RU2015103987A - Отвердитель для краски на основе полуиретана и способ ее нанесения - Google Patents

Отвердитель для краски на основе полуиретана и способ ее нанесения Download PDF

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RU2015103987A
RU2015103987A RU2015103987A RU2015103987A RU2015103987A RU 2015103987 A RU2015103987 A RU 2015103987A RU 2015103987 A RU2015103987 A RU 2015103987A RU 2015103987 A RU2015103987 A RU 2015103987A RU 2015103987 A RU2015103987 A RU 2015103987A
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hardener
paint
coating
transparent coating
active hydrogen
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RU2015103987A
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Томокацу ШИГЕМОРИ
Хироси МОРИТА
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Байер Матириальсайенс Аг
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Priority claimed from JP2012153298A external-priority patent/JP5112570B1/ja
Priority claimed from JP2012247541A external-priority patent/JP5280580B1/ja
Application filed by Байер Матириальсайенс Аг filed Critical Байер Матириальсайенс Аг
Publication of RU2015103987A publication Critical patent/RU2015103987A/ru

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/53Base coat plus clear coat type
    • B05D7/532Base coat plus clear coat type the two layers being cured or baked together, i.e. wet on wet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
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    • B05D7/52Two layers
    • B05D7/53Base coat plus clear coat type
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    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
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    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/7806Nitrogen containing -N-C=0 groups
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    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/7806Nitrogen containing -N-C=0 groups
    • C08G18/7818Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
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    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
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    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/06Polyurethanes from polyesters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

1. Способ нанесения покрытия, которое представляет собой систему двухслойных покрытий с однократным обжигом, характеризующийся тем, что краску для основного покрытия, включающую смолу, содержащую активный водород, наносят без ее отверждения сшиванием, далее краску для прозрачного покрытия, включающую отвердитель и смолу, содержащую активный водород, наносят на основное покрытие, затем основное покрытие и прозрачное покрытие одновременно отверждают сшиванием, отличающийся тем, что краска для прозрачного покрытия представляет собой двухкомпонентную краску на основе полиуретана с молярным отношением от 0,9 до 2,0 в NCO/H (активный водород), а отвердитель представляет собой отвердитель, включающий полиизоцианат, производный от 1,6-гексаметилендиизоцианата, удовлетворяющий всем следующим условиям:1) отвердитель фактически не включает диизоцианатный мономер,2) вязкость отвердителя, когда он не разбавлен никаким органическим растворителем, составляет не более чем 1000 мПа·с/23°C,3) содержание тримера 1,6-гексаметилендиизоцианата в отвердителе составляет не менее чем 60 мас. %.4) Содержание тримера 1,6-гексаметилендиизоцианата в отвердителе составляет менее чем 10 мас. %.2. Способ по п. 1, в котором отвердитель для краски для прозрачного покрытия содержит не менее чем 13 мол. % иминооксадиазиндионового кольца 1,6-гексаметилендиизоцианата.3. Способ по п. 1 или 2, отличающийся тем, что краска для основного слоя включает смолу, содержащую активный водород и блокированный изоцианат.4. Отвердитель для краски для прозрачного покрытия, который применяют в способе по любому одному из п.п. 1-3.5. Многослойная покрытая пленка, состоящая из слоя основного покрытия и слоя прозрачного покрытия,

Claims (5)

1. Способ нанесения покрытия, которое представляет собой систему двухслойных покрытий с однократным обжигом, характеризующийся тем, что краску для основного покрытия, включающую смолу, содержащую активный водород, наносят без ее отверждения сшиванием, далее краску для прозрачного покрытия, включающую отвердитель и смолу, содержащую активный водород, наносят на основное покрытие, затем основное покрытие и прозрачное покрытие одновременно отверждают сшиванием, отличающийся тем, что краска для прозрачного покрытия представляет собой двухкомпонентную краску на основе полиуретана с молярным отношением от 0,9 до 2,0 в NCO/H (активный водород), а отвердитель представляет собой отвердитель, включающий полиизоцианат, производный от 1,6-гексаметилендиизоцианата, удовлетворяющий всем следующим условиям:
1) отвердитель фактически не включает диизоцианатный мономер,
2) вязкость отвердителя, когда он не разбавлен никаким органическим растворителем, составляет не более чем 1000 мПа·с/23°C,
3) содержание тримера 1,6-гексаметилендиизоцианата в отвердителе составляет не менее чем 60 мас. %.
4) Содержание тримера 1,6-гексаметилендиизоцианата в отвердителе составляет менее чем 10 мас. %.
2. Способ по п. 1, в котором отвердитель для краски для прозрачного покрытия содержит не менее чем 13 мол. % иминооксадиазиндионового кольца 1,6-гексаметилендиизоцианата.
3. Способ по п. 1 или 2, отличающийся тем, что краска для основного слоя включает смолу, содержащую активный водород и блокированный изоцианат.
4. Отвердитель для краски для прозрачного покрытия, который применяют в способе по любому одному из п.п. 1-3.
5. Многослойная покрытая пленка, состоящая из слоя основного покрытия и слоя прозрачного покрытия, которую получают способом по любому одному из п.п. 1-3.
RU2015103987A 2012-07-09 2013-07-03 Отвердитель для краски на основе полуиретана и способ ее нанесения RU2015103987A (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2012-153298 2012-07-09
JP2012153298A JP5112570B1 (ja) 2012-07-09 2012-07-09 塗装方法およびポリウレタン塗料用硬化剤
JP2012247541A JP5280580B1 (ja) 2012-11-09 2012-11-09 塗装方法およびポリウレタン塗料用硬化剤
JP2012-247541 2012-11-09
PCT/EP2013/064030 WO2014009220A1 (en) 2012-07-09 2013-07-03 Coating method and hardener for polyurethane paint

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US (2) US9567485B2 (ru)
EP (2) EP2869940B1 (ru)
KR (2) KR102192657B1 (ru)
CN (2) CN104487177B (ru)
AU (2) AU2013289383A1 (ru)
CA (2) CA2878407A1 (ru)
ES (2) ES2726111T3 (ru)
HK (2) HK1203442A1 (ru)
MX (2) MX2015000300A (ru)
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WO2014009220A1 (en) 2014-01-16
KR20150034712A (ko) 2015-04-03
RU2015103989A (ru) 2016-08-27
ES2725568T3 (es) 2019-09-24
EP2869940B1 (en) 2019-02-13
CA2878428A1 (en) 2014-01-16
KR102192657B1 (ko) 2020-12-17
CN104487177A (zh) 2015-04-01
MX2015000300A (es) 2015-04-10
AU2013289383A1 (en) 2015-01-22
HK1203442A1 (en) 2015-10-30
US9802223B2 (en) 2017-10-31
EP2869941A1 (en) 2015-05-13
CA2878407A1 (en) 2014-01-16
ES2726111T3 (es) 2019-10-01
AU2013289382A1 (en) 2015-01-22
MX2015000298A (es) 2015-04-10
US9567485B2 (en) 2017-02-14
US20150322290A1 (en) 2015-11-12
EP2869940A1 (en) 2015-05-13
KR102192652B1 (ko) 2020-12-17
CN104411416A (zh) 2015-03-11
HK1204304A1 (en) 2015-11-13
EP2869941B1 (en) 2019-02-20
WO2014009221A1 (en) 2014-01-16
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CN104487177B (zh) 2018-05-22
US20150147577A1 (en) 2015-05-28

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