PL89177B1 - Synergistic herbicidal mixture[us3888655a] - Google Patents
Synergistic herbicidal mixture[us3888655a] Download PDFInfo
- Publication number
- PL89177B1 PL89177B1 PL1973161846A PL16184673A PL89177B1 PL 89177 B1 PL89177 B1 PL 89177B1 PL 1973161846 A PL1973161846 A PL 1973161846A PL 16184673 A PL16184673 A PL 16184673A PL 89177 B1 PL89177 B1 PL 89177B1
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- denotes
- formula
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- halogen
- radical
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- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 9
- 230000002195 synergetic effect Effects 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 5
- 239000004009 herbicide Substances 0.000 claims abstract description 5
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims abstract description 3
- 239000004480 active ingredient Substances 0.000 claims description 12
- 125000005843 halogen group Chemical group 0.000 claims description 2
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 abstract description 20
- -1 5-chloro-4-methylthiazolyl radical Chemical class 0.000 abstract description 5
- NDTKXJOMFWNZGE-UHFFFAOYSA-N 9-hydroxy-9h-fluorene-1-carboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(O)C3=CC=CC=C3C2=C1 NDTKXJOMFWNZGE-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 229910052736 halogen Inorganic materials 0.000 abstract 7
- 150000002367 halogens Chemical group 0.000 abstract 7
- 150000003254 radicals Chemical class 0.000 abstract 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000004188 dichlorophenyl group Chemical group 0.000 abstract 1
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 1
- 125000005059 halophenyl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- HRDXJKGNWSUIBT-UHFFFAOYSA-N methoxybenzene Chemical group [CH2]OC1=CC=CC=C1 HRDXJKGNWSUIBT-UHFFFAOYSA-N 0.000 abstract 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000013543 active substance Substances 0.000 description 37
- 230000006378 damage Effects 0.000 description 18
- 240000006694 Stellaria media Species 0.000 description 13
- 240000005702 Galium aparine Species 0.000 description 11
- 235000014820 Galium aparine Nutrition 0.000 description 11
- 244000098338 Triticum aestivum Species 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 240000005979 Hordeum vulgare Species 0.000 description 8
- 244000303225 Lamium amplexicaule Species 0.000 description 8
- 235000009198 Lamium amplexicaule Nutrition 0.000 description 8
- 235000010469 Glycine max Nutrition 0.000 description 7
- 244000068988 Glycine max Species 0.000 description 7
- 244000285774 Cyperus esculentus Species 0.000 description 6
- 240000007594 Oryza sativa Species 0.000 description 6
- 241000209140 Triticum Species 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 235000005853 Cyperus esculentus Nutrition 0.000 description 5
- 244000058871 Echinochloa crus-galli Species 0.000 description 5
- 235000011999 Panicum crusgalli Nutrition 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000007340 Hordeum vulgare Nutrition 0.000 description 4
- 240000008042 Zea mays Species 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 241001621841 Alopecurus myosuroides Species 0.000 description 3
- 235000008427 Brassica arvensis Nutrition 0.000 description 3
- 244000024671 Brassica kaber Species 0.000 description 3
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 3
- 241000520028 Lamium Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 241001355178 Setaria faberi Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000007320 Avena fatua Nutrition 0.000 description 2
- 241000209764 Avena fatua Species 0.000 description 2
- 244000192528 Chrysanthemum parthenium Species 0.000 description 2
- 244000024675 Eruca sativa Species 0.000 description 2
- 235000014755 Eruca sativa Nutrition 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000017945 Matricaria Nutrition 0.000 description 2
- 235000007232 Matricaria chamomilla Nutrition 0.000 description 2
- 244000292693 Poa annua Species 0.000 description 2
- 241000209056 Secale Species 0.000 description 2
- 241000220261 Sinapis Species 0.000 description 2
