PT606671E - Emulsoes de organossilicio para tornar hidrofugos substratos porosos - Google Patents
Emulsoes de organossilicio para tornar hidrofugos substratos porososInfo
- Publication number
- PT606671E PT606671E PT93201231T PT93201231T PT606671E PT 606671 E PT606671 E PT 606671E PT 93201231 T PT93201231 T PT 93201231T PT 93201231 T PT93201231 T PT 93201231T PT 606671 E PT606671 E PT 606671E
- Authority
- PT
- Portugal
- Prior art keywords
- units
- porous substrates
- organosilicum
- emulses
- siloxane
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 238000009877 rendering Methods 0.000 abstract 1
- 230000002940 repellent Effects 0.000 abstract 1
- 239000005871 repellent Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- -1 siloxane units Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/495—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
- C04B41/4961—Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Colloid Chemistry (AREA)
- Silicon Polymers (AREA)
- Silicon Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/003,636 US5449712A (en) | 1993-01-13 | 1993-01-13 | Organosilicon emulsions for rendering porous substrates water repellent |
Publications (1)
Publication Number | Publication Date |
---|---|
PT606671E true PT606671E (pt) | 2002-04-29 |
Family
ID=21706834
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PT93201231T PT606671E (pt) | 1993-01-13 | 1993-04-29 | Emulsoes de organossilicio para tornar hidrofugos substratos porosos |
Country Status (8)
Country | Link |
---|---|
US (1) | US5449712A (pt) |
EP (1) | EP0606671B1 (pt) |
JP (1) | JP3682782B2 (pt) |
AT (1) | ATE207506T1 (pt) |
CA (1) | CA2094063C (pt) |
DE (1) | DE69330997D1 (pt) |
ES (1) | ES2166758T3 (pt) |
PT (1) | PT606671E (pt) |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5366810A (en) * | 1992-10-09 | 1994-11-22 | General Electric Company | Water-repellent wallboard |
US5663004A (en) * | 1994-02-15 | 1997-09-02 | Xerox Corporation | Recording sheets containing mildew preventing agents |
GB2297137B (en) * | 1995-01-18 | 1999-02-03 | Uponor Ltd | Plastics pipe |
US5789476A (en) * | 1995-03-03 | 1998-08-04 | Seiko Epson Corporation | Film-forming coating solution and synthetic resin lens |
DE19517346A1 (de) * | 1995-05-11 | 1996-11-14 | Wacker Chemie Gmbh | Emulsionen von Organosiliciumverbindungen für die Hydrophobierung von Baustoffen |
US5674937A (en) * | 1995-04-27 | 1997-10-07 | Dow Corning Corporation | Elastomers from silicone emulsions having self-catalytic crosslinkers |
DE19535005A1 (de) * | 1995-09-21 | 1997-03-27 | Wacker Chemie Gmbh | Wäßrige Organopolysiloxanemulsionen sowie Emulgatoren zu deren Herstellung |
JP3481030B2 (ja) * | 1995-12-20 | 2003-12-22 | 三菱化学株式会社 | 血液分離剤の製造方法 |
DE19605674A1 (de) * | 1996-02-15 | 1997-08-21 | Wacker Chemie Gmbh | Selbstgrundierende Baustoffbeschichtungen |
US6869643B1 (en) * | 1996-02-15 | 2005-03-22 | Wacker-Chemie Gmbh | Self-priming architectural coatings |
GB9605706D0 (en) * | 1996-03-19 | 1996-05-22 | Dow Corning | Method for hydrophobing gypsum |
DE19644225A1 (de) * | 1996-10-24 | 1998-04-30 | Bayer Ag | Antifoulingbeschichtung |
JPH1149954A (ja) * | 1997-07-31 | 1999-02-23 | Toray Dow Corning Silicone Co Ltd | 離型剤 |
US6086664A (en) * | 1998-05-12 | 2000-07-11 | The Boeing Company | Efficient, environmentally acceptable method for waterproofing insulation material |
FR2780065B1 (fr) | 1998-06-17 | 2000-09-15 | Rhodia Chimie Sa | Emulsion aqueuse de resine silicone pour l'hydrofugation de materiaux de construction |
US6099971A (en) * | 1998-09-09 | 2000-08-08 | Plaskolite, Inc. | Polysiloxane abrasion and static resistant coating |
