RU2010139062A - METHOD FOR PRODUCING OPTICALLY ACTIVE SPIRO-HOMOFULLERENES - Google Patents

METHOD FOR PRODUCING OPTICALLY ACTIVE SPIRO-HOMOFULLERENES Download PDF

Info

Publication number
RU2010139062A
RU2010139062A RU2010139062/04A RU2010139062A RU2010139062A RU 2010139062 A RU2010139062 A RU 2010139062A RU 2010139062/04 A RU2010139062/04 A RU 2010139062/04A RU 2010139062 A RU2010139062 A RU 2010139062A RU 2010139062 A RU2010139062 A RU 2010139062A
Authority
RU
Russia
Prior art keywords
optically active
homofullerenes
acac
spiro
producing optically
Prior art date
Application number
RU2010139062/04A
Other languages
Russian (ru)
Other versions
RU2455273C2 (en
Inventor
Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Айрат Рамилевич Туктаров (RU)
Айрат Рамилевич Туктаров
Вячеслав Владимирович Королев (RU)
Вячеслав Владимирович Королев
Леонард Мухибович Халилов (RU)
Леонард Мухибович Халилов
Original Assignee
Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU), Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран filed Critical Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Priority to RU2010139062/04A priority Critical patent/RU2455273C2/en
Publication of RU2010139062A publication Critical patent/RU2010139062A/en
Application granted granted Critical
Publication of RU2455273C2 publication Critical patent/RU2455273C2/en

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ получения оптически активных спиро-гомофуллеренов формулы (1) и (2): ! ! характеризующийся тем, что С60-фуллерен взаимодействует с оптически активными диазосоединениями, генерируемыми in situ окислением гидразонов (-)-ментона и D-(+)-камфоры с помощью MnO2, в о-дихлорбензоле в присутствии трехкомпонентной каталитической системы Pd(acac)2-PPh3-Et3Al, взятыми в мольном соотношении С60: оптически активный гидразон : Pd(acac)2 : PPh3 : Et3Al=0.01:(0.01-0.02):(0.0015-0.0025):(0.003-0.005):(0.006-0.01), при комнатной температуре (~20°С) в течение 1-2 ч. The method of obtaining optically active spiro-homofullerenes of the formula (1) and (2):! ! characterized by the fact that C60-fullerene interacts with optically active diazocompounds generated in situ by oxidation of (-) - menton and D - (+) - camphor hydrazones with MnO2, in o-dichlorobenzene in the presence of the three-component Pd (acac) 2- catalyst system PPh3-Et3Al, taken in the molar ratio C60: optically active hydrazone: Pd (acac) 2: PPh3: Et3Al = 0.01: (0.01-0.02) :( 0.0015-0.0025) :( 0.003-0.005) :( 0.006-0.01), at room temperature (~ 20 ° C) for 1-2 hours

Claims (1)

Способ получения оптически активных спиро-гомофуллеренов формулы (1) и (2):The method of obtaining optically active spiro-homofullerenes of the formula (1) and (2):
Figure 00000001
Figure 00000002
Figure 00000001
Figure 00000002
 характеризующийся тем, что С60-фуллерен взаимодействует с оптически активными диазосоединениями, генерируемыми in situ окислением гидразонов (-)-ментона и D-(+)-камфоры с помощью MnO2, в о-дихлорбензоле в присутствии трехкомпонентной каталитической системы Pd(acac)2-PPh3-Et3Al, взятыми в мольном соотношении С60: оптически активный гидразон : Pd(acac)2 : PPh3 : Et3Al=0.01:(0.01-0.02):(0.0015-0.0025):(0.003-0.005):(0.006-0.01), при комнатной температуре (~20°С) в течение 1-2 ч. characterized by the fact that C 60 fullerene interacts with optically active diazocompounds generated in situ by oxidation of hydrazones of (-) - menton and D - (+) - camphor with MnO 2 , in o - dichlorobenzene in the presence of a three-component Pd (acac) catalyst system 2 -PPh 3 -Et 3 Al, taken in a C 60 molar ratio: optically active hydrazone: Pd (acac) 2 : PPh 3 : Et 3 Al = 0.01: (0.01-0.02) :( 0.0015-0.0025) :( 0.003- 0.005) :( 0.006-0.01), at room temperature (~ 20 ° C) for 1-2 hours.
RU2010139062/04A 2010-09-22 2010-09-22 Method of producing optically active spiro-homofullerenes RU2455273C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2010139062/04A RU2455273C2 (en) 2010-09-22 2010-09-22 Method of producing optically active spiro-homofullerenes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2010139062/04A RU2455273C2 (en) 2010-09-22 2010-09-22 Method of producing optically active spiro-homofullerenes

Publications (2)

Publication Number Publication Date
RU2010139062A true RU2010139062A (en) 2012-03-27
RU2455273C2 RU2455273C2 (en) 2012-07-10

Family

ID=46030585

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2010139062/04A RU2455273C2 (en) 2010-09-22 2010-09-22 Method of producing optically active spiro-homofullerenes

Country Status (1)