- 235000007244 Zea mays Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 235000000183 arugula Nutrition 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 150000004656 dimethylamines Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 235000012432 gingerbread Nutrition 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- REEXLQXWNOSJKO-UHFFFAOYSA-N 2h-1$l^{4},2,3-benzothiadiazine 1-oxide Chemical class C1=CC=C2S(=O)NN=CC2=C1 REEXLQXWNOSJKO-UHFFFAOYSA-N 0.000 description 1
- 241000748223 Alisma Species 0.000 description 1
- 235000017300 Alisma plantago Nutrition 0.000 description 1
- 240000004615 Alisma plantago-aquatica Species 0.000 description 1
- 241000743985 Alopecurus Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000258957 Asteroidea Species 0.000 description 1
- 241000209761 Avena Species 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 244000056139 Brassica cretica Species 0.000 description 1
- 235000003351 Brassica cretica Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000011293 Brassica napus Nutrition 0.000 description 1
- 235000000540 Brassica rapa subsp rapa Nutrition 0.000 description 1
- 235000003343 Brassica rupestris Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000234646 Cyperaceae Species 0.000 description 1
- 241000234653 Cyperus Species 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 241000192043 Echinochloa Species 0.000 description 1
- 241001101998 Galium Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- BAVYZALUXZFZLV-UHFFFAOYSA-O Methylammonium ion Chemical compound [NH3+]C BAVYZALUXZFZLV-UHFFFAOYSA-O 0.000 description 1
- 235000003805 Musa ABB Group Nutrition 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 241000209094 Oryza Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000015266 Plantago major Nutrition 0.000 description 1
- 241000209048 Poa Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 244000082988 Secale cereale Species 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- 241000243774 Trichinella Species 0.000 description 1
- 244000067505 Xanthium strumarium Species 0.000 description 1
- 240000001781 Xanthosoma sagittifolium Species 0.000 description 1
- 241000209149 Zea Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 150000001559 benzoic acids Chemical class 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical class OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 244000038559 crop plants Species 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-O ethylaminium Chemical compound CC[NH3+] QUSNBJAOOMFDIB-UHFFFAOYSA-O 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000004459 forage Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- QHLFJSMAWAWVRU-UHFFFAOYSA-N n-(5-chloro-4-methyl-1,3-thiazol-2-yl)propanamide Chemical compound CCC(=O)NC1=NC(C)=C(Cl)S1 QHLFJSMAWAWVRU-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
- A01N35/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen containing a carbon-to-nitrogen double bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
- A01N45/02—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Przedmiotem wynalazku jest srodek chwasto¬ bójczy zawierajacy jako substancje czynna mie¬ szanine substancji czynnych.Wiadomo, ze podstawione etery ienylowe, kar¬ baminiany, tereftalany, amidy kwasowe, kwasy benzoesowe, kwasy fluorenokarboksylowe i benzo- tiadiazynony maja dzialanie chwastobójcze. Dzia¬ lanie to jest jednak niezadawalajace.Stwierdzono, ze mieszanina skladajaca sie ze zwiazku o wzorze 1, w którym R oznacza nizszy rodnik alkilowy zawierajacy do 4 atomów wegla lub jego soli takich jak sole metali alkalicznych, metali ziem alkalicznych, sole amoniowe, hydro- ksyalkiloamoniowe lub alkiloamoniowe lub hy- drazynowe, na przyklad soli sodowych, litowych, potasowych, wapniowych, zelazowych, metyloamo- niowych, trójmetyloamoniowych, etyloamoniowych, dwuetanoloamoniowych, etanoloamoniowych, dwu - metyloaminowych, dwumetyloetanoloaminowych, hydrazynowych lub fenylohydrazynowych i zwiaz¬ ku o wzorze 2, w którym n oznacza liczbe 1 lub 2, R oznacza rodnik fenylowy, ewentualnie pod¬ stawiony atomem chlorowca lub grupe trójfluoro- metylowa lub grupe o wzorze 3, ma lepsze dzia¬ lanie chwastobójcze niz poszczególne substancje czynne.Substancje czynne mozna stosowac