CN1306873C - 基于1－(2－氯苯基)－4－(n－环己基－n－乙基氨基羰基)－1,4－二氢－5h－四唑－5－酮和敌稗的选择性除莠剂 - Google Patents
基于1－(2－氯苯基)－4－(n－环己基－n－乙基氨基羰基)－1,4－二氢－5h－四唑－5－酮和敌稗的选择性除莠剂 Download PDFInfo
- Publication number
- CN1306873C CN1306873C CNB981040810A CN98104081A CN1306873C CN 1306873 C CN1306873 C CN 1306873C CN B981040810 A CNB981040810 A CN B981040810A CN 98104081 A CN98104081 A CN 98104081A CN 1306873 C CN1306873 C CN 1306873C
- Authority
- CN
- China
- Prior art keywords
- reactive compound
- combination
- rice
- formula
- cyclohexyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004009 herbicide Substances 0.000 title abstract description 12
- LFULEKSKNZEWOE-UHFFFAOYSA-N propanil Chemical compound CCC(=O)NC1=CC=C(Cl)C(Cl)=C1 LFULEKSKNZEWOE-UHFFFAOYSA-N 0.000 title abstract description 6
- LLQPHQFNMLZJMP-UHFFFAOYSA-N Fentrazamide Chemical compound N1=NN(C=2C(=CC=CC=2)Cl)C(=O)N1C(=O)N(CC)C1CCCCC1 LLQPHQFNMLZJMP-UHFFFAOYSA-N 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 claims abstract description 56
- 230000002195 synergetic effect Effects 0.000 claims abstract description 10
- 241000196324 Embryophyta Species 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- -1 compound compound Chemical class 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 5
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 claims description 3
- 229940080818 propionamide Drugs 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 238000009333 weeding Methods 0.000 claims 4
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 26
- 235000009566 rice Nutrition 0.000 abstract description 26
- 241000209140 Triticum Species 0.000 abstract description 3
- 235000021307 Triticum Nutrition 0.000 abstract description 3
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 34
- 238000012360 testing method Methods 0.000 description 31
- 241000209094 Oryza Species 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 230000002363 herbicidal effect Effects 0.000 description 11
- 239000002689 soil Substances 0.000 description 11
- 244000058871 Echinochloa crus-galli Species 0.000 description 10
- 239000007921 spray Substances 0.000 description 10
- 241000511986 Oryza sp. Species 0.000 description 9
- 238000009331 sowing Methods 0.000 description 9
- 240000000178 Monochoria vaginalis Species 0.000 description 7
- 235000011999 Panicum crusgalli Nutrition 0.000 description 7
- 239000013543 active substance Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000003973 irrigation Methods 0.000 description 4
- 230000002262 irrigation Effects 0.000 description 4
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 241000801118 Lepidium Species 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 235000005781 Avena Nutrition 0.000 description 2
- 244000075850 Avena orientalis Species 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- 235000007516 Chrysanthemum Nutrition 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 235000021506 Ipomoea Nutrition 0.000 description 2
