997-02-21 | 2000-03-07 | Exxon Research And Engineering Co. | Nanocomposite materials formed from inorganic layered materials dispersed in a polymer matrix |
| EP0981581B1 (en) | 1997-05-05 | 2002-12-11 | ExxonMobil Chemical Patents Inc. | Composition for tire sidewalls and other rubber constructions |
| US6060549A (en) | 1997-05-20 | 2000-05-09 | Exxon Chemical Patents, Inc. | Rubber toughened thermoplastic resin nano composites |
| US6293327B1 (en) | 1997-06-20 | 2001-09-25 | Sumitomo Rubber Industries, Ltd. | Pneumatic tire |
| US6069202A (en) | 1997-12-10 | 2000-05-30 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomer triblend from an engineering thermoplastic, functionalized ethylene and or diene polymer, and brominated isobutylene p-methylstyrene copolymer |
| US6624220B1 (en) * | 1997-12-15 | 2003-09-23 | Exxonmobil Chemical Patents Inc. | Transparent and colorable elastomeric compositions |
| WO2001085831A2 (en) | 2000-05-05 | 2001-11-15 | The Dow Chemical Company | Functionalized polymer nanocomposites |
| US6710116B1 (en) | 2000-10-18 | 2004-03-23 | Exxonmobil Chemical Patents Inc. | Abrasion resistant transparent and colorable elastomeric compositions |
| CA2425651A1 (en) | 2000-10-11 | 2002-04-18 | Exxonmobil Chemical Patents Inc. | Thermoplastic compositions for halogenated elastomers |
| US6433090B1 (en) | 2001-01-26 | 2002-08-13 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved set foams made therefrom |
| US6561244B2 (en) | 2001-02-01 | 2003-05-13 | The Goodyear Tire & Rubber Company | Tire having tread with colored groove configuration |
| US7485677B2 (en) | 2001-06-08 | 2009-02-03 | Exxonmobil Chemical Patents Inc. | Low permeability nanocomposites |
| US7491764B2 (en) | 2001-06-13 | 2009-02-17 | Exxonmobil Chemical Patents Inc. | Low permeability nanocomposites |
| FR2836085B1 (fr) | 2002-02-20 | 2004-05-28 | Christophe Henry | Procede d'encollage d'elements de bois |
| US20030205456A1 (en) | 2002-05-01 | 2003-11-06 | Jamalabadi Shahnaz Ghassemi | Processing of chemicals in flow-through device with porous media |
| AU2003301053A1 (en) | 2002-12-18 | 2004-07-22 | Bridgestone Corporation | Method for clay exfoliation, compositions therefore, and modified rubber contaiing same |
| WO2004058835A1 (en) | 2002-12-20 | 2004-07-15 | Exxonmobil Chemical Patents Inc. | Polymers substantially free of long chain branching |
| WO2005017013A1 (en) * | 2003-08-01 | 2005-02-24 | Exxonmobil Chemical Patents, Inc. | Low-permeability elastomeric composition |
| US20050027062A1 (en) * | 2003-08-01 | 2005-02-03 | Waddell Walter Harvey | Elastomeric composition |
| US7514491B2 (en) * | 2005-07-18 | 2009-04-07 | Exxonmobil Chemical Patents Inc. | Functionalized isobutylene polymer-inorganic clay nanocomposites and organic-aqueous emulsion process |
-
2007
- 2007-12-14 US US11/957,204 patent/US7906600B2/en active Active
-
2008
- 2008-10-31 AT AT08862044T patent/ATE549182T1/de active
- 2008-10-31 CA CA2688501A patent/CA2688501C/en not_active Expired - Fee Related
- 2008-10-31 WO PCT/US2008/082043 patent/WO2009079102A1/en not_active Ceased
- 2008-10-31 CN CN2008800177998A patent/CN101678713B/zh active Active
- 2008-10-31 RU RU2010128685/05A patent/RU2502756C2/ru active
- 2008-10-31 EP EP08862044A patent/EP2225113B1/en active Active
- 2008-10-31 JP JP2010515296A patent/JP5590726B2/ja active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2266932C2 (ru) * | 2000-05-11 | 2005-12-27 | Эксонмобил Кемикэл Пейтентс Инк. | Эластомерные смеси на изобутиленовой основе |
| RU2299221C2 (ru) * | 2000-10-18 | 2007-05-20 | Эксонмобил Кемикэл Пейтентс Инк. | Эластомерная композиция |
| WO2004081106A1 (en) * | 2003-03-06 | 2004-09-23 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition having moderate cure state |
| RU2004124689A (ru) * | 2003-08-14 | 2006-04-27 | ЛЕНКСЕСС Инк. (CA) | Полимерная композиция, способ ее получения, формованное изделие на ее основе и способ увеличения плотности сшивок галогенированного бутильного каучука |
| WO2006002033A1 (en) * | 2004-06-15 | 2006-01-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions, air barriers, and processes for making the same |
| WO2006071959A1 (en) * | 2004-12-29 | 2006-07-06 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| EP1833912A1 (en) * | 2004-12-29 | 2007-09-19 | ExxonMobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| US20070213444A1 (en) * | 2006-03-10 | 2007-09-13 | Weiqing Weng | Processable branched isoolefin-alkylstyrene elastomers |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2759546C2 (ru) * | 2017-03-10 | 2021-11-15 | Эксонмобил Кемикэл Пейтентс Инк. | Привитые полимеры, предназначенные для диспергирования графена и графита |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2225113A1 (en) | 2010-09-08 |
| US7906600B2 (en) | 2011-03-15 |
| CN101678713A (zh) | 2010-03-24 |
| WO2009079102A1 (en) | 2009-06-25 |
| CA2688501A1 (en) | 2009-06-25 |
| JP5590726B2 (ja) | 2014-09-17 |
| JP2010531386A (ja) | 2010-09-24 |
| CN101678713B (zh) | 2012-01-25 |
| EP2225113B1 (en) | 2012-03-14 |
| US20080139730A1 (en) | 2008-06-12 |
| ATE549182T1 (de) | 2012-03-15 |
| CA2688501C (en) | 2012-08-07 |
| RU2010128685A (ru) | 2012-01-20 |
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