RU2016152469A - Выборочно снимаемые покрытия для металлических и пластиковых подложек - Google Patents

Выборочно снимаемые покрытия для металлических и пластиковых подложек Download PDF

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RU2016152469A
RU2016152469A RU2016152469A RU2016152469A RU2016152469A RU 2016152469 A RU2016152469 A RU 2016152469A RU 2016152469 A RU2016152469 A RU 2016152469A RU 2016152469 A RU2016152469 A RU 2016152469A RU 2016152469 A RU2016152469 A RU 2016152469A
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composition
coating material
pigments
coating
polyisocyanate
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RU2016152469A
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RU2016152469A3 (ru
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Дирк ЗЕГЕР
Кристоф ПЬЕХА
Надине ХОМАНН
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БАСФ Коатингс ГмбХ
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    • C—CHEMISTRY; METALLURGY
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    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/007—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/54—No clear coat specified
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/57—Three layers or more the last layer being a clear coat
    • B05D7/572—Three layers or more the last layer being a clear coat all layers being cured or baked together
    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/003—Polymeric products of isocyanates or isothiocyanates with epoxy compounds having no active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
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    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
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    • C08G2150/00—Compositions for coatings
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    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
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    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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Claims (23)

1. Композиция покрывающего материала, включающая
(i) по меньшей мере, один гидроксилсодержащий сложный полиэфир (А), имеющий ОН число от 250 до 660 мг KOH/г,
(ii) по меньшей мере, один поликарбонатный диол (В), имеющий ОН число от 35 до 500 мг KOH/г, в количестве от 1 до 20 мас. %, в пересчете на общую массу конечной композиции покрывающего материала, и
(iii) по меньшей мере, один полиизоцианат (С), включающий биуретовые группы и, имеющий содержание изоцианатных групп от 5.8 до 27 мас. %,
при этом гидроксилсодержащий сложный полиэфир (А) отличается от поликарбонатного диола (В),
и композиция покрывающего материала
(iv) включает долю органических растворителей менее, чем 420 г/л, и
(v) включает, в пересчете на содержание твердых частиц, от 40 до 100 мас. % связующих веществ.
2. Композиция покрывающего материала по п. 1, в которой гидроксилсодержащий сложный полиэфир (А) является алифатическим и/или разветвленным.
3. Композиция покрывающего материала по п. 1 или п. 2, в которой поликарбонатный диол (В) является алифатическим и/или линейным.
4. Композиция покрывающего материала по п. 1 или 2, в которой поликарбонатный диол (В) имеет ОН число от 100 до 250 мг KOH/г.
5. Композиция покрывающего материала по п. 1 или 2, в которой полиизоцианат (С), включающий биуретовые группы, является алифатическим.
6. Композиция покрывающего материала по п. 1 или 2, в которой полиизоцианат (С), включающий биуретовые группы, составленный на основе гексаметилен диизоцианата и/или изофорон диизоцианата.
7. Композиция покрывающего материала по п. 1 или 2, в которой полиизоцианат (С), включающий биуретовые группы, имеет содержание изоцианатных групп от 15 до 26 мас. %.
8. Композиция покрывающего материала по п. 1 или 2, которая включает пигменты и/или наполнители.
9. Композиция покрывающего материала по п. 8, в которой пигменты выбраны из группы, включающей пигменты, обеспечивающие цвет, пигменты, обеспечивающие эффект, пигменты, обеспечивающие цвет и эффект, и антикоррозионные пигменты, и наполнители выбраны из группы, включающей силикаты, диоксиды кремния, и карбонаты кальция.
10. Композиция покрывающего материала по пп. 1, 2 или 9, включающая компонент (Е), который включает, по меньшей мере, одну эпоксидную смолу или смесь, по меньшей мере, одной эпоксидной смолы с, по меньшей мере, одной гидрокси-функциональной акриловой смолой.
11. Композиция покрывающего материала по пп. 1, 2 или 9, включающая связующее вещество, отличающееся от гидроксилсодержащего сложного полиэфира (А), от поликарбонатного диола (В), от полиизоцианата (С), включающего биуретовые группы, и от компонентов (D) и (Е), если последние присутствуют.
12. Композиция покрывающего материала по пп. 1, 2 или 9, в которой соотношение гидроксильных групп компонентов (А), (В), и, если присутствует, (Е) к изоцианатным группам компонента (С) составляет от 1:1.1 до 1:1.5.
13. Способ получения многослойного покрытия, в котором наносят, по меньшей мере, одну композицию праймера на металлическую подложку и/или пластиковую подложку, на этот слой наносят, по меньшей мере, одну композицию верхнего слоя покрытия, и необязательно на него наносят, по меньшей мере, одну композицию покровного лака, при этом, по меньшей мере, одна из композиций праймера, композиций верхнего слоя покрытия, или композиций покровного лака представляет собой композицию покрывающего материала по любому из пп. 1-12, и впоследствии сшивают химически.
14. Применение композиции покрывающего материала по любому из пп. 1-12 в качестве композиции праймера, композиции верхнего слоя покрытия, или композиции покровного лака для покрытия металлических подложек и/или пластиковых подложек.
15. Применение по п. 14, при этом подложка представляет собой корпус самолета или часть корпуса самолета, лопасти ротора ветроэнергетической системы, корпус корабля или его часть, или машину.
16. Подложка, состоящая из одного или нескольких металлов и/или пластиков, которая была покрыта химически сшитой композицией покрывающего материала по любому из пп. 1-12 или была получена способом по п. 13.
RU2016152469A 2014-06-06 2015-05-21 Выборочно снимаемые покрытия для металлических и пластиковых подложек RU2669804C2 (ru)

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EP14171524.3 2014-06-06
PCT/EP2015/061246 WO2015185367A1 (de) 2014-06-06 2015-05-21 Selektiv abbeizbare beschichtungen für metall- und kunststoffuntergründe

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BR112017005387A2 (pt) * 2014-09-19 2017-12-19 Jotun As composição
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WO2015185367A1 (de) 2015-12-10
BR112016027794A2 (pt) 2017-08-22
CA2948881A1 (en) 2015-12-10
CA2948881C (en) 2019-06-04
US10233354B2 (en) 2019-03-19
JP2017522435A (ja) 2017-08-10
JP6317035B2 (ja) 2018-04-25
EP3152245A1 (de) 2017-04-12
CN106459365B (zh) 2019-09-27
CN106459365A (zh) 2017-02-22
US20170204288A1 (en) 2017-07-20
BR112016027794B1 (pt) 2021-08-17

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