- 241000207783 Ipomoea Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 241000209510 Liliopsida Species 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 241000209117 Panicum Species 0.000 description 2
- 235000006443 Panicum miliaceum subsp. miliaceum Nutrition 0.000 description 2
- 235000009037 Panicum miliaceum subsp. ruderale Nutrition 0.000 description 2
- 244000037751 Persicaria maculosa Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 235000004442 Polygonum persicaria Nutrition 0.000 description 2
- 235000002634 Solanum Nutrition 0.000 description 2
- 241000207763 Solanum Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 1
- CFWRDBDJAOHXSH-SECBINFHSA-N 2-azaniumylethyl [(2r)-2,3-diacetyloxypropyl] phosphate Chemical compound CC(=O)OC[C@@H](OC(C)=O)COP(O)(=O)OCCN CFWRDBDJAOHXSH-SECBINFHSA-N 0.000 description 1
- 241000219144 Abutilon Species 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 241000427159 Achyranthes Species 0.000 description 1
- 241000209136 Agropyron Species 0.000 description 1
- 241000743339 Agrostis Species 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 241000234282 Allium Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000219318 Amaranthus Species 0.000 description 1
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 241001666377 Apera Species 0.000 description 1
- 235000003911 Arachis Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000005340 Asparagus officinalis Nutrition 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000611157 Brachiaria Species 0.000 description 1
- 241000339490 Brachyachne Species 0.000 description 1
- 241000219198 Brassica Species 0.000 description 1
- 235000011331 Brassica Nutrition 0.000 description 1
- 244000056139 Brassica cretica Species 0.000 description 1
- 235000003351 Brassica cretica Nutrition 0.000 description 1
- 235000003343 Brassica rupestris Nutrition 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 241000217446 Calystegia sepium Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 244000036828 Carduus nutans Species 0.000 description 1
- 240000004385 Centaurea cyanus Species 0.000 description 1
- 235000005940 Centaurea cyanus Nutrition 0.000 description 1
- 241000219312 Chenopodium Species 0.000 description 1
- 235000000509 Chenopodium ambrosioides Nutrition 0.000 description 1
- 244000098897 Chenopodium botrys Species 0.000 description 1
- 235000005490 Chenopodium botrys Nutrition 0.000 description 1
- 240000005250 Chrysanthemum indicum Species 0.000 description 1
- 244000192528 Chrysanthemum parthenium Species 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241000132536 Cirsium Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 235000010071 Cucumis prophetarum Nutrition 0.000 description 1
- 244000024469 Cucumis prophetarum Species 0.000 description 1
- 235000003392 Curcuma domestica Nutrition 0.000 description 1
- 244000008991 Curcuma longa Species 0.000 description 1
