RU2008152912A - METHOD FOR COLLECTING 1 '- [METHYLSULFANIL] -1'-ETHYLFORMIL- (C60-Ih) [5,6] FULLERO [2', 3 ', 1,9] -CYCLOPROPANE AND 1'a- (METHYLSULFANIL) ETHYL] - 1'a-Ethylformyl-1'a-CARBA-1 '(2') a-HOMOS (C60-Ih) [5,6] FULLERENA - Google Patents

METHOD FOR COLLECTING 1 '- [METHYLSULFANIL] -1'-ETHYLFORMIL- (C60-Ih) [5,6] FULLERO [2', 3 ', 1,9] -CYCLOPROPANE AND 1'a- (METHYLSULFANIL) ETHYL] - 1'a-Ethylformyl-1'a-CARBA-1 '(2') a-HOMOS (C60-Ih) [5,6] FULLERENA Download PDF

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RU2008152912A
RU2008152912A RU2008152912/04A RU2008152912A RU2008152912A RU 2008152912 A RU2008152912 A RU 2008152912A RU 2008152912/04 A RU2008152912/04 A RU 2008152912/04A RU 2008152912 A RU2008152912 A RU 2008152912A RU 2008152912 A RU2008152912 A RU 2008152912A
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ethyl
methylsulfanil
ethylformyl
fullero
carba
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RU2008152912/04A
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RU2440337C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Айрат Рамилевич Туктаров (RU)
Айрат Рамилевич Туктаров
Арслан Рифхатович Ахметов (RU)
Арслан Рифхатович Ахметов
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Забир Сабирович Муслимов (RU)
Забир Сабирович Муслимов
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Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
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Abstract

Способ совместного получения 1'-[2-(метилсульфанил)этил]-1'-этилформил-(С60-Ih)[5,6]фуллеро[2',3':1,9]циклопропана (1) и 1'а-[2-(метилсульфанил)этил]-1'а-этилформил-1'а-карба-1'(2')а-гомо(С60-Ih)[5,6]фуллерена (2), ! ! характеризующийся тем, что С60-фуллерен взаимодействует с 1-[2-(метилсульфанил)этил]диазоуксусным эфиром в о-дихлорбензоле (о-ДХБ) в присутствии трехкомпонентного катализатора {Pd(acac)2:2PPh3:4Et3Al}, взятыми в мольном соотношении С60:диазосоединение:Pd(acac)2:PPh3: Et3Al=0,01:(0,03-0,07):(0,0015-0,0025):(0,003-0,005):(0,006-0,01), предпочтительно 0,01:0,05:0,002:0,004:0,008, при температуре 80°С в течение 0,2-1,0 ч.  The method of co-production of 1 '- [2- (methylsulfanyl) ethyl] -1'-ethylformyl- (C60-Ih) [5,6] fullero [2', 3 ': 1,9] cyclopropane (1) and 1'a - [2- (methylsulfanyl) ethyl] -1'a-ethylformyl-1'a-carba-1 '(2') a-homo (C60-Ih) [5,6] fullerene (2),! ! characterized in that C60-fullerene interacts with 1- [2- (methylsulfanyl) ethyl] diazoacetic ester in o-dichlorobenzene (o-DCB) in the presence of a three-component catalyst {Pd (acac) 2: 2PPh3: 4Et3Al}, taken in molar ratio C60: diazo compound: Pd (acac) 2: PPh3: Et3Al = 0.01: (0.03-0.07) :( 0.0015-0.0025) :( 0.003-0.005) :( 0.006-0.01 ), preferably 0.01: 0.05: 0.002: 0.004: 0.008, at a temperature of 80 ° C for 0.2-1.0 hours

Claims (1)

