PL97084B1 - Sposob wytwarzania nowych pochodnych benzotriazolu - Google Patents

Sposob wytwarzania nowych pochodnych benzotriazolu Download PDF

Info

Publication number
PL97084B1
PL97084B1 PL1976186652A PL18665276A PL97084B1 PL 97084 B1 PL97084 B1 PL 97084B1 PL 1976186652 A PL1976186652 A PL 1976186652A PL 18665276 A PL18665276 A PL 18665276A PL 97084 B1 PL97084 B1 PL 97084B1
Authority
PL
Poland
Prior art keywords
carbon atoms
radical
formula
radicals
alkylene
Prior art date
Application number
PL1976186652A
Other languages
English (en)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of PL97084B1 publication Critical patent/PL97084B1/pl

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
    • C07D235/06—Benzimidazoles; Hydrogenated benzimidazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D249/18—Benzotriazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/38—Heterocyclic nitrogen compounds
    • C10M133/44—Five-membered ring containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14—Nitrogen-containing compounds
    • C23F11/149—Heterocyclic compounds containing nitrogen as hetero atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/025—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with condensed rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/027—Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/142—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/22—Acids obtained from polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/044—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms having cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/066—Arylene diamines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/10—Amides of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/20—Containing nitrogen-to-oxygen bonds
    • C10M2215/204—Containing nitrogen-to-oxygen bonds containing nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/227—Phthalocyanines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088—Neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089—Overbased salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/102—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon only in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106—Thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/043—Ammonium or amine salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/08—Groups 4 or 14
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/10—Groups 5 or 15
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Lubricants (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

