RU2008106330A - METHOD FOR PRODUCING TRICYCLO [4.2.1.02,5] NONAN-3-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE) - Google Patents

METHOD FOR PRODUCING TRICYCLO [4.2.1.02,5] NONAN-3-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE) Download PDF

Info

Publication number
RU2008106330A
RU2008106330A RU2008106330/04A RU2008106330A RU2008106330A RU 2008106330 A RU2008106330 A RU 2008106330A RU 2008106330/04 A RU2008106330/04 A RU 2008106330/04A RU 2008106330 A RU2008106330 A RU 2008106330A RU 2008106330 A RU2008106330 A RU 2008106330A
Authority
RU
Russia
Prior art keywords
tricyclo
aluminacyclopentane
spiro
ethyl
nonane
Prior art date
Application number
RU2008106330/04A
Other languages
Russian (ru)
Other versions
RU2381230C2 (en
Inventor
Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов (RU)
Владимир Анатольевич Дьяконов
Ольга Александровна Трапезникова (RU)
Ольга Александровна Трапезникова
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Леонард Мухибович Халилов (RU)
Леонард Мухибович Халилов
Татьяна Викторовна Тюмкина (RU)
Татьяна Викторовна Тюмкина
Original Assignee
ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU)
ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU), ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук filed Critical ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU)
Priority to RU2008106330/04A priority Critical patent/RU2381230C2/en
Publication of RU2008106330A publication Critical patent/RU2008106330A/en
Application granted granted Critical
Publication of RU2381230C2 publication Critical patent/RU2381230C2/en

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ получения тpициклo[4.2.1.02,5]нoнaн-3-cпиpo(3'-этил-3'-алюминациклопентана) общей формулы (1) ! ! характеризующийся тем, что 3-метилентрицикло[4.2.1.02,5]нонан подвергают взаимодействию с триэтилалюминием (Еt3Аl) в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении 3-метилен-тpициклo[4.2.1.02,5]нoнaн:Et3Al:Cp2ZrCl2=10:(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в гексане в течение 8-12 ч.The method of producing tricyclo [4.2.1.02,5] nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane) of the general formula (1)! ! characterized in that 3-methylene tricyclo [4.2.1.02.5] nonane is reacted with triethylaluminium (Et3Al) in the presence of a zirconacenedichloride catalyst (Cp2ZrCl2) in a molar ratio of 3-methylene-tricyclo [4.2.1.02.5] nonane: Et3Al: Cp2ZrCl 10: (10-14) :( 0.4-0.6) in an argon atmosphere at a temperature of 20 ° C and normal pressure in hexane for 8-12 hours.

Claims (1)

Способ получения тpициклo[4.2.1.02,5]нoнaн-3-cпиpo(3'-этил-3'-алюминациклопентана) общей формулы (1)The method of obtaining tricyclo [4.2.1.0 2,5 ] nonan-3-spiro (3'-ethyl-3'-aluminacyclopentane) of the general formula (1)
Figure 00000001
Figure 00000001
 характеризующийся тем, что 3-метилентрицикло[4.2.1.02,5]нонан подвергают взаимодействию с триэтилалюминием (Еt3Аl) в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении 3-метилен-тpициклo[4.2.1.02,5]нoнaн:Et3Al:Cp2ZrCl2=10:(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в гексане в течение 8-12 ч. characterized in that 3-methylene tricyclo [4.2.1.0 2,5 ] nonane is reacted with triethylaluminium (Et 3 Al) in the presence of a zirconacenedichloride catalyst (Cp 2 ZrCl 2 ) in a molar ratio of 3-methylene-tricyclo [4.2.1.0 2,5 ] nonane: Et 3 Al: Cp 2 ZrCl 2 = 10: (10-14) :( 0.4-0.6) in an argon atmosphere at a temperature of 20 ° С and normal pressure in hexane for 8-12 h.
RU2008106330/04A 2008-02-18 2008-02-18 Method of producing tricyclo[4.2.1.02,5]nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane) RU2381230C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2008106330/04A RU2381230C2 (en) 2008-02-18 2008-02-18 Method of producing tricyclo[4.2.1.02,5]nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2008106330/04A RU2381230C2 (en) 2008-02-18 2008-02-18 Method of producing tricyclo[4.2.1.02,5]nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane)

Publications (2)

Publication Number Publication Date
RU2008106330A true RU2008106330A (en) 2009-08-27
RU2381230C2 RU2381230C2 (en) 2010-02-10

Family

ID=41149290

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2008106330/04A RU2381230C2 (en) 2008-02-18 2008-02-18 Method of producing tricyclo[4.2.1.02,5]nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane)

Country Status (1)

