RU2017124990A - Высокоэффективные теплоизоляционные продукты - Google Patents

Высокоэффективные теплоизоляционные продукты Download PDF

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Publication number
RU2017124990A
RU2017124990A RU2017124990A RU2017124990A RU2017124990A RU 2017124990 A RU2017124990 A RU 2017124990A RU 2017124990 A RU2017124990 A RU 2017124990A RU 2017124990 A RU2017124990 A RU 2017124990A RU 2017124990 A RU2017124990 A RU 2017124990A
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Russia
Prior art keywords
insulating
adhesive
layers
product according
paragraphs
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RU2017124990A
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English (en)
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RU2017124990A3 (ru
RU2704188C2 (ru
Inventor
Валери Голетто
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Сэн-Гобэн Изовер
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Publication of RU2017124990A3 publication Critical patent/RU2017124990A3/ru
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
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    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Physics & Mathematics (AREA)
  • Structural Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Acoustics & Sound (AREA)
  • Electromagnetism (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Building Environments (AREA)
  • Nonwoven Fabrics (AREA)
  • Thermal Insulation (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (9)

1. Изоляционный продукт, состоящий из по меньшей мере двух изоляционных слов, содержащих аэрогели, причем каждый из указанных слоев содержит от 25 до 95 вес.% аэрогеля и от 5 до 75 вес.% волокон, причем указанные изоляционные слои скреплены органическим клеем, предпочтительно водным, на основе одного или нескольких виниловых полимеров
2. Изоляционный продукт по п. 1, отличающийся тем, что он имеет высшую теплоту сгорания PCS ниже 3 МДж/кг и прочность на растяжение более 1 кПа.
3. Изоляционный продукт по одному из пп. 1 или 2, отличающийся тем, что клей содержит в качестве клеящего агента(ов) один или несколько виниловых полимеров, выбранных, в частности, из гомополимеров или сополимеров поливинилацетата, причем эти полимеры обеспечивают склеивание и первоначально были диспергированы в водной среде в клее, причем сухой экстракт клея обычно составляет от 40 до 60 вес.%, склеивание предпочтительно осуществляют путем испарения водной среды, причем доля виниловых полимеров, от доли адгезионных агентов, присутствующих в клее, составляет по меньшей мере 50%, в частности, по меньшей мере 75%, предпочтительно по меньшей мере 90%, и предпочтительно 100 вес.%.
4. Изоляционный продукт по одному из пп. 1-3, отличающийся тем, что органический клей имеет PCS ниже 24 МДж/кг, и/или тем, что вклад указанного клея в PCS продукта меньше разности между максимальным значением PCS указанного изоляционного продукта и значением PCS всей системы, образованной из изоляционных слоев, не снабженным клеем, в частности, меньше 0,7 МДж/кг.
5. Изоляционный продукт по одному из пп. 1-4, отличающийся тем, что изоляционные слои являются волокнистыми слоями, содержащими аэрогели, причем каждый из указанных волокнистых слоев предпочтительно имеет плотность от 8 до 90 кг/м3, в частности, порядка 10-60 кг/м3, их толщина составляет, в частности, от 6 до 20 мм, в частности, от 8 до 15 мм, причем указанные волокнистые слои предпочтительно представляют собой маты на основе стеклянных волокон E или C, необязательно содержащие, в количестве менее 20% от веса волокон, органические волокна типа полиэтилентерефталата, указанные волокнистые слои предпочтительно были пропитаны химическими реагентами, служащими для получения аэрогеля, чтобы получить указанные изоляционные слои, содержащие аэрогели.
6. Изоляционный продукт по одному из пп. 1-5, отличающийся тем, что каждый изоляционный слой имеет PCS меньше или равную примерно 2,3 МДж/кг.
7. Изоляционный продукт по одному из пп. 1-6, отличающийся тем, что он содержит по меньшей мере два, предпочтительно по меньшей мере три, в частности, четыре или по меньшей мере четыре изоляционных слоя, причем содержание органических клеящих веществ между двумя изоляционными слоями меньше или равно 120 г/м2, предпочтительно меньше или равно 80 г/м2.
8. Изоляционный продукт по одному из пп. 1-7, отличающийся тем, что клеящая композиция включает по меньшей мере один пластификатор.
9. Способ получения изоляционного продукта, включающий по меньшей мере одну стадию склеивания по меньшей мере двух изоляционных слоев, содержащих аэрогели, причем каждый из указанных слоев содержит от 25 до 95 вес.% аэрогелей и от 5 до 75 вес.% волокон, причем указанное склеивание осуществляют с помощью органического клея, предпочтительно водного, на основе одного или нескольких виниловых полимеров.
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