RU2017118488A - Композитная панель с ячеистой термореактивной матрицей, способ изготовления и структура для покрытия стенки, образованная соединением панелей - Google Patents

Композитная панель с ячеистой термореактивной матрицей, способ изготовления и структура для покрытия стенки, образованная соединением панелей Download PDF

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RU2017118488A
RU2017118488A RU2017118488A RU2017118488A RU2017118488A RU 2017118488 A RU2017118488 A RU 2017118488A RU 2017118488 A RU2017118488 A RU 2017118488A RU 2017118488 A RU2017118488 A RU 2017118488A RU 2017118488 A RU2017118488 A RU 2017118488A
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panel
elements
superimposed
paragraphs
basalt fibers
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RU2017118488A
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RU2689880C2 (ru
RU2017118488A3 (ru
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Фабьен ЛЕРУА
Жером МОЖЕ
Жерар БУ
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Хатчинсон
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    • B32B2605/12Ships
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/18Aircraft
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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Claims (29)

1. Композитная панель (10) с ячеистой термореактивной матрицей (9), содержащая по меньшей мере одну подложку (1), которая содержит нетканые короткие базальтовые волокна (2а,3а,4а,5а) и пропитана указанной матрицей, отличающаяся тем, что указанная по меньшей мере одна подложка содержит несколько нетканых элементов (2,3,4,5), наложенных друг на друга по толщине (е) наложения, при этом каждый из указанных нетканых элементов содержит указанные короткие базальтовые волокна и выполнен иглопробивным в указанной толщине без добавления термопластических волокон.
2. Панель (10) по п. 1, отличающаяся тем, что указанные наложенные друг на друга нетканые элементы (2,3,4,5) включают в себя по меньшей мере три и предпочтительно четыре указанных нетканых элемента.
3. Панель (10) по п. 1 или 2, отличающаяся тем, что указанные наложенные друг на друга нетканые элементы (2,3,4,5) выполнены иглопробивными с добавлением непрерывных базальтовых волокон (8).
4. Панель (10) по п. 3, отличающаяся тем, что указанные непрерывные базальтовые волокна (8) образуют параллельные нити основы, пропущенные в указанные наложенные друг на друга нетканые элементы (2,3,4,5), при этом указанные нити основы попарно разделены расстоянием, предпочтительном составляющим от 10 см до 40 см.
5. Панель (10) по п. 4, отличающаяся тем, что указанные непрерывные базальтовые волокна (8) имеют линейную массовую плотность, составляющую от 100 текс до 300 текс, и предпочтительно соответствуют определению “BCF”.
6. Панель (10) по любому из пп. 3-5, отличающаяся тем, что каждый из указанных нетканых элементов (2,3,4,5) образован указанными короткими базальтовыми волокнами (2а,3а,4а,5а) и указанными непрерывными базальтовыми волокнами (8).
7. Панель (10) по любому из пп. 1-6, отличающаяся тем, что каждый из указанных нетканых элементов (2,3,4,5) имеет поверхностную плотность от 480 г/м2 до 2000 г/м2.
8. Панель (10) по п. 1 или 2, отличающаяся тем, что указанные наложенные друг на друга нетканые элементы (2,3,4,5) имеют, каждый, поверхностную плотность более 1000г/м2 и выполнены иглопробивными без добавления каких-либо волокон.
9. Панель (10) по п. 8, отличающаяся тем, что указанные наложенные друг на друга нетканые элементы (2,3,4,5) состоят, каждый, из указанных коротких базальтовых волокон (2а,3а,4а,5а).
10. Панель (10) по любому из пп. 1-9, отличающаяся тем, что указанные короткие базальтовые волокна (2а,3а,4а,5а) имеют средний диаметр, составляющий от 13 мкм до 16 мкм, и среднюю длину, составляющую от 30 мм до 60 мм.
11. Панель (10) по любому из пп. 1-10, отличающаяся тем, что указанная по меньшей мере одна подложка (1), пропитанная указанной термореактивной матрицей (9), содержит указанные наложенные друг на друга нетканые элементы (2,3,4,5) в массовом количестве, составляющем от 15 до 25%, и указанную матрицу в массовом количестве, составляющем от 75 до 85%.
