CA2639175A1 - Ceria and stainless steel based electrodes - Google Patents
Ceria and stainless steel based electrodes Download PDFInfo
- Publication number
- CA2639175A1 CA2639175A1 CA002639175A CA2639175A CA2639175A1 CA 2639175 A1 CA2639175 A1 CA 2639175A1 CA 002639175 A CA002639175 A CA 002639175A CA 2639175 A CA2639175 A CA 2639175A CA 2639175 A1 CA2639175 A1 CA 2639175A1
- Authority
- CA
- Canada
- Prior art keywords
- anode
- phase
- conductive phase
- ceria
- electronically conductive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 title claims abstract description 61
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 239000010935 stainless steel Substances 0.000 title description 19
- 229910001220 stainless steel Inorganic materials 0.000 title description 19
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 35
- 239000004094 surface-active agent Substances 0.000 claims abstract description 32
- 239000002243 precursor Substances 0.000 claims abstract description 28
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 27
- 239000000956 alloy Substances 0.000 claims abstract description 27
- 238000001354 calcination Methods 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 20
- 239000002002 slurry Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000011195 cermet Substances 0.000 claims abstract description 14
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 13
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 5
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 5
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 68
- 238000005470 impregnation Methods 0.000 claims description 55
- 239000003792 electrolyte Substances 0.000 claims description 46
- 239000001301 oxygen Substances 0.000 claims description 30
- 229910052760 oxygen Inorganic materials 0.000 claims description 30
- -1 oxygen ion Chemical class 0.000 claims description 25
- 239000000446 fuel Substances 0.000 claims description 24
- 239000007787 solid Substances 0.000 claims description 17
- 239000002019 doping agent Substances 0.000 claims description 11
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 9
- 238000005245 sintering Methods 0.000 claims description 9
- 238000005868 electrolysis reaction Methods 0.000 claims description 7
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052772 Samarium Inorganic materials 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000003093 cationic surfactant Substances 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 239000003546 flue gas Substances 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000000243 solution Substances 0.000 description 51
- 239000002245 particle Substances 0.000 description 28
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 20
- 238000012360 testing method Methods 0.000 description 16
- 239000002131 composite material Substances 0.000 description 14
- 239000002105 nanoparticle Substances 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000000919 ceramic Substances 0.000 description 10
- 230000008595 infiltration Effects 0.000 description 10
- 238000001764 infiltration Methods 0.000 description 10
- 229910000604 Ferrochrome Inorganic materials 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 8
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 229920002415 Pluronic P-123 Polymers 0.000 description 7
- MWFSXYMZCVAQCC-UHFFFAOYSA-N gadolinium(iii) nitrate Chemical compound [Gd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O MWFSXYMZCVAQCC-UHFFFAOYSA-N 0.000 description 7
- 229910002119 nickel–yttria stabilized zirconia Inorganic materials 0.000 description 7
- 230000010287 polarization Effects 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 238000010345 tape casting Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 5
- 238000001878 scanning electron micrograph Methods 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229940059947 gadolinium Drugs 0.000 description 4
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 3
- 229910002451 CoOx Inorganic materials 0.000 description 2
- 239000013504 Triton X-100 Substances 0.000 description 2
- 229920004890 Triton X-100 Polymers 0.000 description 2
- 229920004897 Triton X-45 Polymers 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000012693 ceria precursor Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 2
- 238000001453 impedance spectrum Methods 0.000 description 2