w dawkach 0,5—5 kg/ha. Stosunek wagowy skladnikowych substancji czynnych 1 : 2 wynosi "5:1 do 1:5, ko¬ rzystnie 3:1 do 1:3.Substancje czynne stosuje sie w uprawach, na przyklad zuboza, ryzu, soji, kukurydzy, ziemniaków, grochu lub fasoli do zwalczania niepozadanych chwastów, na przyklad dwuliscieniowych chwa¬ stów nasiennych, jednoliscieniowych nasiennych chwastów trawiastych oraz Cyperaceae.Mieszaniny mozna stosowac przed wzejsciem roslin i/lub po wzejsciu roslin.Srodek wedlug wynalazku mozna otrzymac w postaci roztworów, emulsji, zawiesin, zawiesin ole¬ jowych, proszków do opylania lub granulatów. Po¬ stacie robocze srodka zaleza calkowicie od celu stosowania. Winny one w kazdym przypadku za¬ wierac substancje czynne w postaci dobrze zdy- spergowanej.Celem otrzymania roztworów do bezposrednie¬ go opryskiwania stosuje sie frakcje olejów mi¬ neralnych o sredniej do wysokiej temperaturze wrzenia,' na przyklad nafte lub olej napedowy, dalej oleje smoly weglowej oraz oleje pochodzenia roslinnego lub zwierzecego oprócz tego cykliczne weglowodory takie jak czterowodonaftalen i alki- lowane naftaleny.Wodne preparaty robocze mozna przygotowac z koncentratów emulsji, past lub proszków zwil- zalnych przez dodanie wody. Do wytworzenia emulsji mozna uzyc same substancje czynne lub rozpuszczone w rozpuszczalniku i zemulgowac w wodzie stosujac substancje zwilzajace i dysper¬ gujace. Mozna równiez otrzymywac koncentraty 89 17789 177 skladajace sie z substancji czynnych, substancji zwilzajacych, przyczepnych, emulgujacych i dy¬ spergujacych. Nastepnie rozcienczac je woda. Co otrzymywania cieczy do opryskiwan mozna sto¬ sowac oleje róznych.typów.Proszki do opylania wykonuje sie przez zmie¬ szanie lub zmielenie razem substancji czynnej ze stalym nosnikiem, na przyklad glina lub nawo¬ zem sztucznym. Granulaty mozna otrzymac przez zwiazanie substancji czynnych na stalych nosnikach. Oprócz tego mozna otrzymac z ole¬ jów zawiesiny do bezposredniego opryskiwania.Nowe zwiazki mozna mieszac z nawozami sztucz¬ nymi, insektycydami, fungicydami lub innymi her¬ bicydami. t Przyklad I. Pedy pszenicy (Triticum aesti- vum), jeczmienia (Hordeum vulgare), gluchego owsa (Avena fatua), wyczynca polnego (Alopecurus myosuroides), przytulii czepnej (Galium aparine), gwiazdnicy pospolitej (Stellaria media), jasnoty rózowej (Lamium amplexicaule) o wysokosci 4—20 cm traktuje sie podanymi dawkami w kg/ha pojedynczych substancji czynnych lub ich mie¬ szanin, kazdorazowo zemiulgowanych lub zdysper- gowanych w 500 litrach wody: I estrem 4-chloro»butyn-2-ylowym-l kwasu N- -3-chlorofenylokambaminowegio w ilosci 1 i 2 kgl/lha, II 5-chloro-4-metylo-2-propionamidotiazolem w ilosci 2 i 3 kg/ha, III eterem 0-<2/,4'-dwunitrofenylowym (3,5-dwu- broimo-4-hydroksyibenzoiaMoksymu w ilosci 0,45 i 1,5 kg/ha, IV kwasem 9-hydroksyfluorenokarboksylowym-9 \ w ilosci 1 i 3 kg/ha, V 2,2-dwutlenkiem 3-izopropylo-2,l,3-benzotia- diazynonu-4 w ilosci 0,75, 1,5, 2 i 3 kg/ha, I + V w ilosci 1,0 + 1,0 kg/ha, II + V w ilosci 2,0 + 1,0 kg/ha, III + V w ilosci 0,75 + 0,75 kg/ha, IV + V w ilosci 1,0 + 2,0 kg/ha.Z tablicy 1 wynika, ze mieszaniny po 8—12 dniach maja lepsze ogólne dzialanie niz poszcze¬ gólne substancje czynne i sa lepiej tolerowane przez rosliny uprawne.Przyklad II. Pedy rycu (Oryza sativa), soji (Soja hispida), kukurydzy (Zea mays), pszenicy (Triticum aesitvum), chwastnicy jednostronnej (Echinochloa crus galli), wlosnicy (Setaria faberii), cibory (Cyperus esculentus), rzepieriia pensylwan¬ skiego (Xanthiuim pensylvanicum), gorczycy (Sina- pis arvensis), babki wodnej (Alisima plantago- -aauatica), przytulii czepnej (Galiuim aparine), ru¬ mianku pospolitego (Matiricaria chomonilla), wy¬ czynca polnego (Alopecurus myosuroides) i wie¬ chliny jednorocznej (Poa annua) o wysokosci 4—20 cm traktuje sie nizej podanymi dawkami w kg/ha pojedynczych zwiazków lub ich miesza- • nin kazdorazowo zemulgowanych lub zdyspergo- wanych w 500 litrach wody: I eterem 2,4'-dwunitro-4-trójfluorometylodwu- fenylowym w ilosci 1,5 i 3 kg/ha, II eterem 4'-nitro-2,4,6-trójchlorodwufenylo- wym w ilosci 2 i 3 kg/ha, III N-(l,l-Dwu\metylopropionylo)-3,5-dwuchloro- benzamidem w ilosci 1 i 3 kg/ha, IV 2-(2-metylo-4-chlorofeno'ksy)-N-metoksyace- tamidem w ilosci 1 i 2 kg/ha, .Roslina Triticum aestivum Hordeum vulgare Avena fatua Alopecurus tmyosuTjoldeis Galium aparine Stellaria media Lamium amplexi- caule I 1 0 0 70 60 2 0 0 90 85 II 2 50 50 40 3 70 75 45 65 r T abl l c a 1 Substancja czynna w kg/ha III '0,75 0 — — 45 1,5 — — . 