RU2432371C2 - Барьерные пленки с карбонатом кальция и их применение - Google Patents
Барьерные пленки с карбонатом кальция и их применение Download PDFInfo
- Publication number
- RU2432371C2 RU2432371C2 RU2008131063A RU2008131063A RU2432371C2 RU 2432371 C2 RU2432371 C2 RU 2432371C2 RU 2008131063 A RU2008131063 A RU 2008131063A RU 2008131063 A RU2008131063 A RU 2008131063A RU 2432371 C2 RU2432371 C2 RU 2432371C2
- Authority
- RU
- Russia
- Prior art keywords
- caco
- film
- carrier resin
- calcium carbonate
- polyolefin
- Prior art date
Links
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title claims abstract description 144
- 229910000019 calcium carbonate Inorganic materials 0.000 title claims abstract description 70
- 230000004888 barrier function Effects 0.000 title claims description 17
- 229920005989 resin Polymers 0.000 claims abstract description 93
- 239000011347 resin Substances 0.000 claims abstract description 93
- 229920000098 polyolefin Polymers 0.000 claims abstract description 42
- 230000035515 penetration Effects 0.000 claims abstract description 18
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 15
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims abstract description 14
- DERLTVRRWCJVCP-UHFFFAOYSA-N ethene;ethyl acetate Chemical compound C=C.CCOC(C)=O DERLTVRRWCJVCP-UHFFFAOYSA-N 0.000 claims abstract description 8
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 6
- 229930195729 fatty acid Natural products 0.000 claims abstract description 6
- 239000000194 fatty acid Substances 0.000 claims abstract description 6
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 4
- 229920001903 high density polyethylene Polymers 0.000 claims description 45
- 239000004700 high-density polyethylene Substances 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 37
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000000155 melt Substances 0.000 claims description 21
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 18
- 239000012756 surface treatment agent Substances 0.000 claims description 16
- 235000013305 food Nutrition 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000000227 grinding Methods 0.000 claims description 13
- 235000021355 Stearic acid Nutrition 0.000 claims description 12
- 238000012545 processing Methods 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 11
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 11
- 239000008117 stearic acid Substances 0.000 claims description 11
- 229920006280 packaging film Polymers 0.000 claims description 9
- 239000012785 packaging film Substances 0.000 claims description 9
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 8
- 241000306287 Sweet potato pakakuy virus Species 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 6
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 6
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 235000021314 Palmitic acid Nutrition 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 238000004381 surface treatment Methods 0.000 claims description 5
- 241001465754 Metazoa Species 0.000 claims description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 235000013339 cereals Nutrition 0.000 claims description 2
- AOHAPDDBNAPPIN-UHFFFAOYSA-N 3-Methoxy-4,5-methylenedioxybenzoic acid Chemical compound COC1=CC(C(O)=O)=CC2=C1OCO2 AOHAPDDBNAPPIN-UHFFFAOYSA-N 0.000 claims 4
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 claims 4
- 239000004705 High-molecular-weight polyethylene Substances 0.000 claims 1
- 238000009512 pharmaceutical packaging Methods 0.000 claims 1
- 239000011295 pitch Substances 0.000 claims 1
- 235000010216 calcium carbonate Nutrition 0.000 abstract description 57
- 230000000694 effects Effects 0.000 abstract description 5
- 239000005022 packaging material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 107
- 239000010410 layer Substances 0.000 description 44
- 230000006872 improvement Effects 0.000 description 15
