RU2480863C2 - Металлокерамическая анодная структура (варианты) и ее применение - Google Patents
Металлокерамическая анодная структура (варианты) и ее применение Download PDFInfo
- Publication number
- RU2480863C2 RU2480863C2 RU2008134998/07A RU2008134998A RU2480863C2 RU 2480863 C2 RU2480863 C2 RU 2480863C2 RU 2008134998/07 A RU2008134998/07 A RU 2008134998/07A RU 2008134998 A RU2008134998 A RU 2008134998A RU 2480863 C2 RU2480863 C2 RU 2480863C2
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- Prior art keywords
- phase
- ceramic
- conductive phase
- electrically conductive
- anode structure
- Prior art date
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 99
- 239000002184 metal Substances 0.000 title claims abstract description 99
- 239000000758 substrate Substances 0.000 claims abstract description 80
- 238000005470 impregnation Methods 0.000 claims abstract description 60
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims abstract description 57
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 36
- 239000004094 surface-active agent Substances 0.000 claims abstract description 35
- 239000002243 precursor Substances 0.000 claims abstract description 31
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 27
- 239000000956 alloy Substances 0.000 claims abstract description 27
- 239000000725 suspension Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims abstract description 10
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 10
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 5
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 70
- 239000003792 electrolyte Substances 0.000 claims description 47
- 239000001301 oxygen Substances 0.000 claims description 34
- 229910052760 oxygen Inorganic materials 0.000 claims description 34
- -1 oxygen ion Chemical class 0.000 claims description 27
- 239000000446 fuel Substances 0.000 claims description 24
- 238000010304 firing Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 18
- 239000011195 cermet Substances 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 13
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000002019 doping agent Substances 0.000 claims description 11
- 238000005245 sintering Methods 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052772 Samarium Inorganic materials 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 239000003546 flue gas Substances 0.000 claims description 4
- 239000010955 niobium Substances 0.000 claims description 4
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- IRGHYODJVHIXDW-UHFFFAOYSA-N [Sr].[Ti].[Nb] Chemical compound [Sr].[Ti].[Nb] IRGHYODJVHIXDW-UHFFFAOYSA-N 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 3
- VIIJTIRNANJGHH-UHFFFAOYSA-N strontium vanadium Chemical compound [V].[Sr] VIIJTIRNANJGHH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 3
- 230000006872 improvement Effects 0.000 abstract description 2
- 238000000137 annealing Methods 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 54
- 229910002490 Ce0.9Gd0.1O2–δ Inorganic materials 0.000 description 23
- 239000002245 particle Substances 0.000 description 18
- 239000010935 stainless steel Substances 0.000 description 16
- 229910001220 stainless steel Inorganic materials 0.000 description 16
- 239000002131 composite material Substances 0.000 description 13
- 239000010408 film Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000000919 ceramic Substances 0.000 description 10
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 10
- 230000008595 infiltration Effects 0.000 description 10
- 238000001764 infiltration Methods 0.000 description 10
- 229910000604 Ferrochrome Inorganic materials 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 239000002105 nanoparticle Substances 0.000 description 9
- 229920002415 Pluronic P-123 Polymers 0.000 description 8
- 238000005266 casting Methods 0.000 description 8
- 230000010287 polarization Effects 0.000 description 8
- MWFSXYMZCVAQCC-UHFFFAOYSA-N gadolinium(iii) nitrate Chemical compound [Gd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O MWFSXYMZCVAQCC-UHFFFAOYSA-N 0.000 description 6