45 70 80 1 0 0 — — IV 3 0 — — 85 90 95 0,75 0 0 40 V 1 0 0 40 60 40 1,5 0 0 60 70 50 2 0 0 70 90 60 3 0 0 80 90 70 I +V 1+1 • 0 0 85 80 80 90 75 II+V 2+1 " 80 80 90 100 75 III+V 0,75+0,75 0 0 — — 90 100 100 IV+V 1+ 2 0 0 — — 100 100 100 0 = bez uszkodzen 100 = calkowite zniszczenie rosliny89 177 V kwasem 2,3,6-trójchlorabenzoesowym w ilo¬ sci 0,5 i 2 kg/ha^ VI kwasem 2-metoksy-3,6-dwuchlorobenzoeso- wym w ilosci 1,5 i 2 kg/ha, VII 2,2-dwutlenkiem 3-izoproipylo-2,l,3-benzotia- diazynonu-4 w ilosci 0,5, 1, 1,5, 2 i 3 kg/ha, I + VII, w ilosci 1,5 + 1,5 kg/ha, II + VII, w ilosci 2 + 2 kg/ha, III + VII, w ilosci 2 + 2 kg/ha, IV + VII, w ilosci 1 + 1 kg/ha, VI + VII, w ilosci 1,5 + 0,5 kg/ha.Z danych zestawionych w tablicach 2, 3 i 4 wy¬ nika, ze po 8—14 .dniach mieszaniny wykazuja lepsze dzialanie ogólne przy korzystniejszej tole¬ rancji przez rosliny uprawne niz poszczególne skladniki mieszaniny.Przyklad III. Rózne rosliny o wysokosci 2—25 cm rosnace w polu traktuje sie nizej po¬ danymi pojedynczymi substancjami czynnymi lub ich mieszaninami, w postaci zawiesin olejowych: I sola sodowa 2,2-dwutlenku 3-izopropylo-2,l,3- -benzotiadiazynonu-4, II sola ^dwumetyloaminowa 2,2-dwutlenku 3-izo- propylo-2,l,3-benzotiadiazynonu-4, III sola dwuetanoloaminowa 2,2-dwutlenku 3- -izopropylo-2,l,3-benzotiadiazynonu-4, Tabl Substancja czynna kg/ha Rosliny uzytkowe Oryza sativa Soja hispida Zea mays Triticum aestivum Rosliny niepozadane Echinochloa crus galli Setaria faberii Cyperus esculentus Xanthium pensylvani- cum Sinapsis arvensis Alisma plantago Galium aiparine Matricaria chamonilla Alopecurus myosuroi- des Poa annua ic a 2 I 2,5 . , — ' — • 83 78 65 50 80 ' 40 .. — . — — * 4,0 • -35. — . ... _. 100 100 95 87 100 70 — — — — Roslina Oryza sativa Soja hispida Zea mays Triticum aestivum Echino¬ chloa cg.Setaria faberii Cyperus esculen- tus Xanthium pensyl- vanicum Sinapis arvensis Alisma plant.- -aqua.Galium aparine Matricaria chamo- nilla Alopecurus myosu- roides I 1,5 — 65 65 45 60 — 3 — 95 90 80 65 95 50 — 1 II 2 — — / \ 60 60 40 — 3 — — 90 90 55 45 60 \ — III 1 ¦ — — 40 60 — 3 1 — — 80 70 55 60 95 55 -• Tablica Substancja IV 1 — — 0 40 ? 45 45 i 20 — j— 2 — — 70 75 55 90 45 — — i 3 czynna w V 0,5 — — — 0 — — — — — — 1 50 55 2 — — \ — — — — — — — 85 95 95 100 kg/ha VI 1,5 — — — — — — — — — 60 65 45 60 2 — — — — — — — — — 1 85 90 ^ 80 95 | VII 0,5 0 0 0 0 0 0 45 1 0 0 0 0 36 40 60 40 40 50 r 1,5 0 0 0 0 45 60 75 .60 60 60 % 2 0 0 0 65 70 95 75 70 90 3 0 0 0 90 95 100 80 80 95 |89177 Tablica 4 Roslina Gryza sativa Soja hdspida ¦.Zea mayis Tritiouim aestCYiun BdhdtnocMoa cjg.Se/tania faibeotii Cyperus eseuienltuB ' Xanffchiuim peosytlvan.Sfonaplis airyensis Alifeima pilamlta-aqua.Galium aparine MatnLcaria chamom.Alopecuirus imyosuir.Poa anniua Substancja czynna w kg/ha ^ I+VII 2,5+1,5 90 90 100 100 100 100 II+VII 2+1 90 85 95 100 100 90 III+VII 1 + 2 80 75 100 100 100 100 IV+VII 1+1 0 70 • 75 100 100 100 100 V+VII 0,5+1,5 0 100 100 80 VI+VII 1,5+0,5 95 ¦ • 95 80 0 = bez uszkodzen 100 = calkowite zniszczenie IV eterem 0-2/,4,-dwunitrofenylowym, 3,5-dwu- bromo-4-Jiydroksybenzaldoksymu, V 3,3-diwujodo-4-hydroksybenzonitrylem, VI 3,5-dwutoramo-4-hydroksy-benzonitrylem.Stosuje sie kazdorazowo dawki 0,15, 0,45, 0,75 i 0,9 kg/ha substancji czynnej. Stosuje sie r3w- niez mieszaniny I+IV, I+V, I+VI, II+IV, II+V, II+VI, III+IV, III+V i III+VI kazdorazowo w dawkach 0,15+0,75, 0,7^+0,15, 0,45+0,45 kg/ha. Po 8—12 dniach stwierdza sie, ze mieszaniny maja lepsze dzialanie chwastobójcze, przy takiej samej tolerancji przez rosliny uprawne, niz poszczegól¬ ne substancje czynne. Wynik próby podaje sie w tablicy 5a-r- g.Roslina Roslina uprawna Tritkum aestivum Hordeum vulgare Secale cereale Chwasty: Galium aparine Lamium amplexicaule Stellaria media T a b 1 i c a 5a I 0,15 0 0 0 0 7 0,45 0 0 0 18 0,75 0 0 0 40 0,9 0 0 0 55 23 42 Substancja czynna ^w kg/ha II 0,15 0 0 0 • 0 0,45 0 0 0 26 9 26 0,75 0 0 0 40 0,9 0 ' 0 0 47 45 III 0,15 0 0 0 