RU2008132805A - Аппарат для получения синтез-газа - Google Patents
Аппарат для получения синтез-газа Download PDFInfo
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- RU2008132805A RU2008132805A RU2008132805/12A RU2008132805A RU2008132805A RU 2008132805 A RU2008132805 A RU 2008132805A RU 2008132805/12 A RU2008132805/12 A RU 2008132805/12A RU 2008132805 A RU2008132805 A RU 2008132805A RU 2008132805 A RU2008132805 A RU 2008132805A
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- pipe
- ceramic material
- gas stream
- oxides
- synthesis gas
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- 230000015572 biosynthetic process Effects 0.000 title claims abstract 7
- 238000003786 synthesis reaction Methods 0.000 title claims abstract 7
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract 17
- 239000007789 gas Substances 0.000 claims abstract 12
- 238000006243 chemical reaction Methods 0.000 claims abstract 6
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 5
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 3
- 150000001247 metal acetylides Chemical class 0.000 claims abstract 3
- 239000001301 oxygen Substances 0.000 claims abstract 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 2
- 230000008021 deposition Effects 0.000 claims abstract 2
- 238000001125 extrusion Methods 0.000 claims abstract 2
- 230000003647 oxidation Effects 0.000 claims abstract 2
- 238000007254 oxidation reaction Methods 0.000 claims abstract 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical class [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract 2
- 150000002910 rare earth metals Chemical class 0.000 claims abstract 2
- 238000002407 reforming Methods 0.000 claims abstract 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract 2
- 238000005245 sintering Methods 0.000 claims abstract 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract 2
- 239000011810 insulating material Substances 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 239000000919 ceramic Substances 0.000 claims 3
- 239000000835 fiber Substances 0.000 claims 3
- 239000000945 filler Substances 0.000 claims 3
- 239000002657 fibrous material Substances 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 229910052747 lanthanoid Inorganic materials 0.000 claims 1
- 150000002602 lanthanoids Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 150000004767 nitrides Chemical class 0.000 claims 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims 1
- -1 silicon dioxide Chemical compound 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
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- B01J7/00—Apparatus for generating gases
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
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- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
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- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
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- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
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- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
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- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00504—Controlling the temperature by means of a burner
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- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/0015—Controlling the temperature by thermal insulation means
- B01J2219/00155—Controlling the temperature by thermal insulation means using insulating materials or refractories
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- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/02—Apparatus characterised by their chemically-resistant properties
- B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
- B01J2219/0218—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components of ceramic
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- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/02—Apparatus characterised by their chemically-resistant properties
- B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
- B01J2219/0263—Ceramic
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0211—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
- C01B2203/0216—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic steam reforming step
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- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0211—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
- C01B2203/0222—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic carbon dioxide reforming step
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- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
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- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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Abstract
1. Аппарат (1) для получения синтез-газа, содержащий по существу цилиндрическую оболочку (2), закрытую с противоположных сторон днищами (3, 4), по меньшей мере одно впускное отверстие (8) для подачи газового потока, содержащего кислород, по меньшей мере одно впускное отверстие (7) для газового потока, содержащего углеводороды, по меньшей мере одно выпускное отверстие для потока синтез-газа, и по меньшей мере одну горелку (9), сообщающуюся с реакционной камерой (15) для частичного окисления и(или) риформинга углеводородов с получением потока синтез-газа, отличающийся тем, что он содержит трубу (12) из керамического материала, проходящую внутри оболочки (2), при этом внутреннее пространство этой трубы (12) из керамического материала образует реакционную камеру (15). ! 2. Аппарат (1) по п.1, отличающийся тем, что труба (12) из керамического материала по существу коаксиальна с оболочкой (2). ! 3. Аппарат (1) по п.1, отличающийся тем, что толщина трубы (12) из керамического материала составляет от 5 до 50 мм, предпочтительно от 20 до 50 мм. ! 4. Аппарат (1) по п.1, отличающийся тем, что труба (12) из керамического материала изготавливается технологией экструзионного прессования и спекания керамического материала, или плазменного осаждения. ! 5. Аппарат (1) по п.1, отличающийся тем, что керамический материал, используемый для изготовления трубы (12), содержит спеченные оксиды алюминия и(или) оксиды циркония, и(или) карбиды, такие как карбиды кремния и(или) оксиды редкоземельных металлов. ! 6. Аппарат (1) по п.1, отличающийся тем, что труба (12) из керамического материала выполнена из стыкуемых друг с другом отрезков трубы. ! 7. Аппарат (1) по п.1, отличающийся тем, что часть трубы
Claims (15)
1. Аппарат (1) для получения синтез-газа, содержащий по существу цилиндрическую оболочку (2), закрытую с противоположных сторон днищами (3, 4), по меньшей мере одно впускное отверстие (8) для подачи газового потока, содержащего кислород, по меньшей мере одно впускное отверстие (7) для газового потока, содержащего углеводороды, по меньшей мере одно выпускное отверстие для потока синтез-газа, и по меньшей мере одну горелку (9), сообщающуюся с реакционной камерой (15) для частичного окисления и(или) риформинга углеводородов с получением потока синтез-газа, отличающийся тем, что он содержит трубу (12) из керамического материала, проходящую внутри оболочки (2), при этом внутреннее пространство этой трубы (12) из керамического материала образует реакционную камеру (15).
