RU2001125922A - Способ селективного окисления первичных спиртов и новые углеводные альдегиды - Google Patents
Способ селективного окисления первичных спиртов и новые углеводные альдегиды Download PDFInfo
- Publication number
- RU2001125922A RU2001125922A RU2001125922/13A RU2001125922A RU2001125922A RU 2001125922 A RU2001125922 A RU 2001125922A RU 2001125922/13 A RU2001125922/13 A RU 2001125922/13A RU 2001125922 A RU2001125922 A RU 2001125922A RU 2001125922 A RU2001125922 A RU 2001125922A
- Authority
- RU
- Russia
- Prior art keywords
- carbohydrate
- group
- carbaldehyde
- monosaccharide
- primary alcohol
- Prior art date
Links
- 150000001720 carbohydrates Chemical class 0.000 title claims abstract 15
- 238000000034 method Methods 0.000 title claims abstract 15
- 230000003647 oxidation Effects 0.000 title claims abstract 5
- 238000007254 oxidation reaction Methods 0.000 title claims abstract 5
- 150000003138 primary alcohols Chemical class 0.000 title claims 6
- -1 nitrosonium ions Chemical class 0.000 claims abstract 7
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims abstract 6
- 239000007800 oxidant agent Substances 0.000 claims abstract 4
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000001483 monosaccharide substituent group Chemical group 0.000 claims 6
- 102000004190 Enzymes Human genes 0.000 claims 5
- 108090000790 Enzymes Proteins 0.000 claims 5
- 229940088598 enzyme Drugs 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 229920002670 Fructan Polymers 0.000 claims 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- 150000001719 carbohydrate derivatives Chemical class 0.000 claims 2
- 125000004122 cyclic group Chemical group 0.000 claims 2
- 229930182470 glycoside Natural products 0.000 claims 2
- 150000002431 hydrogen Chemical group 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- VUZNLSBZRVZGIK-UHFFFAOYSA-N 2,2,6,6-Tetramethyl-1-piperidinol Chemical group CC1(C)CCCC(C)(C)N1O VUZNLSBZRVZGIK-UHFFFAOYSA-N 0.000 claims 1
- 108010011619 6-Phytase Proteins 0.000 claims 1
- 229920000310 Alpha glucan Polymers 0.000 claims 1
- 229920002101 Chitin Polymers 0.000 claims 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229920001503 Glucan Polymers 0.000 claims 1
- 244000068988 Glycine max Species 0.000 claims 1
- 235000010469 Glycine max Nutrition 0.000 claims 1
- 108010001336 Horseradish Peroxidase Proteins 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 108090000604 Hydrolases Proteins 0.000 claims 1
- 102000004157 Hydrolases Human genes 0.000 claims 1
- 108010029541 Laccase Proteins 0.000 claims 1
- 102100038609 Lactoperoxidase Human genes 0.000 claims 1
- 108010023244 Lactoperoxidase Proteins 0.000 claims 1
- 108010054320 Lignin peroxidase Proteins 0.000 claims 1
- 102000004882 Lipase Human genes 0.000 claims 1
- 108090001060 Lipase Proteins 0.000 claims 1
- 239000004367 Lipase Substances 0.000 claims 1
- 229920000057 Mannan Polymers 0.000 claims 1
- 102000003896 Myeloperoxidases Human genes 0.000 claims 1
- 108090000235 Myeloperoxidases Proteins 0.000 claims 1
- 102000004316 Oxidoreductases Human genes 0.000 claims 1
- 108090000854 Oxidoreductases Proteins 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 150000004696 coordination complex Chemical class 0.000 claims 1
- 150000002016 disaccharides Chemical class 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 229950006191 gluconic acid Drugs 0.000 claims 1
- 150000004676 glycans Chemical class 0.000 claims 1
- 150000002338 glycosides Chemical class 0.000 claims 1
- 229940057428 lactoperoxidase Drugs 0.000 claims 1
- 235000019421 lipase Nutrition 0.000 claims 1
- 239000002609 medium Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229920001542 oligosaccharide Polymers 0.000 claims 1
- 150000002482 oligosaccharides Chemical class 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 102000013415 peroxidase activity proteins Human genes 0.000 claims 1
- 108040007629 peroxidase activity proteins Proteins 0.000 claims 1