- 240000001689 Cyanthillium cinereum Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241000234653 Cyperus Species 0.000 description 1
- 241000721045 Daubentonia Species 0.000 description 1
- 241000208175 Daucus Species 0.000 description 1
- 235000017896 Digitaria Nutrition 0.000 description 1
- 241001303487 Digitaria <clam> Species 0.000 description 1
- 241000192043 Echinochloa Species 0.000 description 1
- 241000202829 Eleocharis Species 0.000 description 1
- 241001517310 Eria Species 0.000 description 1
- 241001290564 Fimbristylis Species 0.000 description 1
- 241001101998 Galium Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 235000009438 Gossypium Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000209219 Hordeum Species 0.000 description 1
- 241001327265 Ischaemum Species 0.000 description 1
- 241000208822 Lactuca Species 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 241000520028 Lamium Species 0.000 description 1
- 244000207740 Lemna minor Species 0.000 description 1
- 235000006439 Lemna minor Nutrition 0.000 description 1
- 241000208204 Linum Species 0.000 description 1
- 244000048927 Lolium temulentum Species 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000017945 Matricaria Nutrition 0.000 description 1
- 235000007232 Matricaria chamomilla Nutrition 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 235000003990 Monochoria hastata Nutrition 0.000 description 1
- 241001504654 Mustela nivalis Species 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241001148659 Panicum dichotomiflorum Species 0.000 description 1
- 235000011096 Papaver Nutrition 0.000 description 1
- 240000001090 Papaver somniferum Species 0.000 description 1
- 241001330453 Paspalum Species 0.000 description 1
- 241000219833 Phaseolus Species 0.000 description 1
- 241000219843 Pisum Species 0.000 description 1
- 241001092090 Pittosporum Species 0.000 description 1
- 244000292693 Poa annua Species 0.000 description 1
- 241000205407 Polygonum Species 0.000 description 1
- 235000006386 Polygonum aviculare Nutrition 0.000 description 1
- 244000292697 Polygonum aviculare Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000219295 Portulaca Species 0.000 description 1
- 235000001855 Portulaca oleracea Nutrition 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- 241000218206 Ranunculus Species 0.000 description 1
- 241000219053 Rumex Species 0.000 description 1
- 241000209051 Saccharum Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 241000209056 Secale Species 0.000 description 1
- 241000780602 Senecio Species 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 235000005775 Setaria Nutrition 0.000 description 1
- 241000232088 Setaria <nematode> Species 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 240000006694 Stellaria media Species 0.000 description 1
- 240000001949 Taraxacum officinale Species 0.000 description 1