2. Аппарат (1) по п.1, отличающийся тем, что труба (12) из керамического материала по существу коаксиальна с оболочкой (2).
3. Аппарат (1) по п.1, отличающийся тем, что толщина трубы (12) из керамического материала составляет от 5 до 50 мм, предпочтительно от 20 до 50 мм.
4. Аппарат (1) по п.1, отличающийся тем, что труба (12) из керамического материала изготавливается технологией экструзионного прессования и спекания керамического материала, или плазменного осаждения.
5. Аппарат (1) по п.1, отличающийся тем, что керамический материал, используемый для изготовления трубы (12), содержит спеченные оксиды алюминия и(или) оксиды циркония, и(или) карбиды, такие как карбиды кремния и(или) оксиды редкоземельных металлов.
6. Аппарат (1) по п.1, отличающийся тем, что труба (12) из керамического материала выполнена из стыкуемых друг с другом отрезков трубы.
7. Аппарат (1) по п.1, отличающийся тем, что часть трубы (12) из керамического материала содержит каталитический слой (31), который делит реакционную камеру (15) на две различные зоны реакции (32, 33).
8. Аппарат (1) по п.1, отличающийся тем, что он дополнительно включает промежуток (13) между трубой (12) из керамического материала и оболочкой (20), причем промежуток (13) по существу заполнен изолирующим материалом.
9. Аппарат (1) по п.1, отличающийся тем, что упомянутый изолирующий материал является волокнистым материалом, неволокнистым материалом или их смесью.
10. Аппарат (1) по п.9, отличающийся тем, что волокнистый или неволокнистый изолирующий материал выбран из группы, содержащей жаропрочные оксиды, жаропрочные нитриды, жаропрочные карбиды и их комбинации.
11. Аппарат (1) по п.9, отличающийся тем, что волокнистый или неволокнистый изолирующий материал включает один или более оксидов металла, выбранных из группы, содержащей оксид алюминия, оксиды кремния, такой как диоксид кремния, оксиды редкоземельных металлов (лантаноиды) и их смеси.
12. Аппарат (1) по п.8 или 9, отличающийся тем, что изолирующий наполнитель выполнен в виде свободных волокон, ленты, войлока тканого или нетканого материала.
13. Аппарат (1) по п.8 или 9, отличающийся тем, что изолирующий наполнитель выполнен в виде керамических волокон.
14. Аппарат (1) по п.13, отличающийся тем, что изолирующий наполнитель одержит керамические волокна из оксида алюминия или оксида кремния.
15. Аппарат (1) по п.1, отличающийся тем, что по меньшей мере одна горелка (9) по меньшей мере частично вставлена в кожух (6), выполненный в форме горловины (4а) верхнего днища (4) и имеет по меньшей мере одно впускное отверстие (8) для подачи газового потока, содержащего кислород, и по меньшей мере одно впускное отверстие (7) для газового потока, содержащего углеводороды.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06000429A EP1806176A1 (en) | 2006-01-10 | 2006-01-10 | Apparatus for the production of synthesis gas |
EP06000429.8 | 2006-01-10 |
Publications (2)
Publication Number | Publication Date |
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RU2008132805A true RU2008132805A (ru) | 2010-02-20 |
RU2407585C2 RU2407585C2 (ru) | 2010-12-27 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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RU2008132805/21A RU2407585C2 (ru) | 2006-01-10 | 2006-12-22 | Аппарат для получения синтез-газа |
Country Status (13)
Country | Link |
---|---|
US (2) | US20090220395A1 (ru) |
EP (2) | EP1806176A1 (ru) |
CN (1) | CN101355999B (ru) |
AT (1) | ATE433345T1 (ru) |
AU (1) | AU2006334769B2 (ru) |
BR (1) | BRPI0620930B1 (ru) |
CA (1) | CA2636723C (ru) |
DE (1) | DE602006007244D1 (ru) |
DK (1) | DK1973640T4 (ru) |
EG (1) | EG25399A (ru) |
RU (1) | RU2407585C2 (ru) |
SA (1) | SA07270498B1 (ru) |
WO (1) | WO2007079954A1 (ru) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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EP2703339A1 (en) * | 2012-09-04 | 2014-03-05 | Casale Chemicals S.A. | Burner for the production of synthesis gas |