Country Link
RU (1) RU2381230C2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2594560C2 (en) * 2014-11-21 2016-08-20 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method for producing 2,6,8,11-tetraethyl-4-aryl-1,7-dithia-4-aza-2,6,8,11-tetraaluminacikloundecanes
RU2584686C1 (en) * 2014-11-21 2016-05-20 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method for combined synthesis of 2,6,8,11-tetraethyl-4-phenyl-1,7-dithia-4-aza-2,6,8,11-tetraaluminacycloundecane and 2,4,7,9,12-pentaethyl-5-phenyl-18-dithia-5-aza-2,4,7,9,12-pentaaluminacyclododecane

Also Published As

Publication number Publication date
RU2381230C2 (en) 2010-02-10

Similar Documents

Publication Publication Date Title
EP2520633A3 (en) Phosphor and light emitting device
EP2562546A3 (en) Detection of endometrial secretion markers for assesment of endometriosis& xA;
TW200619205A (en) A method for preparing irbesartan and intermediates thereof
RU2008106330A (en) METHOD FOR PRODUCING TRICYCLO [4.2.1.02,5] NONAN-3-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE)
RU2008106383A (en) METHOD FOR TOGETHER TETRACYCLO [5.4.1.02,6.08,11] DODETS-3-EN-9-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE) AND TETRACYCLO [5.4.1.02,6.08,11] DODETS-4-EN- 9-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE)
RU2009118676A (en) METHOD FOR PRODUCING EXO-TRICYCLO [4.2.1.02,5] NON-7-EN-3-SPIRO-1 '- (3'-Ethyl-3'-ALUMIN) CYCLOPENTANE
RU2007103617A (en) METHOD FOR PRODUCING 6-ETHYL-6-ALUMINASPIRO [3.4] OCTAN
RU2007103618A (en) METHOD FOR PRODUCING 1-ETHYL-1,2,3,3a, 4,5,6,7,8,9-DECAHYDROCYCLONON [b] ALUMINACYCLOPENTANE
RU2007103641A (en) METHOD FOR PRODUCING 1-ETHYL-2,3,4,5,6,7,8,9-OCTAGHYDRO-1H-CYCLOOCT- [b] -ALUMINACYCLOPENTENE
RU2008143882A (en) METHOD FOR PRODUCING EXO-PENTACYCLO [5.4.0.02,9.03,6.08,10] UNDEKAN-4-SPIRO-1 '- (3'-Ethyl-3'-ALUMIN) CYCLOPENTANE
RU2008143821A (en) METHOD FOR PRODUCING EXO-TRICYCLO [4.2.1.02,5] NONAN-3-SPIRO-1 '- (3'-SELENIUM) CYCLOPENTANE
RU2008143795A (en) METHOD FOR PRODUCING EXO-TRICYCLO [4.2.1.02,5] NONAN-3-SPIRO-1 '- (3'-TIA) CYCLOPENTANE
RU2010141245A (en) METHOD FOR PRODUCING METHYL ETHER 2-BENZO [b] FURANCARBOXYLIC ACID
RU2009123085A (en) METHOD FOR PRODUCING 2,3,4-TRIALKYLMAGNESACYCLOPENT-2-ENOV
RU2008102176A (en) METHOD FOR PRODUCING DIISOBUTYL [(2-Isobutyl-1-Alkylcyclopropyl) Ethyl] Alanes
RU2011124568A (en) METHOD FOR PRODUCING α, ω-BIS- (1,5,3-DITIAZEPINAN-3-IL) ALKANOV
RU2008105278A (en) METHOD FOR PRODUCING 11-MAGNESATRICYCLO [10.7.01,12.02,10] NONADEKA-9,12-DIENE
RU2007111455A (en) METHOD FOR PRODUCING 1,2,3,3A, 4,5,6,7,8,9-DECAHYDROCYCLONON [B] -MAGNESACYCLOPENTANE
RU2010141244A (en) METHOD FOR PRODUCING METHYL ETHER 2-BENZO [b] FURANCARBOXYLIC ACID
RU2007122004A (en) METHOD FOR PRODUCING 10-ETHYL-11, 12-DIALKYL-10-ALUMINABicyclo [7.3.01.9] DODECA-8, 11-DIENOV
RU2008105515A (en) METHOD FOR PRODUCING 9-ETHYL-11-ALKYL-9-ALUMINABicyclo [6.3.01.8] UNDEC-1 (8) -ENES
RU2009127289A (en) METHOD FOR PRODUCING 1-ETHYL-2,3-DIALKYL (PHENYL) ALUMINACYCLOPENT-2-ENOV
RU2009124699A (en) METHOD FOR PRODUCING 1-BROMADAMANTHANE
RU2008105285A (en) METHOD FOR PRODUCING 2,5-DIALKYL (2,2,5,5-TETRAALKYL) -3,4-FULLERO [60] TETRAHYDROFURANES
RU2007137616A (en) METHOD FOR OBTAINING AN OPTICALLY ACTIVE COMPLEX OF CYCLOPENTADIENYL-1-NEOMENTIL-4,5,6,7-TETRAHYDROINDENYL ZIRCONIUM

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20110219