- OYIKARCXOQLFHF-UHFFFAOYSA-N isoxaflutole Chemical compound CS(=O)(=O)C1=CC(C(F)(F)F)=CC=C1C(=O)C1=C(C2CC2)ON=C1 OYIKARCXOQLFHF-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 229960003903 oxygen Drugs 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910002370 SrTiO3 Inorganic materials 0.000 description 1
- MOCSSSMOHPPNTG-UHFFFAOYSA-N [Sc].[Y] Chemical compound [Sc].[Y] MOCSSSMOHPPNTG-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000010344 co-firing Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 239000011530 conductive current collector Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 1
- 229940075613 gadolinium oxide Drugs 0.000 description 1
- 229910021526 gadolinium-doped ceria Inorganic materials 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000013101 initial test Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000013335 mesoporous material Substances 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 239000011533 mixed conductor Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Catalysts (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200701245 | 2007-08-31 | ||
| DKPA200701245 | 2007-08-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2639175A1 true CA2639175A1 (en) | 2009-02-28 |
Family
ID=39816598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002639175A Abandoned CA2639175A1 (en) | 2007-08-31 | 2008-08-28 | Ceria and stainless steel based electrodes |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8500842B2 (enExample) |
| EP (1) | EP2031675B1 (enExample) |
| JP (1) | JP5192944B2 (enExample) |
| KR (1) | KR20090023255A (enExample) |
| CN (1) | CN101383418B (enExample) |
| AT (1) | ATE519241T1 (enExample) |
| AU (1) | AU2008207645B2 (enExample) |
| CA (1) | CA2639175A1 (enExample) |
| DK (1) | DK2031675T3 (enExample) |
| ES (1) | ES2367885T3 (enExample) |
| RU (1) | RU2480863C2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114583226A (zh) * | 2022-03-31 | 2022-06-03 | 中国科学技术大学先进技术研究院 | 一种金属支撑质子导体固体氧化物电池及其制备方法 |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5398904B2 (ja) * | 2009-03-16 | 2014-01-29 | コリア・インスティテュート・オブ・サイエンス・アンド・テクノロジー | 気孔傾斜構造のナノ気孔性層を含む燃料極支持型固体酸化物燃料電池及びその製造方法 |
| US9240597B2 (en) * | 2010-10-13 | 2016-01-19 | University Of South Carolina | Ni modified ceramic anodes for direct-methane solid oxide fuel cells |
| EP2638587B1 (en) | 2010-11-11 | 2015-03-04 | The Technical University of Denmark | Method for producing a solid oxide cell stack |
| WO2012075486A2 (en) * | 2010-12-03 | 2012-06-07 | Federal-Mogul Corporation | Powder metal component impregnated with ceria and/or yttria and method of manufacture |
| WO2013060669A1 (en) * | 2011-10-24 | 2013-05-02 | Technical University Of Denmark | A modified anode/electrolyte structure for a solid oxide electrochemical cell and a method for making said structure |
| JP2015501515A (ja) * | 2011-10-24 | 2015-01-15 | テクニカル・ユニヴァーシティ・オブ・デンマーク | 固体酸化物電気化学セル用の高性能燃料電極 |
| FI2823079T3 (fi) | 2012-02-23 | 2023-05-04 | Treadstone Tech Inc | Korrosiota kestävä ja sähköä johtava metallin pinta |
| US9631286B2 (en) | 2012-04-13 | 2017-04-25 | Danmarks Tekniske Universitet | High performance reversible electrochemical cell for H2O electrolysis or conversion of CO2 and H2O to fuel |
| RU2510385C1 (ru) * | 2012-10-01 | 2014-03-27 | Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук | Твердооксидный композитный материал для мембран электрохимических устройств |
| TWI482660B (zh) * | 2012-12-11 | 2015-05-01 | Ind Tech Res Inst | 電極及其製備方法 |
| US9525179B2 (en) * | 2013-03-13 | 2016-12-20 | University Of Maryland, College Park | Ceramic anode materials for solid oxide fuel cells |
| CN103280339A (zh) * | 2013-04-12 | 2013-09-04 | 上海大学 | 一种用于超级电容器的氧化铈电极的制备方法 |
| US9181148B2 (en) * | 2013-05-22 | 2015-11-10 | Saudi Arabian Oil Company | Ni/CGO and Ni-Ru/CGO based pre-reforming catalysts formulation for methane rich gas production from diesel processing for fuel cell applications |
| EP2808932A1 (en) | 2013-05-31 | 2014-12-03 | Topsøe Fuel Cell A/S | Metal-supported solid oxide cell |
| GB2517927B (en) * | 2013-09-04 | 2018-05-16 | Ceres Ip Co Ltd | Process for forming a metal supported solid oxide fuel cell |
| CN104710845A (zh) * | 2013-12-13 | 2015-06-17 | 通用电气公司 | 组合物及其相应的装置、方法 |
| GB2524638B (en) * | 2015-02-06 | 2016-04-06 | Ceres Ip Co Ltd | Electrolyte forming process |
| US20180200695A1 (en) * | 2017-01-18 | 2018-07-19 | Saudi Arabian Oil Company | Structured catalysts for pre-reforming hydrocarbons |
| US10953388B1 (en) | 2019-12-27 | 2021-03-23 | Saudi Arabian Oil Company | Ni—Ru—CgO based pre-reforming catalyst for liquid hydrocarbons |
