PT1778706E - Novos ácidos de hidróxido de selénio e seus derivados, aplicações em nutrição, cosméticos e fármacos - Google Patents
Novos ácidos de hidróxido de selénio e seus derivados, aplicações em nutrição, cosméticos e fármacos Download PDFInfo
- Publication number
- PT1778706E PT1778706E PT05769627T PT05769627T PT1778706E PT 1778706 E PT1778706 E PT 1778706E PT 05769627 T PT05769627 T PT 05769627T PT 05769627 T PT05769627 T PT 05769627T PT 1778706 E PT1778706 E PT 1778706E
- Authority
- PT
- Portugal
- Prior art keywords
- sub
- ceramide
- pharmaceutics
- cosmetics
- derivatives
- Prior art date
Links
- 239000002537 cosmetic Substances 0.000 title abstract 3
- 239000002253 acid Substances 0.000 title abstract 2
- 235000016709 nutrition Nutrition 0.000 title abstract 2
- 150000007513 acids Chemical class 0.000 title 1
- 230000035764 nutrition Effects 0.000 title 1
- -1 ceramide 2 Chemical compound 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- YDNKGFDKKRUKPY-JHOUSYSJSA-N C16 ceramide Natural products CCCCCCCCCCCCCCCC(=O)N[C@@H](CO)[C@H](O)C=CCCCCCCCCCCCCC YDNKGFDKKRUKPY-JHOUSYSJSA-N 0.000 abstract 2
- WAYLDHLWVYQNSQ-KEFDUYNTSA-N N-2-hydroxylignoceroylsphingosine Chemical compound CCCCCCCCCCCCCCCCCCCCCCC(O)C(=O)N[C@@H](CO)[C@H](O)\C=C\CCCCCCCCCCCCC WAYLDHLWVYQNSQ-KEFDUYNTSA-N 0.000 abstract 2
- CRJGESKKUOMBCT-VQTJNVASSA-N N-acetylsphinganine Chemical compound CCCCCCCCCCCCCCC[C@@H](O)[C@H](CO)NC(C)=O CRJGESKKUOMBCT-VQTJNVASSA-N 0.000 abstract 2
- ATGQXSBKTQANOH-UWVGARPKSA-N N-oleoylphytosphingosine Chemical compound CCCCCCCCCCCCCC[C@@H](O)[C@@H](O)[C@H](CO)NC(=O)CCCCCCC\C=C/CCCCCCCC ATGQXSBKTQANOH-UWVGARPKSA-N 0.000 abstract 2
- MIUIRGGKIICMBP-NFOZDHADSA-N [27-oxo-27-[[(2s,3s,4r)-1,3,4-trihydroxyoctadecan-2-yl]amino]heptacosyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCCCCCCCCCCCCC(=O)N[C@@H](CO)[C@H](O)[C@H](O)CCCCCCCCCCCCCC MIUIRGGKIICMBP-NFOZDHADSA-N 0.000 abstract 2
- ZGBFGAHZKZQSLG-UMCOJZBLSA-N [30-oxo-30-[[(e,2s,3r,6r)-1,3,6-trihydroxyoctadec-4-en-2-yl]amino]triacontyl] (9z,12z)-octadeca-9,12-dienoate Chemical compound CCCCCCCCCCCC[C@@H](O)\C=C\[C@@H](O)[C@H](CO)NC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCC\C=C/C\C=C/CCCCC ZGBFGAHZKZQSLG-UMCOJZBLSA-N 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 229940106189 ceramide Drugs 0.000 abstract 2
- ZVEQCJWYRWKARO-UHFFFAOYSA-N ceramide Natural products CCCCCCCCCCCCCCC(O)C(=O)NC(CO)C(O)C=CCCC=C(C)CCCCCCCCC ZVEQCJWYRWKARO-UHFFFAOYSA-N 0.000 abstract 2
- 229940048864 ceramide 1 Drugs 0.000 abstract 2
- 229940099417 ceramide 2 Drugs 0.000 abstract 2
- 229940044176 ceramide 3 Drugs 0.000 abstract 2
- 150000002632 lipids Chemical class 0.000 abstract 2
- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 2
- SHGAZHPCJJPHSC-XFYACQKRSA-M 13-cis-retinoate Chemical compound [O-]C(=O)/C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C SHGAZHPCJJPHSC-XFYACQKRSA-M 0.000 abstract 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-M 9-cis,12-cis-Octadecadienoate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O OYHQOLUKZRVURQ-HZJYTTRNSA-M 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 abstract 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 abstract 1
