RU2076066C1 - Осажденная кремниевая кислота, способ ее получения и вулканизуемая резиновая смесь - Google Patents
Осажденная кремниевая кислота, способ ее получения и вулканизуемая резиновая смесь Download PDFInfo
- Publication number
- RU2076066C1 RU2076066C1 RU94035656/26A RU94035656A RU2076066C1 RU 2076066 C1 RU2076066 C1 RU 2076066C1 RU 94035656/26 A RU94035656/26 A RU 94035656/26A RU 94035656 A RU94035656 A RU 94035656A RU 2076066 C1 RU2076066 C1 RU 2076066C1
- Authority
- RU
- Russia
- Prior art keywords
- silicic acid
- precipitated silicic
- ratio
- surface area
- rubber
- Prior art date
Links
- 235000012239 silicon dioxide Nutrition 0.000 title claims abstract description 93
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229920001971 elastomer Polymers 0.000 title claims abstract description 44
- 239000005060 rubber Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims description 22
- 238000002360 preparation method Methods 0.000 title description 6
- 230000008569 process Effects 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 239000000945 filler Substances 0.000 claims abstract description 15
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 11
- 238000002459 porosimetry Methods 0.000 claims abstract description 9
- 239000011148 porous material Substances 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 239000000725 suspension Substances 0.000 claims abstract description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000007513 acids Chemical class 0.000 claims abstract description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 3
- 239000011707 mineral Substances 0.000 claims abstract description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 9
- 239000013049 sediment Substances 0.000 claims description 3
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 230000003993 interaction Effects 0.000 claims 2
- 239000012071 phase Substances 0.000 claims 1
- 239000007790 solid phase Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 12
- 239000007787 solid Substances 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 239000002244 precipitate Substances 0.000 abstract description 2
- 125000005372 silanol group Chemical group 0.000 abstract description 2
- 239000012321 sodium triacetoxyborohydride Substances 0.000 abstract 3
- 125000005624 silicic acid group Chemical class 0.000 description 32
- 239000006185 dispersion Substances 0.000 description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 10
- 230000008021 deposition Effects 0.000 description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 229910000077 silane Inorganic materials 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
- 235000019353 potassium silicate Nutrition 0.000 description 6
- 244000043261 Hevea brasiliensis Species 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920003052 natural elastomer Polymers 0.000 description 5
- 229920001194 natural rubber Polymers 0.000 description 5
- 150000001282 organosilanes Chemical class 0.000 description 5
- 238000000227 grinding Methods 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000002296 dynamic light scattering Methods 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- -1 hydrocarbon radical Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 1
- KZTCAXCBXSIQSS-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-4-n-phenylbenzene-1,4-diamine Chemical compound C=1C=C(N)C=CC=1N(C(C)CC(C)C)C1=CC=CC=C1 KZTCAXCBXSIQSS-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000012491 analyte Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- REQPQFUJGGOFQL-UHFFFAOYSA-N dimethylcarbamothioyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SC(=S)N(C)C REQPQFUJGGOFQL-UHFFFAOYSA-N 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920006113 non-polar polymer Polymers 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920003246 polypentenamer Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- AUMBZPPBWALQRO-UHFFFAOYSA-L zinc;n,n-dibenzylcarbamodithioate Chemical compound [Zn+2].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 AUMBZPPBWALQRO-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
