JP2014530216A - 二酸化炭素を水素と反応させることによるギ酸の製造法 - Google Patents

二酸化炭素を水素と反応させることによるギ酸の製造法 Download PDF

Info

Publication number
JP2014530216A
JP2014530216A JP2014533856A JP2014533856A JP2014530216A JP 2014530216 A JP2014530216 A JP 2014530216A JP 2014533856 A JP2014533856 A JP 2014533856A JP 2014533856 A JP2014533856 A JP 2014533856A JP 2014530216 A JP2014530216 A JP 2014530216A
Authority
JP
Japan
Prior art keywords
phase
formic acid
mixture
tertiary amine
complex catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2014533856A
Other languages
English (en)
Japanese (ja)
Inventor
シャウプ トーマス
シャウプ トーマス
バイ オリヴァー
バイ オリヴァー
アントン　マイアー
マイアー アントン
マリアフリース ドナタ
マリア フリース ドナタ
フーゴ ランドルフ
フーゴ ランドルフ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of JP2014530216A publication Critical patent/JP2014530216A/ja
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2014533856A 2011-10-07 2012-10-02 二酸化炭素を水素と反応させることによるギ酸の製造法 Withdrawn JP2014530216A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11184297.7 2011-10-07
EP11184297 2011-10-07

Publications (1)

Publication Number Publication Date
JP2014530216A true JP2014530216A (ja) 2014-11-17

Family

ID=46963751

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2014533856A Withdrawn JP2014530216A (ja) 2011-10-07 2012-10-02 二酸化炭素を水素と反応させることによるギ酸の製造法

Country Status (10)

Country Link
EP (1) EP2763950A2 (https=)
JP (1) JP2014530216A (https=)
KR (1) KR20140074373A (https=)
CN (1) CN103974927A (https=)
BR (1) BR112014008338A2 (https=)
CA (1) CA2851175A1 (https=)
IN (1) IN2014DN03122A (https=)
RU (1) RU2014118032A (https=)
SG (1) SG11201400997TA (https=)
WO (1) WO2013050367A2 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201112231D0 (en) 2011-07-15 2011-08-31 Verdant Bioproducts Ltd Micro-organism
US8596013B2 (en) 2012-04-04 2013-12-03 Valinge Innovation Ab Building panel with a mechanical locking system
US9428438B2 (en) 2012-11-27 2016-08-30 Basf Se Process for preparing formic acid
WO2016024293A1 (en) 2014-08-12 2016-02-18 Council Of Scientific & Industrial Research Metal catalyzed process for reduction of co2 to sodium formate and formic acid

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474959A (en) * 1982-05-22 1984-10-02 Bp Chemicals Limited Production of formate salts from carbon dioxide, hydrogen and amines
GB8424672D0 (en) * 1984-09-29 1984-11-07 Bp Chem Int Ltd Production of formic acid
NZ227890A (en) * 1988-02-17 1992-02-25 Bp Chemical Ltd Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen
DE102004040789A1 (de) 2004-08-23 2006-03-02 Basf Ag Verfahren zur Herstellung von Ameisensäure
US20100063320A1 (en) * 2007-03-23 2010-03-11 Nina Challand Method for producing formic acid
RU2012102459A (ru) * 2009-06-26 2013-08-10 Басф Се Способ получения муравьиной кислоты

Also Published As

Publication number Publication date
EP2763950A2 (de) 2014-08-13
IN2014DN03122A (https=) 2015-05-22
CA2851175A1 (en) 2013-04-11
KR20140074373A (ko) 2014-06-17
SG11201400997TA (en) 2014-09-26
WO2013050367A2 (de) 2013-04-11
WO2013050367A3 (de) 2013-10-03
CN103974927A (zh) 2014-08-06
RU2014118032A (ru) 2015-11-20
BR112014008338A2 (pt) 2017-04-18

Similar Documents

Publication Publication Date Title
JP5734286B2 (ja) 蟻酸の製法
JP2014508119A (ja) 二酸化炭素と水素との反応によってギ酸を製造するための方法
JP5566534B2 (ja) 二酸化炭素と水素との反応によるギ酸の製造方法
TWI473785B (zh) 使用金屬螯配位體催化劑用於醋酸之生產的羰基化方法
US8791297B2 (en) Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8946462B2 (en) Process for preparing formic acid by reaction of carbon dioxide with hydrogen
JP5543025B2 (ja) 二酸化炭素と水素との反応によるギ酸の製造方法
JP2014522823A (ja) 二酸化炭素と水素との反応によるギ酸の製造方法
US20130012739A1 (en) Process for preparing formic acid by reacting carbon dioxide with hydrogen
US20130090496A1 (en) Process for preparing formic acid by reacting carbon dioxide with hydrogen
US20120157711A1 (en) Process for preparing formic acid by reacting carbon dioxide with hydrogen
JP2014530216A (ja) 二酸化炭素を水素と反応させることによるギ酸の製造法
US8877965B2 (en) Process for preparing formic acid by reaction of carbon dioxide with hydrogen
RS52828B (sr) Karbonilacioni postupak koji koristi katalizatore sa metalnim tridentantnim ligandima
US20120071690A1 (en) Production of formamides
JP2015502922A (ja) 二酸化炭素と水素との反応によるギ酸の製造方法
CN103506166B (zh) 失活铑膦催化剂的活化方法
CA2637325C (en) Process for the production of acetic acid
TW202342653A (zh) 方法

Legal Events

Date Code Title Description
A761 Written withdrawal of application

Free format text: JAPANESE INTERMEDIATE CODE: A761

Effective date: 20150421