RU2014118032A - Способ получения муравьиной кислоты путем превращения диоксида углерода с водородом - Google Patents
Способ получения муравьиной кислоты путем превращения диоксида углерода с водородом Download PDFInfo
- Publication number
- RU2014118032A RU2014118032A RU2014118032/04A RU2014118032A RU2014118032A RU 2014118032 A RU2014118032 A RU 2014118032A RU 2014118032/04 A RU2014118032/04 A RU 2014118032/04A RU 2014118032 A RU2014118032 A RU 2014118032A RU 2014118032 A RU2014118032 A RU 2014118032A
- Authority
- RU
- Russia
- Prior art keywords
- phase
- mixture
- tertiary amine
- formic acid
- lower phase
- Prior art date
Links
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title claims abstract 27
- 235000019253 formic acid Nutrition 0.000 title claims abstract 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract 6
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract 3
- 239000001569 carbon dioxide Substances 0.000 title claims abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract 3
- 239000001257 hydrogen Substances 0.000 title claims abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- 230000001131 transforming effect Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract 21
- 150000003512 tertiary amines Chemical class 0.000 claims abstract 21
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract 20
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract 12
- 239000003054 catalyst Substances 0.000 claims abstract 12
- 239000002798 polar solvent Substances 0.000 claims abstract 9
- 150000001412 amines Chemical class 0.000 claims abstract 8
- 238000005191 phase separation Methods 0.000 claims abstract 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract 6
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims abstract 6
- 238000000605 extraction Methods 0.000 claims abstract 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims abstract 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 6
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims abstract 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract 2
- 238000006243 chemical reaction Methods 0.000 claims abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 2
- 230000000737 periodic effect Effects 0.000 claims abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 2
- 239000011541 reaction mixture Substances 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims 13
- 238000004821 distillation Methods 0.000 claims 10
- 238000005979 thermal decomposition reaction Methods 0.000 claims 6
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 238000003776 cleavage reaction Methods 0.000 claims 4
- 230000007017 scission Effects 0.000 claims 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 230000002051 biphasic effect Effects 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- DIAIBWNEUYXDNL-UHFFFAOYSA-N n,n-dihexylhexan-1-amine Chemical compound CCCCCCN(CCCCCC)CCCCCC DIAIBWNEUYXDNL-UHFFFAOYSA-N 0.000 claims 1
- 230000007420 reactivation Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
- B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11184297.7 | 2011-10-07 | ||
| EP11184297 | 2011-10-07 | ||
| PCT/EP2012/069458 WO2013050367A2 (de) | 2011-10-07 | 2012-10-02 | Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2014118032A true RU2014118032A (ru) | 2015-11-20 |
Family
ID=46963751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014118032/04A RU2014118032A (ru) | 2011-10-07 | 2012-10-02 | Способ получения муравьиной кислоты путем превращения диоксида углерода с водородом |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP2763950A2 (https=) |
| JP (1) | JP2014530216A (https=) |
| KR (1) | KR20140074373A (https=) |
| CN (1) | CN103974927A (https=) |
| BR (1) | BR112014008338A2 (https=) |
| CA (1) | CA2851175A1 (https=) |
| IN (1) | IN2014DN03122A (https=) |
| RU (1) | RU2014118032A (https=) |
| SG (1) | SG11201400997TA (https=) |
| WO (1) | WO2013050367A2 (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201112231D0 (en) | 2011-07-15 | 2011-08-31 | Verdant Bioproducts Ltd | Micro-organism |
| US8596013B2 (en) | 2012-04-04 | 2013-12-03 | Valinge Innovation Ab | Building panel with a mechanical locking system |
| US9428438B2 (en) | 2012-11-27 | 2016-08-30 | Basf Se | Process for preparing formic acid |
| WO2016024293A1 (en) | 2014-08-12 | 2016-02-18 | Council Of Scientific & Industrial Research | Metal catalyzed process for reduction of co2 to sodium formate and formic acid |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4474959A (en) * | 1982-05-22 | 1984-10-02 | Bp Chemicals Limited | Production of formate salts from carbon dioxide, hydrogen and amines |
| GB8424672D0 (en) * | 1984-09-29 | 1984-11-07 | Bp Chem Int Ltd | Production of formic acid |
| NZ227890A (en) * | 1988-02-17 | 1992-02-25 | Bp Chemical Ltd | Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen |
| DE102004040789A1 (de) | 2004-08-23 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von Ameisensäure |
| US20100063320A1 (en) * | 2007-03-23 | 2010-03-11 | Nina Challand | Method for producing formic acid |
| RU2012102459A (ru) * | 2009-06-26 | 2013-08-10 | Басф Се | Способ получения муравьиной кислоты |
-
2012
- 2012-10-02 IN IN3122DEN2014 patent/IN2014DN03122A/en unknown
- 2012-10-02 CN CN201280059095.3A patent/CN103974927A/zh active Pending
- 2012-10-02 SG SG11201400997TA patent/SG11201400997TA/en unknown
- 2012-10-02 BR BR112014008338A patent/BR112014008338A2/pt not_active IP Right Cessation
- 2012-10-02 WO PCT/EP2012/069458 patent/WO2013050367A2/de not_active Ceased
- 2012-10-02 KR KR1020147011873A patent/KR20140074373A/ko not_active Withdrawn
- 2012-10-02 RU RU2014118032/04A patent/RU2014118032A/ru not_active Application Discontinuation
- 2012-10-02 CA CA2851175A patent/CA2851175A1/en not_active Abandoned
- 2012-10-02 EP EP12766684.0A patent/EP2763950A2/de not_active Withdrawn
- 2012-10-02 JP JP2014533856A patent/JP2014530216A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP2763950A2 (de) | 2014-08-13 |
| IN2014DN03122A (https=) | 2015-05-22 |
| CA2851175A1 (en) | 2013-04-11 |
| KR20140074373A (ko) | 2014-06-17 |
| SG11201400997TA (en) | 2014-09-26 |
| WO2013050367A2 (de) | 2013-04-11 |
| WO2013050367A3 (de) | 2013-10-03 |
| JP2014530216A (ja) | 2014-11-17 |
| CN103974927A (zh) | 2014-08-06 |
| BR112014008338A2 (pt) | 2017-04-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA93 | Acknowledgement of application withdrawn (no request for examination) |
Effective date: 20151005 |