| US12322811B2 (en) * | 2021-07-29 | 2025-06-03 | Nissan North America, Inc. | Metal-supported anode for solid oxide fuel cell |
| CN119213587A (zh) * | 2022-04-06 | 2024-12-27 | 联邦科学技术研究组织 | 电极组合物 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3377265A (en) * | 1964-11-16 | 1968-04-09 | Mobil Oil Corp | Electrochemical electrode |
| JPH01186561A (ja) * | 1988-01-14 | 1989-07-26 | Hitachi Ltd | 燃料電池 |
| JPH01189866A (ja) * | 1988-01-25 | 1989-07-31 | Hitachi Ltd | 溶融塩型燃料電池用アノードとその製造方法 |
| DK167163B1 (da) | 1991-02-13 | 1993-09-06 | Risoe Forskningscenter | Fastoxidbraendselscelle til oxidation af ch4 |
| US5312582A (en) * | 1993-02-04 | 1994-05-17 | Institute Of Gas Technology | Porous structures from solid solutions of reduced oxides |
| RU2125324C1 (ru) * | 1996-11-11 | 1999-01-20 | Горина Лилия Федоровна | Способ изготовления единичного высокотемпературного топливного элемента и его компонентов: катода, электролита, анода, токопрохода, интерфейсного и электроизолирующего слоев |
| US6682842B1 (en) * | 1999-07-31 | 2004-01-27 | The Regents Of The University Of California | Composite electrode/electrolyte structure |
| US6752979B1 (en) | 2000-11-21 | 2004-06-22 | Very Small Particle Company Pty Ltd | Production of metal oxide particles with nano-sized grains |
| EP1530814A4 (en) * | 2002-06-06 | 2009-05-27 | Univ Pennsylvania | CERAMIC ANODES AND PROCESS FOR PRODUCING THESE ANODES |
| WO2004062006A1 (en) * | 2002-12-16 | 2004-07-22 | The Trustees Of The University Of Pennsylvania | High performance ceramic anodes and method of producing the same |
| RU2236722C1 (ru) * | 2003-06-10 | 2004-09-20 | Мятиев Ата Атаевич | Электрод-электролитная пара на основе двуокиси церия (варианты), способ ее изготовления (варианты) и органогель |
| US20090220829A1 (en) * | 2003-12-24 | 2009-09-03 | Anna Berta Lopes Correia Tavares | Solid Oxide Fuel Cell |
| US20050221163A1 (en) * | 2004-04-06 | 2005-10-06 | Quanmin Yang | Nickel foam and felt-based anode for solid oxide fuel cells |
| RU2356132C2 (ru) * | 2004-06-10 | 2009-05-20 | Текникал Юниверсити Оф Денмарк | Твердооксидный топливный элемент |
| KR100924700B1 (ko) * | 2005-01-12 | 2009-11-03 | 테크니칼 유니버시티 오브 덴마크 | 소결 중 수축률 및 공극률이 조절된 다층 구조물의 제조방법, 상기 제조방법에 따라 제조된 다층 구조물 및 상기 다층 구조물을 포함하는 고체 산화물 연료전지 |
| DE602006013786D1 (de) * | 2005-02-02 | 2010-06-02 | Univ Denmark Tech Dtu | Verfahren zur herstellung einer reversiblen festoxidbrennstoffzelle |
| RU2403655C9 (ru) | 2005-04-21 | 2011-04-20 | Члены Правления Университета Калифорнии | Инфильтрация исходного материала и способ покрытия |
| DK1760817T3 (da) * | 2005-08-31 | 2013-10-14 | Univ Denmark Tech Dtu | Reversibel fastoxidbrændselscellestak og fremgangsmåde til fremstilling af samme |
-
2008
- 2008-08-21 AT AT08014830T patent/ATE519241T1/de not_active IP Right Cessation
- 2008-08-21 EP EP08014830A patent/EP2031675B1/en not_active Not-in-force
- 2008-08-21 DK DK08014830.7T patent/DK2031675T3/da active
- 2008-08-21 ES ES08014830T patent/ES2367885T3/es active Active
- 2008-08-27 US US12/199,571 patent/US8500842B2/en not_active Expired - Fee Related
- 2008-08-28 JP JP2008219434A patent/JP5192944B2/ja not_active Expired - Fee Related
- 2008-08-28 CA CA002639175A patent/CA2639175A1/en not_active Abandoned
- 2008-08-29 AU AU2008207645A patent/AU2008207645B2/en not_active Ceased
- 2008-08-29 RU RU2008134998/07A patent/RU2480863C2/ru not_active IP Right Cessation
- 2008-08-29 KR KR1020080084905A patent/KR20090023255A/ko not_active Ceased
- 2008-08-29 CN CN200810130977.XA patent/CN101383418B/zh not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114583226A (zh) * | 2022-03-31 | 2022-06-03 | 中国科学技术大学先进技术研究院 | 一种金属支撑质子导体固体氧化物电池及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DK2031675T3 (da) | 2011-11-14 |
| HK1130118A1 (en) | 2009-12-18 |
| ES2367885T3 (es) | 2011-11-10 |
| AU2008207645A1 (en) | 2009-03-19 |
| JP5192944B2 (ja) | 2013-05-08 |
| CN101383418A (zh) | 2009-03-11 |
| JP2009110934A (ja) | 2009-05-21 |
| KR20090023255A (ko) | 2009-03-04 |
| AU2008207645B2 (en) | 2012-04-19 |
| US8500842B2 (en) | 2013-08-06 |
| US20090061272A1 (en) | 2009-03-05 |
| RU2480863C2 (ru) | 2013-04-27 |
| ATE519241T1 (de) | 2011-08-15 |
| RU2008134998A (ru) | 2010-03-10 |
| CN101383418B (zh) | 2014-06-25 |
| EP2031675B1 (en) | 2011-08-03 |
| EP2031675A1 (en) | 2009-03-04 |
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| EEER | Examination request |
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| FZDE | Discontinued |
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