- LCTONWCANYUPML-UHFFFAOYSA-M Pyruvate Chemical compound CC(=O)C([O-])=O LCTONWCANYUPML-UHFFFAOYSA-M 0.000 abstract 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract 1
- RJFAYQIBOAGBLC-BYPYZUCNSA-N Selenium-L-methionine Chemical compound C[Se]CC[C@H](N)C(O)=O RJFAYQIBOAGBLC-BYPYZUCNSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 235000019728 animal nutrition Nutrition 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 abstract 1
- 229940049918 linoleate Drugs 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 229940105132 myristate Drugs 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- 229940049964 oleate Drugs 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 abstract 1
- 239000008194 pharmaceutical composition Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 239000011669 selenium Substances 0.000 abstract 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C391/00—Compounds containing selenium
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/16—Inorganic salts, minerals or trace elements
- A23L33/165—Complexes or chelates
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/095—Sulfur, selenium, or tellurium compounds, e.g. thiols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P3/00—Drugs for disorders of the metabolism
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P3/00—Drugs for disorders of the metabolism
- A61P3/02—Nutrients, e.g. vitamins, minerals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P35/00—Antineoplastic agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Engineering & Computer Science (AREA)
- Epidemiology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- General Chemical & Material Sciences (AREA)
- Nutrition Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Food Science & Technology (AREA)
- Hematology (AREA)
- Dermatology (AREA)
- Diabetes (AREA)
- Inorganic Chemistry (AREA)
- Mycology (AREA)
- Obesity (AREA)
- Polymers & Plastics (AREA)
- Birds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cosmetics (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0408181A FR2873376B1 (fr) | 2004-07-23 | 2004-07-23 | Nouveaux seleno-hydroxyacides et leurs derives, applications en nutrition, cosmetique et pharmacie |
Publications (1)
Publication Number | Publication Date |
---|---|
PT1778706E true PT1778706E (pt) | 2009-09-09 |
Family
ID=34950061
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PT05769627T PT1778706E (pt) | 2004-07-23 | 2005-07-22 | Novos ácidos de hidróxido de selénio e seus derivados, aplicações em nutrição, cosméticos e fármacos |
Country Status (17)
Country | Link |
---|---|
US (1) | US7381416B2 (pt) |
EP (1) | EP1778706B1 (pt) |
JP (1) | JP5398983B2 (pt) |
KR (1) | KR101198244B1 (pt) |
CN (1) | CN101098879B (pt) |
AT (1) | ATE435850T1 (pt) |
AU (1) | AU2005263649B8 (pt) |
BR (1) | BRPI0513733B8 (pt) |
CA (1) | CA2574629C (pt) |
DE (1) | DE602005015330D1 (pt) |
DK (1) | DK1778706T3 (pt) |
ES (1) | ES2328051T3 (pt) |
FR (1) | FR2873376B1 (pt) |
MX (1) | MX2007000877A (pt) |
PL (1) | PL1778706T3 (pt) |