Przedmiotem wynalazku jest sposób wytwarza¬ nia nowych pochodnych benzotriaizolu majacych zdolnosc paisyiwoiwtania metali.Stosowanie pochodnych benzotriazolu do pasy- wowania metali, zwlaszcza miedzi, w róznych sro¬ dowiskach, jest znane od dawna. Jednakze stoso¬ wanie benzotatiazolu i wielu jego pochodnych do tego celu jest ograniczone, z powodu malej roz¬ puszczalnosci tych zwiazków, zwlaszcza w olejach mineralnych. Wad tyoh nie maja wytwarzane spo¬ sobem wedlug wynalazku nowe pochodne benzo¬ triazolu o ogólnym wzoTize 1, w którym X ozna¬ cza atom azotu lub grupe o wzorze =OR, w któ¬ rym R oznacza atom wodoru laib rodnik alkilowy o 1—4 atomlach wegla, A oznacza pierscien ben¬ zenowy lub naftalenowy, ewentualnie podstawio¬ ny jednym lub wieksza liczba rodników alkilo¬ wych o 1—12, zwlaszcza o 1—4 atomach wegla albo jednym lub wieksza liczba" rodników aral- kiiowych o 7—9 atomach wegla, zwlaszcza rodni¬ kiem a, a-dwanmetylobeozylowyim, a Rt i R2 sa jednakowe lub rózne i oznaczaja grupy o wzorze RsO[/alkileno/0]x —(alkilen), w którym R8 ozna¬ cza atom wodoru lub rodnik alkilowy o 1—20 atomach wefelfc, „alkilen" oznacza prosty lub roz¬ galeziony rodnik alkiienowy o 2 lub 3 atomach wegla, a x oznacza liczbe zero, 1, 2, 3 lub 4, albo Rt i R2 oznaczaja rodniki alkenylowe o 2—20 ato¬ mach wegla lub rodniki cyjanoalkilowe o 2—5 ato- mach wegla, albo tez Rx ma wyzej podane zna¬ czenie, a R2 oznacza atom wodoru, rodnik alkilo¬ wy o 1—20 atomach wegla, rodnik arylowy o 6—10 atomach wegla, rodnik cykloalkilowy o 5—12 ato¬ mach wegla, rodnik aralkilowy o 7—Q atomach wegla, rodnik heterocykliczny lub grupe o wzo¬ rze 2, w którym A i X maja wyzej podane zna¬ czenie.Sposobem wedlug wynalazku wytwarza sie rów¬ niez nowe zwiazki o wzorze objetym wzorem 1, a mianowicie griupe zwiazków jo wzorze la, w któ¬ rym X ma wyzej podane znaczenie, a korzystnie oznacza atom azotu, R4 i e£ sa. jednakowe lub rózne i oznaczaja rodniki alkilowe o 1—20 ato¬ mach wegla, rodniki arylowe o 6—10 atomach we¬ gla, rodniki cykloalkiiowe o 5—12 atomach we¬ gla, rodniki araikiiowe o 7—9 atoimach wegla lub rodniki heterocykliczne, a R6 oznacza rodnik aral¬ kilowy o 7—9 atomach wegla, korzystnie rodnik a, a^dwumetyilobeozylowy.Zwiazki o wzorze .1 sa zasadami ManniCha i ko¬ rzystne wlasciwosci majazwlaszcza te zwiazki o wzorze 1, w którym X oznacza atom azotu i A oznacza pierscien benzenowy, jak równiez zwiazki o wzorrze la, w którym wszystkie symbole maja wyzej podane znaczenie.Korzystnie jest równiez, gdy podstawnik przy atomie azotu w zwiazku o wzorze 1 tworzy funkcje polarna, a szczególnie, gdy co najmniej jeden z 970843 97084 4 pcwlstawników R± i R2, a zwlaszcza kazdy z nich, oznacza grupe o wzorze R80[/iailkii]]en/iO]x-/alikilen/, w którym R8 ma wyzej podane znaczenie, a ko¬ rzystnie oznaoza atom wodoru i x oznacza ko¬ rzystnieizero. 5 Gdy X oznacza grupe =C-R, w którym R ozna¬ cza rodnik alkilowy o 1—4 atomach wegla, wów¬ czas korzystnie R oznacza rodnik metylowy.Gdy A oznacza podstawiony rodnik fenylowy lub naftylowy, wówczas korzystnie jest to rodnik io fenylowy, zawierajacy jako podstawniki rodniki alkilowe o 1—4 atomach wegla, zwlaszcza rodniki metylowe, albo rodniki aralkilowe, zwlaszcza rod- mik a, a-dwumetylobenzylowy.Gdy Rt i/albo R2 oznaczaja rodniki alkenyilowe, 15 wówczas rodnika te zawieraja korzystnie 3—20 atomów wegla i oznaczaja na przyklad rodniki alkilowe, butenylowe, oktenylowe, decenylowe, do- decenylowe, tetradeoenylowe i oiktadecenyliawe (oleilowe). 20 Gdy Rj i/albo R2 oznaczaja grupy o wzorze R80[/alkilen/0]x/alkilen/, wówczas we wzorze tym R8 korzystnie oznacza atom wodoru lufo rodnik alkilowy o 1—18, zwlaszcza o 1—8 atomach we¬ gla, na przyklad grupy hydiroksyetylowe, meto- 25 ksyetylowe, n-butoksyetylowe, metoksyetoksyetylo- we, n-butoksyetoksyetylowe i nHoktyloksypropylo- ksyflowe. ' Jiako grupy cyjanoalkiilowe podstawniki R± i/albo R2 korzystnie oznaczaja grupy cyjanometylowe i cy- 30 %janoetylowe.Gdy Ri ma wyzej podane znaczenie, R2 moze tez oznaczac atom wodoru, rodmiik alkilowy, airy- lowy, cykloalkilowy, aralkilowy lub heterocyklicz¬ ny albo grupe o wzorze 2, w którym A i X maja 35 wyzej