RU2016105829A - Способ формирования твердооксидных топливных элементов с металлической опорой - Google Patents
Способ формирования твердооксидных топливных элементов с металлической опорой Download PDFInfo
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- RU2016105829A RU2016105829A RU2016105829A RU2016105829A RU2016105829A RU 2016105829 A RU2016105829 A RU 2016105829A RU 2016105829 A RU2016105829 A RU 2016105829A RU 2016105829 A RU2016105829 A RU 2016105829A RU 2016105829 A RU2016105829 A RU 2016105829A
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- Prior art keywords
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- firing
- reducing
- nickel
- sintering
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- 238000000034 method Methods 0.000 title claims 18
- 239000000446 fuel Substances 0.000 title claims 6
- 229910052751 metal Inorganic materials 0.000 title claims 6
- 239000002184 metal Substances 0.000 title claims 6
- 238000010304 firing Methods 0.000 claims 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 5
- 229910000480 nickel oxide Inorganic materials 0.000 claims 5
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims 5
- 239000001301 oxygen Substances 0.000 claims 5
- 229910052760 oxygen Inorganic materials 0.000 claims 5
- 238000005245 sintering Methods 0.000 claims 4
- 229910000420 cerium oxide Inorganic materials 0.000 claims 3
- 239000003153 chemical reaction reagent Substances 0.000 claims 3
- 239000002131 composite material Substances 0.000 claims 3
- 239000003792 electrolyte Substances 0.000 claims 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical group O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 239000011195 cermet Substances 0.000 claims 1
- 238000005056 compaction Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000011261 inert gas Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/12—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8828—Coating with slurry or ink
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8896—Pressing, rolling, calendering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1097—Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
Claims (24)
1. Способ формирования твердооксидного топливного элемента с металлической опорой, включающий:
a) нанесение на металлическую опорную пластину слоя зеленого анода, содержащего оксид никеля и оксид церия, легированный редкоземельным элементом;
b) предварительный обжиг слоя анода в условиях невосстановительной среды для формирования композитного материала;
c) обжиг композитного материала в восстановительной среде для формирования спеченного металлокерамического материала;
d) обеспечение электролита и
e) обеспечение катода,
причем восстановительная среда содержит источник кислорода.
2. Способ по п. 1, в котором восстановительная среда на стадии с) обжига содержит инертный газ, газообразный восстанавливающий реагент и газообразный источник кислорода.
3. Способ по п. 2, в котором восстанавливающий реагент выбирают из водорода, монооксида углерода и их сочетаний.
4. Способ по п. 2, в котором газообразный источник кислорода выбирают из диоксида углерода, водяного пара и их сочетаний.
5. Способ по п. 2, в котором восстановительная среда на стадии с) обжига содержит источник кислорода в количестве от 0,01 до 50 об.% и/или восстанавливающий реагент в количестве от 0,5 до 50 об.%.
6. Способ по любому из п.п. 1-5, в котором парциальное давление кислорода в восстановительной среде на стадии с) обжига находится от 10-14 до 10-22 бар.
7. Способ по любому из п.п. 1-5, в котором на стадии с) обжига оксид никеля перед спеканием восстанавливают до металлического никеля.
8. Способ по любому из п.п. 1-5, в котором на стадии с) обжига оксид никеля перед восстановлением до металлического никеля по меньшей мере частично спекают.
9. Способ по любому из п.п. 1-5, в котором предварительный обжиг слоя зеленого анода и/или обжиг композитного материала происходит при температуре от 950°С до 1100°С.
10. Способ по любому из п.п. 1-5, включающий жесткое крепление металлической опорной пластины в процессе выполнения по меньшей мере одной из стадий нагрева, выбранной из: предварительного обжига анода, обжига анода, спекания анода, спекания электролита, спекания катода или их сочетаний.
11. Способ по любому из п.п. 1-5, в котором оксид никеля и оксид церия, легированный редкоземельным элементом, измельчают в порошок с распределением d90 размеров частиц от 0,1 мкм до 4 мкм.
12. Способ по любому из п.п. 1-5, в котором оксид никеля и оксид церия, легированный редкоземельным элементом, наносят как печатную краску.
13. Способ по п. 12, в котором нанесение слоя зеленого анода включает начальное нанесение печатной краски на металлическую опорную пластину и высушивание печатной краски для обеспечения напечатанного слоя толщиной от 5 до 40 мкм.
14. Способ по любому из п.п. 1-5 и 13, включающий также стадию уплотнения слоя зеленого анода под давлением от 100 до 300 МПа.
15. Способ по любому из п.п. 1-5 и 13, включающий также стадию повторного окисления спеченного никеля перед обеспечением электролита.
16. Твердооксидный топливный элемент с металлической опорой, полученный с использованием способа по любому предыдущему пункту.