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 241000219422 Urtica Species 0.000 description 1
- 241000159750 Urtica cannabina Species 0.000 description 1
- 241001573053 Vandellia Species 0.000 description 1
- 241000219873 Vicia Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 241000405217 Viola <butterfly> Species 0.000 description 1
- 241001506766 Xanthium Species 0.000 description 1
- 241000209149 Zea Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 244000193174 agave Species 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000013066 combination product Substances 0.000 description 1
- 229940127555 combination product Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000003373 curcuma longa Nutrition 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004459 forage Substances 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 239000007952 growth promoter Substances 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 210000001699 lower leg Anatomy 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- 229940042880 natural phospholipid Drugs 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000013348 organic food Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- CTYRPMDGLDAWRQ-UHFFFAOYSA-N phenyl hydrogen sulfate Chemical compound OS(=O)(=O)OC1=CC=CC=C1 CTYRPMDGLDAWRQ-UHFFFAOYSA-N 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000004577 thatch Substances 0.000 description 1
- ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
- 229960000278 theophylline Drugs 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000013976 turmeric Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
- A01N29/10—Halogen attached to an aliphatic side chain of an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
包含(a)1-(2-氯苯基)-4-(N-环己基-N-乙基氨基羰基)-1，4-二氢-5H-四唑-5-酮和(b)N-(3，4-二氯苯基)丙酰胺(Propanil)的新的除莠活性化合物组合在适当的重量比下表现出增效活性，可以用作多种作物(例如稻米和小麦)的选择性除莠剂。
Description
本发明涉及已知化合物1-(2-氯苯基)-4-(N-环己基-N-乙基氨基羰基)-1，4-二氢-5H-四唑-5-酮和已知的活性化合物敌稗(Propanil)的新的除莠增效活性化合物组合，它可以成功地用来选择性控制多种作物的杂草。
化合物1-(2-氯苯基)-4-(N-环己基-N-乙基氨基羰基)-1，4-二氢-5H-四唑-5-酮也称为1-(2-氯苯基)-4-(N-环己基-N-乙基氨基甲酰基)-5(4H)-四唑啉酮或1-(2-氯苯基)-N-环己基-N-乙基-4，5-二氢-5-氧代-1H-四唑-1-甲酰胺，是公知的除莠活性物质(参见EP 612 735/US 5362704)。然而，该化合物单独的除莠活性并不总能令人满意。
通常称为敌稗的化合物(也可以称为N-(3，4-二氯苯基)丙酰胺或3′，4′-二氯-3-戊酮-N-丙酰苯胺)是长期以来已知的除莠活性化合物，并且被作为市售产品的成分。然而，该化合物单独的除莠活性也并不总能令人满意。
令人惊讶的是，生物学试验现在表明一种新的活性化合物组合在除莠活性方面具有明显的增效作用，可以用作有效的宽范围组合产品，特别适用于作物例如稻米和小麦(尤其是稻米)的杂草的选择性控制。所述组合包括
(a)有效量的式(I)的1-(2-氯苯基)-4-(N-环己基-N-乙基氨基羰基)-1，4-二氢-5H-四唑-5-酮：
和
(b)有效量的式(II)的N-(3，4-二氯苯基)丙酰胺(Propanil)：
令人惊讶的是，本发明的活性化合物组合的除莠活性比各独立的活性化合物的活性之和高得多。
这意味着，出现了意外的增效作用，而不仅仅是作用的补充。许多作物都可以耐受该新的活性化合物组合，甚至难以控制的杂草都可以用本发明的新活性化合物组合加以控制。
本发明的活性组合物组合可以用于例如下述植物：
双子叶杂草种类：芥属、独行菜属、拉拉藤属、繁缕属、母菊属、青黄菊属、牛膝菊属、藜属、荨麻属、千里光属、苋属、马齿苋属、苍耳属、旋花属、番薯属、蓼属、田菁属、豚草属、蓟属、飞廉属、枯苣菜属、茄属、萍菜属、节节菜属、母草属、野芝麻属、斑鸠菊属、苘麻属、刺酸模属、曼陀螺属、堇菜属、鼬瓣花属、罂粟属、矢车菊属、车轴草属、毛茛草属和蒲公英属。
双子叶作物种类：棉属、大豆属、甜菜属、胡萝卜属、菜豆属、豌豆属、茄属、亚麻属、番薯属、野豌豆属、烟草属、番茄属、落花生属、芸苔属、莴苣属、香瓜属和姜黄属。
单子叶杂草种类：稗属、狗尾草属、黍属、马唐属、梯牧草属、早熟禾属、狐茅属、