JP4083323B2 (ja) * | 1998-10-29 | 2008-04-30 | 東レ・ダウコーニング株式会社 | 有機ケイ素化合物系エマルジョンの製造方法 |
ES2212658T3 (es) * | 1998-12-10 | 2004-07-16 | Dow Corning Corporation | Emulsiones acuosas de silano estabilizadas. |
US6824879B2 (en) | 1999-06-10 | 2004-11-30 | Honeywell International Inc. | Spin-on-glass anti-reflective coatings for photolithography |
CA2374944A1 (en) | 1999-06-10 | 2000-12-21 | Nigel Hacker | Spin-on-glass anti-reflective coatings for photolithography |
US6268457B1 (en) | 1999-06-10 | 2001-07-31 | Allied Signal, Inc. | Spin-on glass anti-reflective coatings for photolithography |
US6207720B1 (en) * | 1999-06-25 | 2001-03-27 | Crompton Corporation | Hydrolyzable silane emulsions and method for preparing the same |
GB9929085D0 (en) * | 1999-12-09 | 2000-02-02 | Safeguard Chemicals Limited | Composition and method for the treatment of concrete and masonry |
US6403163B1 (en) | 2000-06-27 | 2002-06-11 | Chemrex, Inc. | Method of treating surfaces with organosilicon water repellent compositions |
FR2810989A1 (fr) | 2000-06-30 | 2002-01-04 | Rhodia Chimie Sa | Dispersion aqueuse a base base d'huiles silicone visqueuses reticulables par condensation en un elastomere, adherent utilisable notamment comme mastics ou peintures, procede de preparation |
WO2003044600A1 (en) | 2001-11-15 | 2003-05-30 | Honeywell International Inc. | Spin-on anti-reflective coatings for photolithography |
WO2004035473A1 (en) * | 2002-10-14 | 2004-04-29 | Akzo Nobel N.V. | Colloidal silica dispersion |
US7553888B2 (en) | 2002-10-14 | 2009-06-30 | Akzo Nobel N.V. | Aqueous dispersion |
US7344783B2 (en) * | 2003-07-09 | 2008-03-18 | Shell Oil Company | Durable hydrophobic surface coatings using silicone resins |
US8053159B2 (en) | 2003-11-18 | 2011-11-08 | Honeywell International Inc. | Antireflective coatings for via fill and photolithography applications and methods of preparation thereof |
KR100633177B1 (ko) * | 2005-03-24 | 2006-10-12 | 김정하 | pH 조절을 이용한 상온건조 무기도료 조성물과 그제조방법 및 용도 |
CN101189314B (zh) * | 2005-04-18 | 2012-07-04 | 陶氏康宁公司 | 含有有机硅树脂的建筑涂料组合物 |
JP5095418B2 (ja) * | 2005-12-28 | 2012-12-12 | Agcエスアイテック株式会社 | 撥水性無機粉体 |
DE102006054158A1 (de) * | 2006-11-16 | 2008-05-21 | Wacker Chemie Ag | Ultrahydrophobe Beschichtungen |
US8642246B2 (en) | 2007-02-26 | 2014-02-04 | Honeywell International Inc. | Compositions, coatings and films for tri-layer patterning applications and methods of preparation thereof |
DE102007013077A1 (de) | 2007-03-19 | 2008-09-25 | Wacker Chemie Ag | Wässrige Anstrichmittel |
JP4678411B2 (ja) * | 2008-02-22 | 2011-04-27 | 信越化学工業株式会社 | 皮膜形成性オルガノポリシロキサンエマルジョン組成物 |
KR20110079845A (ko) * | 2008-10-24 | 2011-07-08 | 다우 코닝 코포레이션 | 실리콘-함유 화합물을 함유하는 조성물 |
BRPI0916051A2 (pt) * | 2008-11-06 | 2015-11-10 | Akzo Nobel Coatings Int Bv | ''uso de um sólido que compreende pelo menos um organossilano e um material veículo para hodrofobizar argamassas, pó que comprrende pelo menos um organossilano e um material veículo apropriado para hidrofobizar argamassas, processo de fabricação de uma formulação de argamassa seca, e, formulação de argamassa seca'' |
US20100196723A1 (en) * | 2009-02-04 | 2010-08-05 | Hycrete, Inc. | Surface Applied Waterproofing Compositions And Methods For Concrete Systems |
WO2011084346A2 (en) * | 2010-01-07 | 2011-07-14 | University Of Hawaii | Corrosion protection coatings and methods of making the same |
US8557877B2 (en) | 2009-06-10 | 2013-10-15 | Honeywell International Inc. | Anti-reflective coatings for optically transparent substrates |