podane znaczenie.Gdy R2 oznacza rodnik alkilowy, to korzystnie zawiera on 1—12 atomów wegla, jako rodndk ary- lowy oznaoza korzystnie rodmiik fenylowy lub naf- tyloiwy, jako rodnik cykloadfciilowy oznacza zwlasz- 40 cza rodnik cykloheksylowy, jako rodnik arailkilo- wy oznacza korzystnie rodnik benzylowy, a jiako irodndk heterocykliczny zwlaszcza rodnik piperydy- nowy lub morfolinowy.R4 i R5 korzystnie maja znaczenie podane wy- 45 zaj dla R2.Najkorzystniejsze wlasciwosci maja jednak zwia¬ zki o wzorze 1, w którym A oznacza pierscien ben¬ zenowy, ewentualnie podstawiony rodnikiem me¬ tylowym lub dwumetylobenzylowym, a Ri i R2 sa 50 jednakowe lub rózne i oznaczaja grupy o wzorze R^O[/alkilen/0]x-/alkilen/, w którym R8 oznacza a/tom wodoru lub nizszy rodnik alkilowy, a x ko¬ rzystnie oznacza zero, albo Ri oznacza grupe o tym wzorze, a R2 oznacza atom wodoru lub niz- 55 szy rodnik alkilowy.Przykladami zwiazków wytwarzanych sposobem wedlug wynalazku sa nastepujace zwiazki: 1Hdwuetanoloamliinlometylobenzotriaizol, lndwuetanoloaminomety^beinziimiidazioi, 60 lHdwutiizopropanoloamiinlom 1^dwiuizoprjopanoloamiinomety^ N,Nnbis/!l'-foenzotriazolailometylo/^etan^ N,Njbis^l%benziimidaizolilarr^ na, 65 N,N^bis/l%ber^otriazo'M'lometyW4 na, 1-/N^metyloetanoloamiinometylo/-benzotriazol, NjNHbis/r-lbeniztaidazol^ butanol, N,N^is/l/^benzimidiazolilometylo/-3-metoksypropy- loamina, l-dwualJiloajndinjometylo-2-butylobenziinidazol, l-/NHmety]oe4anoloamiinome daizol, N,N-ibdisyir^benGotriazoiiloimetylo/-etoiksyetoiksyp(ro- ipyloamiina, N,N-'bis tt,N-fo,is/l%benizotriaz0lilometylo/^^ N,N-ibiis/il'^Denzotaiazolilometylo/^allitó NjN^iMsi/^S-iaya^diwuimetylObenzylo-l^benzotriazolilo- metyilo/^dodecyloaimina i Wdwunn-ibutyilloamiinometylo/^^ benzyiloZ-benzotriazol.Sposobem (wedlug wynalazku zwiazki o wzorze 1, w którym wszystkie symbole maja wyzeó po¬ dane iznaozenie, wytwarza sie przez reakcje zwiaz¬ ku o wzorze 3, w którym A i X maja wyzej po¬ dane znacznie, z aldehydem mrówkowym i z ami¬ na o wzorze 4, w którym Rj i A maja wyzej po¬ dane znacznie.Zwiazki o wzorze 3, nadajace sie jako produkty wyjsciowe w tym procesie, obejmuj% benzotria- • zole, benzimidazole i zwiazki znane z brytyjskiego opisu patentowego benzoitriazole. Korzystnie jednak jako zwiazek o wzorze 3 stosuje sie sam benzotriazol.Aldehyd mrówkowy korzystnie stosuje sie w ta¬ kiej postaci, w j«akiej wystepuje on w handlu, na przyklad w postaci formaliny lub papaformalde- hydu.Przykladami odpowiednich amin o wzorze 4 sa aminy pierwszorzedowe o wzoirze RiNH2, w któ- ryim iRt ima wyzej podane znaczenie i drugotize- dowe aminy o wzorze (Ri) (/R2) NH, w którym Rt i R2 maja wyzej podane znaczenie.Skladniki reakcji, to jest zwiazki o wzorach 3 i 4 oraz aildehyd mrówkowy, stosuje sie w róz¬ nych stosunkach wzajemnych, w zaleznosci od te¬ go, czy zwiazek o wzorze* 4 jest amina pierwszo- rzedowa czy dnugorzedowa. Jezeli zwiazek o wzo¬ rze 4 jest amina ipienwiszorzedowa, to stosunek mo¬ lowy zwiazku o wzorze 3, aldehydu mrówkowego i aminy io wzorze 4 moze zasadniczo wynosic 2,0 : 2,0 :1,0 albo 1,0 :1,0 :1,0 zas gdy zwiazek o wzoirze 4 jest amina drugorzedowa, to stosunek ten wynosi korzystnie zasadniczo 1,0 :1,0 :1,0.Slposobem wedlug wynalazku proces prowadzi sie korzystnie utrzymujac wszystkie skladniki re¬ akcji w podwyzszonej temperaturze, na przyklad 50—il20°C. W razie potrzeby mozna najpierw pod¬ dawac reakcji zwiazek o wzorze 3 z aldehydem mrówkowym i otrzymany izwiazek N-imetylolowy poddawac reakcji z aimina o wzorze 4.Stwierdzono, ze zwiazki o wzorach 1 i la, w których wszystkie symbole maja wyzej podane zniaczenie, maja bardzo dobra zdolnosc ipasywo- wania metali, a równoczesnie sa dobrze rozpusz¬ czalne w wielu cieczach stosowanyah do róznych celów tjotez nadaja sie do wytwarzania srodków97084 do pasywowania metali. Srodka tafcie korzystnie zawieraja 0,001—&/o wagowych zwiazku o wzorze 1 lub la w stosunku do calkowitej masy.Przykladami cieklych czynników stosowanych w takich sirodkach sa smary na podstawie oleju mi¬ neralnego lub syntetycznego eatru kar.boksyilowego, ciecze hydrauliczne na podstawie olejów mineral¬ nych, estirów fosforanowych, wodnych (mieszanin poiiiglikolu z estrem poliglikolowym, ukladSw gli- kolowych, albo emulsja typu olej w wodzie albo woda w oleju, jiak równiez ciecze stosowane przy obróbce metali, majace jako podstawe oleje mi¬ neralne lub ulady wodne, a takze wodno-giikloilowe srodki zapobiegajace zamarzamiiu.W zaleznosci od rodzaju cieklego czynnika srod¬ ki te zawieraja jeden lub wieksza liczbe dodat¬ ków. Przykladami takich dodatków w cieklych czynnikach nie opartych na wodzie sa antyutle- niacze, inne pasywatory metali, initabfiltory rdzy, substancje polepszajace lepkosc, substancje obni- zaijace (temperature plynnosci, dyspergaifcory, de¬ tergenty i dzialajace pod wysokim cisnieniem sub- istanicje przeoiwscierne.Przyklady I—XIV. 23,82 czesci benzotriazolu i 21,03 czesci dwuetanoioaminy miesza sie z 75 czesciami etanolu i "6,0 czesciami aldehydu mrów- ^JbOfwego, dodanego w postaci 36«/o roztworu wod¬ nego i mieszanine -utrzymuje w stanie wrzenia pod idhlodndca zwrotna w ciagu 8 godzin, po iczyim chlo¬ dzi i odparowuje rozpuszczalnik pod cisnieniem obnizonym za pomoca stoumieniowej pampy wod¬ nej. Pozostalosc przedestylowuje sie pod takim -sa¬ mym cisnieniem azeotropowOj stosujac 3 porcje po 50 ml etanolu. Otrzymuje sie 1-dwuetanoloami- no-metylobenzotriazol z wydajnoscia wynoszaca 0W0 wydajnosci iteoretycznej.Dalsze próby prowadzi sie w sposób analogiczny do wyzej opisanego, przy czyni jezeli jako pro¬ dukt wyjsciowy stosuje sie amine pierwszarze- ckarwa, to ilosc jej w stosunku molowym jest o po¬ lowe mniejsza. W przypadku stosowania amin o wyzszych ciezarach czasteczkowych, w celu uzy¬ skania dobrej wydajnosci reakcje prowadzi sie w czasie dluzszym od 8 godzin, a mianowicie do okolo 16 godzin. Jezeli otrzymane produkty sta¬ nowia ciala stale, to korzystnie przekiryat&lizorwuje rie je z octanu etylu.Otozyirnane zwiazki sa przewaznie zwiazkami podstawionymi przy atomie azotu w pozycji 1, aczkolwiek widmo rnagnetyoznego rezonansu ja¬ drowego wykazuje, ze w pewnej mierze (do 20§/o) powstaja równiez produkty podstawione przy ato¬ mie azotu w pozycji 2.W tablicy 1 podano zwiazki o wzorze 1, w któ¬ rym A oznacza pierscien benzenowy, wytworzone z drugorzedowych amin, w tablicy 2 — zwiazki o wzorze 5 wytworzone z pierwszorzedowych amin i w tablicy 3 — zwiazki o wzorze 6 otrzymane z drugorzedowych amin (modyfikowane benzo- triazoie). Znaczenie symboli we wzorach podano w tablicach, w których tez podano wyniki analizy elementarnej produktów, przy czym waartosci po¬ dane w górnym wierszu stanowia wartosci obli¬ czone teoretycznie, a w dolnym wierszu wartosci otrzymane w wyniku analizy. 3 fcl 1 1* 11 ni IV V VI X N CH N CH N CH Ki 7 -CH2CH2OH -CH2CH2OH -CHaCH^CH -CH2CH2OH —CH2CH^OH2 -CHjiCH=CH2 1 . 1R2 -CH2CH2OH -CH^HjOH -CHS -CH8 -\^Hf\*ix ^ C^Hj -CHflCH= CHj Tabl •0 f . 80 72 95 62 ' 71 91 i ca 1 Konsys¬ tencja iproduktu cialo stale cialo stale syrop cialo stale olej olej • Tempera¬ tura top¬ nienia lub wrzenia °C /2—54 00—01 — 79—80 temperatu¬ ra wrzenia il26°C/0,4 mim Hg C 55,93 55,56 61,28 61,24 58,25 58,20 64,39 64,10 68,42 68,19 74,01 73,38 Analiza °; H 6,78 6,88 7,23 7,37 6,80 6,49 7,32 7,42 7,01 7,27 7,49 7,67 <9 1 N I 4 m 23,73 23,55 17,87 17,60 2748 ft7,98 ,49 ,21 24,56 24,83 18,50 18,7697084 Tatoli ca 2 3 ST lad i* a i.VII VIII IX X XI XII X N CH N CH N CH R -Ci8HS5 -CisH,5 -CHgCH =CH2 -OH2CH=CH2 -CH^OCH, -CHs/jrOCH, Wydajnosc °/o 90 95 76 82 75 68 Konsystencja produktu wosk syrop cialo stale cialo stale cialo stale cialo stale Tempera¬ tura top¬ nienia °C — czystosci 114—115 111—112 98—100*) 120—121 C 72,59 72,21 Analiza ° H 8,88 9,12 /o N 18,53 18,46 produktu tylko 90% 63,95 63,91 71,92 72,12 61,54 60,56 74,01 73,88 ,33 ,48 ,99 6,23 ,98 ,99 7,49 7,67 ,72 ,84 22,08 22,09 '27,92 27,57 18,50 18,76 * po przekrystalizowaniu z etanolu Tablica 3 3 Nume przyk XIII XIV Ri n-C4H9 C13H27" R2 n-C4H9 C1SH27" Wydajnosc •/• 91 91 Konsysten¬ cja pro¬ duktu syrop syrop Tempera¬ tura top¬ nienia — C 76,19 75,88 80,00 79,61 Analiza °/o H 8,99 9,02 11,35 11,35 _ N 14,81 14,80 8,89 8,94 "C13Hfr7„ oznacza srednia wartosc rodników alkilowych w preparacie Kemamine S 650 firmy Hunka Che¬ mical Products PL