PT (1) | PT1778706E (pt) |
WO (1) | WO2006008190A2 (pt) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2850441B1 (fr) * | 2003-01-24 | 2005-03-11 | Renault Sa | Dispositif de commande interne de boite de vitesses mecanique |
US7586003B2 (en) * | 2005-07-14 | 2009-09-08 | Zinpro Corporation | Derivatives of seleno-amino acids |
FR2907785B1 (fr) | 2006-10-27 | 2009-01-16 | Tetrahedron Sas | Procede de preparation de l'acide 2-hydroxy-4-methylselenobutyrique, seul ou en melange avec son analogue soufre, ainsi que leurs utilisations en nutrition, en particulier en nutrition animale |
US20080286387A1 (en) * | 2007-05-20 | 2008-11-20 | Muhammed Majeed | Standardized method for recovering enriched Indian date extract (IDE), properties of IDE and applications thereof |
CN100548311C (zh) * | 2007-06-13 | 2009-10-14 | 中国科学技术大学 | 硒代硫酸钠在制备临床补硒和治疗癌症药物中的应用及快速制备方法 |
WO2009036368A2 (en) | 2007-09-14 | 2009-03-19 | Nitto Denko Corporation | Drug carriers |
FR2935393B1 (fr) * | 2008-08-29 | 2012-08-24 | Tetrahedron | Bacteries et levures enrichies en selenium organique a partir de composes seleno-hydroxyacides et leurs applications en nutrition, cosmetique et pharmacie |
FR2935394B1 (fr) * | 2008-08-29 | 2013-03-08 | Eco Solution | Microorganismes photosynthetiques enrichis en selenium organique a partir de composes seleno-hydroxyacides et leurs applications en nutrition, cosmetique et pharmacie |
WO2010096382A1 (en) * | 2009-02-17 | 2010-08-26 | Novus International Inc. | Processes for the production of proteins containing selenium using yeast cells |
TWI495725B (zh) * | 2009-08-28 | 2015-08-11 | Metabolium | 利用硒羥酸化合物由而富含硒的光合微生物,以及彼於營養品、化妝品與藥品的應用 |
JP2013522213A (ja) * | 2010-03-09 | 2013-06-13 | ノーバス・インターナショナル・インコーポレイテッド | ラクトン中間体を経由するホモセリンからのメチオニンまたはセレノメチオニンの製造 |
EP2800737B1 (en) | 2012-01-06 | 2020-02-19 | Novus International Inc. | Sulfoxide-based surfactants |
CN102558005A (zh) * | 2012-01-11 | 2012-07-11 | 张家港阿拉宁生化技术有限公司 | 一种对环境友好的合成硒代蛋氨酸的方法 |
EP2812372B1 (en) * | 2012-02-09 | 2018-09-26 | Novus International Inc. | Heteroatom containing cyclic dimers |
US9452143B2 (en) | 2012-07-12 | 2016-09-27 | Novus International, Inc. | Matrix and layer compositions for protection of bioactives |
FR3019463B1 (fr) | 2014-04-08 | 2017-06-23 | Tetrahedron | Nouveaux composes organo-selenies, procede de fabrication et applications en pharmacie notamment comme agents anti-tumoraux |
AU2016285870B2 (en) * | 2015-07-02 | 2020-03-12 | Novus International Inc. | Antimicrobial compositions and uses thereof |
US10584306B2 (en) | 2017-08-11 | 2020-03-10 | Board Of Regents Of The University Of Oklahoma | Surfactant microemulsions |
CN107518282A (zh) * | 2017-10-19 | 2017-12-29 | 安徽顶康食品有限公司 | 一种富硒黑小麦桑叶营养挂面及其制备方法 |
CN109232342A (zh) * | 2018-10-15 | 2019-01-18 | 禄丰天宝磷化工有限公司 | 一种硒代蛋氨酸羟基类似物的制备方法 |
CN112876394A (zh) * | 2021-02-09 | 2021-06-01 | 中国科学院福建物质结构研究所 | 一种dl-羟基硒代蛋氨酸的制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT397200B (de) * | 1988-06-03 | 1994-02-25 | Birkmayer Joerg Ddr | Verwendung von selenmethionin zur herstellung eines arzneimittels |
GB2312621B (en) * | 1996-05-02 | 1998-03-11 | Pharma Nord Uk Limited | Anti-oxidant medicament |