EP2289988A1 (de) * | 2009-08-24 | 2011-03-02 | Sika Technology AG | Zusammensetzungen auf Basis von silanterminierten Polymeren |
DE102010003579A1 (de) * | 2010-04-01 | 2011-10-06 | Evonik Degussa Gmbh | Formulierung geeignet zur Verwendung als Antigraffiti-Beschichtung mit verbesserten Benetzungseigenschaften |
US9260629B2 (en) | 2010-09-02 | 2016-02-16 | United Technologies Corporation | Hydrophobic coating for coated article |
US8864898B2 (en) | 2011-05-31 | 2014-10-21 | Honeywell International Inc. | Coating formulations for optical elements |
EP2812376A1 (en) * | 2012-02-08 | 2014-12-17 | Dow Corning Corporation | Coating applications |
WO2016167892A1 (en) | 2015-04-13 | 2016-10-20 | Honeywell International Inc. | Polysiloxane formulations and coatings for optoelectronic applications |
DE102015214501A1 (de) * | 2015-07-30 | 2017-02-02 | Wacker Chemie Ag | Wässrige Anstrichmittel |
CN108137408B (zh) * | 2015-10-12 | 2021-07-27 | 瓦克麦德龙化学私人有限公司 | 自分散性混合物硅添加剂组合物、其乳液及其用途 |
WO2017184231A1 (en) | 2016-04-20 | 2017-10-26 | Dow Corning Corporation | Lithium alkylsiliconate composition, coating, and method of making same |
KR101702863B1 (ko) * | 2016-08-22 | 2017-02-06 | 주식회사 이레하이테크이앤씨 | 콘크리트의 내구성과 표면강화성능을 증진시키는 침투성 무기계 도막 양생제 조성물 및 이의 제조방법 |
US10968418B1 (en) * | 2017-10-27 | 2021-04-06 | Group Holdings, Llc | Compositions for maintaining clean surfaces and methods for making and using clean surface technology |
US10982112B2 (en) * | 2018-02-20 | 2021-04-20 | Chemical Dynamics Llc | Hydrophobic silicone coating |
BE1026746B1 (nl) * | 2018-10-31 | 2020-06-04 | Vandersanden Steenfabrieken N V | Waterafstotend metselwerk |
CN113511836B (zh) * | 2021-08-17 | 2022-09-23 | 海南大学 | 一种建筑材料防水剂及其制备方法,以及防水蒸压加气建材 |
CN113773686B (zh) * | 2021-09-18 | 2023-04-18 | 西安为开化工科技有限公司 | 一种混凝土耐磨抗腐剂的制备方法及应用 |
Family Cites Families (35)
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US2398672A (en) * | 1942-08-21 | 1946-04-16 | Gen Electric | Method of preparing organopolysiloxanes |
US2676182A (en) * | 1950-09-13 | 1954-04-20 | Dow Corning | Copolymeric siloxanes and methods of preparing them |
US2736721A (en) * | 1952-10-08 | 1956-02-28 | Optionally | |
DE1017883B (de) * | 1954-07-08 | 1957-10-17 | Fellows Gear Shaper Co | Schalt- und Vorschubeinrichtung fuer Zahnradherstellungsmaschinen |
DE2029446C3 (de) * | 1970-06-15 | 1979-06-28 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zum Imprägnieren von Mauerwerk, Beton und Fassadenaußenputz |
US4159206A (en) * | 1977-03-18 | 1979-06-26 | Rohm And Haas Company | Weatherable, abrasion resistant coating composition, method, and coated articles |
US4175159A (en) * | 1978-07-31 | 1979-11-20 | General Electric Company | Silicone emulsions for treating silicate particulate matter |
US4433013A (en) * | 1979-05-31 | 1984-02-21 | Dynamit Nobel Aktiengesellschaft | Process for imparting hydrophobicity to mineral substrates |
US4342796A (en) * | 1980-09-10 | 1982-08-03 | Advanced Chemical Technologies, Inc. | Method for inhibiting corrosion of internal structural members of reinforced concrete |
DE3037220A1 (de) * | 1980-10-02 | 1982-04-29 | Dynamit Nobel Ag, 5210 Troisdorf | Stabile waessrige impraenierloesungen aus hydrolierten alkyltrialkoxisilanan |
US4435219A (en) * | 1982-06-02 | 1984-03-06 | Ppg Industries, Inc. | Stable inorganic coating composition for adherent, inorganic coatings |
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CA1243434A (en) * | 1983-01-28 | 1988-10-18 | Leroy E. Thayer | Siloxane-pva coating compositions |
US4525502A (en) * | 1983-05-05 | 1985-06-25 | General Electric Company | Water based resin emulsions |