14 3 6 0,45 0 0 0 28 0,75 0 0 0 45 40 0,9 0 0 0 60 32 50 Tablica 5b Roslina Substancja czynna w kg/ha IV 0,15 0,45 0,75 0,9 V 0,15 0,45 0,75 0,9 VI 0,15 0,45 0,75 0,9 Rosliny uprawne: Triticum aestivum Hordeum vulgare Secale acereale Chwasty: Galium aparine Lamium amplexicaule Stellaria media 0 0 0 12 7 0 0 0 33 22 0 0 45 0 60 48 0 0 0 14 6 12 7 54 43 37 74 67 58 0 0 0 11 8 7 0 0 0 0 40 31 7 48 60 5089 177 9 10 Tablica 5c Roslina Rosliny uprawne Triticum aestivum Hordeus vulgare Secale acereale Chwasty Galium aparine Lamium amplexicule Stellaria media Substancja czynna w kg/ha I+IV 0,15+0,75 0 0 70 90 75 0,75+:515 0 0 0 80 68 78 0,45+0,45 0 0 0 83 80 85 i+v | 0,15+0,75 12 7 96 78 80 0,75 + 0,15 0 0 0 90 65 77 0,45+0,45 1 0 6 88 82 81 Tablica 5d Roslina Rosliny uprawne Triticum aestivum Hordeus vulgare Secale cereale Chwasty Galium aparine Lamium amplexicule Stellaria media Substancja czynna w kg/ha . I+VI 0,15+0,75 0 0 76 73 75 0,75+0,'l5 0 0 0 90 •60 73 0,45+0,45 0 0 87 76 80 II+IV 0,15+0,75 0,75 + 0,15 0 68 82 80 0 0 82 70 79 ¦-¦ 0,45+0,45 1 Ó 0 80 78 90 1 Tablica 5e Roslina Rosliny uprawne Triticum aestivum Hordeum vulgare Secale cereale Chwasty Galium aparine Lamium amplexicaule Stellaria media Substancja czynna w kg/ha II+V 0,15+0,75 12 7 ¦: 97 80 85 0,75 + 0,15 Q 0 0 95 67 83 0,45+0,45 6 93 75 02 11+VI 0,15+0,75 0 : 0 78 74 80 0,75 + 0,15 0 0 0 90 66 85 0,45+0,45 | 5 0 0 84 73 88 Tablica 5f Roslina Rosliny uprawne Triticum aestivum Hordeum vulgare Secale cereale Chwasty Galium aparine Lamium amplexicaule Stellaria media Substancja czynna w kg/ha III+IV 0,15+0,75 0 0 . 67 80 74 0,75+ 0,15 0 0 0 83 64 76 0,45+0,45 0 0 0 80 78 82 III+V 0,15+0,75 12 7 IGO 83 80 0,75+ 0,15 0 0 0 97 76 93 0,45+0,^5 6 95 77 1 8411 Tablica 5g Roslina Rosliny uprawne: Triticum aestivum Hordeum vulgare Secale cereale Chwasty Galium aparine Lamium ample- xicaule Stellaria media Substancja czynna i kg/ha | III+VI | 0,15+0,75 0 0 80 75 72 0,75+0,15 0 0 0 92 70 | 83 " 0,45+0,45 1 0 0 ~*86 78 79 89 177 12 Przyklad IV. Rózne rosliny o wysokosci 4—27 cm rosnace w szklarni traktuje sie nizej podanymi pojedynczymi substancjami czynnymi lub ich mieszaninami, w postaci zawiesin: I 2,2-dwutlenkiem 3-izopropylo-2,l,3-benzotia- diazynonu-4, II 3,5-dwuibromo-4-hydroksybenzonitrylem, III 3,5-dwujotio-4-hydroksybenzonitrylem, IV eterem 0-2',4'-dwunitafenylowym 3,5-dwu- 'broino-4-hydroksybenzaldoksymu.Wymienione substancje czynne stosuje sie w dawkach 1,0, 1,5, 2,0 i 3,0 kg/ha oraz mieszaniny I+III, I+II, I+IV w dawkach 2,0+1,0, 1,0+2,0, 1,0+1,0 i 1,5+1,5 kg/ha oraz porównawcze: V l-p-chlorofenylo-3,3-dwumetylomocznikiem w dawkach 2,0 i 3,0 kg/ha i mieszanine V+I w dawce 2,0+1,0 kg/ha.Po 12—15 dniach stwierdzono, ze mieszaniny I+II, I+III i I+V sa lepiej tolerowane przez ro¬ sliny uprawne i maja takie same dzialanie chwa¬ stobójcze jak substancje czynne V i mieszanina V+I. Wynttki prób podaje sie w tablicy 6a-^d. 0 = bez uszkodzen 100 = calkowite zniszczenie rosliny Roslina Rosliny^uprawne Triticum aestivuim Hordeum vulgare Secale cereale Chwasty Galium aparine Lamium amplerficaule Stellaria media T a b 1 i c a 6a Substancja czynna w kg/ha I 1,0 0 0 0 40 40 60 1,5 • 0 0 0 60 50 70 2,0 0 0 0 70 60 90 3,0 0 0 0 80 70 95 II 1,0 8 50 60 54 1,5 12 6 67 70 78 2,0 • 8 14 90 85 90 3,0 18 100 100 100 III 1,0 17 75 70 60 1,5 18 90 80 83 2,0 18 98 94 97 3,0 26 31 100 100 100 Roslina Rosliny uprawne Triticum aestivum Hordeum vulgare Secale cereale Chwasty Galium aparine Lamium amplexicaule Stellaria media T a b 1 i c a 6b Substancja czynna vi IV 1,0 0 7 6 65 50 1,5 45 80 70 2,0 12 60 95 93 3,0 19 18 100 100 100 r kg/ha V 2,0 40 47 56 90 100 100 3,0 70 80 95 95 100 10013 89 177 Tablica 6c 14 Roslina Rosliny uprawne Triticum aestivuim Hordeum vulgare Secale cereale Chwasty Galium aparine Lamium amplexicaule Stellaria media i Substancja czynna kg/ha I+II 2,0+1,0 8 100 100 100 1,0+2,0 8 14 100 100 100 1,0+1,0 ' 5 8 100 100 100 1,5+1,5 12 6 100 100 100 I+III 2,0+1,0 17 100 100 100 1,0+2,0 18 100 100 100 1,0+ 1,0 17 100 100 100 1,5+1,5 18 100 100 100 Roslina Rosliny uprawne Triticum aestivu Hordeum vulgare Secale cereale Chwasty Galium aparine Lamium amplexicaule Stellaria media Tablica 6d Substancja czynna w kg/ha 1+TV 2,0+1,0 . 