PL80540B1 - - Google Patents
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- Publication number
- PL80540B1 PL80540B1 PL1970139472A PL13947270A PL80540B1 PL 80540 B1 PL80540 B1 PL 80540B1 PL 1970139472 A PL1970139472 A PL 1970139472A PL 13947270 A PL13947270 A PL 13947270A PL 80540 B1 PL80540 B1 PL 80540B1
- Authority
- PL
- Poland
- Prior art keywords
- compound
- magnesium halide
- anhydrous magnesium
- solvent
- titanium compound
- Prior art date
Links
- 238000000034 method Methods 0.000 claims description 47
- -1 hydrocarbon radicals Chemical class 0.000 claims description 31
- 239000011777 magnesium Substances 0.000 claims description 26
- 239000010936 titanium Substances 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 20
- 229920000642 polymer Polymers 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 18
- 150000004820 halides Chemical class 0.000 claims description 17
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 150000002902 organometallic compounds Chemical class 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 11
- 150000003609 titanium compounds Chemical class 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 9
- 238000002083 X-ray spectrum Methods 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 230000000737 periodic effect Effects 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 150000004678 hydrides Chemical class 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 3
- 150000001350 alkyl halides Chemical class 0.000 claims description 3
- 150000005840 aryl radicals Chemical group 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- 150000002366 halogen compounds Chemical class 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 239000012442 inert solvent Substances 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 claims description 2
- 239000013557 residual solvent Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 239000007792 gaseous phase Substances 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 239000012265 solid product Substances 0.000 claims 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 26
- 229910001629 magnesium chloride Inorganic materials 0.000 description 13
- 239000004698 Polyethylene Substances 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 3
- 229910001623 magnesium bromide Inorganic materials 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910010199 LiAl Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1438269 | 1969-03-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL80540B1 true PL80540B1 (en, 2012) | 1975-08-30 |
Family
ID=11145017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1970139472A PL80540B1 (en, 2012) | 1969-03-21 | 1970-03-18 |
Country Status (16)
| Country | Link |
|---|---|
| AT (1) | AT304068B (en, 2012) |
| BE (1) | BE747727A (en, 2012) |
| CS (1) | CS153072B2 (en, 2012) |
| DE (1) | DE2013008C3 (en, 2012) |
| DK (1) | DK157453C (en, 2012) |
| ES (1) | ES377754A1 (en, 2012) |
| FR (1) | FR2039686A5 (en, 2012) |
| GB (1) | GB1299532A (en, 2012) |
| IL (1) | IL34097A (en, 2012) |
| NL (1) | NL160281C (en, 2012) |
| PL (1) | PL80540B1 (en, 2012) |
| RO (1) | RO57972A (en, 2012) |
| SE (1) | SE366922B (en, 2012) |
| SU (1) | SU379096A3 (en, 2012) |
| YU (1) | YU35965B (en, 2012) |
| ZA (1) | ZA701850B (en, 2012) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7113778A (en, 2012) * | 1970-10-13 | 1972-04-17 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2918458A (en) * | 1955-05-23 | 1959-12-22 | Phillips Petroleum Co | Process and catalyst for production of olefin polymers |
| BE584091A (en, 2012) * | 1958-10-30 | |||
| FR1291788A (fr) * | 1960-03-21 | 1962-04-27 | Shell Int Research | Procédé de préparation de nouveaux catalyseurs de polymérisation |
-
1970
- 1970-03-17 SE SE03511/70A patent/SE366922B/xx unknown
- 1970-03-17 DK DK131670A patent/DK157453C/da not_active IP Right Cessation
- 1970-03-17 NL NL7003761.A patent/NL160281C/xx not_active IP Right Cessation
- 1970-03-18 ZA ZA701850A patent/ZA701850B/xx unknown
- 1970-03-18 SU SU1414321A patent/SU379096A3/ru active
- 1970-03-18 IL IL34097A patent/IL34097A/xx unknown
- 1970-03-18 PL PL1970139472A patent/PL80540B1/pl unknown
- 1970-03-18 GB GB02993/70A patent/GB1299532A/en not_active Expired
- 1970-03-19 YU YU698/70A patent/YU35965B/xx unknown
- 1970-03-19 FR FR7009802A patent/FR2039686A5/fr not_active Expired
- 1970-03-19 DE DE2013008A patent/DE2013008C3/de not_active Expired
- 1970-03-19 AT AT256770A patent/AT304068B/de not_active IP Right Cessation
- 1970-03-20 ES ES377754A patent/ES377754A1/es not_active Expired
- 1970-03-20 RO RO62835A patent/RO57972A/ro unknown
- 1970-03-20 BE BE747727D patent/BE747727A/xx not_active IP Right Cessation
- 1970-03-20 CS CS188270A patent/CS153072B2/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2039686A5 (en, 2012) | 1971-01-15 |
| RO57972A (en, 2012) | 1975-02-15 |
| CS153072B2 (en, 2012) | 1974-02-22 |
| YU69870A (en) | 1981-04-30 |
| DE2013008A1 (de) | 1970-09-24 |
| DK157453C (da) | 1990-05-21 |
| DK157453B (da) | 1990-01-08 |
| ES377754A1 (es) | 1972-11-01 |
| IL34097A0 (en) | 1970-05-21 |
| ZA701850B (en) | 1971-01-27 |
| NL160281C (nl) | 1979-10-15 |
| NL160281B (nl) | 1979-05-15 |
| SU379096A3 (en, 2012) | 1973-04-18 |
| SE366922B (en, 2012) | 1974-05-13 |
| IL34097A (en) | 1973-08-29 |
| DE2013008C3 (de) | 1974-10-31 |
| YU35965B (en) | 1981-11-13 |
| BE747727A (fr) | 1970-09-21 |
| DE2013008B2 (de) | 1974-03-21 |
| NL7003761A (en, 2012) | 1970-09-23 |
| GB1299532A (en) | 1972-12-13 |
| AT304068B (de) | 1972-12-27 |
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