- C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/19—Oil-absorption capacity, e.g. DBP values
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicon Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4334201 | 1993-10-07 | ||
| DEP4334201.9 | 1993-10-07 | ||
| DEP4427137.9 | 1994-07-30 | ||
| DE4427137A DE4427137B4 (de) | 1993-10-07 | 1994-07-30 | Fällungskieselsäure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2076066C1 true RU2076066C1 (ru) | 1997-03-27 |
| RU94035656A RU94035656A (ru) | 1997-04-20 |
Family
ID=25930239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU94035656/26A RU2076066C1 (ru) | 1993-10-07 | 1994-10-06 | Осажденная кремниевая кислота, способ ее получения и вулканизуемая резиновая смесь |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0647591B1 (Direct) |
| JP (1) | JP2556670B2 (Direct) |
| KR (1) | KR0140827B1 (Direct) |
| CN (1) | CN1036990C (Direct) |
| BR (1) | BR9404019A (Direct) |
| DE (2) | DE4427137B4 (Direct) |
| ES (1) | ES2081223T3 (Direct) |
| FI (1) | FI107143B (Direct) |
| RU (1) | RU2076066C1 (Direct) |
| TR (1) | TR28814A (Direct) |
| TW (1) | TW288031B (Direct) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2445259C2 (ru) * | 2006-05-26 | 2012-03-20 | Эвоник Дегусса Гмбх | Осажденная кремниевая кислота, способ ее получения |
| RU2502754C2 (ru) * | 2011-07-20 | 2013-12-27 | Общество с ограниченной ответственностью "Научно-технический центр "Кама" | Резиновая смесь |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6977065B1 (en) | 1993-10-07 | 2005-12-20 | Degussa Ag | Precipitated silicas |
| DE19617039A1 (de) * | 1995-06-01 | 1996-12-05 | Degussa | Fällungskieselsäuren, Verfahren zu ihrer Herstellung und Verwendung von vulkanisierbaren Kautschukmischungen |
| IN188702B (Direct) * | 1995-06-01 | 2002-10-26 | Degussa | |
| DE19526476A1 (de) * | 1995-07-20 | 1997-01-23 | Degussa | Fällungskieselsäure |
| DE19527278A1 (de) * | 1995-07-26 | 1997-01-30 | Degussa | Fällungskieselsäure |
| DE19642448A1 (de) * | 1996-03-27 | 1997-10-02 | Degussa | Fällungskieselsäure |
| WO1997045366A1 (en) * | 1996-05-31 | 1997-12-04 | Ppg Industries, Inc. | Amorphous precipitated silica |
| EP0902758B1 (en) * | 1996-05-31 | 2001-06-06 | PPG Industries Ohio, Inc. | Amorphous precipitated silica |
| US5891949A (en) * | 1997-05-02 | 1999-04-06 | J.M. Huber Corporation | Natural rubber compound |
| US5929156A (en) * | 1997-05-02 | 1999-07-27 | J.M. Huber Corporation | Silica product for use in elastomers |
| DE19740440A1 (de) * | 1997-09-15 | 1999-03-18 | Degussa | Leicht dispergierbare Fällungskieselsäure |
| IL122851A0 (en) * | 1998-01-05 | 1998-08-16 | Rotem Amfert Negev Ltd | Optimally dispersible precipitated silica particulates process for their preparation and their use |
| JPH11236208A (ja) * | 1998-02-25 | 1999-08-31 | Nippon Silica Ind Co Ltd | ゴム補強用含水ケイ酸 |
| US6121346A (en) * | 1998-03-02 | 2000-09-19 | The Goodyear Tire & Rubber Company | Rubber compositions containing fillers having aggregates containing different particle sizes |
| DE19840153A1 (de) | 1998-09-03 | 2000-04-20 | Degussa | Fällungskieselsäure |
| JP2000319513A (ja) * | 1999-05-12 | 2000-11-21 | Nippon Silica Ind Co Ltd | シリコーンゴム補強充填剤 |
| US6624233B2 (en) | 1999-05-31 | 2003-09-23 | Pirelli Pneumatici S.P.A. | Low rolling resistance tire for vehicles |
| BR0011098A (pt) * | 1999-05-31 | 2002-03-26 | Pirelli | Pneu com baixa resistência ao rolamento para veìculos, banda de rodagem com baixa resistência ao rolamento para pneus de veìculo, e, método para redução da resistência ao rolamento de um pneu |
| HUP0204138A3 (en) * | 1999-07-28 | 2004-08-30 | Grace Gmbh & Co Kg | Preciptated silica, a process to make it, and its use |