0 7 6 100 100 100 1,0+2,0 12 100 100 100 1,0+1,0 0 7 6 100 100 100 1,5+ 1,5 100 100 100 i+v 1,0+2,0 • 1 40 47 56 100 100 100 0 = bez uszkodzen 100 = calkowite zniszczenie rosliny Przyklad V. Rózne rosliny o wysokosci v 3—20 cm rosnace w szklarni traktuje sie nizej 45 podanymi pojedynczymi substancjami czynnymi lub ich mieszaninami w postaci emulsji, dyspersji, wodnych roztworów lub zawiesin: I 2,2-dwutlenkiem 3-izopropylo-2,l,3-benzotia- diazynonu-4 0,5, 0,75, 1, 1,5 kg/ha substan¬ cji czynnej, II sola sodowa 2,2-dwutlenku 3-izopropylo- -2,l,3-benzotiadiazynonu-4 0,5, 0,75, 1, 1,5 kg/ha substancji czynnej, III sola dwumetyloaminowa 2,2-dwutlenku 3- -izopropylo-2,l,3-benzotiadiazynonu-4 0,5, 0,75, 1, 1,5 kg/ha substancji czynnej, IV sola dwuetanoloaminowa 2,2-dwutlenku 3- -izopropylo-2,l,3-benzotiadiazynonu-4 0,5, 0,75, 1, 1,5 kg/ha substancji czynnej, V eterem 4'-natro-2,4-dwuchlorodwufenylo- wym 0,5, 0,75, 1, 1,5 kg/ha substancji czyn¬ nej, 50 55 60 65 VI eterem 2,4-dwunitro-4-trójflruorometylodwu- fenylowym 0,5, 0,75, 1, 1,5 kg/ha substan¬ cji czynnej, VII eterem 4'-nitro-2,4,6-trójchlorodwufenylo- wym 0,5, 0,75, 1, 1,5 kg/ha substancji czyn¬ nej, VIII eterem 4'-nitro-2,4-dwuchloro-6-fluorodwu- fenylowym 0,5, 0,75,. 1, 1,5 kg/ha substancji czynnej, IX eterem 2,4-dwuchloro-4/-nitro-3-metoksy- dwufenylowym 0,5, 0,75, 1, 1,5 kg/ha sub¬ stancji czynnej.Mieszaniny I+V, I+VI, I+VII, I+VIII, I+IX, II+V, II+VI, II+VII, II+VIII, II+IX, III+V, III+VI, III+VII, III+VIII, III+IX, IV+V, IV+VI, IV+VII, IV+VIII, IV+IX stosowano w dawkach 0,5+1, 1+0,5, 0,75+0,75 kg/ha substancji czynnej.Po 2—3 tygodniach stwierdzono, ze mieszaniny wykazuja lepsze dzialanie chwastobójcze przy jed¬ nakowej tolerancji przez rosliny uprawne, anizeli pojedyncze substancje czynne. Wyniki podano w tablicy 7a -5- e.Tablica 7a Substancja czynna kg/ha Rosliny uzytkowe Oryza sartiva Glycine max Rosliny niepozadane Echinochloa crus galli Cyperus esculentus Sinapis arvensis I 0,5 0 Q 4 0,75 0.- 0 7 40 45 1 0 0 60 60 1,5 0 0 70 75 II 0,5 0 0 2 0,75 0 0 8 40 1 0 0 45 50 1,5 0 0 70 75 III 0,5 0 0 0,75 0 0 9 40 1 0 0 50 55 1,5 0 0 70 80 IV 0,5 0 0 7 1 0 0 12 53 62 1,5 0 0 17 78 85 0,75 Q 0 42 V 0,5 0 0 50 1 0 60 1,5 70 50 0,75 0 0 50 0 100 bez uszkodzen calkowite zniszczenie Tablica 7b Substancja czynna kg/ha Rosliny uzytkowe Oryza sativa Glycine max Rosliny niepoza¬ dane Echinochloa crus galli Cyperus esculentus Sinapis arvensis l 0,5 0 0 40 0,75 0 0 50 40 VI 1 0 0 60 ' 50 1,5 65 45 60 0,5 0 — 0,75 0 — 40 VII 1 0 — 70 45 1,5 - 5 . — 85 45 60 0,5 0 — 40 0,75 — 60 40 VIII 1 8 — 65 45 1,5 — 80 40 60 0,5 3 0 45 17 0,75 0 55 IX 1 0 60 32 40 1,5 75 45 55 00 c© •^ -^ 0 = bez uszkodzen 100 = calkowite zniszczenieTablica 7c Substancja czynna kg/ha Rosliny uzytkowe Oryza sativa Glycine max Rosliny niepozadane Echinochloa crus galli Cyperus esculentus Sinapis arvensis I+V 0,5 1 0 100 90 100 1 0,5 0 0 95 100 100 0,75 0,75 0 0 98 100 100 I+VI 0,5 1 0 0 90 .96 100 1 0,5 0 0 85 100 100 0,75 0,75 0 0 87 100 100 I+VII 0,5 1 0 90 87 100 1 0,5 0 85 100 100 0,75 0,75 0 90 95 100 I+VIII 0,5 1 8 100 95 100 1 0,5 0 95 100 100 0,75 0,75 100 100 100 I+IX 0,5 1 0 100 92 100 1 0,5 3 0 98 100 100 0,75 0,75 0 100 100 100 11+V 0,5 1 0 98 90 97 1 0,5 0 0 96 97 100 0,75 0,75 0 0 95 90 100 II+VI 0,5 1 0 0 100 100 100 1 0,5 0 0 95 97 100 0,75 0,75 o 1 0 96 94 100 0 = bez uszkodzen * 100 = calkowite zniszczenie Tablica 7d Substancja czynna kg/ha Rosliny uzytkowe Oryza sativa Glycine max Rosliny niepozadane Echinochloa crus galli Cyperus esculentus Sinapis a 11+VII 0,5 1 0 100 90 100 1 0,5 0 90 95 100 0?5 0,7.R 0 90 84 98 II+VIII 0,5 1 8 100 93 100 1 0,5 0 94 97 100 0,75 0,75 100 95 100 11+IX 0,5 1 0 97 92 100 1 0,5 3 0 98 96 100 0,75 0,75 0 95 90 100 III+V 0,5 1 . 0 100 90 98 1 0,5 0 0 95 100 100 0,75 0,75 0 0 95 95 100 III+VI 0,5 1 0 0 100 97 100 1 0,5 0 0 92 98 100 0,75 0,75 0 0 95 96 100 III+VII 0,5 1 0 100 88 100 1 0,5 0 90 95 100 0,75 0,75 0 90 86 100 III+VIII 0,5 1 8 100 95 100 1 0,5 0 95 100 100 0,75 0,75 100 97 100 0 = bez uszkodzen 100 = calkowite zniszczenieco Tablica 7e Substancja czynna kg/ha Rosliny uzytkowe Oryza sativa Glycine max Rosliny niepozadane Echinochloa crus galli Cyperus esculentus Sinapis aa:vensis III+IX 0,5 1 0 100 95 100 1 0,5 " 3 0 90 100 100 0,75 0,75 0 100 97 100 IV+V 0,5 1 0 100 90 97 1 0,5 0 0 100 100 100 075 0,75 0 0 98 90 100 IV+VI 0,5 1 0 0 100 97 100 1 0,5 0 0 90 95 100 0,75 0,75 0 0 100 95 100 IV+VII 0,5 1 0 100 95 100 1 0,5 0 90 95 100 0,75 0,75 0 86 85 97 IV+VIII 0,5 1 8 100 97 100 1 0,5 0 92 100 100 0,75 0,75 100 95 100 IV+IX 0,5 1 0 100 98 100 1 0,5 3 0 97 100 100 0,75 0,75 0 100 95 100 0 = bez uszkodzen 100 = calkowite zniszczenie89 177 21 PL