- 229910002119 nickel–yttria stabilized zirconia Inorganic materials 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910002651 NO3 Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 210000003371 toe Anatomy 0.000 description 4
- 238000013183 transoesophageal echocardiography Methods 0.000 description 4
- 239000013504 Triton X-100 Substances 0.000 description 3
- 229920004890 Triton X-100 Polymers 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229910002367 SrTiO Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 229920004897 Triton X-45 Polymers 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 2
- 238000001453 impedance spectrum Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 238000004626 scanning electron microscopy Methods 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 description 1
- 229910017563 LaCrO Inorganic materials 0.000 description 1
- MOCSSSMOHPPNTG-UHFFFAOYSA-N [Sc].[Y] Chemical compound [Sc].[Y] MOCSSSMOHPPNTG-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000010344 co-firing Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 1
- 229940075613 gadolinium oxide Drugs 0.000 description 1
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000013335 mesoporous material Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 239000011533 mixed conductor Substances 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- VSSLEOGOUUKTNN-UHFFFAOYSA-N tantalum titanium Chemical compound [Ti].[Ta] VSSLEOGOUUKTNN-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- RVRKDGLTBFWQHH-UHFFFAOYSA-N yttrium zirconium Chemical compound [Y][Zr][Y] RVRKDGLTBFWQHH-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Catalysts (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200701245 | 2007-08-31 | ||
| DKPA200701245 | 2007-08-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008134998A RU2008134998A (ru) | 2010-03-10 |
| RU2480863C2 true RU2480863C2 (ru) | 2013-04-27 |
Family
ID=39816598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008134998/07A RU2480863C2 (ru) | 2007-08-31 | 2008-08-29 | Металлокерамическая анодная структура (варианты) и ее применение |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8500842B2 (enExample) |
| EP (1) | EP2031675B1 (enExample) |
| JP (1) | JP5192944B2 (enExample) |
| KR (1) | KR20090023255A (enExample) |
| CN (1) | CN101383418B (enExample) |
| AT (1) | ATE519241T1 (enExample) |
| AU (1) | AU2008207645B2 (enExample) |
| CA (1) | CA2639175A1 (enExample) |
| DK (1) | DK2031675T3 (enExample) |
| ES (1) | ES2367885T3 (enExample) |
| RU (1) | RU2480863C2 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5398904B2 (ja) * | 2009-03-16 | 2014-01-29 | コリア・インスティテュート・オブ・サイエンス・アンド・テクノロジー | 気孔傾斜構造のナノ気孔性層を含む燃料極支持型固体酸化物燃料電池及びその製造方法 |
| US9240597B2 (en) * | 2010-10-13 | 2016-01-19 | University Of South Carolina | Ni modified ceramic anodes for direct-methane solid oxide fuel cells |
| EP2638587B1 (en) | 2010-11-11 | 2015-03-04 | The Technical University of Denmark | Method for producing a solid oxide cell stack |
| WO2012075486A2 (en) * | 2010-12-03 | 2012-06-07 | Federal-Mogul Corporation | Powder metal component impregnated with ceria and/or yttria and method of manufacture |
| WO2013060669A1 (en) * | 2011-10-24 | 2013-05-02 | Technical University Of Denmark | A modified anode/electrolyte structure for a solid oxide electrochemical cell and a method for making said structure |
| JP2015501515A (ja) * | 2011-10-24 | 2015-01-15 | テクニカル・ユニヴァーシティ・オブ・デンマーク | 固体酸化物電気化学セル用の高性能燃料電極 |
| FI2823079T3 (fi) | 2012-02-23 | 2023-05-04 | Treadstone Tech Inc | Korrosiota kestävä ja sähköä johtava metallin pinta |
| US9631286B2 (en) | 2012-04-13 | 2017-04-25 | Danmarks Tekniske Universitet | High performance reversible electrochemical cell for H2O electrolysis or conversion of CO2 and H2O to fuel |
| RU2510385C1 (ru) * | 2012-10-01 | 2014-03-27 | Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук | Твердооксидный композитный материал для мембран электрохимических устройств |