- 238000001125 extrusion Methods 0.000 description 12
- 238000004806 packaging method and process Methods 0.000 description 11
- 239000004698 Polyethylene Substances 0.000 description 9
- 239000012792 core layer Substances 0.000 description 9
- 229920000573 polyethylene Polymers 0.000 description 9
- -1 polyethylene Polymers 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 239000002609 medium Substances 0.000 description 5
- 238000007664 blowing Methods 0.000 description 4
- 229920006262 high density polyethylene film Polymers 0.000 description 4
- 239000004579 marble Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000007655 standard test method Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 238000001238 wet grinding Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229920006178 high molecular weight high density polyethylene Polymers 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000825 pharmaceutical preparation Substances 0.000 description 2
- 229940127557 pharmaceutical product Drugs 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- TVZRAEYQIKYCPH-UHFFFAOYSA-N 3-(trimethylsilyl)propane-1-sulfonic acid Chemical compound C[Si](C)(C)CCCS(O)(=O)=O TVZRAEYQIKYCPH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011104 metalized film Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002943 palmitic acids Chemical class 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
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- B32—LAYERED PRODUCTS
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- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
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- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Wrappers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| US75565905P | 2005-12-29 | 2005-12-29 | |
| US60/755,659 | 2005-12-29 |
Publications (2)
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| RU2008131063A RU2008131063A (ru) | 2010-02-10 |
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| JP (1) | JP5420252B2 (enExample) |
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| CN (2) | CN103012912B (enExample) |
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| NZ (1) | NZ569414A (enExample) |
| RU (1) | RU2432371C2 (enExample) |
| WO (1) | WO2007078454A2 (enExample) |
| ZA (1) | ZA200805414B (enExample) |
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| US20090045210A1 (en) | 2007-08-18 | 2009-02-19 | Tilton Christopher R | Pliable ground calcium carbonates storage articles and method of making same |
| KR100948190B1 (ko) * | 2008-11-05 | 2010-03-17 | 조남수 | 저수조 라이닝용 복합 폴리에틸렌 판재 및 이를 이용한 저수조 라이닝 방법 |
| JP5097191B2 (ja) * | 2009-11-20 | 2012-12-12 | 鷹觜建設株式会社 | 樹脂用無機充填剤及び複合樹脂組成物の製造方法 |
| HUE029337T2 (en) * | 2010-04-12 | 2017-02-28 | Omya Int Ag | Composition for blow molding |
| EP2585519A1 (en) * | 2010-06-23 | 2013-05-01 | Dow Global Technologies LLC | Masterbatch composition |
| US8507581B2 (en) | 2010-09-21 | 2013-08-13 | Green Folks & Macleod, Llc | Stone based copolymer substrate |
| US8987363B2 (en) | 2011-04-12 | 2015-03-24 | J.M. Huber Corporation | Narrow particle size distribution calcium carbonate and methods of making same |
| JP5461614B2 (ja) | 2011-05-31 | 2014-04-02 | 株式会社Ｔｂｍ | 無機物質粉末高配合薄膜シートの製造方法 |
| CN102532702B (zh) * | 2011-12-19 | 2014-03-12 | 西华大学 | 杏鲍菇生产专用培养基调节袋及其制备方法 |
| EP2628775A1 (en) | 2012-02-17 | 2013-08-21 | Omya Development AG | Mineral material powder with high dispersion ability and use of said mineral material powder |
| HUE031169T2 (en) | 2012-10-16 | 2017-06-28 | Omya Int Ag | Process for controlled chemical reaction of a solid filler surface and additives to produce a surface-treated filler product |
| US8937139B2 (en) * | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| CN105263708B (zh) | 2013-03-14 | 2019-05-07 | 智能星球技术公司 | 可再制浆和可回收的复合包装制品及相关方法 |
| WO2014153073A1 (en) | 2013-03-14 | 2014-09-25 | Smart Planet Technologies, Inc. | Composite structures for packaging articles and related methods |