Claims (3)
1. Zastrzezenie patentowe Srodek chwastobójczy, znamienny tym, ze jako substancje czynna zawiera mieszanine zwiazku o wzorze 1, w którym R oznacza nizszy rodnik 22 alkilowy zawierajacy do 4 atomów wegla, lub soli tego zwiazku i zwiazku o wzorze 2, w którym n oznacza liczbe 1 lub
2. , R oznacza rodnik fe- nylowy ewentualnie podstawiony atomem chloro¬ wca lub grupa trójfluorometyIowa lub grupe o wzorze
3. Wzór 1 (NOo)^ V0-R '2'n Wzór 2 A -N=CH / V OH Br Wzór 3 PL
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| PL1973184051A PL92054B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184054A PL91868B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184052A PL91882B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973161846A PL89177B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184050A PL92145B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184053A PL91883B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184055A PL92142B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
Family Applications Before (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1973184051A PL92054B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184054A PL91868B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184052A PL91882B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1973184050A PL92145B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184053A PL91883B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
| PL1973184055A PL92142B1 (en) | 1972-04-13 | 1973-04-11 | Synergistic herbicidal mixture[us3888655a] |
Country Status (29)
| Country | Link |
|---|---|
| US (1) | US3888655A (pl) |
| JP (4) | JPS4914636A (pl) |
| AR (1) | AR213606A1 (pl) |
| AT (7) | AT324038B (pl) |
| BE (1) | BE798204A (pl) |
| BG (8) | BG20277A3 (pl) |
| BR (1) | BR7302710D0 (pl) |
| CA (1) | CA1018789A (pl) |
| CH (1) | CH575707A5 (pl) |
| CS (1) | CS192461B2 (pl) |
| DE (1) | DE2217722C2 (pl) |
| DK (1) | DK137702C (pl) |
| EG (1) | EG11078A (pl) |
| ES (1) | ES413606A1 (pl) |
| FR (1) | FR2180097B1 (pl) |
| GB (1) | GB1417279A (pl) |
| HU (1) | HU166808B (pl) |
| IL (1) | IL41840A (pl) |
| IT (1) | IT980159B (pl) |
| KE (1) | KE2630A (pl) |
| MY (1) | MY7600183A (pl) |
| NL (1) | NL182772C (pl) |
| OA (1) | OA04402A (pl) |
| PH (1) | PH10948A (pl) |
| PL (7) | PL92054B1 (pl) |
| SE (3) | SE388754B (pl) |
| SU (8) | SU500737A3 (pl) |
| TR (1) | TR17279A (pl) |
| ZA (1) | ZA732518B (pl) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54126686A (en) * | 1978-03-24 | 1979-10-02 | Matsuyama Sekyu Kagaku Kk | Method of recovering liquid phase oxidating catalyst |
| JPS6136793U (ja) * | 1984-08-10 | 1986-03-07 | 日吉工業株式会社 | 高圧ホ−スと接手金具の接続構造 |
| JPS6252390U (pl) * | 1985-09-20 | 1987-04-01 | ||
| JPH0464687U (pl) * | 1990-10-17 | 1992-06-03 | ||
| DE4315878A1 (de) | 1993-05-12 | 1994-11-17 | Basf Ag | Magnesiumsalz von 3-Isopropyl-2,1,3-benzothiadiazin-4-on-2,2 -dioxid, Verfahren zu seiner Herstellung und seine Verwendung zur Bekämpfung von unerwünschtem Pflanzenwuchs |
| DE59503065D1 (de) * | 1994-11-28 | 1998-09-10 | Elpatronic Ag | Verfahren zur Inbetriebnahme oder Umrüstung einer Zargenschweissmaschine sowie ein modulares Magazin zum Durchführen des Verfahrens |
| DE19505036A1 (de) * | 1995-02-15 | 1996-08-22 | Basf Ag | Verfahren zur Herstellung von Ammonium-Salzen von 3-Isopropyl-2,1,3-benzothidadizin-4-on-2,2-dioxid |
| US6218337B1 (en) | 1996-09-27 | 2001-04-17 | Basf Aktiengesellschaft | Solid mixtures of 3-isopropyl-2,1,3-benzothiadiazin-4-one-2,2,-dioxide or its salts |
| MXPA05006514A (es) * | 2002-12-16 | 2006-03-17 | Valent Biosciences Corp | Composicion herbicida que comprende un inhibidor de ps-ii e inductor de sar. |
| DK2258188T3 (da) * | 2003-03-13 | 2014-05-26 | Basf Se | Herbicide blandinger indeholdende picolinafen |
