PT2242797E - Agentes de coesão livres de formaldeído para a produção de produtos de madeira - Google Patents
Agentes de coesão livres de formaldeído para a produção de produtos de madeira Download PDFInfo
- Publication number
- PT2242797E PT2242797E PT09710940T PT09710940T PT2242797E PT 2242797 E PT2242797 E PT 2242797E PT 09710940 T PT09710940 T PT 09710940T PT 09710940 T PT09710940 T PT 09710940T PT 2242797 E PT2242797 E PT 2242797E
- Authority
- PT
- Portugal
- Prior art keywords
- weight
- lignocellulose
- monomer
- monomers
- wood
- Prior art date
Links
- 239000002023 wood Substances 0.000 title claims description 63
- 239000011230 binding agent Substances 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 claims abstract description 122
- 229920000642 polymer Polymers 0.000 claims abstract description 47
- 239000000463 material Substances 0.000 claims abstract description 44
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 12
- 239000006185 dispersion Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 9
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract description 7
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 7
- 125000000524 functional group Chemical group 0.000 claims abstract description 5
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims abstract description 5
- 150000003141 primary amines Chemical class 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 47
- 238000004519 manufacturing process Methods 0.000 claims description 26
- 239000011120 plywood Substances 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 13
- 229920002522 Wood fibre Polymers 0.000 claims description 12
- 239000002025 wood fiber Substances 0.000 claims description 12
- 238000010276 construction Methods 0.000 claims description 8
- 238000007906 compression Methods 0.000 claims description 7
- 230000006835 compression Effects 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 5
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 2
- 239000005022 packaging material Substances 0.000 claims description 2
- 150000002118 epoxides Chemical class 0.000 claims 2
- 239000004593 Epoxy Substances 0.000 abstract 1
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- -1 amine anhydride Chemical class 0.000 description 28
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 27
- 239000000203 mixture Substances 0.000 description 26
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 20
- 238000006116 polymerization reaction Methods 0.000 description 18
- 150000003254 radicals Chemical class 0.000 description 18
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- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 10
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- 150000002924 oxiranes Chemical class 0.000 description 9
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- 125000000129 anionic group Chemical group 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 5
- 150000001991 dicarboxylic acids Chemical class 0.000 description 5
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000001747 exhibiting effect Effects 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 4
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
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- 241000294754 Macroptilium atropurpureum Species 0.000 description 4
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
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- 238000010528 free radical solution polymerization reaction Methods 0.000 description 4
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- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 3
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 3
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 3
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 240000008892 Helianthus tuberosus Species 0.000 description 3
- 235000003230 Helianthus tuberosus Nutrition 0.000 description 3
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- 235000004431 Linum usitatissimum Nutrition 0.000 description 3
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- 125000002091 cationic group Chemical group 0.000 description 3
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- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 3
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- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
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- JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
Landscapes
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- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
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| PL2242797T3 (pl) | 2008-02-11 | 2012-06-29 | Basf Se | Bezformaldehydowe środki wiążące do wytwarzania tworzyw drzewnych |
| EP2172333A1 (de) * | 2008-09-19 | 2010-04-07 | Basf Se | Mehrschichtige lignucellulosehaltige Formkörper mit geringer Formaldehydemission |
| US9994482B2 (en) | 2009-08-11 | 2018-06-12 | Johns Manville | Curable fiberglass binder |
| US9604878B2 (en) | 2009-08-11 | 2017-03-28 | Johns Manville | Curable fiberglass binder comprising salt of inorganic acid |
| US8372900B2 (en) * | 2009-08-19 | 2013-02-12 | Johns Manville | Cellulosic composite with binder comprising salt of inorganic acid |
| US9365963B2 (en) | 2009-08-11 | 2016-06-14 | Johns Manville | Curable fiberglass binder |
| US8920923B2 (en) * | 2010-03-04 | 2014-12-30 | Basf Se | Lignocellulose materials having good mechanical properties |
| US8623501B2 (en) * | 2010-03-04 | 2014-01-07 | Basf Se | Lignocellulose materials having good mechanical properties |