17. Батарея топливных элементов, содержащая два или более топливных элементов по п. 16.
18. Применение топливного элемента по п. 16 для генерирования электрической энергии.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1315744.1 | 2013-09-04 | ||
| GB1315744.1A GB2517927B (en) | 2013-09-04 | 2013-09-04 | Process for forming a metal supported solid oxide fuel cell |
| PCT/GB2014/052546 WO2015033103A1 (en) | 2013-09-04 | 2014-08-20 | Process for forming a metal supported solid oxide fuel cell |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2016105829A true RU2016105829A (ru) | 2017-10-09 |
| RU2670423C2 RU2670423C2 (ru) | 2018-10-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2016105829A RU2670423C2 (ru) | 2013-09-04 | 2014-08-20 | Способ формирования твердооксидных топливных элементов с металлической опорой |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US10003080B2 (ru) |
| EP (1) | EP3042412B1 (ru) |
| JP (2) | JP2016533016A (ru) |
| KR (1) | KR102232286B1 (ru) |
| CN (1) | CN105518921B (ru) |
| CA (1) | CA2922876C (ru) |
| GB (1) | GB2517927B (ru) |
| HK (1) | HK1204150A1 (ru) |
| MX (1) | MX2016002175A (ru) |
| RU (1) | RU2670423C2 (ru) |
| SG (1) | SG11201601148SA (ru) |
| WO (1) | WO2015033103A1 (ru) |
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| TWI558568B (zh) * | 2015-11-03 | 2016-11-21 | 行政院原子能委員會核能研究所 | 透氣金屬基板、金屬支撐固態氧化物燃料電池及其製作方法 |
| GB2550317B (en) * | 2016-03-09 | 2021-12-15 | Ceres Ip Co Ltd | Fuel cell |
| KR20180126525A (ko) | 2016-03-18 | 2018-11-27 | 오사까 가스 가부시키가이샤 | 전기 화학 소자, 전기 화학 모듈, 전기 화학 장치 및 에너지 시스템 |
| KR102109231B1 (ko) * | 2016-09-30 | 2020-05-11 | 주식회사 엘지화학 | 고체 산화물 연료전지의 운전 방법 |
| TWI620376B (zh) * | 2016-10-21 | 2018-04-01 | 行政院原子能委員會核能硏究所 | 可攜式火焰發電裝置、金屬支撐型固態氧化物燃料電池及製作方法 |
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| US20210013535A1 (en) * | 2018-04-13 | 2021-01-14 | Nissan Motor Co., Ltd. | Metal-supported cell and method for manufacturing metal-supported cell |
| JP7245036B2 (ja) * | 2018-11-28 | 2023-03-23 | 太陽誘電株式会社 | 燃料電池スタックおよびその製造方法 |
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- 2014-08-20 JP JP2016539626A patent/JP2016533016A/ja not_active Withdrawn
- 2014-08-20 CN CN201480048585.2A patent/CN105518921B/zh active Active
- 2014-08-20 SG SG11201601148SA patent/SG11201601148SA/en unknown
- 2014-08-20 WO PCT/GB2014/052546 patent/WO2015033103A1/en active Application Filing
- 2014-08-20 MX MX2016002175A patent/MX2016002175A/es unknown
- 2014-08-20 RU RU2016105829A patent/RU2670423C2/ru active
- 2014-08-20 CA CA2922876A patent/CA2922876C/en active Active
- 2014-08-20 EP EP14756114.6A patent/EP3042412B1/en active Active
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| HK1204150A1 (en) | 2015-11-06 |
| KR102232286B1 (ko) | 2021-03-26 |
| US20150064596A1 (en) | 2015-03-05 |
| EP3042412A1 (en) | 2016-07-13 |
| GB201315744D0 (en) | 2013-10-16 |
| JP2019204788A (ja) | 2019-11-28 |
| KR20160048810A (ko) | 2016-05-04 |
| JP6794505B2 (ja) | 2020-12-02 |
| MX2016002175A (es) | 2016-07-05 |
| US10003080B2 (en) | 2018-06-19 |
| GB2517927B (en) | 2018-05-16 |
| WO2015033103A1 (en) | 2015-03-12 |
| CN105518921A (zh) | 2016-04-20 |
| EP3042412B1 (en) | 2020-11-25 |
| RU2670423C2 (ru) | 2018-10-23 |
| SG11201601148SA (en) | 2016-03-30 |
| CA2922876C (en) | 2022-07-12 |
| CN105518921B (zh) | 2019-06-25 |
| CA2922876A1 (en) | 2015-03-12 |
| GB2517927A (en) | 2015-03-11 |
| JP2016533016A (ja) | 2016-10-20 |
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