Claims (2)

  1. Zastrzezenia patentowe 1. Sposób wytwarzania nowych pochodnych ben- zotiriazolu o ogólnym wzorze 1, w którym X ozna¬ cza latam azotu lub grupe o wzorze =C-R, w któ¬ rym R oznacza atom wodoru lub rodnik alkilowy o .1—4 atomach wegla, A oznacza pierscien ben¬ zenowy lub naftalenowy, ewentualnie podstawio¬ ny jednym lub wieksza liczba rodników alkilo¬ wych o 1^12 atomach wegla albo jednym lub wieksza liczbo rodników arialkilowyoh o 7—9 ato¬ mach V wegla, a Ri ii ,R2 sa jednakowe lub rózne i oznaczaja grupy o wzorze R^O[/alkilen/0]x-/alki- len/, w którym R8 oznacza atom wodoru lub rod¬ nik lalikilowy o 1—20 atomach wegla, alkilen ozna¬ cza rodnik alkilenoiwy o lancuchu prostym lub rozgalezionym, zawierajacym 2 lub 3 atomy we¬ gla, a x oznacza liczbe zero, 1, 2, 3 albo^ 4, albo 45 Ri i R2 oznaczaja, rodniki alkenylowe o 2—20 ato¬ mach wegla lub rodniki cyjamoalkiipfwe o 2—5 atomach wegla, albo tez Ri ma wyzej podane zli¬ czenie, a R2 oznacza atom wodoru, rodnik alkilo¬ wy o 1—20 atomach weglia, rodnik aryloiwy o 6—10 5° atomach wegla, rodnik cykloalkilowy o 5—12 ato¬ mach wegla, rodnik aralkilowy o 7—9 atomach wegla, rodnik heterocykliczny lub grupe o wzo¬ rze 2, w którym A i X maja wyzej podane zna¬ czenie, znamienny tym, ze zwiazek o ogólnym wzo- 55 rze 3, w którym A i X maja wyzej podane zna¬ czenie, poddaje sie reakcji z aldehydem mrówko¬ wym i ze zwiazkiem o ogólnym wizorze 4, w któ¬ rym Rx i R2 maja wyzej podane znaczenie.
  2. 2. Sposób wedlug zastrz. 1, znamienny tym, ze 60 jako zwiazek o wzorze 3 stosuje sie benzotriazol.97084 *xN^ R< CH2N^ ¦R« ¦R. Hzar fa rN, -n\: XH2- tizór Z AJ H- rNkY LN/X (i Vitor 5 -N<^ Wzór 4 VR297084 ;x CH; NR Wzór 5 CH*N' Wzdrc R< R2 Drukarnia Narodowa Zaklad Nr 6, zam. 219/78 Cena 45 zl PL
PL1976186652A 1975-01-23 1976-01-20 Sposob wytwarzania nowych pochodnych benzotriazolu PL97084B1 (pl)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB292975A GB1466558A (en) 1975-01-23 1975-01-23 Additives for functional fluids