DE102013020856A1 (de) * | 2013-12-12 | 2015-06-18 | Linde Aktiengesellschaft | Reformerrohr und Einrichtung sowie Verfahren zur Herstellung eines Synthesegases |
WO2017012881A1 (en) | 2015-07-23 | 2017-01-26 | Casale Sa | Apparatus for the production of synthesis gas |
US10364398B2 (en) | 2016-08-30 | 2019-07-30 | Thermochem Recovery International, Inc. | Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas |
US11555157B2 (en) * | 2020-03-10 | 2023-01-17 | Thermochem Recovery International, Inc. | System and method for liquid fuel production from carbonaceous materials using recycled conditioned syngas |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
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BE543073A (ru) * | 1954-09-18 | 1900-01-01 | ||
DE3040712A1 (de) * | 1980-10-29 | 1982-05-27 | W.C. Heraeus Gmbh, 6450 Hanau | Reaktionsbehaelter |
US4709643A (en) * | 1987-02-24 | 1987-12-01 | Prutech Ii | Primary stage combustor lining |
CA1332220C (en) * | 1988-09-06 | 1994-10-04 | Arthur Albert Lietz | Erosion resistant, ceramic fiber lining |
US5567398A (en) * | 1990-04-03 | 1996-10-22 | The Standard Oil Company | Endothermic reaction apparatus and method |
US5254318A (en) * | 1992-07-20 | 1993-10-19 | Stone & Webster Engineering Corporation | Lined reformer tubes for high pressure reformer reactors |
SE501345C2 (sv) * | 1993-06-10 | 1995-01-23 | Kvaerner Pulping Tech | Reaktor för förgasning och partiell förbränning |
US20020182132A1 (en) * | 2000-10-04 | 2002-12-05 | Lesieur Roger R. | Fuel gas reformer assemblage |
EP1419812B1 (en) * | 2002-11-15 | 2015-09-16 | Haldor Topsoe A/S | High temperature fixed bed reactor and its use |
DE10320965B4 (de) * | 2003-05-09 | 2012-03-15 | Linde Ag | Vorrichtung zur reaktiven Umsetzung von Gasströmen |
DE10320966A1 (de) † | 2003-05-09 | 2004-11-25 | Linde Ag | Wärmeisolierter Hochtemperaturreaktor |
US8652421B2 (en) * | 2005-11-03 | 2014-02-18 | Emd Millipore Corporation | Immunoassay product and process |
-
2006
- 2006-01-10 EP EP06000429A patent/EP1806176A1/en not_active Withdrawn
- 2006-12-22 AT AT06841115T patent/ATE433345T1/de not_active IP Right Cessation
- 2006-12-22 BR BRPI0620930A patent/BRPI0620930B1/pt active IP Right Grant
- 2006-12-22 EP EP06841115.6A patent/EP1973640B2/en active Active
- 2006-12-22 CA CA2636723A patent/CA2636723C/en active Active
- 2006-12-22 US US12/159,181 patent/US20090220395A1/en not_active Abandoned
- 2006-12-22 WO PCT/EP2006/012429 patent/WO2007079954A1/en active Search and Examination
- 2006-12-22 CN CN200680050788.0A patent/CN101355999B/zh active Active
- 2006-12-22 DK DK06841115.6T patent/DK1973640T4/en active
- 2006-12-22 RU RU2008132805/21A patent/RU2407585C2/ru active
- 2006-12-22 DE DE602006007244T patent/DE602006007244D1/de active Active
- 2006-12-22 AU AU2006334769A patent/AU2006334769B2/en active Active
-
2007
- 2007-01-07 SA SA7270498A patent/SA07270498B1/ar unknown
-
2008
- 2008-07-07 EG EG2008071150A patent/EG25399A/xx active
-
2013
- 2013-03-21 US US13/848,574 patent/US20130216447A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
DK1973640T4 (en) | 2015-11-16 |
US20090220395A1 (en) | 2009-09-03 |
EG25399A (en) | 2011-12-27 |
BRPI0620930A2 (pt) | 2011-11-29 |
CN101355999A (zh) | 2009-01-28 |
WO2007079954A1 (en) | 2007-07-19 |
BRPI0620930B1 (pt) | 2016-11-01 |
CA2636723C (en) | 2015-04-07 |
EP1973640B2 (en) | 2015-08-05 |
AU2006334769A1 (en) | 2007-07-19 |
RU2407585C2 (ru) | 2010-12-27 |
DE602006007244D1 (de) | 2009-07-23 |
EP1973640A1 (en) | 2008-10-01 |
DK1973640T3 (da) | 2009-10-12 |
US20130216447A1 (en) | 2013-08-22 |
EP1806176A1 (en) | 2007-07-11 |
CA2636723A1 (en) | 2007-07-19 |
AU2006334769B2 (en) | 2010-07-29 |
CN101355999B (zh) | 2012-01-04 |
ATE433345T1 (de) | 2009-06-15 |
EP1973640B1 (en) | 2009-06-10 |
SA07270498B1 (ar) | 2010-10-05 |
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