RU2007126041A - METHOD FOR PRODUCING 10,11-DIALKYL-9-MAGNESIZABLE [6.3.0] UNDEKA-1 (8), 10-DIENOV - Google Patents

METHOD FOR PRODUCING 10,11-DIALKYL-9-MAGNESIZABLE [6.3.0] UNDEKA-1 (8), 10-DIENOV Download PDF

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RU2007126041A
RU2007126041A RU2007126041/04A RU2007126041A RU2007126041A RU 2007126041 A RU2007126041 A RU 2007126041A RU 2007126041/04 A RU2007126041/04 A RU 2007126041/04A RU 2007126041 A RU2007126041 A RU 2007126041A RU 2007126041 A RU2007126041 A RU 2007126041A
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undeka
dialkyl
magnesizable
dienov
producing
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RU2007126041/04A
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RU2355695C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
конов Владимир Анатольевич Дь (RU)
Владимир Анатольевич Дьяконов
Регина Адиковна Зиннурова (RU)
Регина Адиковна Зиннурова
Алексей Александрович Макаров (RU)
Алексей Александрович Макаров
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
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Институт нефтехимии и катализа РАН (RU)
Институт нефтехимии и катализа РАН
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Claims (1)

Способ получения 10,11-диалкил-9-магнезабицикло[6.3.0]ундека-1(8),10-диенов общей формулы (1)The method of obtaining 10,11-dialkyl-9-magnesabicyclo [6.3.0] undeka-1 (8), 10-dienes of the general formula (1)
Figure 00000001
Figure 00000001
 характеризующийся тем, что смесь циклооктина и диалкилацетилена (гекс-3-ин, окт-4-ин, дец-5-ин) подвергают взаимодействию с н-BuMgCl в присутствии катализатора цирконацендихлорида Cp2ZrCl2 в мольном соотношении циклооктин:диалкилацетилен:н-BuMgCl:Cp2ZrCl2=10:10:(22-26):(1.0-1.4) в атмосфере аргона при нормальном давлении в диэтиловом эфире, при комнатной температуре в течение 5-7 ч. characterized in that the mixture of cyclooctin and dialkylacetylene (hex-3-in, oct-4-in, dec-5-in) is reacted with n-BuMgCl in the presence of a Cp 2 ZrCl 2 zirconacene dichloride catalyst in a cyclooctin: dialkylacetylene: n- molar ratio BuMgCl: Cp 2 ZrCl 2 = 10: 10: (22-26) :( 1.0-1.4) in an argon atmosphere at normal pressure in diethyl ether, at room temperature for 5-7 hours.
RU2007126041/04A 2007-07-09 2007-07-09 Method of obtaining 10,11-dialkyl-9-magnesabicyclo[6,3,0]undeca-1(8),10-dienes RU2355695C2 (en)

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RU2007126041/04A RU2355695C2 (en) 2007-07-09 2007-07-09 Method of obtaining 10,11-dialkyl-9-magnesabicyclo[6,3,0]undeca-1(8),10-dienes

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RU2007126041/04A RU2355695C2 (en) 2007-07-09 2007-07-09 Method of obtaining 10,11-dialkyl-9-magnesabicyclo[6,3,0]undeca-1(8),10-dienes

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RU2355695C2 RU2355695C2 (en) 2009-05-20

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