| CN103435883A (zh) * | 2013-07-18 | 2013-12-11 | 华南师范大学 | 一种碳酸钙高填充高性能可降解聚乙烯薄膜的制备方法 |
| EP2843005A1 (en) | 2013-08-26 | 2015-03-04 | Omya International AG | Earth alkali carbonate, surface modified by at least one polyhydrogensiloxane |
| JP6129089B2 (ja) * | 2014-01-27 | 2017-05-17 | 川上産業株式会社 | 緩衝封筒 |
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| EP2975078A1 (en) * | 2014-08-14 | 2016-01-20 | Omya International AG | Surface-treated fillers for breathable films |
| CN104443916A (zh) * | 2014-09-12 | 2015-03-25 | 马蕾 | 一次性垃圾收集袋及其制造方法 |
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| CN114835968B (zh) * | 2022-04-11 | 2025-03-21 | 张家港禾福新材料科技有限公司 | 一种无机母粒及其制造方法及应用该母粒的聚乙烯薄膜 |
| ES2993746B2 (es) * | 2023-06-28 | 2025-10-29 | Dow Global Technologies Llc | Peliculas multicapa con fluencia, rasgado y dardo mejorados |
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- 2006-11-20 NZ NZ569414A patent/NZ569414A/en not_active IP Right Cessation
- 2006-11-20 CN CN201210365596.6A patent/CN103012912B/zh not_active Expired - Fee Related
- 2006-11-20 US US12/086,651 patent/US9321249B2/en not_active Expired - Fee Related
- 2006-11-20 BR BRPI0620849-5A patent/BRPI0620849A2/pt not_active IP Right Cessation
- 2006-11-20 ES ES06838255T patent/ES2734900T3/es active Active
- 2006-11-20 RU RU2008131063A patent/RU2432371C2/ru not_active IP Right Cessation
- 2006-11-20 AU AU2006333448A patent/AU2006333448B2/en not_active Ceased
- 2006-11-20 CA CA2635513A patent/CA2635513C/en not_active Expired - Fee Related
- 2006-11-20 JP JP2008548516A patent/JP5420252B2/ja not_active Expired - Fee Related
- 2006-11-20 EP EP06838255.5A patent/EP1969186B1/en not_active Not-in-force
- 2006-11-20 KR KR1020127006336A patent/KR101244327B1/ko not_active Expired - Fee Related
- 2006-11-20 KR KR1020087015842A patent/KR101170703B1/ko not_active Expired - Fee Related
- 2006-11-20 WO PCT/US2006/045179 patent/WO2007078454A2/en not_active Ceased
- 2006-11-20 CN CN2006800497450A patent/CN101351597B/zh not_active Expired - Fee Related
-
2008
- 2008-06-05 IL IL191963A patent/IL191963A/en not_active IP Right Cessation
- 2008-06-20 NO NO20082799A patent/NO20082799L/no not_active Application Discontinuation
- 2008-06-20 ZA ZA200805414A patent/ZA200805414B/xx unknown
-
2016
- 2016-03-22 US US15/076,865 patent/US11117357B2/en not_active Expired - Fee Related
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| US5236963A (en) * | 1991-08-23 | 1993-08-17 | Amoco Corporation | Oriented polymeric microporous films |
| RU2173265C2 (ru) * | 1996-03-07 | 2001-09-10 | Шеврон Кемикал Компани Эл Эл Си | Многослойная полимерная пленка, упаковка на ее основе и упаковочное изделие |
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Also Published As
| Publication number | Publication date |
|---|---|
| ZA200805414B (en) | 2009-04-29 |
| CN103012912A (zh) | 2013-04-03 |
| WO2007078454A3 (en) | 2008-03-20 |
| BRPI0620849A2 (pt) | 2011-11-22 |
| CN103012912B (zh) | 2015-03-18 |
| US11117357B2 (en) | 2021-09-14 |
| KR20080081301A (ko) | 2008-09-09 |
| CA2635513C (en) | 2015-06-02 |
| US20090324979A1 (en) | 2009-12-31 |
| US20160200885A1 (en) | 2016-07-14 |
| ES2734900T3 (es) | 2019-12-12 |
| AU2006333448B2 (en) | 2011-08-11 |
| EP1969186B1 (en) | 2019-04-24 |
| KR20120048011A (ko) | 2012-05-14 |
| EP1969186A4 (en) | 2012-05-30 |
| EP1969186A2 (en) | 2008-09-17 |
| AU2006333448A1 (en) | 2007-07-12 |
| CA2635513A1 (en) | 2007-07-12 |
| US9321249B2 (en) | 2016-04-26 |
| IL191963A0 (en) | 2008-12-29 |
| JP5420252B2 (ja) | 2014-02-19 |
| JP2009522400A (ja) | 2009-06-11 |
| KR101244327B1 (ko) | 2013-03-19 |
| WO2007078454A2 (en) | 2007-07-12 |
| KR101170703B1 (ko) | 2012-08-07 |
| NZ569414A (en) | 2012-02-24 |
| NO20082799L (no) | 2008-09-04 |
| RU2008131063A (ru) | 2010-02-10 |
| CN101351597B (zh) | 2013-07-17 |
| IL191963A (en) | 2015-05-31 |
| CN101351597A (zh) | 2009-01-21 |
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