- 229940085127 phytase Drugs 0.000 claims 1
- 229920001282 polysaccharide Polymers 0.000 claims 1
- 239000005017 polysaccharide Substances 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- 235000014633 carbohydrates Nutrition 0.000 abstract 1
- 239000008139 complexing agent Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 150000002772 monosaccharides Chemical group 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/24—Preparation of oxygen-containing organic compounds containing a carbonyl group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P19/00—Preparation of compounds containing saccharide radicals
- C12P19/04—Polysaccharides, i.e. compounds containing more than five saccharide radicals attached to each other by glycosidic bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Saccharide Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Compounds Of Unknown Constitution (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99200536 | 1999-02-24 | ||
| EP99200536.3 | 1999-02-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2001125922A true RU2001125922A (ru) | 2005-03-10 |
Family
ID=8239920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2001125922/13A RU2001125922A (ru) | 1999-02-24 | 2000-02-24 | Способ селективного окисления первичных спиртов и новые углеводные альдегиды |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US6875861B1 (enExample) |
| EP (2) | EP1173409B8 (enExample) |
| JP (2) | JP2004512805A (enExample) |
| KR (1) | KR20010102361A (enExample) |
| AT (1) | ATE308514T1 (enExample) |
| AU (2) | AU773835B2 (enExample) |
| BR (2) | BR0008478A (enExample) |
| CA (1) | CA2362717A1 (enExample) |
| CZ (1) | CZ20013042A3 (enExample) |
| DE (1) | DE60023680T2 (enExample) |
| DK (1) | DK1173409T3 (enExample) |
| ES (1) | ES2255979T3 (enExample) |
| HU (2) | HUP0200203A2 (enExample) |
| MX (1) | MXPA01008603A (enExample) |
| NZ (1) | NZ513649A (enExample) |
| PL (2) | PL350567A1 (enExample) |
| RU (1) | RU2001125922A (enExample) |
| WO (2) | WO2000050388A1 (enExample) |
| ZA (2) | ZA200106737B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2573904C2 (ru) * | 2009-05-05 | 2016-01-27 | Эвоник Дегусса Гмбх | Ферментативный способ получения альдегидов |
| RU2579510C2 (ru) * | 2011-04-12 | 2016-04-10 | Эвоник Дегусса Гмбх | Непрерывный способ получения карбонильных соединений посредством содержащего нитроксильный радикал катализатора |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69713876T2 (de) | 1996-03-28 | 2003-02-13 | The Procter & Gamble Company, Cincinnati | Nassfestigkeit aufweisende papierprodukte aus aldehyd-funtionalisierten zellulosefasern und polymeren |
| US6228126B1 (en) | 1999-08-17 | 2001-05-08 | National Starch And Chemical Investment Holding Corporation | Paper prepared from aldehyde modified cellulose pulp and the method of making the pulp |
| MXPA00007979A (es) * | 1999-08-17 | 2002-03-08 | Nat Starch Chem Invest | Aldehidos de polisacaridos preparados por un metodo de oxidacion y usados como aditivos de resistencia en la fabricacion de papel. |
| US6586588B1 (en) | 1999-08-17 | 2003-07-01 | National Starch And Chemical Investment Holding Corporation | Polysaccharide aldehydes prepared by oxidation method and used as strength additives in papermaking |
| US6695950B1 (en) | 1999-08-17 | 2004-02-24 | National Starch And Chemical Investment Holding Corporation | Aldehyde modified cellulose pulp for the preparation of high strength paper products |
| US6368456B1 (en) | 1999-08-17 | 2002-04-09 | National Starch And Chemical Investment Holding Corporation | Method of making paper from aldehyde modified cellulose pulp with selected additives |
| US6582559B2 (en) | 2000-05-04 | 2003-06-24 | Sca Hygiene Products Zeist B.V. | Aldehyde-containing polymers as wet strength additives |
| US6540876B1 (en) | 2000-05-19 | 2003-04-01 | National Starch And Chemical Ivnestment Holding Corporation | Use of amide or imide co-catalysts for nitroxide mediated oxidation |