| DE10112652A1 (de) | 2001-03-16 | 2002-09-19 | Degussa | Inhomogene Kieselsäuren für Elastomerenmischungen |
| DE10146325A1 (de) * | 2001-09-20 | 2003-04-10 | Degussa | Fällungskieselsäure mit hohem BET/CTAB-Verhältnis |
| KR100560223B1 (ko) * | 2002-06-05 | 2006-03-10 | 삼성코닝 주식회사 | 고정도 연마용 금속 산화물 분말 및 이의 제조방법 |
| DE10330221A1 (de) * | 2002-08-03 | 2004-02-12 | Degussa Ag | Hochdispersible Fällungskieselsäure |
| BR0313213B1 (pt) * | 2002-08-03 | 2012-09-04 | ácido silìcico de precipitação, seu processo de preparação, misturas elastoméricas, misturas de caucho vulcanizáveis e/ou vulcanizados, e pneus. | |
| AU2003255291A1 (en) * | 2002-08-03 | 2004-02-25 | Degussa Ag | High-surface precipitation silicic acids |
| DE10330118A1 (de) * | 2002-08-03 | 2004-02-12 | Degussa Ag | Fällungskieselsäure mit hoher Oberfläche |
| BRPI0406904A (pt) | 2003-01-22 | 2005-12-13 | Degussa | ácidos silìcicos especialmente precipitados para aplicações em borrachas |
| US7625971B2 (en) * | 2003-08-19 | 2009-12-01 | Tokuyama Corporation | Silica-loaded granular rubber and process for producing the same |
| DE102004005411A1 (de) * | 2004-02-03 | 2005-08-18 | Degussa Ag | Hydrophobe Fällungskieselsäure für Entschäumerformulierungen |
| MY144631A (en) | 2004-05-24 | 2011-10-14 | Nycomed Pharma As | Particulate comprising a calcium-containing compound and a sugar alcohol |
| MXPA06013840A (es) | 2004-06-01 | 2007-04-16 | Nycomed Pharma As | Tableta masticable, chupable y tragable que contiene un compuesto que contiene calcio, como una sustancia activa. |
| SE529160C2 (sv) * | 2004-12-27 | 2007-05-15 | Svenska Aerogel Ab | En metod för framställning av agglomerat av utfällt silikamaterial, ett mikroporöst material innefattande sådana agglomerat och användning därav |
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- 1994-07-30 DE DE4427137A patent/DE4427137B4/de not_active Expired - Lifetime
- 1994-09-13 TW TW083108447A patent/TW288031B/zh active
- 1994-09-27 DE DE59400068T patent/DE59400068D1/de not_active Revoked
- 1994-09-27 EP EP94115165A patent/EP0647591B1/de not_active Revoked
- 1994-09-27 ES ES94115165T patent/ES2081223T3/es not_active Expired - Lifetime
- 1994-10-05 TR TR01023/94A patent/TR28814A/xx unknown
- 1994-10-05 CN CN94117058A patent/CN1036990C/zh not_active Expired - Fee Related
- 1994-10-06 RU RU94035656/26A patent/RU2076066C1/ru not_active IP Right Cessation
- 1994-10-06 KR KR1019940025507A patent/KR0140827B1/ko not_active Expired - Fee Related
- 1994-10-06 FI FI944679A patent/FI107143B/fi active
- 1994-10-07 BR BR9404019A patent/BR9404019A/pt not_active IP Right Cessation
- 1994-10-07 JP JP6243783A patent/JP2556670B2/ja not_active Expired - Fee Related
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2445259C2 (ru) * | 2006-05-26 | 2012-03-20 | Эвоник Дегусса Гмбх | Осажденная кремниевая кислота, способ ее получения |
| RU2502754C2 (ru) * | 2011-07-20 | 2013-12-27 | Общество с ограниченной ответственностью "Научно-технический центр "Кама" | Резиновая смесь |
Also Published As
| Publication number | Publication date |
|---|---|
| FI107143B (fi) | 2001-06-15 |
| KR0140827B1 (ko) | 1998-06-01 |
| FI944679L (fi) | 1995-04-08 |
| TR28814A (tr) | 1997-04-03 |
| DE59400068D1 (de) | 1996-02-01 |
| DE4427137A1 (de) | 1995-04-13 |
| DE4427137B4 (de) | 2007-08-23 |
| RU94035656A (ru) | 1997-04-20 |
| BR9404019A (pt) | 1995-06-27 |
| CN1109445A (zh) | 1995-10-04 |
| JPH07172815A (ja) | 1995-07-11 |
| EP0647591A1 (de) | 1995-04-12 |
| TW288031B (Direct) | 1996-10-11 |
| KR950011329A (ko) | 1995-05-15 |
| ES2081223T3 (es) | 1996-02-16 |
| EP0647591B1 (de) | 1995-12-20 |
| JP2556670B2 (ja) | 1996-11-20 |
| FI944679A0 (fi) | 1994-10-06 |
| CN1036990C (zh) | 1998-01-14 |
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| Date | Code | Title | Description |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20031007 |