| CN104478829A (zh) * | 2014-11-12 | 2015-04-01 | 浙江中山化工集团股份有限公司 | 一种苯达松二甲胺盐原药的制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE572662A (pl) * | 1957-11-05 | |||
| US3708277A (en) * | 1966-08-30 | 1973-01-02 | Basf Ag | Herbicidal method |
| DE1913266C2 (de) * | 1969-03-15 | 1985-07-18 | Basf Ag, 6700 Ludwigshafen | Herbizid |
| DE1913850A1 (de) * | 1969-03-19 | 1970-10-01 | Basf Ag | Herbizid |
| DE1918946A1 (de) * | 1969-04-15 | 1970-10-22 | Basf Ag | Herbizid |
-
1972
- 1972-04-13 DE DE2217722A patent/DE2217722C2/de not_active Expired
-
1973
- 1973-03-15 BG BG024999A patent/BG20277A3/xx unknown
- 1973-03-15 BG BG024997A patent/BG20275A3/xx unknown
- 1973-03-15 BG BG024995A patent/BG20274A3/xx unknown
- 1973-03-15 BG BG024996A patent/BG19364A3/xx unknown
- 1973-03-15 BG BG024994A patent/BG20273A3/xx unknown
- 1973-03-15 BG BG025000A patent/BG20278A3/xx unknown
- 1973-03-15 BG BG024998A patent/BG20276A3/xx unknown
- 1973-03-15 BG BG022999A patent/BG20752A3/xx unknown
- 1973-03-19 JP JP48031078A patent/JPS4914636A/ja active Pending
- 1973-03-20 IL IL41840A patent/IL41840A/xx unknown
- 1973-03-21 CA CA166,996A patent/CA1018789A/en not_active Expired
- 1973-03-22 US US343629A patent/US3888655A/en not_active Expired - Lifetime
- 1973-03-23 PH PH14459A patent/PH10948A/en unknown
- 1973-04-03 EG EG123/73A patent/EG11078A/xx active
- 1973-04-03 TR TR17279A patent/TR17279A/xx unknown
- 1973-04-05 CH CH487773A patent/CH575707A5/xx not_active IP Right Cessation
- 1973-04-06 SE SE7304922A patent/SE388754B/xx unknown
- 1973-04-10 NL NLAANVRAGE7304999,A patent/NL182772C/xx not_active IP Right Cessation
- 1973-04-11 IT IT49364/73A patent/IT980159B/it active
- 1973-04-11 PL PL1973184051A patent/PL92054B1/pl unknown
- 1973-04-11 HU HUBA2909A patent/HU166808B/hu unknown
- 1973-04-11 OA OA54879A patent/OA04402A/xx unknown
- 1973-04-11 PL PL1973184054A patent/PL91868B1/pl unknown
- 1973-04-11 PL PL1973184052A patent/PL91882B1/pl unknown
- 1973-04-11 PL PL1973161846A patent/PL89177B1/pl unknown
- 1973-04-11 PL PL1973184050A patent/PL92145B1/pl unknown
- 1973-04-11 PL PL1973184053A patent/PL91883B1/pl unknown
- 1973-04-11 PL PL1973184055A patent/PL92142B1/pl unknown
- 1973-04-12 ES ES413606A patent/ES413606A1/es not_active Expired
- 1973-04-12 SU SU2009995A patent/SU500737A3/ru active
- 1973-04-12 SU SU1906703A patent/SU469229A3/ru active
- 1973-04-12 SU SU2009521A patent/SU535880A3/ru active
- 1973-04-12 DK DK199373A patent/DK137702C/da not_active IP Right Cessation
- 1973-04-12 ZA ZA732518A patent/ZA732518B/xx unknown
- 1973-04-12 SU SU2009520A patent/SU493056A3/ru active
- 1973-04-12 SU SU2009996A patent/SU523626A3/ru active
- 1973-04-12 SU SU2009993A patent/SU495801A3/ru active
- 1973-04-12 GB GB1755373A patent/GB1417279A/en not_active Expired
- 1973-04-12 SU SU2009994A patent/SU522767A3/ru active
- 1973-04-13 BR BR732710A patent/BR7302710D0/pt unknown
- 1973-04-13 FR FR7313532A patent/FR2180097B1/fr not_active Expired
- 1973-04-13 AT AT328573A patent/AT324038B/de not_active IP Right Cessation
- 1973-04-13 AR AR247543A patent/AR213606A1/es active
- 1973-04-13 AT AT808474A patent/ATA808474A/de unknown
- 1973-04-13 BE BE130003A patent/BE798204A/xx not_active IP Right Cessation
- 1973-04-13 AT AT808474*7A patent/AT328220B/de not_active IP Right Cessation
- 1973-04-13 AT AT808674*7A patent/AT328221B/de not_active IP Right Cessation
- 1973-04-13 CS CS732646A patent/CS192461B2/cs unknown
- 1973-04-13 AT AT808174A patent/ATA808174A/de unknown
- 1973-04-13 AT AT808574*7A patent/AT326947B/de not_active IP Right Cessation
- 1973-04-13 AT AT808174*7A patent/AT327606B/de not_active IP Right Cessation
-
1974
- 1974-03-28 SU SU2009997A patent/SU520012A3/ru active
-
1976
- 1976-03-08 SE SE7603082A patent/SE404287B/xx not_active IP Right Cessation
- 1976-03-09 SE SE7603124A patent/SE419818B/xx not_active IP Right Cessation
- 1976-05-25 KE KE2630*UA patent/KE2630A/xx unknown
- 1976-12-30 MY MY183/76A patent/MY7600183A/xx unknown
-
1981
- 1981-01-28 JP JP56010282A patent/JPS5915884B2/ja not_active Expired
- 1981-01-28 JP JP1028381A patent/JPS56131503A/ja active Pending
- 1981-01-28 JP JP1028481A patent/JPS56131504A/ja active Pending
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