PL421602A1 - Kompleksy metalu i kwasu askorbinowego, sposób ich otrzymywania i zastosowanie - Google Patents
Kompleksy metalu i kwasu askorbinowego, sposób ich otrzymywania i zastosowanieInfo
- Publication number
- PL421602A1 PL421602A1 PL421602A PL42160217A PL421602A1 PL 421602 A1 PL421602 A1 PL 421602A1 PL 421602 A PL421602 A PL 421602A PL 42160217 A PL42160217 A PL 42160217A PL 421602 A1 PL421602 A1 PL 421602A1
- Authority
- PL
- Poland
- Prior art keywords
- complexes
- metal
- obtaining
- ascorbic acid
- applications
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 3
- 239000002184 metal Substances 0.000 title abstract 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 title 2
- 229960005070 ascorbic acid Drugs 0.000 title 1
- 235000010323 ascorbic acid Nutrition 0.000 title 1
- 239000011668 ascorbic acid Substances 0.000 title 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P21/00—Plant growth regulators
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Virology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Mycology (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pretreatment Of Seeds And Plants (AREA)
Abstract
Przedmiotem zgłoszenia są kompleksy metalu i kwasu askorbinowego o ogólnym wzorze MO(OH)z(Asc)x • yH2O, gdzie M jest metalem stanowiącym tytan lub wanad; Asc oznacza C6H7O6; x stanowi liczbę całkowitą od 1 do 4; y stanowi liczbę całkowitą od 0 do 5; z stanowi 0 albo 1; stosunek molowy M do Asc wynosi od 1:1 do 1:4. Przedmiotem zgłoszenia jest również sposób otrzymywania tych kompleksów i ich zastosowanie w uprawie roślin.
Priority Applications (16)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL421602A PL239086B1 (pl) | 2017-05-15 | 2017-05-15 | Sposób otrzymywania kompleksów metalu i kwasu askorbinowego oraz zastosowanie kompleksów otrzymanych tym sposobem |
| JP2019563805A JP7136475B2 (ja) | 2017-05-15 | 2018-05-15 | 金属およびアスコルビン酸錯体の製剤、それらの入手および使用 |
| PCT/PL2018/050021 WO2018236235A2 (en) | 2017-05-15 | 2018-05-15 | Formulations of metal and ascorbic acid complexes, their obtaining and use |
| RU2019139372A RU2764545C2 (ru) | 2017-05-15 | 2018-05-15 | Применение комплексов металла и аскорбиновой кислоты |
| HUE18811670A HUE064785T2 (hu) | 2017-05-15 | 2018-05-15 | Fém- és aszkorbinsav-komplexeket tartalmazó készítmények alkalmazása növénytermesztésben |
| EP18811670.1A EP3624591B1 (en) | 2017-05-15 | 2018-05-15 | Use of formulations of metal and ascorbic acid complexes in cultivation of plants |
| PL18811670.1T PL3624591T3 (pl) | 2017-05-15 | 2018-05-15 | Zastosowanie formulacji kompleksów metali i kwasu askorbinowego w uprawie roślin |
| LTEPPCT/PL2018/050021T LT3624591T (lt) | 2017-05-15 | 2018-05-15 | Metalo ir askorbo rūgšties kompleksų kompozicijų panaudojimas augalų kultivavimui |
| UAA201911615A UA125447C2 (uk) | 2017-05-15 | 2018-05-15 | Застосування складів на основі комплексів металу та аскорбінової кислоти |
| US16/613,677 US12022830B2 (en) | 2017-05-15 | 2018-05-15 | Formulations of metal and ascorbic acid complexes, their obtaining and use |
| MX2019013653A MX2019013653A (es) | 2017-05-15 | 2018-05-15 | Formulaciones de complejos metalicos y de acido ascorbico, su obtencion y utilizacion. |
| KR1020197037023A KR102642336B1 (ko) | 2017-05-15 | 2018-05-15 | 금속 및 아스코르브산 복합체의 제형, 이의 수득 및 용도 |
| BR112019023857-3A BR112019023857A2 (pt) | 2017-05-15 | 2018-05-15 | Formulações de complexos metálicos e de ácido ascórbico, sua obtenção e uso |
| CN201880032596.XA CN110708957B (zh) | 2017-05-15 | 2018-05-15 | 金属和抗坏血酸复合物的制剂、及其获得和用途 |