| US7138035B2 (en) | 2001-05-08 | 2006-11-21 | National Starch And Chemical Investment Holding Corporation | Process for the selective modification of carbohydrates by peroxidase catalyzed oxidation |
| KR100395653B1 (ko) * | 2001-05-29 | 2003-08-21 | 주식회사 이제 | 카르복실 키토산의 제조방법 |
| US6919447B2 (en) | 2001-06-06 | 2005-07-19 | Weyerhaeuser Company | Hypochlorite free method for preparation of stable carboxylated carbohydrate products |
| KR20030000999A (ko) * | 2001-06-28 | 2003-01-06 | 장판식 | 키틴 또는 키토산내에서 1차 알콜기만을 선택적으로산화시키는 키틴 또는 키토산의 연속 산화방법 |
| US6916466B2 (en) | 2001-07-11 | 2005-07-12 | Sca Hygiene Products Ab | Coupling of modified cyclodextrins to fibers |
| EP1329498A1 (en) * | 2002-01-18 | 2003-07-23 | Nederlandse Organisatie voor Toegepast-Natuuurwetenschappelijk Onderzoek TNO | Process for cleaning filters |
| US6789744B2 (en) * | 2002-01-29 | 2004-09-14 | Valeo Electrical Systems, Inc. | Fluid heater with a variable mass flow path |
| US7001483B2 (en) | 2003-08-05 | 2006-02-21 | Weyerhaeuser Company | Apparatus for making carboxylated pulp fibers |
| US7125469B2 (en) * | 2003-10-16 | 2006-10-24 | The Procter & Gamble Company | Temporary wet strength resins |
| JP5122821B2 (ja) | 2003-11-28 | 2013-01-16 | イーストマン ケミカル カンパニー | セルロースインターポリマー及び酸化方法 |
| US20050121160A1 (en) * | 2003-12-08 | 2005-06-09 | Sca Hygiene Products Ab | Process for the separation of organic nitrosonium and/or hydroxylamine compounds by means of cation exchange resins and recovery and oxidation processes based thereon |
| US20050154206A1 (en) * | 2003-12-08 | 2005-07-14 | Sca Hygiene Products Ab | Process for the recovery of nitroxy compounds from organic solutions and oxidation process |
| WO2005059152A1 (en) * | 2003-12-18 | 2005-06-30 | Cerestar Holding B.V. | Oxidation of carbohydrates by means of peroxidases and nitroxy radicals |
| EP1580228A1 (en) * | 2004-03-24 | 2005-09-28 | Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO | Process for gelatinising starch using a biodegradable polymer material bearing aldehyde groups |
| GB2417029A (en) | 2004-08-11 | 2006-02-15 | Sca Hygiene Prod Ab | Oxidation of hydroxyl groups using nitrosonium ions |
| JP4929581B2 (ja) * | 2004-11-01 | 2012-05-09 | 凸版印刷株式会社 | 水溶性ポリウロン酸の製造方法 |
| US7923231B2 (en) | 2004-12-17 | 2011-04-12 | Cargill, Incorporated | Production of glucuronic acid using myo-inositol oxygenase from cryptococcus neoformans |
| US7259218B2 (en) * | 2005-02-17 | 2007-08-21 | The Procter + Gamble Company | Processes for making temporary wet strength additives |
| WO2006121803A1 (en) | 2005-05-05 | 2006-11-16 | Sensient Flavors Inc. | Production of beta-glucans and mannans |
| US7932548B2 (en) * | 2006-07-14 | 2011-04-26 | 4D-S Pty Ltd. | Systems and methods for fabricating self-aligned memory cell |
| US8992728B2 (en) * | 2007-11-26 | 2015-03-31 | The University Of Tokyo | Cellulose nanofiber, production method of same and cellulose nanofiber dispersion |
| US8507256B2 (en) * | 2009-11-24 | 2013-08-13 | Foster-Miller, Inc. | Sorption reinforced catalytic coating system and method for the degradation of threat agents |
| US9446147B2 (en) * | 2011-02-24 | 2016-09-20 | The Ohio State University | Membrane stabilizing compositions and methods |
| ES2734726T3 (es) * | 2014-03-11 | 2019-12-11 | Du Pont | Poli alfa-1,2-glucano oxidado como reforzante de detergente |
| BR112021014931A2 (pt) | 2019-01-31 | 2021-09-28 | Organofuel Sweden Ab | Processo para a produção de produtos de madeira oxidada |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3632802A (en) * | 1968-12-06 | 1972-01-04 | Univ Southern Illinois | Oxidation of carbohydrates |
| JPS5054684A (enExample) | 1973-09-14 | 1975-05-14 | ||
| FR2545101B1 (fr) * | 1983-04-29 | 1985-08-16 | Agronomique Inst Nat Rech | Procede de modification des pectines de betterave, produits obtenus et leurs applications |