属、臂形草属、毒麦属、雀麦属、燕麦属、莎草属、高粮属、冰草属、狗牙根属、雨久花属、飘拂草属、慈姑属、荸荠属、蔗草属、雀稗属。鸭嘴草属、尖瓣花属、龙爪茅属、剪股颖属、看麦娘属和Apera。
单子叶作物种类：稻属、玉蜀黍属、小麦属、大麦属、燕麦属、黑麦属、高粮属、黍属、甘蔗属、凤梨属、天门冬属和葱属。
然而，本发明的活性化合物组合并不局限于这些属类，也同样延伸到其它植物。
本发明的活性化合物组合的增效作用在特定的浓度比时特别显著。然而，活性化合物组合中活性化合物的重量比可以在较宽的范围内改变。每重量份式(I)活性化合物一般使用0.10-1000重量份、优选0.05-500重量份、特别优选0.1-100重量份式(II)活性化合物。
该活性化合物或活性化合物组合可以转变为常规制剂，例如溶液剂、乳剂、可湿性粉剂、悬浮液、粉末剂、粉剂、糊剂、可溶性粉剂、粒剂、悬乳液浓缩物、用活性化合物浸渍的天然或合成材料和在聚合物材料中的微胶囊。
这些制剂可以通过常规方式生产，例如将活性化合物与增量剂(即液体溶剂和/或固体载体)可选地与表面活性剂(即润滑剂和/或分散剂和/或泡沫形成剂)一起混合。
如果用水作增量剂，则可以用例如有机溶剂作辅助溶剂。适宜的液体溶剂主要有：芳族化合物例如二甲苯、甲苯或烷基萘、氯代芳族化合物和氯代脂族烃例如氯苯、氯乙烯或二氯甲烷，脂族烃例如环己烷或石蜡。例如石油馏分、矿物油和植物油，醇类化合物例如丁醇和乙二醇及其醚和酯，酮类化合物例如丙酮、甲乙酮、甲基异丁基酮或环己酮，强极性溶剂例如二甲基甲酰胺和二甲基亚砜，和水。
适宜的固体载体是例如：铵盐和土地天然矿物质例如高岭土、粘土、滑石、白垩、石英、硅镁土、蒙脱石或硅藻土，和土地合成矿物质例如细碎分散的二氧化硅、氧化铝和硅酸盐；适宜的粒剂用固体载体是例如压碎和粉碎的天然岩石例如方解石、大理石、浮石，海泡石和白云石，或者无机合成粒剂和有机食物，和有机材料的粒剂例如锯末、椰子壳、玉米芯和烟草杆；适宜的润滑剂和/或泡沫成形剂是例如非离子和阴离子型乳化剂，例如聚氧化乙烯脂肪酸酯、聚氧化乙烯脂肪醇醚例如烷基芳基聚乙二醇醚、烷基磺酸盐、烷基硫酸盐、芳基硫酸盐和蛋白质水解产物；适宜的分散剂是例如木素-亚硫酸盐废液和甲基纤维素。
在制剂中可以使用增粘剂例如羧甲基纤维素和粉末、颗粒或胶乳形式的天然和合成聚合物例如阿拉伯胶、聚乙烯醇和聚乙酸乙烯酯，或者天然磷脂例如脑磷脂和卵磷脂，和合成磷脂。其它的添加剂可以是矿物油和植物油。
还可以使用例如着色剂例如无机颜料例如氧化铁；氧化钛和普鲁士蓝，和有机染料例如茜素染料，偶氮染料和金属酞菁染料和微量营养剂例如铁、镁、硼、铜、钴、钼和锌的盐。
制剂通常包括0.1-95％(重量)活性物质和可选的安全剂例如化合物N-(4-甲基苯基)-N′-(1-甲基-1-苯基乙基)脲(SK-223，dymvon)，优选0.5-90％(重量)的活性化合物和可选的安全剂。
一般来说，本发明的活性化合物组合是已经混合的形式。然而，活性化合物组合中的活性化合物也可以独立地制备，使用时混合，也就是说以罐装合剂的形式施用。
该新的活性化合物组合直接或以其制剂的形式以与其它已知除莠剂的混合物的形式使用，还可以是最终制剂或罐装合剂。也可以是与其它其它已知活性化合物例如杀真菌剂、杀昆虫剂、杀螨剂、杀线虫剂、鸟驱避剂、生长促进剂、植物营养剂和土壤调节剂的混合物。此外，对于特定的目的特别是使用萌芽后法，混入植物能够耐受的矿物油或植物油(例如″Oleo Dupont 11E″，市面有售)或铵盐例如硫酸铵或硫氰酸铵，作用制剂的另外的添加剂。
新的活性化合物组合可以直接使用，以其制剂的形式或者通过进一步稀释制备的使用形式，例如待用溶液、悬浮液、乳液、粉末、糊剂和粒剂。它们以常规的方式使用例如灌溉、喷洒、喷雾、撒播或撒布。
本发明的活性化合物组合的施用比率可以在一定的范围内变化，它们尤其取决于气候和土壤条件。一般来说，施用比率为每公顷0.05-5kg、优选每公顷0.05-2kg、特别是在每公顷0.1-1.0kg之间。
本发明的活性化合物组合可以在植物萌芽之前或之后施用，即采用萌芽前和萌芽后法。
新活性化合物组合的良好的除莠活性在下面的实施例中显而易见。尽管活性化合物单独时表现出较弱的除莠活性，但其组合都表现出对杂草的非常有效的控制，并且该控制超过了其活性的简单加合。
在除莠剂中，当活性化合物组合的活性超过单独施用活性化合物的时，便出现了增效作用。
对于给定的两种除莠剂的组合预期活性可如下计算(参见COLBY，S.R.；″Calculating synergistic and antagonistic responses of herbicidecombinations″，Weeds 15，第20-22页，1967)：
如果X＝在施用比率为p kg/ha时，除莠剂A(式(I)的活性化合物)的损害百分数
Y＝在施用比率为p kg/ha时，除莠剂B(式(II)的活性化合物)的损害百分数
E＝在施用比率为p kg/ha时，预期除莠剂A和除莠剂B会引起的损害百分数
则E＝X+Y-(X*Y/100)
如果实际损害超过了该计算值，则该组合在活性方面是超加合性的，即表现出增效作用。
下述实施例揭示了本发明的活性化合物组合的除莠活性超过了该计算值，即新的活性化合物组合具有增效作用。
使用实施例：
为制备本试验所需的活性化合物制剂，称出适量的上述式(I)的活性成分的50％浓度水可分散性粉剂(50WP)和活性成分含量为360克/升(360 EC)的上式(II)活性化合物(Propanil)市售乳液浓缩物，用水稀释至所需浓度，通过混合制备两种活性成分的各种组合。
所用缩写的意义如下：
a.i.＝活性成分；
实测值＝测得的损害或活性(％)；
计算值＝用上述COLBY公式计算得到的损害或活性(％)。
试验按照下述的方法在不同的地理位置进行，从不同国家(菲律宾、意大利、日本)观察到的结果由于在各地区非常不同的施用条件有所分散。
实施例A：移植稻米试验(菲律宾)
为制备喷雾制剂，将上述活性成分制剂与水混合。调节浓度，使得施用比率对应于450升水/公顷。
将稻米种子(1-2叶期)移植到水稻田试验场(2.5米×2.5米)中。移植7天后，将喷雾制剂施用到试验区(用手动喷雾器)。处理1天后，给土壤灌溉至5厘米水深；静置水深保持不变。
施用活性化合物4周后，相对于未处理对照组目测评定(％)对稻米植物的损害程度和对萌芽杂草Echinochloa crus galli和Monochoriavaginalis的除莠效果。
数字表示：
0％＝无作用/损害(如同未处理的对照物)
100％＝完全破坏
结果示于下表A中。
表A：移植的稻米(菲律宾)
| 试验植物(损害或作用的百分数) | ||||
| 活性成分或组合 | 施用比率(g a.i./ha) | Echinochloacrus galli实测值计算值 | Monochoriavaginalis实测值计算值 | 稻米(Oryza sp.)实测值 |
| (I)(已知) | 125 | 99 | 97 | 0 |
| (II)(已知) | 900 | 93 | 55 | 0 |