| TWI482660B (zh) * | 2012-12-11 | 2015-05-01 | Ind Tech Res Inst | 電極及其製備方法 |
| US9525179B2 (en) * | 2013-03-13 | 2016-12-20 | University Of Maryland, College Park | Ceramic anode materials for solid oxide fuel cells |
| CN103280339A (zh) * | 2013-04-12 | 2013-09-04 | 上海大学 | 一种用于超级电容器的氧化铈电极的制备方法 |
| US9181148B2 (en) * | 2013-05-22 | 2015-11-10 | Saudi Arabian Oil Company | Ni/CGO and Ni-Ru/CGO based pre-reforming catalysts formulation for methane rich gas production from diesel processing for fuel cell applications |
| EP2808932A1 (en) | 2013-05-31 | 2014-12-03 | Topsøe Fuel Cell A/S | Metal-supported solid oxide cell |
| GB2517927B (en) * | 2013-09-04 | 2018-05-16 | Ceres Ip Co Ltd | Process for forming a metal supported solid oxide fuel cell |
| CN104710845A (zh) * | 2013-12-13 | 2015-06-17 | 通用电气公司 | 组合物及其相应的装置、方法 |
| GB2524638B (en) * | 2015-02-06 | 2016-04-06 | Ceres Ip Co Ltd | Electrolyte forming process |
| US20180200695A1 (en) * | 2017-01-18 | 2018-07-19 | Saudi Arabian Oil Company | Structured catalysts for pre-reforming hydrocarbons |
| US10953388B1 (en) | 2019-12-27 | 2021-03-23 | Saudi Arabian Oil Company | Ni—Ru—CgO based pre-reforming catalyst for liquid hydrocarbons |
| US12322811B2 (en) * | 2021-07-29 | 2025-06-03 | Nissan North America, Inc. | Metal-supported anode for solid oxide fuel cell |
| CN114583226B (zh) * | 2022-03-31 | 2024-07-12 | 电堆科技(合肥)有限公司 | 一种金属支撑质子导体固体氧化物电池及其制备方法 |
| CN119213587A (zh) * | 2022-04-06 | 2024-12-27 | 联邦科学技术研究组织 | 电极组合物 |
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| RU2125324C1 (ru) * | 1996-11-11 | 1999-01-20 | Горина Лилия Федоровна | Способ изготовления единичного высокотемпературного топливного элемента и его компонентов: катода, электролита, анода, токопрохода, интерфейсного и электроизолирующего слоев |
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- 2008-08-21 EP EP08014830A patent/EP2031675B1/en not_active Not-in-force
- 2008-08-21 DK DK08014830.7T patent/DK2031675T3/da active
- 2008-08-21 ES ES08014830T patent/ES2367885T3/es active Active
- 2008-08-27 US US12/199,571 patent/US8500842B2/en not_active Expired - Fee Related
- 2008-08-28 JP JP2008219434A patent/JP5192944B2/ja not_active Expired - Fee Related
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- 2008-08-29 RU RU2008134998/07A patent/RU2480863C2/ru not_active IP Right Cessation
- 2008-08-29 KR KR1020080084905A patent/KR20090023255A/ko not_active Ceased
- 2008-08-29 CN CN200810130977.XA patent/CN101383418B/zh not_active Expired - Fee Related
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| US5312582A (en) * | 1993-02-04 | 1994-05-17 | Institute Of Gas Technology | Porous structures from solid solutions of reduced oxides |
| RU2125324C1 (ru) * | 1996-11-11 | 1999-01-20 | Горина Лилия Федоровна | Способ изготовления единичного высокотемпературного топливного элемента и его компонентов: катода, электролита, анода, токопрохода, интерфейсного и электроизолирующего слоев |
| US6682842B1 (en) * | 1999-07-31 | 2004-01-27 | The Regents Of The University Of California | Composite electrode/electrolyte structure |
| RU2236722C1 (ru) * | 2003-06-10 | 2004-09-20 | Мятиев Ата Атаевич | Электрод-электролитная пара на основе двуокиси церия (варианты), способ ее изготовления (варианты) и органогель |
Also Published As
| Publication number | Publication date |
|---|---|
| DK2031675T3 (da) | 2011-11-14 |
| HK1130118A1 (en) | 2009-12-18 |
| ES2367885T3 (es) | 2011-11-10 |
| AU2008207645A1 (en) | 2009-03-19 |
| JP5192944B2 (ja) | 2013-05-08 |
| CA2639175A1 (en) | 2009-02-28 |
| CN101383418A (zh) | 2009-03-11 |
| JP2009110934A (ja) | 2009-05-21 |
| KR20090023255A (ko) | 2009-03-04 |
| AU2008207645B2 (en) | 2012-04-19 |
| US8500842B2 (en) | 2013-08-06 |
| US20090061272A1 (en) | 2009-03-05 |
| ATE519241T1 (de) | 2011-08-15 |
| RU2008134998A (ru) | 2010-03-10 |
| CN101383418B (zh) | 2014-06-25 |
| EP2031675B1 (en) | 2011-08-03 |
| EP2031675A1 (en) | 2009-03-04 |
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