DE3323908A1 (de) * | 1983-07-02 | 1985-01-10 | Bayer Ag, 5090 Leverkusen | Siliconharz-emulsion |
JPS60127371A (ja) * | 1983-12-13 | 1985-07-08 | Hoechst Gosei Kk | コロイダルシリカを主体とした無機質塗装材 |
JPS60156513A (ja) * | 1984-01-27 | 1985-08-16 | Shin Etsu Chem Co Ltd | 消泡剤組成物 |
US4525213A (en) * | 1984-03-02 | 1985-06-25 | Nox-Crete Chemicals, Incorporated | Composition for waterproofing and inhibiting erosion and corrosion of silicon dioxide containing substrates |
FR2565593B1 (fr) * | 1984-06-12 | 1986-12-12 | Rhone Poulenc Spec Chim | Compositions d'emulsions aqueuses pour le traitement antiadherent et hydrofuge de materiaux cellulosiques |
JPS61195129A (ja) * | 1985-02-22 | 1986-08-29 | Toray Silicone Co Ltd | 有機けい素重合体の製造方法 |
USRE33759E (en) * | 1986-02-14 | 1991-12-03 | Pcr Group, Inc. | Aqueous systems containing silanes for rendering masonry surfaces water repellant |
US4717599A (en) * | 1986-03-20 | 1988-01-05 | General Electric Company | Water repellent for masonry |
US4814017A (en) * | 1986-10-03 | 1989-03-21 | Ppg Industries, Inc. | Aqueous organoalkoxysilane/metal oxide sol-gel compositions |
US4990377A (en) * | 1988-05-02 | 1991-02-05 | Pcr Group, Inc. | Buffered silane emulsions having low volatile organic compounds when cured |
US4877654A (en) * | 1988-05-02 | 1989-10-31 | Pcr, Inc. | Buffered silane emulsions for rendering porous substrates water repellent |
JPH07107134B2 (ja) * | 1988-05-30 | 1995-11-15 | 信越化学工業株式会社 | シリコーンエマルジョン組成物 |
FR2638166B1 (fr) * | 1988-08-31 | 1991-01-11 | Rhone Poulenc Chimie | Dispersion aqueuse a base de resine silicone pouvant reticuler en un elastomere par elimination de l'eau |
DE3911479A1 (de) * | 1989-04-08 | 1990-10-11 | Goldschmidt Ag Th | Zubereitung zur wasserabweisenden impraegnierung poroeser mineralischer baustoffe |
US5037873A (en) * | 1989-08-08 | 1991-08-06 | Pcr Group, Inc. | Water-repellent silane emulsions comprising copolymers of acrylic acid and alkyl methacrylates |
DE3932025A1 (de) * | 1989-09-26 | 1991-04-04 | Wacker Chemie Gmbh | Waessrige dispersionen von organopolysiloxanen |
US5226954A (en) * | 1989-12-22 | 1993-07-13 | Toyo Ink Manufacturing Co., Ltd. | Organosilicon composition |
DE4114498A1 (de) * | 1991-05-03 | 1992-11-05 | Wacker Chemie Gmbh | Organopolysiloxan- alkyltrialkoxysilanemulsionen zur impraegnierung von zementgebundenen faserbauteilen |
DE4128893A1 (de) * | 1991-05-03 | 1992-11-05 | Wacker Chemie Gmbh | Beschichtungen auf siliconharzbasis |
GB9118465D0 (en) * | 1991-08-29 | 1991-10-16 | Imperial College | Steroid sulphatase inhibitors |
JP3251658B2 (ja) * | 1992-08-26 | 2002-01-28 | 東レ・ダウコーニング・シリコーン株式会社 | シリコーン水性エマルジョン組成物 |
-
1993
- 1993-01-13 US US08/003,636 patent/US5449712A/en not_active Expired - Lifetime
- 1993-04-15 CA CA002094063A patent/CA2094063C/en not_active Expired - Lifetime
- 1993-04-29 DE DE69330997T patent/DE69330997D1/de not_active Expired - Lifetime
- 1993-04-29 PT PT93201231T patent/PT606671E/pt unknown
- 1993-04-29 EP EP93201231A patent/EP0606671B1/en not_active Expired - Lifetime
- 1993-04-29 AT AT93201231T patent/ATE207506T1/de not_active IP Right Cessation
- 1993-04-29 ES ES93201231T patent/ES2166758T3/es not_active Expired - Lifetime
- 1993-09-16 JP JP25372793A patent/JP3682782B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ATE207506T1 (de) | 2001-11-15 |
EP0606671B1 (en) | 2001-10-24 |
US5449712A (en) | 1995-09-12 |
DE69330997D1 (de) | 2001-11-29 |
ES2166758T3 (es) | 2002-05-01 |
JPH06234919A (ja) | 1994-08-23 |
CA2094063C (en) | 2004-09-28 |
CA2094063A1 (en) | 1994-07-14 |
EP0606671A1 (en) | 1994-07-20 |
JP3682782B2 (ja) | 2005-08-10 |
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