FR2782642B1 (fr) * | 1998-08-31 | 2001-12-07 | Xavier Forceville | Utilisation du selenium pour le traitement de patients atteints d'un syndrome de reponse inflammatoire systemique (sirs), et composition pour la mise en oeuvre du traitement |
WO2000067762A2 (en) * | 1999-05-11 | 2000-11-16 | Anticancer, Inc. | Selenium-containing pro-drugs for cancer therapy |
FR2827859B1 (fr) * | 2001-07-30 | 2005-09-23 | Lipha | Derives 4-(arylthio) - ou 4-(heteroarylthio) -butyrique dans la preparation de medicaments destines au traitement du diabete |
GB0202900D0 (en) * | 2002-02-07 | 2002-03-27 | Laxdale Ltd | Novel formulations of drugs |
US6911550B2 (en) * | 2003-02-21 | 2005-06-28 | Zinpro Corporation | Derivatives of seleno-amino acids with improved bioavailability and method for their preparation |
JP4016104B2 (ja) * | 2003-03-19 | 2007-12-05 | 独立行政法人産業技術総合研究所 | 新規セレニルリンカー及びその用途 |
-
2004
- 2004-07-23 FR FR0408181A patent/FR2873376B1/fr not_active Expired - Fee Related
-
2005
- 2005-07-22 KR KR1020077004217A patent/KR101198244B1/ko active IP Right Grant
- 2005-07-22 EP EP05769627A patent/EP1778706B1/en active Active
- 2005-07-22 WO PCT/EP2005/008746 patent/WO2006008190A2/en active Application Filing
- 2005-07-22 AU AU2005263649A patent/AU2005263649B8/en active Active
- 2005-07-22 PT PT05769627T patent/PT1778706E/pt unknown
- 2005-07-22 JP JP2007521918A patent/JP5398983B2/ja active Active
- 2005-07-22 US US11/187,617 patent/US7381416B2/en active Active
- 2005-07-22 DK DK05769627T patent/DK1778706T3/da active
- 2005-07-22 AT AT05769627T patent/ATE435850T1/de active
- 2005-07-22 DE DE602005015330T patent/DE602005015330D1/de active Active
- 2005-07-22 PL PL05769627T patent/PL1778706T3/pl unknown
- 2005-07-22 MX MX2007000877A patent/MX2007000877A/es active IP Right Grant
- 2005-07-22 CA CA2574629A patent/CA2574629C/en active Active
- 2005-07-22 CN CN2005800294790A patent/CN101098879B/zh active Active
- 2005-07-22 BR BRPI0513733A patent/BRPI0513733B8/pt active IP Right Grant
- 2005-07-22 ES ES05769627T patent/ES2328051T3/es active Active
Also Published As
Publication number | Publication date |
---|---|
BRPI0513733A (pt) | 2008-05-13 |
BRPI0513733B1 (pt) | 2021-04-13 |
CN101098879A (zh) | 2008-01-02 |
DE602005015330D1 (de) | 2009-08-20 |
EP1778706A2 (en) | 2007-05-02 |
AU2005263649B2 (en) | 2011-04-14 |
KR101198244B1 (ko) | 2012-11-07 |
BRPI0513733B8 (pt) | 2021-05-25 |
CN101098879B (zh) | 2011-06-15 |
JP5398983B2 (ja) | 2014-01-29 |
AU2005263649B8 (en) | 2011-05-19 |
US7381416B2 (en) | 2008-06-03 |
US20060105960A1 (en) | 2006-05-18 |
FR2873376A1 (fr) | 2006-01-27 |
FR2873376B1 (fr) | 2006-11-24 |
PL1778706T3 (pl) | 2009-12-31 |
ES2328051T3 (es) | 2009-11-06 |
JP2008507490A (ja) | 2008-03-13 |
CA2574629A1 (en) | 2006-01-26 |
ATE435850T1 (de) | 2009-07-15 |
KR20070050446A (ko) | 2007-05-15 |
WO2006008190A3 (en) | 2007-08-30 |
AU2005263649A1 (en) | 2006-01-26 |
CA2574629C (en) | 2013-04-02 |
WO2006008190A2 (en) | 2006-01-26 |
EP1778706B1 (en) | 2009-07-08 |
DK1778706T3 (da) | 2009-08-31 |
MX2007000877A (es) | 2007-06-11 |
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