RU2007111455A -
METHOD FOR PRODUCING 1,2,3,3A, 4,5,6,7,8,9-DECAHYDROCYCLONON [B] -MAGNESACYCLOPENTANE
- Google Patents
METHOD FOR PRODUCING 1,2,3,3A, 4,5,6,7,8,9-DECAHYDROCYCLONON [B] -MAGNESACYCLOPENTANE
Download PDF
Info
Publication number
RU2007111455A
RU2007111455ARU2007111455/04ARU2007111455ARU2007111455ARU 2007111455 ARU2007111455 ARU 2007111455ARU 2007111455/04 ARU2007111455/04 ARU 2007111455/04ARU 2007111455 ARU2007111455 ARU 2007111455ARU 2007111455 ARU2007111455 ARU 2007111455A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Институт нефтехимии и катализа РАН (RU), Институт нефтехимии и катализа РАНfiledCriticalИнститут нефтехимии и катализа РАН (RU)
Priority to RU2007111455/04ApriorityCriticalpatent/RU2342390C1/en
Publication of RU2007111455ApublicationCriticalpatent/RU2007111455A/en
Application grantedgrantedCritical
Publication of RU2342390C1publicationCriticalpatent/RU2342390C1/en
Organic Low-Molecular-Weight Compounds And Preparation Thereof
(AREA)
Claims (1)
Способ получения 1,2,3,3а,4,5,6,7,8,9-декагидроциклонона[b]магнезациклопентана(1),The method of obtaining 1,2,3,3a, 4,5,6,7,8,9-decahydrocyclonone [b] magnesacyclopentane (1),
характеризующийся тем, что 1,2-нонадиен подвергают взаимодействию с диэтилмагнием Et2Mg в присутствии катализатора цирконацендихлорида Cp2ZrCl2 при мольном соотношении 1,2-нонадиен: Et2Mg:Cp2ZrCl2=10:(10-14):(0,4-0,6) в атмосфере аргона при нормальном давлении и комнатной температуре, в диэтиловом эфире, в течение 8-12 ч.characterized in that the 1,2-nonadiene is reacted with diethyl magnesium Et 2 Mg in the presence of a catalyst of zirconacene dichloride Cp 2 ZrCl 2 at a molar ratio of 1,2 nonadiene: Et 2 Mg: Cp 2 ZrCl 2 = 10: (10-14): (0.4-0.6) in an argon atmosphere at normal pressure and room temperature, in diethyl ether, for 8-12 hours
RU2007111455/04A2007-03-282007-03-28METHOD OF OBTAINING 1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]-MAGNESACYCLOPENTANE
RU2342390C1
(en)
METHOD FOR TOGETHER TETRACYCLO [5.4.1.02,6.08,11] DODETS-3-EN-9-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE) AND TETRACYCLO [5.4.1.02,6.08,11] DODETS-4-EN- 9-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE)