| CN102917847B (zh) * | 2010-05-27 | 2015-05-06 | 巴斯夫欧洲公司 | 用于颗粒状和/或纤维状基底的粘合剂 |
| CN103068933B (zh) * | 2010-06-17 | 2016-02-10 | 巴斯夫欧洲公司 | 水性粘合剂组合物 |
| US8651286B2 (en) * | 2010-12-15 | 2014-02-18 | Johns Manville | Spunbond polyester mat with binder comprising salt of inorganic acid |
| US9157016B2 (en) * | 2012-10-01 | 2015-10-13 | Georgia-Pacific Chemicals Llc | Modified polyphenol binder compositions and methods for making and using same |
| GB201517867D0 (en) | 2015-10-09 | 2015-11-25 | Knauf Insulation Ltd | Wood particle boards |
| CN109478019A (zh) | 2016-07-05 | 2019-03-15 | Asml荷兰有限公司 | 用于检查设备的照射源、检查设备和检查方法 |
| WO2022116363A1 (zh) * | 2020-12-02 | 2022-06-09 | 北京化工大学 | 粘合剂和用其制备的人造板 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE7440894U (de) | 1975-04-17 | Deutsche Novopan Gmbh | Mehrschichtige Spanplatte | |
| GB1366081A (en) * | 1971-03-25 | 1974-09-11 | Ethylene Plastique Sa | Process for the treatment of the surface of a substrate with ethylene -maleic anhydride copolymer particles |
| DE2306771B2 (de) | 1973-02-12 | 1977-04-07 | Deutsche Novopan GmbH, 3400 Göttingen | Verfahren zur herstellung von spanplatten |
| US3998768A (en) | 1974-12-24 | 1976-12-21 | E. I. Du Pont De Nemours And Company | Thermosetting powder coating composition of a blend of acrylic polymers having different glass transition temperatures and a blocked polyisocyanate cross-linking agent |
| DE2832509C2 (de) | 1978-07-25 | 1986-02-20 | Deutsche Novopan KG, 3400 Göttingen | Verfahren zur Herstellung von Spanplatten |
| DE2851589C3 (de) | 1978-11-29 | 1983-06-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 8000 München | Mehrschichtige Span- oder Faserplatte, die in einem Teilbereich bzw. Teilbereichen einen Aminoplast als Bindemittel enthält |
| DE3820376A1 (de) | 1988-06-15 | 1989-12-21 | Novopan Gmbh | Verfahren zur herstellung von mehrschichtigen spanplatten |
| DE4003422A1 (de) | 1990-02-06 | 1991-08-08 | Basf Ag | Waessrige polyurethanzubereitungen |
| JPH07310064A (ja) * | 1994-05-16 | 1995-11-28 | Iida Kogyo Kk | リグノセルロース用の接着剤 |
| DE4431316C1 (de) | 1994-09-02 | 1996-05-02 | Schlingmann Gmbh & Co | Verfahren zur Verminderung der Formaldehydabgabe von Holzspan- oder Faserplatten |
| DE19606393A1 (de) | 1996-02-21 | 1997-08-28 | Basf Ag | Formaldehydfreie Bindemittel für Formkörper |
| JPH09272855A (ja) * | 1996-04-03 | 1997-10-21 | I T C:Kk | リグノセルロースまたはそれを含む材料の耐水性接着剤 |
| DE19729161A1 (de) | 1997-07-08 | 1999-01-14 | Basf Ag | Thermisch härtbare, wässrige Zusammensetzungen |
| DE19956420C1 (de) | 1999-11-24 | 2001-03-15 | Alberdingk Boley Gmbh | Bindemittel zur Herstellung von Formkörpern und unter Verwendung dieses Bindemittels hergestellte Formkörper |
| JP2003055629A (ja) * | 2001-06-04 | 2003-02-26 | Kao Corp | リグノセルロース用接着剤 |
| DE10151569A1 (de) | 2001-10-23 | 2003-04-30 | Basf Ag | Thermisch härtbare Bindemittel |
| DE10253498A1 (de) | 2001-12-07 | 2003-07-03 | Basf Ag | Verwendung von wäßrigen Bindemitteln bei der konstruktiven Holzverleimung |
| US20080265222A1 (en) * | 2004-11-03 | 2008-10-30 | Alex Ozersky | Cellulose-Containing Filling Material for Paper, Tissue, or Cardboard Products, Method for the Production Thereof, Paper, Tissue, or Carboard Product Containing Such a Filling Material, or Dry Mixture Used Therefor |
| DE102005005205A1 (de) | 2005-02-03 | 2006-08-10 | Basf Ag | Verwendung einer wässrigen Polymerdispersion als Bindemittel für cellulosische Fasern sowie zur Herstellung von Filtermaterialien |
| DE602006020736D1 (de) * | 2005-08-26 | 2011-04-28 | Asahi Fibreglass Co | Wässriges bindemittel für anorganische faser sowie davon gebrauch machender wärme- und/oder schalldämmungsstoff |
| DE102006019184A1 (de) | 2006-04-21 | 2007-10-25 | Basf Ag | Verwendung einer wässrigen Polymerzusammensetzung als Bindemittel für faserförmige oder körnige Substrate |
| ES2468550T3 (es) | 2007-02-07 | 2014-06-16 | Basf Se | Procedimiento para la preparación de una composición polim�rica acuosa usando reguladores de cadena radicalarios solubles en agua |
| PL2242797T3 (pl) | 2008-02-11 | 2012-06-29 | Basf Se | Bezformaldehydowe środki wiążące do wytwarzania tworzyw drzewnych |
-
2009
- 2009-02-11 PL PL09710940T patent/PL2242797T3/pl unknown
- 2009-02-11 DK DK09710940.9T patent/DK2242797T3/da active
- 2009-02-11 EP EP09710940A patent/EP2242797B1/de active Active
- 2009-02-11 PT PT09710940T patent/PT2242797E/pt unknown
- 2009-02-11 HR HR20120216T patent/HRP20120216T1/hr unknown
- 2009-02-11 JP JP2010546318A patent/JP2011511874A/ja not_active Ceased
- 2009-02-11 US US12/866,987 patent/US8466247B2/en not_active Expired - Fee Related
- 2009-02-11 AT AT09710940T patent/ATE540078T1/de active
- 2009-02-11 ES ES09710940T patent/ES2379757T3/es active Active
- 2009-02-11 RS RS20120079A patent/RS52177B/sr unknown
- 2009-02-11 WO PCT/EP2009/051554 patent/WO2009101100A2/de not_active Ceased
- 2009-02-11 SI SI200930224T patent/SI2242797T1/sl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2379757T3 (es) | 2012-05-03 |
| SI2242797T1 (sl) | 2012-05-31 |
| ATE540078T1 (de) | 2012-01-15 |
| WO2009101100A2 (de) | 2009-08-20 |
| US20110009530A1 (en) | 2011-01-13 |
| EP2242797A2 (de) | 2010-10-27 |
| EP2242797B1 (de) | 2012-01-04 |
| PL2242797T3 (pl) | 2012-06-29 |
| JP2011511874A (ja) | 2011-04-14 |
| HRP20120216T1 (hr) | 2012-03-31 |
| DK2242797T3 (da) | 2012-05-07 |
| RS52177B (sr) | 2012-08-31 |
| WO2009101100A3 (de) | 2009-10-29 |
| US8466247B2 (en) | 2013-06-18 |
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