RU2014153237A - Способ получения синтетических жидких углеводородов из природного газа - Google Patents

Способ получения синтетических жидких углеводородов из природного газа Download PDF

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RU2014153237A
RU2014153237A RU2014153237A RU2014153237A RU2014153237A RU 2014153237 A RU2014153237 A RU 2014153237A RU 2014153237 A RU2014153237 A RU 2014153237A RU 2014153237 A RU2014153237 A RU 2014153237A RU 2014153237 A RU2014153237 A RU 2014153237A
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synthesis gas
gas
natural gas
steam reforming
synthesis
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RU2648331C2 (ru
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Вадим Сергеевич Ермолаев
Илья Сергеевич Ермолаев
Владимир Зальманович Мордкович
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ИНФРА ИксТиЭл ТЕКНОЛОДЖИ ЛИМИТЕД
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Priority to RU2014153237A priority Critical patent/RU2648331C2/ru
Priority to PCT/RU2015/000927 priority patent/WO2016105253A1/en
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Abstract

1. Способ получения синтетических жидких углеводородов из природного газа, включающий в себя последовательное проведение парового риформинга природного газа в реакторе с получением синтез-газа, извлечения диоксида углерода из синтез-газа до остаточного содержания диоксида углерода в синтез-газе не более 5 об.% методом жидкостной абсорбции, извлечения из синтез-газа излишка водорода на установке с водородпроницаемыми мембранами до получения соотношения H:CO в интервале 1,9-2,3 и синтеза жидких углеводородов из синтез-газа методом Фишера-Тропша.2. Способ по п. 1, извлеченный из синтез газа излишек водорода используют в качестве топливного газа в процессе парового риформинга.3. Способ по п. 1, отличающийся тем, что диоксид углерода после его извлечения из синтез-газа смешивают с природным газом и подают на вход реактора парового риформинга.4. Способ по любому из пп. 1-3, отличающийся тем, что паровой риформинг проводят под давлением смеси природного газа с паром в пределах 22-35 бар.

Claims (4)

1. Способ получения синтетических жидких углеводородов из природного газа, включающий в себя последовательное проведение парового риформинга природного газа в реакторе с получением синтез-газа, извлечения диоксида углерода из синтез-газа до остаточного содержания диоксида углерода в синтез-газе не более 5 об.% методом жидкостной абсорбции, извлечения из синтез-газа излишка водорода на установке с водородпроницаемыми мембранами до получения соотношения H2:CO в интервале 1,9-2,3 и синтеза жидких углеводородов из синтез-газа методом Фишера-Тропша.
2. Способ по п. 1, извлеченный из синтез газа излишек водорода используют в качестве топливного газа в процессе парового риформинга.
3. Способ по п. 1, отличающийся тем, что диоксид углерода после его извлечения из синтез-газа смешивают с природным газом и подают на вход реактора парового риформинга.
4. Способ по любому из пп. 1-3, отличающийся тем, что паровой риформинг проводят под давлением смеси природного газа с паром в пределах 22-35 бар.
RU2014153237A 2014-12-26 2014-12-26 Способ получения синтетических жидких углеводородов из природного газа RU2648331C2 (ru)

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RU2014153237A RU2648331C2 (ru) 2014-12-26 2014-12-26 Способ получения синтетических жидких углеводородов из природного газа
PCT/RU2015/000927 WO2016105253A1 (en) 2014-12-26 2015-12-25 Process for producing synthetic liquid hydrocarbons from natural gas
US15/540,016 US20170349838A1 (en) 2014-12-26 2015-12-25 Process for producing synthetic liquid hydrocarbons from natural gas

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CN106744684B (zh) * 2016-12-29 2018-08-03 中国科学院力学研究所 一种基于离子膜反应器的甲烷重整转化分离装置
CA3068117C (en) * 2017-06-28 2024-04-16 University Of South Florida Systems and methods for producing liquid fuels from landfill gases
RU2729790C1 (ru) * 2020-02-28 2020-08-12 Игорь Анатольевич Мнушкин Газохимическое производство водорода
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US5504118A (en) * 1986-05-08 1996-04-02 Rentech, Inc. Process for the production of hydrocarbons
JP4084664B2 (ja) * 2001-03-05 2008-04-30 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 中間留出物の製造方法
US6881394B2 (en) 2001-10-09 2005-04-19 Conocophillips Company Steam reformer for methane with internal hydrogen separation and combustion
AU2004234588B2 (en) * 2003-05-02 2009-04-09 Johnson Matthey Plc Production of hydrocarbons by steam reforming and Fischer-Tropsch reaction
AU2007239819B2 (en) * 2006-03-30 2010-12-02 Nippon Steel Engineering Co., Ltd. Liquid fuel synthesis system
CN105749831A (zh) * 2008-04-09 2016-07-13 万罗赛斯公司 使用微通道工艺技术升级碳质材料的方法
JP5301330B2 (ja) * 2009-03-27 2013-09-25 独立行政法人石油天然ガス・金属鉱物資源機構 液体炭化水素の合成方法及び液体炭化水素の合成システム
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