| (I)+(II)(按照本发明) | 125+900 | 100(99.9) | 100(98.7) | 0 |
实施例B：播种稻米试验(菲律宾)
为制备喷雾制剂，将上述活性成分制剂与水混合。调节浓度，使得施用比率对应于450升水/公顷。
将稻米种子播种到水稻田(用水饱和的土壤)试验场(2.5米×2.5米)中。播种7天后，将喷雾制剂施用到试验区(用手动喷雾器)。处理1天后，给土壤灌溉至5厘米水深；静置水深保持不变。
施用活性化合物4周后，相对于未处理对照组目测评定(％)对稻米植物的损害程度和对萌芽杂草Echinochloa crus galli、Monochoriavaginalis和Sphenonclea的除莠效果。
数字表示：
0％＝无作用/损害(如同未处理的对照物)
100％＝完全破坏
结果示于下表B1和B2中。
表B1：播种稻米试验(菲律宾)
| 试验植物(损害或作用的百分数) | |||
| 活性成分或组合 | 施用比率(g a.i./ha) | Monochoriavaginalis实测值 计算值 | 稻米(Oryza sp.)实测值 |
| (I)(已知) | 50 | 68 | 1 |
| (II)(已知) | 900 | 87 | 2 |
| (I)+(II)(按照本发明) | 50+900 | 98(95.8) | 13 |
表B2：播种稻米试验(菲律宾)
| 试验植物(损害或作用的百分数) | ||||
| 活性成分或组合 | 施用比率(g a.i./ha) | Ecbinochloacrus galli实测值 计算值 | Monochoriavaginalis实测值 计算值 | 稻米(Oryza sp.)实测值 计算值 |
| (I)(已知) | 50 | 96 | 62 | 2 |
| (II)(已知) | 900 | 87 | 58 | 3 |
| (I)+(II)(按照本发明) | 50+900 | 100(99.5) | 94(84) | 35 |
实施例C：播种稻米试验(意大利)
为制备喷雾制剂，将上述活性成分制剂与水混合。调节浓度，使得施用比率对应于450升水/公顷。
将稻米种子播种到水稻田(润湿的土壤)试验场(2米×5米)中。播种两周后，将喷雾制剂施用到试验区(用手动喷雾器)。处理3天后，给土壤灌溉至5厘米水深；静置水深保持不变。
施用活性化合物4周后，相对于未处理对照组目测评定(％)对稻米植物的损害程度和对萌芽杂草Echinochloa crus galli、Digitariaascendens，Panicumdichotomiflorm和Polygonum persicaria的除莠效果。
数字表示：
0％＝无作用/损害(如同未处理的对照物)
100％＝完全破坏
结果示于下表C1和C2中。
表C1：播种稻米试验(意大利)
| 试验植物(损害或作用的百分数) | |||
| 活性成分或组合 | 施用比率(g a.i./ha) | Monochoriavaginalis实测值 计算值 | 稻米(Oryza sp.)实测值 |
| (I)(已知) | 300 | 35 | 0 |
| (II)(已知) | 1500 | 45 | 0 |
| (I)+(II)(按照本发明) | 300+1500 | 92(64.3) | 0 |
表C2：播种稻米试验(菲律宾)
| 试验植物(损害或作用的百分数) | |||||
| 活性成分或组合 | 施用比率(g a.i./ha) | Digitariaascendens实测值 计算值 | Panicumdichotomiflorum实测值 计算值 | Polygonumpersicaria实测值 计算值 | 稻米(Oryza sp.)实测值 |
| (I)(已知) | 300 | 70 | 60 | 70 | 0 |
| (II)(已知) | 1500 | 75 | 67 | 70 | 0 |
| (I)+(II)(按照本发明) | 300+1500 | 100(92.5) | 92(87) | 100(91) | 0 |
实施例D：播种稻米试验(温室，日本)
为制备适宜的喷雾制剂，通过与水混合，将上述活性成分稀释至所需的浓度。
给培育植物的容器(尺寸：20cm×20cm×9cm；表面积1/2000Ar)中装上来自水稻田的土壤，将稻米种子和Echinochloa crus galli种子播种到保持在润湿条件下的土壤中。在稻米和Echinochloa crus galli的1.5-2叶期，喷洒稀释的活性成分制剂(叶处理)。制剂的活性成分的浓度并不重要；关键是每单位面积活性成分的施用比率。
处理1天后，给土壤灌溉至5厘米深；随后的试验保持在3厘米水深下进行。
施用活性化合物3周后，相对于未处理对照组目测评定(％)对稻米植物的损害程度(或除莠效果)。
数字表示：
0％＝无作用/损害(如同未处理的对照物)
100％＝完全破坏
结果示于下表D1至D4中。
表D1：温室试验(日本1996)
| 试验植物(损害或作用的百分数) | |||
| 活性成分或组合 | 施用比率(ga.i./ha) | Echinochloacrus galli实测值 计算值 | 稻米、(Oryza sp.)实测值 计算值 |
| (I)(已知) | 50 | 50 | 5 |
| (II)(已知) | 450 | 10 | 0 |
| (I)+(II)(按照本发明) | 50+450 | 80(55) | 5(5) |
表D2：温室试验(日本1996)
| 试验植物(损害或作用的百分数) | |||
| 活性成分或组合 | 施用比率(g a.i./ha) | Echinochloacrus galli实测值 计算值 | 稻米(Oryza sp.)实测值 计算值 |
| (I)(已知) | 100 | 80 | 10 |
| (II)(已知) | 450 | 10 | 0 |
| (I)+(II)(按照本发明) | 100+450 | 93(82) | 10(10) |
表D3：温室试验(日本1996)
| 试验植物(损害或作用的百分数) | |||
| 活性成分或组合 | 施用比率(g a.i./ha) | Echinochloacrus galli实测值 计算值 | 稻米(Oryza sp.)实测值 计算值 |
| (I)(已知) | 50 | 50 | 5 |
| (II)(已知) | 900 | 50 | 0 |
| (I)+(II)(按照本发明) | 50+900 | 90(75) | 5(5) |
表D4：温室试验(日本1996)
| 试验植物(损害或作用的百分数) | |||
| 活性成分或组合 | 施用比率(g a.i./ha) | Echinochloacrus galli实测值 计算值 | 稻米(Oryza sp.)实测值 计算值 |
| (I)(已知) | 100 | 80 | 10 |
| (II)(已知) | 900 | 50 | 0 |