| ES18811670T ES2965899T3 (es) | 2017-05-15 | 2018-05-15 | Uso de formulaciones de complejos de metal y ácido ascórbico en cultivo de plantas |
| CA3062628A CA3062628C (en) | 2017-05-15 | 2018-05-15 | Formulations of metal and ascorbic acid complexes, their obtaining and use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL421602A PL239086B1 (pl) | 2017-05-15 | 2017-05-15 | Sposób otrzymywania kompleksów metalu i kwasu askorbinowego oraz zastosowanie kompleksów otrzymanych tym sposobem |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL421602A1 true PL421602A1 (pl) | 2018-11-19 |
| PL239086B1 PL239086B1 (pl) | 2021-11-02 |
Family
ID=64213651
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL421602A PL239086B1 (pl) | 2017-05-15 | 2017-05-15 | Sposób otrzymywania kompleksów metalu i kwasu askorbinowego oraz zastosowanie kompleksów otrzymanych tym sposobem |
| PL18811670.1T PL3624591T3 (pl) | 2017-05-15 | 2018-05-15 | Zastosowanie formulacji kompleksów metali i kwasu askorbinowego w uprawie roślin |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL18811670.1T PL3624591T3 (pl) | 2017-05-15 | 2018-05-15 | Zastosowanie formulacji kompleksów metali i kwasu askorbinowego w uprawie roślin |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US12022830B2 (pl) |
| EP (1) | EP3624591B1 (pl) |
| JP (1) | JP7136475B2 (pl) |
| KR (1) | KR102642336B1 (pl) |
| CN (1) | CN110708957B (pl) |
| BR (1) | BR112019023857A2 (pl) |
| CA (1) | CA3062628C (pl) |
| ES (1) | ES2965899T3 (pl) |
| HU (1) | HUE064785T2 (pl) |
| LT (1) | LT3624591T (pl) |
| MX (1) | MX2019013653A (pl) |
| PL (2) | PL239086B1 (pl) |
| RU (1) | RU2764545C2 (pl) |
| UA (1) | UA125447C2 (pl) |
| WO (1) | WO2018236235A2 (pl) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL239086B1 (pl) | 2017-05-15 | 2021-11-02 | Intermag Spolka Z Ograniczona Odpowiedzialnoscia | Sposób otrzymywania kompleksów metalu i kwasu askorbinowego oraz zastosowanie kompleksów otrzymanych tym sposobem |
| WO2023076494A1 (en) * | 2021-10-27 | 2023-05-04 | Sound Agriculture Company | Substituted furanones and use thereof for agricultural applications |
| CN114804193B (zh) * | 2022-04-13 | 2023-09-22 | 攀枝花学院 | 低浓度工业钛液除铁的方法及制备高纯度二氧化钛的方法 |
| KR20240157898A (ko) | 2023-04-26 | 2024-11-04 | 국립창원대학교 산학협력단 | 아르코르빅 산을 함유하는 망간더스트 환원제, 아르코르빅 산을 이용한 망간더스트 내 망간 침출방법 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US21A (en) * | 1836-09-05 | Granite-machine for dressing or hammering | ||
| HU170693B (pl) | 1975-06-21 | 1977-08-28 | ||
| HU186758B (en) * | 1980-12-29 | 1985-09-30 | Kerteszeti Egyetem | Compositions for conditioning plants containing titane |
| CN1003302B (zh) | 1985-10-22 | 1989-02-15 | 北京有色金属研究总院 | 植物生长调节剂用的钛-抗坏血酸固体化合物的合成 |
| JPS62249902A (ja) * | 1986-04-22 | 1987-10-30 | Kirin Brewery Co Ltd | 植物の養液栽培法 |
| AU592211B2 (en) * | 1987-07-23 | 1990-01-04 | Kerteszet I Es Elelmiszer Ipari Egyetem | Method for improving and increasing the multiplication biological properties and power of resistance against pathogens of living creatures-such as domestic animals and plants-and for favourable control of physiological process |
| PL163688B1 (pl) | 1990-02-28 | 1994-04-29 | Julian Kazibut | Sposób otrzymywania preparatu tytanowego, zwłaszcza dla rolnIcW/a |
| US5186738A (en) * | 1990-04-05 | 1993-02-16 | Texas A&M University System | Vanadyl compositions and methods for applying the compositions to promote plant growth |
| PL172871B1 (pl) | 1994-03-14 | 1997-12-31 | Inst Nawozow Sztucznych | Płynny nawóz z tytanem |