Способ совместного получения 1'-[2-(метилсульфанил)этил]-1'-этилформил-(С60-Ih)[5,6]фуллеро[2',3':1,9]циклопропана (1) и 1'а-[2-(метилсульфанил)этил]-1'а-этилформил-1'а-карба-1'(2')а-гомо(С60-Ih)[5,6]фуллерена (2),The method of co-production of 1 '- [2- (methylsulfanyl) ethyl] -1'-ethylformyl- (C 60 -I h ) [5,6] fullero [2', 3 ': 1,9] cyclopropane (1) and 1 'a- [2- (methylsulfanyl) ethyl] -1'a-ethylformyl-1'a-carba-1' (2 ') a-homo (C 60 -I h ) [5,6] fullerene (2),
Figure 00000001
Figure 00000001
 характеризующийся тем, что С60-фуллерен взаимодействует с 1-[2-(метилсульфанил)этил]диазоуксусным эфиром в о-дихлорбензоле (о-ДХБ) в присутствии трехкомпонентного катализатора {Pd(acac)2:2PPh3:4Et3Al}, взятыми в мольном соотношении С60:диазосоединение:Pd(acac)2:PPh3: Et3Al=0,01:(0,03-0,07):(0,0015-0,0025):(0,003-0,005):(0,006-0,01), предпочтительно 0,01:0,05:0,002:0,004:0,008, при температуре 80°С в течение 0,2-1,0 ч. characterized in that C 60 -fullerene interacts with 1- [2- (methylsulfanyl) ethyl] diazoacetic ester in o-dichlorobenzene (o-DCB) in the presence of a three-component catalyst {Pd (acac) 2 : 2PPh 3 : 4Et 3 Al}, taken in a molar ratio of C 60 : diazo compound: Pd (acac) 2 : PPh 3 : Et 3 Al = 0.01: (0.03-0.07) :( 0.0015-0.0025) :( 0.003-0.005 ) :( 0.006-0.01), preferably 0.01: 0.05: 0.002: 0.004: 0.008, at a temperature of 80 ° C for 0.2-1.0 hours
RU2008152912/04A 2008-12-31 2008-12-31 METHOD FOR COMBINED SYNTHESIS OF 1'-[2-(METHYLSULPHANYL)ETHYL]-1'-ETHYLFORMYL-(C60-Ih)[5,6]FULLERO[2',3':1,9]CYCLOPROPANE AND 1'a-[2-(METHYLSULPHANYL)ETHYL]-1'a-ETHYLFORMYL -1'a-CARBA-1'(2')a-HOMO(C60-Ih)[5,6]FULLERENE RU2440337C2 (en)

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RU2008152912/04A RU2440337C2 (en) 2008-12-31 2008-12-31 METHOD FOR COMBINED SYNTHESIS OF 1'-[2-(METHYLSULPHANYL)ETHYL]-1'-ETHYLFORMYL-(C60-Ih)[5,6]FULLERO[2',3':1,9]CYCLOPROPANE AND 1'a-[2-(METHYLSULPHANYL)ETHYL]-1'a-ETHYLFORMYL -1'a-CARBA-1'(2')a-HOMO(C60-Ih)[5,6]FULLERENE

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RU2008152912/04A RU2440337C2 (en) 2008-12-31 2008-12-31 METHOD FOR COMBINED SYNTHESIS OF 1'-[2-(METHYLSULPHANYL)ETHYL]-1'-ETHYLFORMYL-(C60-Ih)[5,6]FULLERO[2',3':1,9]CYCLOPROPANE AND 1'a-[2-(METHYLSULPHANYL)ETHYL]-1'a-ETHYLFORMYL -1'a-CARBA-1'(2')a-HOMO(C60-Ih)[5,6]FULLERENE

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2478615C2 (en) * 2011-06-16 2013-04-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING 1'-[2"-(METHYLTHIO)ETHYL]- 1'-[S-ALKYLCARBOTHIOYL]-(C60-Ih)[5,6]FULLERO[2',3':1,9]CYCLOPROPANES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2478615C2 (en) * 2011-06-16 2013-04-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING 1'-[2"-(METHYLTHIO)ETHYL]- 1'-[S-ALKYLCARBOTHIOYL]-(C60-Ih)[5,6]FULLERO[2',3':1,9]CYCLOPROPANES

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