| (I)+(II)(按照本发明) | 100+900 | 100(55) | 10(10) |
Claims (6)
1.选择性除莠组合物，其特征在于含有包括下述两种增效活性化合物的组合：
(a)式(I)的1-(2-氯苯基)-4-(N-环己基-N-乙基氨基羰基)-1，4-二氢-5H-四唑-5-酮：
和
(b)式(II)的N-(3，4-二氯苯基)丙酰胺：
其中，每重量份式(I)活性化合物使用0.1-100重量份式(II)活性化合物。
2.按照权利要求1的选择性除莠组合物，其特征在于每重量份式(I)活性化合物使用4.5-18重量份式(II)活性化合物。
3.按照权利要求1的选择性除莠组合物，其特征在于它除了包含新的活性化合物组合外还包括安全剂。
4.选择性控制杂草的方法，其特征在于使按照权利要求1-3的活性化合物组合作用于杂草和/或其生境。
5.权利要求1-3中任一权项的活性化合物组合在选择性控制杂草中的用途。
6.制备选择性除莠组合物的方法，其特征在于将权利要求1-3的活性化合物组合与增量剂和/或表面活性剂混合。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19701845 | 1997-01-21 | ||
| DE19701845.9 | 1997-01-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1195475A CN1195475A (zh) | 1998-10-14 |
| CN1306873C true CN1306873C (zh) | 2007-03-28 |
Family
ID=7817845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB981040810A Expired - Fee Related CN1306873C (zh) | 1997-01-21 | 1998-01-21 | 基于1－(2－氯苯基)－4－(n－环己基－n－乙基氨基羰基)－1,4－二氢－5h－四唑－5－酮和敌稗的选择性除莠剂 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5928991A (zh) |
| JP (1) | JP4068707B2 (zh) |
| KR (1) | KR100479612B1 (zh) |
| CN (1) | CN1306873C (zh) |
| BR (1) | BR9800354A (zh) |
| CO (1) | CO5040024A1 (zh) |
| DE (1) | DE19801637A1 (zh) |
| ES (1) | ES2136035B1 (zh) |
| ID (1) | ID19573A (zh) |
| IT (1) | IT1298151B1 (zh) |
| PA (1) | PA8444801A1 (zh) |
| TW (1) | TW490288B (zh) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999052366A1 (en) * | 1998-04-15 | 1999-10-21 | E.I. Du Pont De Nemours And Company | Herbicidal mixtures |
| DE10142336A1 (de) * | 2001-08-30 | 2003-03-20 | Bayer Cropscience Ag | Selektive Herbizide enthaltend ein Tetrazolinon-Derivat |
| CN102875540A (zh) * | 2012-10-30 | 2013-01-16 | 南开大学 | 2-苯并恶嗪酮基-5-环己氨基羰基四唑酮的除草活性 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5362704A (en) * | 1993-02-25 | 1994-11-08 | Nihon Bayer Agrochem K.K. | Herbicidal tetrazolinones |
| CN1129517A (zh) * | 1994-10-18 | 1996-08-28 | 拜尔公司 | 基于芳基尿嘧啶类的用于水稻栽培中的除莠剂 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4868321A (en) * | 1983-11-04 | 1989-09-19 | Fmc Corporation | Isothiocyanate intermediates |
-
1998
- 1998-01-14 US US09/007,131 patent/US5928991A/en not_active Expired - Fee Related
- 1998-01-16 KR KR10-1998-0001151A patent/KR100479612B1/ko not_active IP Right Cessation
- 1998-01-16 ES ES009800074A patent/ES2136035B1/es not_active Expired - Fee Related
- 1998-01-17 DE DE19801637A patent/DE19801637A1/de not_active Ceased
- 1998-01-19 IT IT98MI000081A patent/IT1298151B1/it active IP Right Grant
- 1998-01-19 CO CO98001956A patent/CO5040024A1/es unknown
- 1998-01-19 ID IDP980060A patent/ID19573A/id unknown
- 1998-01-19 BR BR9800354-2A patent/BR9800354A/pt not_active IP Right Cessation
- 1998-01-19 JP JP02014198A patent/JP4068707B2/ja not_active Expired - Fee Related
- 1998-01-20 TW TW087100673A patent/TW490288B/zh not_active IP Right Cessation
- 1998-01-20 PA PA19988444801A patent/PA8444801A1/es unknown