| US4983748A (en) | 1984-08-17 | 1991-01-08 | National Starch And Chemical Investment Holding Corporation | Acetals useful for the preparation of polysaccharide derivatives |
| DE3705785A1 (de) * | 1987-02-24 | 1988-09-01 | Basf Ag | Verfahren zur herstellung von polyenaldehyden |
| NL194919C (nl) | 1993-09-07 | 2003-07-04 | Tno | Werkwijze voor het oxideren van koolhydraten. |
| NL9301905A (nl) * | 1993-11-04 | 1995-06-01 | Inst Voor Agrotech Onderzoek | Werkwijze voor het oxideren van koolhydraten. |
| NL1000495C2 (nl) * | 1995-06-02 | 1996-12-03 | Avebe Coop Verkoop Prod | Geoxideerde polymere koolhydraatethers voor toepassing als sequestreer- middel, alsmede werkwijzen ter bereiding daarvan. |
| WO1997025468A1 (en) * | 1996-01-12 | 1997-07-17 | Novo Nordisk A/S | Fabric treated with cellulase and oxidoreductase |
| DE19723629B4 (de) * | 1997-06-05 | 2008-12-11 | Wacker Chemie Ag | Verfahren zum Behandeln von Lignin, ligninhaltigen Materialien oder ähnlichen Stoffen |
| EP0905306A1 (de) * | 1997-09-26 | 1999-03-31 | Consortium für elektrochemische Industrie GmbH | Mehrkomponentensystem zum Verändern, Abbau oder Bleichen von Lignin, ligninhaltigen Materialien sowie Verfahren zu seiner Anwendung |
| FI105690B (fi) * | 1997-11-04 | 2000-09-29 | Valtion Teknillinen | Menetelmä hapetetun tärkkelyksen valmistamiseksi |
| FI974139L (fi) * | 1997-11-04 | 1999-05-05 | Valtion Teknillinen | Menetelmä selluloosan modifioimiseksi |
| CN1309719A (zh) * | 1997-12-19 | 2001-08-22 | 诺沃奇梅兹有限公司 | 由酚氧化酶改性多糖 |
-
2000
- 2000-02-24 US US09/913,603 patent/US6875861B1/en not_active Expired - Fee Related
- 2000-02-24 AU AU28329/00A patent/AU773835B2/en not_active Ceased
- 2000-02-24 WO PCT/NL2000/000118 patent/WO2000050388A1/en not_active Ceased
- 2000-02-24 MX MXPA01008603A patent/MXPA01008603A/es not_active Application Discontinuation
- 2000-02-24 HU HU0200203A patent/HUP0200203A2/hu unknown
- 2000-02-24 JP JP2000601184A patent/JP2004512805A/ja active Pending
- 2000-02-24 PL PL00350567A patent/PL350567A1/xx not_active Application Discontinuation
- 2000-02-24 CA CA002362717A patent/CA2362717A1/en not_active Abandoned
- 2000-02-24 KR KR1020017010752A patent/KR20010102361A/ko not_active Withdrawn
- 2000-02-24 NZ NZ513649A patent/NZ513649A/en not_active IP Right Cessation
- 2000-02-24 PL PL00356989A patent/PL356989A1/xx not_active Application Discontinuation
- 2000-02-24 ES ES00906769T patent/ES2255979T3/es not_active Expired - Lifetime
- 2000-02-24 BR BR0008478-6A patent/BR0008478A/pt not_active IP Right Cessation
- 2000-02-24 EP EP00906769A patent/EP1173409B8/en not_active Expired - Lifetime
- 2000-02-24 EP EP00906768A patent/EP1177308A2/en not_active Withdrawn
- 2000-02-24 HU HU0105299A patent/HUP0105299A3/hu unknown
- 2000-02-24 JP JP2000600972A patent/JP2002537374A/ja active Pending
- 2000-02-24 RU RU2001125922/13A patent/RU2001125922A/ru unknown
- 2000-02-24 CZ CZ20013042A patent/CZ20013042A3/cs unknown
- 2000-02-24 US US09/914,182 patent/US6831173B1/en not_active Expired - Fee Related
- 2000-02-24 AU AU28328/00A patent/AU773792B2/en not_active Ceased
- 2000-02-24 DE DE60023680T patent/DE60023680T2/de not_active Expired - Lifetime
- 2000-02-24 AT AT00906769T patent/ATE308514T1/de not_active IP Right Cessation
- 2000-02-24 DK DK00906769T patent/DK1173409T3/da active
- 2000-02-24 WO PCT/NL2000/000117 patent/WO2000050621A2/en not_active Ceased
- 2000-02-24 BR BR0008474-3A patent/BR0008474A/pt not_active IP Right Cessation
-
2001
- 2001-08-15 ZA ZA200106737A patent/ZA200106737B/xx unknown
- 2001-08-20 ZA ZA200106850A patent/ZA200106850B/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2573904C2 (ru) * | 2009-05-05 | 2016-01-27 | Эвоник Дегусса Гмбх | Ферментативный способ получения альдегидов |
| RU2579510C2 (ru) * | 2011-04-12 | 2016-04-10 | Эвоник Дегусса Гмбх | Непрерывный способ получения карбонильных соединений посредством содержащего нитроксильный радикал катализатора |
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