| US6077811A (en) * | 1995-06-06 | 2000-06-20 | Mitchell; James P. | Vanadium compositions to enhance plant growth and edible fruit yield |
| AU725833B2 (en) | 1996-03-21 | 2000-10-19 | Edenspace Systems Corporation | Method for hyperaccumulation of metals in plant shoots |
| JP3401501B2 (ja) * | 2000-08-25 | 2003-04-28 | 有限会社 農業科学研究所 | 農園芸用資材 |
| SE521121C2 (sv) | 2001-03-19 | 2003-09-30 | Norogard Ab | Komposition för resorption av mikronäringsämnen i växter samt förfarande för dess framställning och användning |
| WO2010015026A1 (en) * | 2008-08-08 | 2010-02-11 | Fred Chestren Hoberg | Control of diseases in crops |
| CN101671207B (zh) * | 2009-09-23 | 2010-09-08 | 湖南大方农化有限公司 | 一种杀菌增产药肥及其使用方法 |
| CN101838159B (zh) | 2009-12-04 | 2012-08-29 | 中化化肥有限公司 | 一种含有钛络合物的液体肥料及其制备方法、含有该液体肥料的固体肥料 |
| EP2870122A4 (en) * | 2012-07-05 | 2015-12-16 | Brian Jon Knochenmus | AGRICULTURAL COMPOSITIONS AND APPLICATIONS USING MINERAL COMPOUNDS |
| PL227766B1 (pl) * | 2013-07-29 | 2018-01-31 | Intermag Spólka Z Ograniczona Odpowiedzialnoscia | Preparat zawierający tytan, sposób wytwarzania preparatu zawierającego tytan oraz zastosowanie preparatu zawierającego tytan w uprawie roślin |
| AU2014101391B4 (en) | 2014-09-01 | 2015-09-03 | Suunil Sudhakar Chaudhry | Multifunctional organic agricultural fertilizer composition and process for preparation thereof |
| PL239086B1 (pl) | 2017-05-15 | 2021-11-02 | Intermag Spolka Z Ograniczona Odpowiedzialnoscia | Sposób otrzymywania kompleksów metalu i kwasu askorbinowego oraz zastosowanie kompleksów otrzymanych tym sposobem |
-
2017
- 2017-05-15 PL PL421602A patent/PL239086B1/pl unknown
-
2018
- 2018-05-15 JP JP2019563805A patent/JP7136475B2/ja active Active
- 2018-05-15 CA CA3062628A patent/CA3062628C/en active Active
- 2018-05-15 CN CN201880032596.XA patent/CN110708957B/zh active Active
- 2018-05-15 KR KR1020197037023A patent/KR102642336B1/ko active Active
- 2018-05-15 PL PL18811670.1T patent/PL3624591T3/pl unknown
- 2018-05-15 US US16/613,677 patent/US12022830B2/en active Active
- 2018-05-15 EP EP18811670.1A patent/EP3624591B1/en active Active
- 2018-05-15 BR BR112019023857-3A patent/BR112019023857A2/pt not_active Application Discontinuation
- 2018-05-15 LT LTEPPCT/PL2018/050021T patent/LT3624591T/lt unknown
- 2018-05-15 HU HUE18811670A patent/HUE064785T2/hu unknown
- 2018-05-15 RU RU2019139372A patent/RU2764545C2/ru active
- 2018-05-15 WO PCT/PL2018/050021 patent/WO2018236235A2/en not_active Ceased
- 2018-05-15 ES ES18811670T patent/ES2965899T3/es active Active
- 2018-05-15 UA UAA201911615A patent/UA125447C2/uk unknown
- 2018-05-15 MX MX2019013653A patent/MX2019013653A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US12022830B2 (en) | 2024-07-02 |
| PL239086B1 (pl) | 2021-11-02 |
| LT3624591T (lt) | 2024-01-10 |
| RU2019139372A3 (pl) | 2021-07-27 |
| HUE064785T2 (hu) | 2024-04-28 |
| EP3624591B1 (en) | 2023-10-04 |
| CA3062628A1 (en) | 2018-12-27 |
| BR112019023857A2 (pt) | 2020-06-02 |
| KR102642336B1 (ko) | 2024-02-28 |
| MX2019013653A (es) | 2020-01-13 |
| JP2020519681A (ja) | 2020-07-02 |
| PL3624591T3 (pl) | 2024-04-15 |
| US20210076681A1 (en) | 2021-03-18 |
| UA125447C2 (uk) | 2022-03-09 |
| CA3062628C (en) | 2023-08-29 |
| ES2965899T3 (es) | 2024-04-17 |
| JP7136475B2 (ja) | 2022-09-13 |
| EP3624591A2 (en) | 2020-03-25 |
| RU2764545C2 (ru) | 2022-01-18 |
| CN110708957A (zh) | 2020-01-17 |
| CN110708957B (zh) | 2021-12-07 |
| WO2018236235A2 (en) | 2018-12-27 |
| WO2018236235A3 (en) | 2019-04-04 |
| RU2019139372A (ru) | 2021-06-16 |
| KR20200004886A (ko) | 2020-01-14 |
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