Publications (1)

Publication Number Publication Date
PL97084B1 true PL97084B1 (pl) 1978-02-28

Family

ID=9748727

Family Applications (1)

Application Number Title Priority Date Filing Date
PL1976186652A PL97084B1 (pl) 1975-01-23 1976-01-20 Sposob wytwarzania nowych pochodnych benzotriazolu

Country Status (18)

Country Link
JP (1) JPS6224427B2 (pl)
AT (1) AT343655B (pl)
AU (1) AU502892B2 (pl)
BE (1) BE837796A (pl)
BR (1) BR7600385A (pl)
CA (1) CA1077047A (pl)
CH (1) CH597198A5 (pl)
DD (1) DD123745A5 (pl)
DE (1) DE2601719A1 (pl)
ES (1) ES444523A1 (pl)
FR (1) FR2298543A1 (pl)
GB (1) GB1466558A (pl)
IT (1) IT1060209B (pl)
NL (1) NL7600732A (pl)
PL (1) PL97084B1 (pl)
SE (1) SE426243B (pl)
SU (1) SU582759A3 (pl)
ZA (1) ZA76372B (pl)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4268610A (en) * 1979-11-05 1981-05-19 Hercules Incorporated Photoresist formulations
DE3172025D1 (en) * 1980-07-15 1985-10-03 Ciba Geigy Ag Printing ink and its use in the manufacture of textured, foamed resinous materials
EP0088724B1 (de) * 1982-02-26 1988-05-18 Ciba-Geigy Ag Benzotriazolgemische, Verfahren zu deren Herstellung und ihre Verwendung als Metallpassivatoren
GB2152073B (en) * 1983-12-23 1986-10-22 Ciba Geigy Lubricant stabilizer additives
JPS63191514U (pl) * 1987-05-28 1988-12-09
JPH01127127U (pl) * 1988-02-25 1989-08-30
US4880551A (en) * 1988-06-06 1989-11-14 R. T. Vanderbilt Company, Inc. Antioxidant synergists for lubricating compositions
JPH0236132U (pl) * 1988-08-31 1990-03-08
EP0428383A1 (en) * 1989-11-13 1991-05-22 Shikoku Chemicals Corporation Process for surface treatment of copper and copper alloy
US4997585A (en) * 1990-03-30 1991-03-05 Exxon Research And Engineering Company Aromatic substituted benzotriazole containing lubricants having improved oxidation stability
GB9013142D0 (en) * 1990-06-13 1990-08-01 Ciba Geigy Ag Chemical compounds useful as metal deactivators
JPH06100881A (ja) * 1992-09-18 1994-04-12 Kyoseki Seihin Gijutsu Kenkyusho:Kk 冷凍機油組成物
US5441563A (en) * 1993-07-06 1995-08-15 Armstrong World Industries, Inc. Highly insoluble azole embossing inhibitor and the use thereof
TW399094B (en) * 1995-04-11 2000-07-21 Ciba Sc Holding Ag Compounds with (benzo)triazole radicals
US5548003A (en) * 1995-08-14 1996-08-20 Armstrong World Industries, Inc. Azole-aldehyde addition product embossing inhibitors and the use thereof
US5622922A (en) * 1995-12-27 1997-04-22 Exxon Chemical Patents Inc. Method of solubilizing a benzotriazole with a thiadiazole
US5824721A (en) * 1996-06-10 1998-10-20 Armstrong World Industries, Inc. Water soluble triazole derivative embossing inhibitor and the use thereof
JP3702069B2 (ja) * 1997-05-07 2005-10-05 東洋アルミニウム株式会社 アルミニウム顔料組成物
GB9924358D0 (en) * 1999-10-14 1999-12-15 Brad Chem Technology Ltd Corrosion inhibiting compositions
CN104649985A (zh) * 2013-11-25 2015-05-27 刘现梅 一种水溶性的甲基苯骈三氮唑的次甲基衍生物及其制备方法
US11788026B2 (en) * 2021-07-28 2023-10-17 Afton Chemical Corporation Hydraulic fluid

