RU2217488C2 - Детергентные составы - Google Patents

Детергентные составы Download PDF

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RU2217488C2
RU2217488C2 RU2000127756/04A RU2000127756A RU2217488C2 RU 2217488 C2 RU2217488 C2 RU 2217488C2 RU 2000127756/04 A RU2000127756/04 A RU 2000127756/04A RU 2000127756 A RU2000127756 A RU 2000127756A RU 2217488 C2 RU2217488 C2 RU 2217488C2
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polymer
composition according
surfactant
detergent
polymer mixture
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RU2000127756/04A
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RU2000127756A (ru
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Майкл Пол АРОНСОН
Чарльз Руперт Телфорд БРАУН
Роберт Джеймс ЧЭТФИЛД
Питер ФЭРЛИ
Иан Тимоти Нортон
Джейсон Ричард УИЛЬЯМС
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Унилевер Н.В.
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/228—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with phosphorus- or sulfur-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Epidemiology (AREA)
  • Molecular Biology (AREA)
  • Birds (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Изобретение относится к пенящимся детергентным составам, которые могут применяться в индивидуальных моющих средствах, изготавливаемых в виде вязких жидкостей, кремов или гелей. Указанный состав, представляющий собой загущенную подвижную жидкость с измененной вязкостью при сдвиге, включает а) пенящийся детергент, включающий поверхностно-активное вещество, выбранное из анионного, амфотерного и цвитерионного поверхностно-активных веществ; б) 5 - 90 вес.% полиольного материала, выбранного из глицерина, сорбита, гександиола, пропан-1,2-диола, 1,3-бутиленгликоля, пропиленгликоля, гексиленгликоля, а также полиэтиленгликолей и полипропиленгликолей, имеющих молекулярную массу в интервале 100-4000, и в) 0,1 - 10% полимера или полимерной смеси, способной образовывать обратимый гель, причем полимер или полимерная смесь присутствуют в составе в виде множества отдельных гелевых частиц, имеющих размер менее 200 мкм и включающих полисахаридную цепь природного происхождения. Также описан способ получения детергентного состава. Технический результат: полученные гели со сдвигом вязкости способны лучше сохранять форму при выдавливании. 2 с. и 12 з.п.ф-лы, 4 ил.

Description

Таблицын

Claims (14)

1. Водный детергентный состав, представляющий собой загущенную подвижную жидкость с измененной вязкостью при сдвиге, который включает а) пенящийся детергент, включающий поверхностно-активное вещество, выбранное из анионного, амфотерного и цвитерионного поверхностно-активных веществ, причем состав содержит, по меньшей мере, 3 вес.% анионного поверхностно-активного вещества; б) от 5 до 90 вес.% полиольного материала, выбранного из глицерина, сорбита, гександиола, пропан-1,2-диола, 1,3-бутиленгликоля, пропиленгликоля, гексиленгликоля, а также полиэтиленгликолей и полипропиленгликолей, имеющих молекулярную массу в интервале 100-4000; в) от 0,1 до 10 вес.% полимера или полимерной смеси, способной образовывать обратимый гель, причем полимер или полимерная смесь присутствуют в составе в виде множества отдельных гелевых частиц, имеющих размер менее чем 200 мкм и указанный полимер или полимерная смесь включает полисахаридную цепь природного происхождения.
2. Состав по п.1, включающий от 5 до 50 вес.% полиольного материала от веса детергентного состава.
3. Состав по п.1 или 2, включающий 5-25 вес.% анионного поверхностно-активного вещества.
4. Состав по любому из пп.1-3, включающий анионное поверхностно-активное вещество с меньшим количеством цвитерионного поверхностно-активного вещества.
5. Состав по любому из пп.1-4, в котором пенящееся поверхностно-активное вещество включает неионное поверхностно-активное вещество, выбранное из алкилгликозидов, O-алканоилгликозидов, блочных сополимеров полиэтиленоксида и полипропиленоксида, алкилполигидроксиамидов, алкилальдобионамидов и их смесей.
6. Состав по любому из предшествующих пунктов, в котором полимер или полимерная смесь включает каппа-каррагенан.
7. Состав по любому из предшествующих пунктов, в котором полимер или полимерная смесь включает агар.
8. Состав по любому из предшествующих пунктов, включающий от 0,1 до 10 вес.% полимера или полимерной смеси.
9. Состав по любому из предшествующих пунктов, включающий суспендированные частицы жидкого или твердого вещества, иного, чем полимерный гель.
10. Состав по п.9, в котором суспендированную фазу выбирают из силиконовых масел или смол, триглицеридных масел или восков, минерального масла, вазелина, полиэтилена или их смесей.
11. Состав по п.9, в котором суспендированными частицами является солнцезащитный агент.
12. Способ получения детергентного состава по любому из пп.1-11, который включает образование горячего подвижного водного раствора полимера или полимерной смеси, охлаждение раствора до температуры гелеобразования с одновременным осуществлением сдвига раствора и введение пенообразующего поверхностно-активного вещества до или после охлаждения.
13. Способ по п.12, в котором поверхностно-активное вещество добавляют к раствору после охлаждения до 35°С или ниже.
14. Способ по п.13, в котором полимер или полимерная смесь включает каппа-каррагенан, а поверхностно-активное вещество присутствует в водном растворе во время охлаждения, во время которого также проводят сдвиг раствора.
RU2000127756/04A 1998-04-03 1999-03-22 Детергентные составы RU2217488C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9807269.7A GB9807269D0 (en) 1998-04-03 1998-04-03 Detergent compositions
GB9807269.7 1998-04-03

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RU2000127756A RU2000127756A (ru) 2002-11-10
RU2217488C2 true RU2217488C2 (ru) 2003-11-27

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US (1) US6329331B1 (ru)
EP (1) EP1066366B1 (ru)
JP (1) JP4625580B2 (ru)
KR (1) KR100614161B1 (ru)
CN (1) CN1230513C (ru)
AR (1) AR014796A1 (ru)
AU (1) AU749720B2 (ru)
BR (1) BR9909395B1 (ru)
CA (1) CA2324956C (ru)
CZ (1) CZ302724B6 (ru)
DE (1) DE69926872T2 (ru)
ES (1) ES2247796T3 (ru)
GB (1) GB9807269D0 (ru)
HK (1) HK1038583A1 (ru)
HU (1) HUP0102359A3 (ru)
ID (1) ID26415A (ru)
MX (1) MXPA00009601A (ru)
MY (1) MY120177A (ru)
PL (1) PL191306B1 (ru)
RU (1) RU2217488C2 (ru)
WO (1) WO1999051716A1 (ru)

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