PL94135B1 - - Google Patents

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Publication number
PL94135B1
PL94135B1 PL1975178367A PL17836775A PL94135B1 PL 94135 B1 PL94135 B1 PL 94135B1 PL 1975178367 A PL1975178367 A PL 1975178367A PL 17836775 A PL17836775 A PL 17836775A PL 94135 B1 PL94135 B1 PL 94135B1
Authority
PL
Poland
Prior art keywords
alcohol
hydrogenation
carried out
palladium
catalyst
Prior art date
Application number
PL1975178367A
Other languages
English (en)
Original Assignee
Richter Gedeon Vegyeszeti Gyar Rt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Richter Gedeon Vegyeszeti Gyar Rt filed Critical Richter Gedeon Vegyeszeti Gyar Rt
Publication of PL94135B1 publication Critical patent/PL94135B1/pl

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/19—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds in six-membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (8)

  1. Zastrzezenia patentowe 1. Sposób wytwarzania 5,6,7,8-czterowodoronaftolu-2 przez katalityczne uwodornianie 0-naftolu, zna¬ mienny tym, ze uwodornianie prowadzi sie w alkoholu o 1-3 atomach wegla, w srodowisku kwasnym, w obecnosci katalizatora palladowego ewentualnie zawierajacego aktywatory, pod cisnieniem 1,2-20 atmosfer, korzystnie 4-6 atmosfer I w temperaturze 40-100°C, korzystnie 70-90°C.
  2. 2. Sposób wedlug zastrz. 1, znamienny tym, ze alkohol o 1-3 atomach wegla stosuje sie z zawartoscia wody wynoszaca co najwyzej 10%.
  3. 3. Sposób wedlug zastrz. 1, znamienny tym, ze jako alkohol stosuje sfe metanol.
  4. 4. Sposób wedlug zastrz. 1, znamienny tym, zenal czesc wagowa 0-naftolu stosuje sie 1-20, korzystnie 5—10 czesci wagowych alkoholu, korzystnie metanolu.
  5. 5. Sposób wedlug zastrz. 1, znamienny tym, ti uwodornianie prowadzi sie w obecnosci lodowate¬ go kwasu octowego lub kwasu solnego.
  6. 6. Sposób wedlug zastrz. 1, znamienny tym, ze uwodornianie prowadzi sie przy wartosci pH wynoszacej 1-4.
  7. 7. Sposób wedlug zastrz. 1, znamienny tym, ze jako katalizator stosuja sie pallad na nosniku, korzystnie weglu aktywnym.
  8. 8. Sposób wedlug zastrz. 7, z n a m i e r n y t y m, ze jako katalizator stosuje sie 2-10% pallad osadzony na weglu aktywnym. Prac. Poligraf. UP PRL naklad 120+18 Cena 10 zl i.-' PL
PL1975178367A 1974-02-28 1975-02-27 PL94135B1 (pl)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
HURI534A HU168845B (pl) 1974-02-28 1974-02-28

Publications (1)

Publication Number Publication Date
PL94135B1 true PL94135B1 (pl) 1977-07-30

Family

ID=11000945

Family Applications (1)

Application Number Title Priority Date Filing Date
PL1975178367A PL94135B1 (pl) 1974-02-28 1975-02-27

Country Status (7)

Country Link
BE (1) BE826145A (pl)
BG (1) BG24660A3 (pl)
CS (1) CS188218B2 (pl)
DD (1) DD116596A5 (pl)
HU (1) HU168845B (pl)
PL (1) PL94135B1 (pl)
SU (1) SU584757A3 (pl)

Also Published As

Publication number Publication date
CS188218B2 (en) 1979-02-28
BE826145A (fr) 1975-06-16
BG24660A3 (en) 1978-04-12
HU168845B (pl) 1976-07-28
DD116596A5 (pl) 1975-12-05
SU584757A3 (ru) 1977-12-15

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