RU2008144404A - METHOD FOR COLLECTING 1 '- (3-1H-INDOLMETHYL) -1'-Ethylformyl- (C60-Ih) [5,6] FULLERO [2', 3 ': 1,9] CYCLOPROPANE AND 1'a- (3- 1H-INDOLMETHYL) -1'a-Ethylformyl-1'a-CARBA-1 '(2') a-HOMO (C60-Ih) [5,6] FULLERENA - Google Patents

METHOD FOR COLLECTING 1 '- (3-1H-INDOLMETHYL) -1'-Ethylformyl- (C60-Ih) [5,6] FULLERO [2', 3 ': 1,9] CYCLOPROPANE AND 1'a- (3- 1H-INDOLMETHYL) -1'a-Ethylformyl-1'a-CARBA-1 '(2') a-HOMO (C60-Ih) [5,6] FULLERENA Download PDF

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RU2008144404A
RU2008144404A RU2008144404/04A RU2008144404A RU2008144404A RU 2008144404 A RU2008144404 A RU 2008144404A RU 2008144404/04 A RU2008144404/04 A RU 2008144404/04A RU 2008144404 A RU2008144404 A RU 2008144404A RU 2008144404 A RU2008144404 A RU 2008144404A
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indolmethyl
ethylformyl
fullero
carba
cyclopropane
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RU2008144404/04A
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Russian (ru)
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RU2440340C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Айрат Рамилевич Туктаров (RU)
Айрат Рамилевич Туктаров
Арслан Рифхатович Ахметов (RU)
Арслан Рифхатович Ахметов
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Забир Сабирович Муслимов (RU)
Забир Сабирович Муслимов
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Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
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Abstract

Способ совместного получения 1'-(3-1H-индолметил)-1'-этилформил-(C60-Ih)[5,6]фуллеро[2',3':1,9]циклопропана и 1'a-(3-1H-индолметил)-1'a-этилформил-1'a-карба-1'(2')а-гомо(C60-Ih)[5,6]фуллерена общей формулы (1) и (2) ! ! отличающийся тем, что С60-фуллерен взаимодействует с этил 2-(3-1Н-индолметил)-2-диазоацетатом в о-дихлорбензоле в присутствии трехкомпонентного катализатора {Pd(acac)2:2PPh3:4Et3Al}, взятыми в мольном соотношении C60:этил 2-(3-1Н-индолметил)-2-диазоацетат:Pd(acac)2:PPh3:Et3Al=0,01:(0,01-0,10):(0,0015-0,0025):(0,003-0,005):(0,006-0,01), предпочтительно 0,01:0,05:0,002:0,004:0,008, при температуре 80°С в течение 0,5-1,5 ч. The method of co-production of 1 '- (3-1H-indolmethyl) -1'-ethylformyl- (C60-Ih) [5,6] fullero [2', 3 ': 1,9] cyclopropane and 1'a- (3- 1H-indolmethyl) -1'a-ethylformyl-1'a-carba-1 '(2') a-homo (C60-Ih) [5,6] fullerene of the general formulas (1) and (2)! ! characterized in that C60-fullerene interacts with ethyl 2- (3-1H-indolmethyl) -2-diazoacetate in o-dichlorobenzene in the presence of a three-component catalyst {Pd (acac) 2: 2PPh3: 4Et3Al}, taken in a molar ratio of C60: ethyl 2- (3-1H-indolmethyl) -2-diazoacetate: Pd (acac) 2: PPh3: Et3Al = 0.01: (0.01-0.10) :( 0.0015-0.0025) :( 0.003 -0.005) :( 0.006-0.01), preferably 0.01: 0.05: 0.002: 0.004: 0.008, at a temperature of 80 ° C for 0.5-1.5 hours

Claims (1)

