RU2008138903A - METHOD FOR COLLECTING 1'-ALKYL-1'-ETHYLFORMIL- (C60-Ih) [5,6] FULLERO [2 ', 3': 1,9] CYCLOPROPANES AND 1'a-ALKYL-1'a-EthylFormyl-1 'a-CARBA-1' (2 ') a-HOMO (C60-Ih) [5,6] FULLERENES - Google Patents

METHOD FOR COLLECTING 1'-ALKYL-1'-ETHYLFORMIL- (C60-Ih) [5,6] FULLERO [2 ', 3': 1,9] CYCLOPROPANES AND 1'a-ALKYL-1'a-EthylFormyl-1 'a-CARBA-1' (2 ') a-HOMO (C60-Ih) [5,6] FULLERENES Download PDF

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RU2008138903A
RU2008138903A RU2008138903/04A RU2008138903A RU2008138903A RU 2008138903 A RU2008138903 A RU 2008138903A RU 2008138903/04 A RU2008138903/04 A RU 2008138903/04A RU 2008138903 A RU2008138903 A RU 2008138903A RU 2008138903 A RU2008138903 A RU 2008138903A
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alkyl
ethylformyl
fullero
cyclopropanes
carba
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RU2008138903/04A
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RU2404154C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Айрат Рамилевич Туктаров (RU)
Айрат Рамилевич Туктаров
Арслан Рифхатович Ахметов (RU)
Арслан Рифхатович Ахметов
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Раис Асхатович Садыков (RU)
Раис Асхатович Садыков
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Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
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Abstract

Способ совместного получения 1'-алкил-1'-этилформил-(С60-Ih)[5,6]фуллеро[2',3':1,9]циклопропанов и 1'а-алкил-1'а-этилформил-1'а-карба-1'(2')а-гомо(С60-Ih)[5,6]фуллеренов общей формулы (1) и (2): ! ! характеризующийся тем, что С60-фуллерен взаимодействует с α-алкилдиазоуксусным эфиром общей формулы N2C(alkyl)COOEt, где alkyl=Et, i-Pr, i-Bu, Bn, в о-дихлорбензоле в присутствии трехкомпонентного катализатора {Pd(acac)2:2РРh3:4Еt3Аl}, взятыми в мольном соотношении С60; α-алкилдиазоуксусный эфир:Pd(acac)2:РРh3:Et3Al=0,01:(0,05-0,15):(0,0015-0,0025):(0,003-0,005):(0,006-0,01), предпочтительно 0,01:0,1:0,002:0,004:0,008, при температуре 40°С в течение 0,25-1,0 ч. The method of co-production of 1'-alkyl-1'-ethylformyl- (C60-Ih) [5,6] fullero [2 ', 3': 1,9] cyclopropanes and 1'a-alkyl-1'a-ethylformyl-1 'a-carba-1' (2 ') a-homo (C60-Ih) [5,6] fullerenes of the general formulas (1) and (2):! ! characterized in that C60-fullerene interacts with an α-alkyl diazoacetate ester of the general formula N2C (alkyl) COOEt, where alkyl = Et, i-Pr, i-Bu, Bn, in o-dichlorobenzene in the presence of a three-component catalyst {Pd (acac) 2 : 2PPh3: 4Et3Al} taken in a molar ratio of C60; α-alkyl diazoacetic ester: Pd (acac) 2: PPh3: Et3Al = 0.01: (0.05-0.15) :( 0.0015-0.0025) :( 0.003-0.005) :( 0.006-0, 01), preferably 0.01: 0.1: 0.002: 0.004: 0.008, at a temperature of 40 ° C for 0.25-1.0 hours

Claims (1)

Способ совместного получения 1'-алкил-1'-этилформил-(С60-Ih)[5,6]фуллеро[2',3':1,9]циклопропанов и 1'а-алкил-1'а-этилформил-1'а-карба-1'(2')а-гомо(С60-Ih)[5,6]фуллеренов общей формулы (1) и (2):The method of co-production of 1'-alkyl-1'-ethylformyl- (C 60 -I h ) [5,6] fullero [2 ', 3': 1,9] cyclopropanes and 1'a-alkyl-1'a-ethylformyl -1'a-carba-1 '(2') a-homo (C 60 -I h ) [5,6] fullerenes of the general formulas (1) and (2):
Figure 00000001
Figure 00000001
 характеризующийся тем, что С60-фуллерен взаимодействует с α-алкилдиазоуксусным эфиром общей формулы N2C(alkyl)COOEt, где alkyl=Et, i-Pr, i-Bu, Bn, в о-дихлорбензоле в присутствии трехкомпонентного катализатора {Pd(acac)2:2РРh3:4Еt3Аl}, взятыми в мольном соотношении С60; α-алкилдиазоуксусный эфир:Pd(acac)2:РРh3:Et3Al=0,01:(0,05-0,15):(0,0015-0,0025):(0,003-0,005):(0,006-0,01), предпочтительно 0,01:0,1:0,002:0,004:0,008, при температуре 40°С в течение 0,25-1,0 ч. characterized in that the C 60 fullerene interacts with an α-alkyl diazoacetic ester of the general formula N 2 C (alkyl) COOEt, where alkyl = Et, i-Pr, i-Bu, Bn, in o-dichlorobenzene in the presence of a three-component catalyst {Pd ( acac) 2 : 2PPh 3 : 4Et 3 Al} taken in a molar ratio of C 60 ; α-Alkyldiazoacetic ester: Pd (acac) 2 : PPh 3 : Et 3 Al = 0.01: (0.05-0.15) :( 0.0015-0.0025) :( 0.003-0.005) :( 0.006 -0.01), preferably 0.01: 0.1: 0.002: 0.004: 0.008, at a temperature of 40 ° C for 0.25-1.0 hours
RU2008138903/04A 2008-09-30 2008-09-30 METHOD FOR COMBINED SYNTHESIS OF 1'-ALKYL-1'-ETHYLFORMYL-(C60-Ih)[5,6]FULLERO[2',3';1,9]CYCLOPROPANES AND 1'a-ALKYL-1'a-ETHYLFORMYL-1'a-CARBA-1'(2')a-HOMO(C60-Ih)[5,6]FULLERENES RU2404154C2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2459805C2 (en) * 2010-05-28 2012-08-27 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING 1a-METHYL-1a-(3'-THIOALKYLPROP-2'-YL)-1aH-1(9)a-homo(C60-Ih)[5,6]FULLERENES

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* Cited by examiner, † Cited by third party
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RU2478615C2 (en) * 2011-06-16 2013-04-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING 1'-[2"-(METHYLTHIO)ETHYL]- 1'-[S-ALKYLCARBOTHIOYL]-(C60-Ih)[5,6]FULLERO[2',3':1,9]CYCLOPROPANES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2459805C2 (en) * 2010-05-28 2012-08-27 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING 1a-METHYL-1a-(3'-THIOALKYLPROP-2'-YL)-1aH-1(9)a-homo(C60-Ih)[5,6]FULLERENES

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