RU2014153237A - Способ получения синтетических жидких углеводородов из природного газа - Google Patents
Способ получения синтетических жидких углеводородов из природного газа Download PDFInfo
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- RU2014153237A RU2014153237A RU2014153237A RU2014153237A RU2014153237A RU 2014153237 A RU2014153237 A RU 2014153237A RU 2014153237 A RU2014153237 A RU 2014153237A RU 2014153237 A RU2014153237 A RU 2014153237A RU 2014153237 A RU2014153237 A RU 2014153237A
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
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- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
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- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
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- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
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- C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
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- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
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- C10K1/00—Purifying combustible gases containing carbon monoxide
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- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
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Abstract
1. Способ получения синтетических жидких углеводородов из природного газа, включающий в себя последовательное проведение парового риформинга природного газа в реакторе с получением синтез-газа, извлечения диоксида углерода из синтез-газа до остаточного содержания диоксида углерода в синтез-газе не более 5 об.% методом жидкостной абсорбции, извлечения из синтез-газа излишка водорода на установке с водородпроницаемыми мембранами до получения соотношения H:CO в интервале 1,9-2,3 и синтеза жидких углеводородов из синтез-газа методом Фишера-Тропша.2. Способ по п. 1, извлеченный из синтез газа излишек водорода используют в качестве топливного газа в процессе парового риформинга.3. Способ по п. 1, отличающийся тем, что диоксид углерода после его извлечения из синтез-газа смешивают с природным газом и подают на вход реактора парового риформинга.4. Способ по любому из пп. 1-3, отличающийся тем, что паровой риформинг проводят под давлением смеси природного газа с паром в пределах 22-35 бар.
Claims (4)
1. Способ получения синтетических жидких углеводородов из природного газа, включающий в себя последовательное проведение парового риформинга природного газа в реакторе с получением синтез-газа, извлечения диоксида углерода из синтез-газа до остаточного содержания диоксида углерода в синтез-газе не более 5 об.% методом жидкостной абсорбции, извлечения из синтез-газа излишка водорода на установке с водородпроницаемыми мембранами до получения соотношения H2:CO в интервале 1,9-2,3 и синтеза жидких углеводородов из синтез-газа методом Фишера-Тропша.
2. Способ по п. 1, извлеченный из синтез газа излишек водорода используют в качестве топливного газа в процессе парового риформинга.
3. Способ по п. 1, отличающийся тем, что диоксид углерода после его извлечения из синтез-газа смешивают с природным газом и подают на вход реактора парового риформинга.
4. Способ по любому из пп. 1-3, отличающийся тем, что паровой риформинг проводят под давлением смеси природного газа с паром в пределах 22-35 бар.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2014153237A RU2648331C2 (ru) | 2014-12-26 | 2014-12-26 | Способ получения синтетических жидких углеводородов из природного газа |
PCT/RU2015/000927 WO2016105253A1 (en) | 2014-12-26 | 2015-12-25 | Process for producing synthetic liquid hydrocarbons from natural gas |
US15/540,016 US20170349838A1 (en) | 2014-12-26 | 2015-12-25 | Process for producing synthetic liquid hydrocarbons from natural gas |
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RU2014153237A RU2648331C2 (ru) | 2014-12-26 | 2014-12-26 | Способ получения синтетических жидких углеводородов из природного газа |
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RU2014153237A true RU2014153237A (ru) | 2016-07-20 |
RU2648331C2 RU2648331C2 (ru) | 2018-03-23 |
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RU2014153237A RU2648331C2 (ru) | 2014-12-26 | 2014-12-26 | Способ получения синтетических жидких углеводородов из природного газа |
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US (1) | US20170349838A1 (ru) |
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CN106744684B (zh) * | 2016-12-29 | 2018-08-03 | 中国科学院力学研究所 | 一种基于离子膜反应器的甲烷重整转化分离装置 |
CA3068117C (en) * | 2017-06-28 | 2024-04-16 | University Of South Florida | Systems and methods for producing liquid fuels from landfill gases |
RU2729790C1 (ru) * | 2020-02-28 | 2020-08-12 | Игорь Анатольевич Мнушкин | Газохимическое производство водорода |
GB2612647B (en) * | 2021-11-09 | 2024-04-24 | Nordic Electrofuel As | Fuel generation system and process |
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US5504118A (en) * | 1986-05-08 | 1996-04-02 | Rentech, Inc. | Process for the production of hydrocarbons |
JP4084664B2 (ja) * | 2001-03-05 | 2008-04-30 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 中間留出物の製造方法 |
US6881394B2 (en) | 2001-10-09 | 2005-04-19 | Conocophillips Company | Steam reformer for methane with internal hydrogen separation and combustion |
AU2004234588B2 (en) * | 2003-05-02 | 2009-04-09 | Johnson Matthey Plc | Production of hydrocarbons by steam reforming and Fischer-Tropsch reaction |
AU2007239819B2 (en) * | 2006-03-30 | 2010-12-02 | Nippon Steel Engineering Co., Ltd. | Liquid fuel synthesis system |
CN105749831A (zh) * | 2008-04-09 | 2016-07-13 | 万罗赛斯公司 | 使用微通道工艺技术升级碳质材料的方法 |
JP5301330B2 (ja) * | 2009-03-27 | 2013-09-25 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 液体炭化水素の合成方法及び液体炭化水素の合成システム |
GB201115929D0 (en) * | 2011-09-15 | 2011-10-26 | Johnson Matthey Plc | Improved hydrocarbon production process |
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2014
- 2014-12-26 RU RU2014153237A patent/RU2648331C2/ru active
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2015
- 2015-12-25 WO PCT/RU2015/000927 patent/WO2016105253A1/en active Application Filing
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US20170349838A1 (en) | 2017-12-07 |
RU2648331C2 (ru) | 2018-03-23 |
WO2016105253A1 (en) | 2016-06-30 |
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