RU2017107429A - Способ получения синтез-газа - Google Patents

Способ получения синтез-газа Download PDF

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RU2017107429A
RU2017107429A RU2017107429A RU2017107429A RU2017107429A RU 2017107429 A RU2017107429 A RU 2017107429A RU 2017107429 A RU2017107429 A RU 2017107429A RU 2017107429 A RU2017107429 A RU 2017107429A RU 2017107429 A RU2017107429 A RU 2017107429A
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synthesis gas
gas stream
stream
partial
hydrogen
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RU2734821C2 (ru
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Альбрехт ХАЙНЦЕЛЬ
Рашид МАБРУК
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Линде Акциенгезелльшафт
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Claims (10)

1. Способ получения углеводородов (23), согласно которому из содержащего углеводороды сырьевого потока (1) получают первый (3) и второй (4) частичные сырьевые потоки, при этом первый частичный сырьевой поток (3) превращают путем парциального окисления или автотермического риформинга (R) в первый поток синтез-газа (8), а второй частичный сырьевой поток (4) превращают посредством парового риформинга (D) во второй поток синтез-газа (10) и затем объединяют с первым потоком синтез-газа (8) с образованием третьего потока синтез-газа (5), по меньшей мере первую часть (11) которого посредством синтеза Фишера-Тропша (F) превращают в поток неочищенного продукта (16), содержащий углеводороды с разными длинами цепей, из которого легкие углеводороды отделяют в остаточный газ (17), чтобы вернуть их в процесс и использовать в парциальном окислении или автотермическом риформинге (R), отличающийся тем, что из по меньшей мере одной части (19) остаточного газа (17) выделяют ненасыщенные углеводороды (21), чтобы получить по существу не содержащий ненасыщенных углеводородов поток (20) для применения в качестве сырья для парциального окисления или автотермического риформинга (R).
2. Способ по п. 1, отличающийся тем, что ненасыщенные углеводороды (21), выделенные из по меньшей мере одной части (19) остаточного газа (17), используют в процессе для нижнего обогрева или выпускают как актив в качестве продукта для вторичной переработки или сжигания.
3. Способ по п. 1, отличающийся тем, что соотношение объемных расходов первого частичного сырьевого потока (3) и второго частичного сырьевого потока (4) регулируют так, чтобы установить соотношение водорода и моноксида углерода в третьем потоке синтез-газа (5).
4. Способ по п. 1, отличающийся тем, что соотношение объемных расходов первого (8) потока синтез-газа и второго (10) потока синтез-газа перед их объединением в третий поток синтез-газа (5) изменяют путем регулируемого ответвления одного или нескольких частичных потоков, чтобы установить отношение водорода к моноксиду углерода в третьем потоке синтез-газа (5).
5. Способ по п. 3, отличающийся тем, что соотношение объемных расходов первого (8) потока синтез-газа и второго (10) потока синтез-газа перед их объединением в третий поток синтез-газа (5) изменяют путем регулируемого ответвления одного или нескольких частичных потоков, чтобы установить отношение водорода к моноксиду углерода в третьем потоке синтез-газа (5).
6. Способ по одному из пп. 3-5, отличающийся тем, что отношение водорода к моноксиду углерода в третьем потоке синтез-газа (5) устанавливают в интервале от 1,5 до 2,5.
7. Способ по одному из пп. 1-5, отличающийся тем, что третий поток синтез-газа (5) охлаждают в холодильнике (K) водой с образованием водяного пара, который в дальнейшем используется для получения электроэнергии, причем водяной пар после перегрева в системе утилизации отходящего тепла реактора парового риформинга (D) дросселируют в сопряженной с электрогенератором паровой турбине.
8. Способ по одному из пп. 1-5, отличающийся тем, что третий поток синтез-газа (5) разделяют на первый и второй частичные потоки синтез-газа (11, 12), причем первый частичный поток синтез-газа (11) используют как сырье для синтеза Фишера-Тропша (F), а второй частичный поток синтез-газа (12) подвергают реакции конверсии водяного газа (W), чтобы снизить содержание CO во втором частичном потоке синтез-газа (12) и повысить содержание водорода.
9. Способ по п. 8, отличающийся тем, что второй частичный поток синтез-газа (13) после реакции конверсии водяного газа (W) подвергают короткоцикловой адсорбции (D), при этом получают обогащенный водородом поток (14) и нагруженный отделенными газовыми компонентами поток (15) промывного газа.
10. Способ по п. 9, отличающийся тем, что обогащенный водородом поток (14) применяют для гидрирования (Z) тяжелых углеводородов, полученных в синтезе Фишера-Тропша (F), и/или для обессеривания сырьевого потока (1) или одного или обоих частичных сырьевых потоков (3, 4).
RU2017107429A 2016-03-08 2017-03-07 Способ получения синтез-газа RU2734821C2 (ru)

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DE102016002728.2A DE102016002728A1 (de) 2016-03-08 2016-03-08 Verfahren zur Erzeugung von Synthesegas

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CA2958526A1 (en) 2017-09-08
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DE102016002728A1 (de) 2017-09-14
RU2734821C2 (ru) 2020-10-23
US9790433B2 (en) 2017-10-17
CN107416770A (zh) 2017-12-01

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