Способ совместного получения 1'-(3-1H-индолметил)-1'-этилформил-(C60-Ih)[5,6]фуллеро[2',3':1,9]циклопропана и 1'a-(3-1H-индолметил)-1'a-этилформил-1'a-карба-1'(2')а-гомо(C60-Ih)[5,6]фуллерена общей формулы (1) и (2)The method of co-production of 1 '- (3-1H-indolmethyl) -1'-ethylformyl- (C60-Ih) [5,6] fullero [2', 3 ': 1,9] cyclopropane and 1'a- (3- 1H-indolmethyl) -1'a-ethylformyl-1'a-carba-1 '(2') a-homo (C60-Ih) [5,6] fullerene of the general formulas (1) and (2)
Figure 00000001
Figure 00000001
 отличающийся тем, что С60-фуллерен взаимодействует с этил 2-(3-1Н-индолметил)-2-диазоацетатом в о-дихлорбензоле в присутствии трехкомпонентного катализатора {Pd(acac)2:2PPh3:4Et3Al}, взятыми в мольном соотношении C60:этил 2-(3-1Н-индолметил)-2-диазоацетат:Pd(acac)2:PPh3:Et3Al=0,01:(0,01-0,10):(0,0015-0,0025):(0,003-0,005):(0,006-0,01), предпочтительно 0,01:0,05:0,002:0,004:0,008, при температуре 80°С в течение 0,5-1,5 ч. characterized in that C60-fullerene interacts with ethyl 2- (3-1H-indolmethyl) -2-diazoacetate in o-dichlorobenzene in the presence of a three-component catalyst {Pd (acac) 2: 2PPh3: 4Et3Al}, taken in a molar ratio of C60: ethyl 2- (3-1H-indolmethyl) -2-diazoacetate: Pd (acac) 2: PPh3: Et3Al = 0.01: (0.01-0.10) :( 0.0015-0.0025) :( 0.003 -0.005) :( 0.006-0.01), preferably 0.01: 0.05: 0.002: 0.004: 0.008, at a temperature of 80 ° C for 0.5-1.5 hours
RU2008144404/04A 2008-11-10 2008-11-10 METHOD FOR COMBINED SYNTHESIS OF 1'-(3-1H-INDOLEMETHYL)-1'-ETHYLFORMYL-(C60-Ih)[5,6]FULLERO[2'3':1,9]CYCLOPROPANE AND 1'a-(3-1H-INDOLEMETHYL)1'a-ETHYLFORMYL-1'a-CARBA-1'(2')a-HOMO(C60-Ih)[5,6]FULLERENE RU2440340C2 (en)

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RU2008144404/04A RU2440340C2 (en) 2008-11-10 2008-11-10 METHOD FOR COMBINED SYNTHESIS OF 1'-(3-1H-INDOLEMETHYL)-1'-ETHYLFORMYL-(C60-Ih)[5,6]FULLERO[2'3':1,9]CYCLOPROPANE AND 1'a-(3-1H-INDOLEMETHYL)1'a-ETHYLFORMYL-1'a-CARBA-1'(2')a-HOMO(C60-Ih)[5,6]FULLERENE

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RU2008144404/04A RU2440340C2 (en) 2008-11-10 2008-11-10 METHOD FOR COMBINED SYNTHESIS OF 1'-(3-1H-INDOLEMETHYL)-1'-ETHYLFORMYL-(C60-Ih)[5,6]FULLERO[2'3':1,9]CYCLOPROPANE AND 1'a-(3-1H-INDOLEMETHYL)1'a-ETHYLFORMYL-1'a-CARBA-1'(2')a-HOMO(C60-Ih)[5,6]FULLERENE

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2447018C2 (en) * 2010-06-02 2012-04-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING CHOLESTERYL CYCLOPROPA[1,9](C60-Ih)[5,6]FULLERENE-3'CARBOXYLATE

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2698834A1 (en) * 2012-08-17 2014-02-19 LANXESS Deutschland GmbH Fullerene derivatives with reduced electron affinity and a photovoltaic cell using the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2447018C2 (en) * 2010-06-02 2012-04-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING CHOLESTERYL CYCLOPROPA[1,9](C60-Ih)[5,6]FULLERENE-3'CARBOXYLATE

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