12. Панель (10) по любому из пп. 1-11, отличающаяся тем, что указанная термореактивная матрица (9) содержит:
от 50 до 65 мас.% смолы на водной основе, выбранной из группы, в которую входят меламиноформальдегидные смолы, фенольные смолы и столярные клеи, и предпочтительно меламиноформальдегидную смолу;
от 3 до 15 мас.% пенообразователя для получения открытых ячеек, который предпочтительно содержит изобутан или изопентан;
от 0,5 до 2 мас.% катализатора, предпочтительно содержащего амин гидрохлорид;
от 30 до 45 мас.% водного растворителя, такого как вода.
13. Панель (10) по любому из пп. 1-12, отличающаяся тем, что указанные наложенные друг на друга нетканые элементы (2,3,4,5), пропитанные указанной термореактивной матрицей (9), имеют плотность от 60 кг/м3 до 1200 кг/м3 и толщину от 5 мм до 30 мм.
14. Панель (10) по любому из пп. 1-13, отличающаяся тем, что дополнительно содержит:
по меньшей мере один лист алюминиевой фольги, находящийся снаружи указанных наложенных друг на друга нетканых элементов указанной по меньшей мере одной подложки (1), и/или
наружный слой, образующий защитное покрытие панели, который выбирают из группы, в которую входят каучуки, термопластические полимеры, эпоксидные краски и полиуретаны.
15. Панель (10) по любому из пп. 1-14, отличающаяся тем, что имеет теплопроводность, меньшую или равную 50 мВтм-1⋅К-1 и/или герметичность по отношению к криогенным текучим средам, и/или огнестойкость.
16. Структура (20) для покрытия стенки, предназначенная для придания указанной стенке свойств теплоизоляции в отношении криогенных текучих сред и/или огнестойкости и/или герметичности по отношению к этим текучим средам, при этом структура выполнена, в частности, с возможностью покрытия платформы, палубы или корпуса плавучей установки для производства сжиженного газа в открытом море,
отличающаяся тем, что содержит соединение панелей (10) по любому из пп. 1-15, предназначенное для крепления на указанной стенке, при этом панели соединены между собой при помощи средств (13) герметичного соединения, предпочтительно содержащих композитные шнуры на основе коротких базальтовых волокон (2а,3а,4а,5а), пропитанных ячеистой термореактивной матрицей (9), идентичной или отличной от матрицы панелей.
17. Способ изготовления панели (10) по любому из пп. 1-15, отличающийся тем, что включает в себя следующие последовательные этапы:
а) иглопробивание указанных наложенных друг на друга нетканых элементов (2,3,4,5) указанной по меньшей мере одной подложки (1) в указанной толщине (е) наложения без добавления термопластических волокон, предпочтительно с добавлением непрерывных базальтовых волокон (8),
b) пропитка указанных иглопробивных наложенных друг на друга нетканых элементов указанной термореактивной матрицей (9),
c) каландрирование указанных пропитанных нетканых элементов,
d) сушка указанных пропитанных и каландрированных нетканых элементов, затем
e) прессование указанных пропитанных, каландрированных и высушенных нетканых элементов между нагревательными плитами с контролируемым промежутком.
RU2017118488A 2014-11-14 2015-11-06 Композитная панель с ячеистой термореактивной матрицей, способ изготовления и структура для покрытия стенки, образованная соединением панелей RU2689880C2 (ru)

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FR1461005 2014-11-14
FR1461005A FR3028447B1 (fr) 2014-11-14 2014-11-14 Panneau composite a matrice thermodurcissable cellulaire, procede de fabrication et structure de revetement de paroi formee d'un assemblage de panneaux.
PCT/IB2015/058584 WO2016075602A1 (fr) 2014-11-14 2015-11-06 Panneau composite a matrice thermodurcissable cellulaire, procede de fabrication et structure de revetement de paroi formee d'un assemblage de panneaux.

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EP3218538A1 (fr) 2017-09-20
JP6669746B2 (ja) 2020-03-18
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WO2016075602A1 (fr) 2016-05-19
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