- 1998-01-21 CN CNB981040810A patent/CN1306873C/zh not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5362704A (en) * | 1993-02-25 | 1994-11-08 | Nihon Bayer Agrochem K.K. | Herbicidal tetrazolinones |
| CN1129517A (zh) * | 1994-10-18 | 1996-08-28 | 拜尔公司 | 基于芳基尿嘧啶类的用于水稻栽培中的除莠剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR9800354A (pt) | 1999-09-08 |
| US5928991A (en) | 1999-07-27 |
| JP4068707B2 (ja) | 2008-03-26 |
| KR100479612B1 (ko) | 2005-06-17 |
| CO5040024A1 (es) | 2001-05-29 |
| TW490288B (en) | 2002-06-11 |
| IT1298151B1 (it) | 1999-12-20 |
| DE19801637A1 (de) | 1998-07-23 |
| KR19980070559A (ko) | 1998-10-26 |
| ID19573A (id) | 1998-07-23 |
| ES2136035A1 (es) | 1999-11-01 |
| ITMI980081A1 (it) | 1999-07-19 |
| JPH10203913A (ja) | 1998-08-04 |
| ES2136035B1 (es) | 2000-05-01 |
| PA8444801A1 (es) | 2001-10-10 |
| CN1195475A (zh) | 1998-10-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105357964B (zh) | 包含壬酸和特定als抑制剂的除草剂组合产品 | |
| US6090750A (en) | Herbicidal combinations | |
| UA115125C2 (uk) | Синергічна гербіцидна комбінація, що містить темботріон | |
| JPH07509695A (ja) | ヘテロアリールオキシアセトアミドをベースとする除草剤 | |
| US6365550B1 (en) | Flufenacet-based herbicidal compositions | |
| KR20110111323A (ko) | 나프탈람을 포함하는 제초 조성물 | |
| CZ303831B6 (cs) | Herbicidní prostredek, jeho pouzití, zpusob jeho výroby a zpusob hubení plevelu | |
| EP3697214B1 (en) | Synergistically effective herbicide composition comprising pelargonic acid and flazasulfuron | |
| JP2009120503A (ja) | 除草剤 | |
| AU2016200567B1 (en) | A synergistic herbicidal composition and the method of controlling the growth of undesired plants | |
| CN1081440C (zh) | 以n－异丙基－n－(4－氟苯基) (5－三氟甲基－1,3,4－噻二唑－2－基氧基)乙酰胺为基础的除草组合物 | |
| CN1306873C (zh) | 基于1－(2－氯苯基)－4－(n－环己基－n－乙基氨基羰基)－1,4－二氢－5h－四唑－5－酮和敌稗的选择性除莠剂 | |
| PL89177B1 (en) | Synergistic herbicidal mixture[us3888655a] | |
| AU2017230275B2 (en) | Herbicidal compositions comprising carfentrazone-ethyl and bromoxynil | |
| US6174838B1 (en) | Herbicides based on 4-bromo-1-methyl-5-trifluoromethyl-3-(2-fluoro-4-chloro-5-isoproxycarbonylphenyl)pyrazole | |
| AU594853B2 (en) | Herbicidal composition | |
| CN107404875A (zh) | 包含异噁氟草和吡氟草胺的除草组合物 | |
| US4294607A (en) | Herbicidal compositions | |
| HU188843B (en) | Synergetic herbicidal composition comprising benzothiazolyl-oxy-acetamide-derivative and thiolcarbamate-derivative as active substance | |
| MXPA97001836A (en) | Herbici combinations | |
| MXPA99001934A (en) | Herbicides based on 4-bromo-1-methyl-5-trifluoromethyl-3-(2-fluoro-4-chloro-5-isopropoxycarbonylphenyl)pyrazole | |
| JPS58154505A (ja) | 除草剤組成物 | |
| PL92144B1 (zh) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: GR Ref document number: 1048939 Country of ref document: HK |
|
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: WD Ref document number: 1015222 Country of ref document: HK |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070328 Termination date: 20150121 |
|
| EXPY | Termination of patent right or utility model |