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1081282A (en) * 1964-08-14 1967-08-31 Geigy Uk Ltd Bis-benzotriazoles and compositions containing same

Also Published As

Publication number Publication date
FR2298543A1 (fr) 1976-08-20
DE2601719A1 (de) 1976-07-29
DD123745A5 (pl) 1977-01-12
AU502892B2 (en) 1979-08-09
CH597198A5 (pl) 1978-03-31
ES444523A1 (es) 1977-06-16
AT343655B (de) 1978-06-12
SE7600160L (sv) 1976-07-26
SE426243B (sv) 1982-12-20
ATA42476A (de) 1977-10-15
BR7600385A (pt) 1976-08-31
CA1077047A (en) 1980-05-06
DE2601719C2 (pl) 1988-01-07
JPS5198276A (pl) 1976-08-30
BE837796A (fr) 1976-07-22
JPS6224427B2 (pl) 1987-05-28
FR2298543B1 (pl) 1979-02-02
NL7600732A (nl) 1976-07-27
SU582759A3 (ru) 1977-11-30
IT1060209B (it) 1982-07-10
ZA76372B (en) 1977-01-26
GB1466558A (en) 1977-03-09
AU1050876A (en) 1977-07-28

Similar Documents

Publication Publication Date Title
PL97084B1 (pl) Sposob wytwarzania nowych pochodnych benzotriazolu
CA1249280A (en) Metal deactivators
EP0022701B1 (en) Improved poly(alkylene oxide) compositions containing a bridged dimer of a hydroxylsubstituted aromatic carboxylic acid or a salt thereof
EP0088724B1 (de) Benzotriazolgemische, Verfahren zu deren Herstellung und ihre Verwendung als Metallpassivatoren
US4177155A (en) Additives for water-based functional fluids
JPS62167755A (ja) 潤滑剤、圧媒液または金属工作媒液と窒素含有イオウ化合物を含有する組成物
CA2289408C (en) Corrosion inhibitor compositions
CA2291417C (en) Corrosion inhibitor compositions
US4107060A (en) Lubricant compositions containing biocidal, antirust additives
US3308161A (en) Alkali metal-dimethyl dodecyl amine salts of oxyacids of phosphorous and sulfur
JPH07108882B2 (ja) 多機能性チアジアゾール製造用の中間体化合物
US4260505A (en) Tris-(polyalkoxyalkylated) isocyanurate compounds and their use as functional fluids
US5538652A (en) Dimercaptothiadiazole-mercaptan coupled compounds as multifunctional additives for lubricants and fuels
US4283399A (en) Parasticide
El-Sayed et al. Synthesis and evaluation of some chromene derivatives as antioxidant with surface activity
US5000873A (en) N-(hydrophobe aromatic)pyridinium compounds
AU695224B2 (en) Dimercaptothiadiazole-mercaptan coupled compounds as multifunctional additives for lubricants and fuels
EP0026709B1 (en) Poly(alkylene oxide)composition containing a nitro-substituted aromatic compound
US4672118A (en) N-(hydrophobe aromatic)pyridinium compounds
JPH0617268A (ja) 防食剤
US3385858A (en) High molecular weight fatty piperazine amphoteric surfactants
Hassan et al. Synthesis and applications of some new antioxidant and anticorrosive additives for Egyptian diesel motor oils
US4262119A (en) Tris-(polyalkoxylated), isocyanurates
US4455429A (en) Oxazolines of 2-(alkylthio)succinic acids as an additive for drilling muds
Nessim Synthesis and Applications of Pyridazinones for Base Oil Improvement