Country Link
RU (1) RU2455273C2 (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006290788A (en) * 2005-04-11 2006-10-26 Matsushita Electric Ind Co Ltd Fullerene derivative, method for producing fullerene film by using the same and method for producing field-effect transistor
RU2348604C1 (en) * 2007-07-23 2009-03-10 Институт нефтехимии и катализа РАН Method of obtaining polyhydro[60]fullerenes

Also Published As

Publication number Publication date
RU2455273C2 (en) 2012-07-10

Similar Documents

Publication Publication Date Title
EA201291227A1 (en) CATALYST OF METHANE AROMATION, METHOD OF MANUFACTURING AND METHOD OF USING THE CATALYST
PE20130252A1 (en) AGOMELATIN INTERMEDIATES AND METHOD OF PREPARING THESE
RU2010139062A (en) METHOD FOR PRODUCING OPTICALLY ACTIVE SPIRO-HOMOFULLERENES
RU2008105019A (en) N-SUBSTITUTED 4-METHYL-2,6-DICHLORONICOTINOIL-UREA AS AN ANIDOT 2,4-D IN SUNFLOWER
RU2009124700A (en) METHOD FOR PRODUCING (C60-Ih) [5,6] FULLERO [2 ', 3': 1,9] CYCLOPROPANE
AR081730A1 (en) COMPOSITION OF CONTROL OF PHYTO-DISEASES AND METHOD TO CONTROL PHYTO-DISEASES
RU2008144404A (en) METHOD FOR COLLECTING 1 '- (3-1H-INDOLMETHYL) -1'-Ethylformyl- (C60-Ih) [5,6] FULLERO [2', 3 ': 1,9] CYCLOPROPANE AND 1'a- (3- 1H-INDOLMETHYL) -1'a-Ethylformyl-1'a-CARBA-1 '(2') a-HOMO (C60-Ih) [5,6] FULLERENA
RU2009124837A (en) METHOD FOR PRODUCING CYCLOALKYLIDENE HOMO (C60-Ih) [5,6] FULLERENA
RU2010150252A (en) METHOD FOR PRODUCING AZIRIDINO [2 ', 3': 1,2] FULLERENA [60]
RU2011129489A (en) METHOD FOR PRODUCING 3'-METHYL-3'-FURYL-OR 3'-METHYL-3'-THIENYL-3'H-CYCLOPROPA [1.9] (C60-Ih) [5.6] FULLERENES
RU2010122563A (en) METHOD FOR PRODUCING CHOLESTERIL CYCLOPROPA [1,9] (С60-Ih) [5,6] FULLEREN-3`CARBOXYLATE
RU2008138903A (en) METHOD FOR COLLECTING 1'-ALKYL-1'-ETHYLFORMIL- (C60-Ih) [5,6] FULLERO [2 ', 3': 1,9] CYCLOPROPANES AND 1'a-ALKYL-1'a-EthylFormyl-1 'a-CARBA-1' (2 ') a-HOMO (C60-Ih) [5,6] FULLERENES
RU2008142156A (en) METHOD FOR PRODUCING 1'a-METHYL-1'a-EthylFormyl-1'a-CARBA-1 '(2') - a-HOMO (C60-Ih) [5,6] FULLERENA
RU2010122565A (en) METHOD FOR SELECTIVE OBTAINING 1 '- [2-METHYLESULFANIL) -ETHYL] -1'-Ethylformylcyclopropa [2', 3 ': 1.9] (C60-Ih) [5,6] FULLERENA
Шаманов et al. Îñîáåííîñòè çàïóñêà ñòðóéíîãî àïïàðàòà â ïåðâîì êîíòóðå ÿäåðíîé ïàðîïðîèçâîäÿùåé
RU2007104483A (en) METHOD FOR PRODUCING 1-HYDROXYADAMANTAN-4-OH
RU2009124879A (en) METHOD FOR PRODUCING 1 '(2') A-HOMOS (C60-Ih) [5,6] FULLERENA
RU2009145309A (en) METHOD FOR PRODUCING (C60-Ih) [5,6] FULLERO [2 ', 3': 1,9] CYCLOPROPAN-1'-IL (CYCLOalkyl) METHANONS
RU2009138209A (en) N-SUBSTITUTED AMIDES 2-HYDROXY-4-OXO-4- (41-CHLOROPHENYL) 2-BUTHENIC ACID, MANIFESTING ANTI-MICROBIAL ACTIVITY
RU2008152912A (en) METHOD FOR COLLECTING 1 '- [METHYLSULFANIL] -1'-ETHYLFORMIL- (C60-Ih) [5,6] FULLERO [2', 3 ', 1,9] -CYCLOPROPANE AND 1'a- (METHYLSULFANIL) ETHYL] - 1'a-Ethylformyl-1'a-CARBA-1 '(2') a-HOMOS (C60-Ih) [5,6] FULLERENA
Hovakimyan LITERARY GERONTOLOGY AS A NEW AREA OF RESEARCH
Твердохлебова et al. Phonetic smile
Журавлева et al. MIEPS
RU2010131802A (en) METHOD FOR PRODUCING ADAMANTANOL-1
RU2012145643A (en) METHOD FOR SELECTIVE PRODUCTION OF 1'-ALKYL-1'-S-PENTYL-CARBOTIOYL-CYCLOPROPA [2 ', 3': 1,9] (C60-Ih) [5,6] FULLERENES

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20120923