PL376995A1 - Fenyloizotiocyjaniany z dwiema grupami funkcyjnymi, sposób i produkty pośrednie do ich wytwarzania - Google Patents
Fenyloizotiocyjaniany z dwiema grupami funkcyjnymi, sposób i produkty pośrednie do ich wytwarzaniaInfo
- Publication number
- PL376995A1 PL376995A1 PL376995A PL37699503A PL376995A1 PL 376995 A1 PL376995 A1 PL 376995A1 PL 376995 A PL376995 A PL 376995A PL 37699503 A PL37699503 A PL 37699503A PL 376995 A1 PL376995 A1 PL 376995A1
- Authority
- PL
- Poland
- Prior art keywords
- cyanates
- thio
- production
- phenyliso
- intermediate products
- Prior art date
Links
- 150000001913 cyanates Chemical class 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000001588 bifunctional effect Effects 0.000 title 1
- 239000013067 intermediate product Substances 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000011814 protection agent Substances 0.000 abstract 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/76—Nitrogen atoms to which a second hetero atom is attached
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/34—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfuric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C307/00—Amides of sulfuric acids, i.e. compounds having singly-bound oxygen atoms of sulfate groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C307/04—Diamides of sulfuric acids
- C07C307/06—Diamides of sulfuric acids having nitrogen atoms of the sulfamide groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C331/00—Derivatives of thiocyanic acid or of isothiocyanic acid
- C07C331/16—Isothiocyanates
- C07C331/28—Isothiocyanates having isothiocyanate groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/20—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
- C07D211/18—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/70—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
- C07D295/26—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/52—Radicals substituted by nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
- C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/14—Radicals substituted by singly bound hetero atoms other than halogen
- C07D333/20—Radicals substituted by singly bound hetero atoms other than halogen by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Hydrogenated Pyridines (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Wynalazek dotyczy sposobu wytwarzania fenyloizo(tio)-cyjanianów o ogólnym wzorze (I), zgodnie z którym związek o ogólnym wzorze (II) lub jego addukt HCl poddaje się reakcji ze środkiem fosgenującym, przy czym W oznacza atom tlenu lub siarki, a Ar i A mają znaczenie podane w zastrzeżeniu 1. Wynalazek dotyczy również zastosowania fenyloizo(tio)cyjanianów do wytwarzania środków ochrony roślin.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10250614 | 2002-10-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL376995A1 true PL376995A1 (pl) | 2006-01-23 |
| PL214983B1 PL214983B1 (pl) | 2013-10-31 |
Family
ID=32185288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL376995A PL214983B1 (pl) | 2002-10-30 | 2003-10-29 | Sposób wytwarzania fenyloizo(tio)cyjanianów, fenyloizo(tio)cyjaniany, amidy kwasu aminobenzoiloamidosulfonowego, amidy kwasu nitrobenzoiloamidosulfonowego i sposób wytwarzania amidów kwasu aminobenzoiloamidosulfonowego |
Country Status (18)
| Country | Link |
|---|---|
| US (3) | US7820846B2 (pl) |
| EP (2) | EP2537829B1 (pl) |
| JP (1) | JP4738812B2 (pl) |
| KR (1) | KR101055954B1 (pl) |
| CN (1) | CN100368392C (pl) |
| AR (1) | AR041861A1 (pl) |
| AU (1) | AU2003287972B2 (pl) |
| BR (2) | BRPI0315932B1 (pl) |
| CA (1) | CA2504410C (pl) |
| EA (1) | EA010872B1 (pl) |
| ES (1) | ES2565961T3 (pl) |
| HU (1) | HUE027607T2 (pl) |
| IL (1) | IL167983A (pl) |
| MX (1) | MXPA05004546A (pl) |
| PL (1) | PL214983B1 (pl) |
| UA (1) | UA89941C2 (pl) |
| WO (1) | WO2004039768A1 (pl) |
| ZA (1) | ZA200504331B (pl) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1989111B (zh) | 2004-07-22 | 2012-12-05 | 巴斯福股份公司 | 生产3-苯基(硫代)尿嘧啶和二硫代尿嘧啶的方法 |
| EP1957443A2 (de) * | 2005-12-01 | 2008-08-20 | Basf Se | Verfahren zur herstellung von sulfonamiden |
| DE102005057681A1 (de) * | 2005-12-01 | 2007-06-06 | Basf Ag | Verfahren zur Herstellung fluorierter m-Nitro-Benzoesäurechloride |
| BRPI0818408B1 (pt) * | 2007-10-12 | 2024-01-09 | Basf Se | Processos para preparar diamidas sulfúricas e ingredientes herbicidas ativos |
| ES2440940T3 (es) | 2009-11-13 | 2014-01-31 | Basf Se | Compuestos de 3-(3,4-dihidro-2H-benzo[1,4]oxazin-6-il)-1H-pirimidin-2,4-diona como herbicidas |
| US10436790B2 (en) | 2011-09-28 | 2019-10-08 | Waters Technologies Corporation | Rapid fluorescence tagging of glycans and other biomolecules with enhanced MS signals |
| US11352325B2 (en) | 2011-09-28 | 2022-06-07 | Waters Technologies Corporation | Rapid fluorescence tagging of glycans and other biomolecules with enhanced MS signals |
| JP6193237B2 (ja) * | 2011-09-28 | 2017-09-06 | ウオーターズ・テクノロジーズ・コーポレイシヨン | 強められたms信号を有するグリカンおよび他の生体分子の迅速蛍光タグ付け |
| CN102702056B (zh) * | 2012-05-31 | 2014-09-24 | 北京师范大学 | 一种一锅法合成取代间苯二异硫氰酸酯的方法、合成的取代间苯二异硫氰酸酯化合物 |
| DK3748340T3 (da) | 2014-10-30 | 2022-04-19 | Waters Technologies Corp | Fremgangsmåder til hurtig præparering af mærkede glykosylaminer og til analyse af glykosylerede biomolekyler, som fremstiller samme |
| CN115536714B (zh) | 2014-11-13 | 2026-04-24 | 沃特世科技公司 | 快速标记的n-聚糖的液相色谱校准方法 |
| MY197583A (en) | 2016-05-24 | 2023-06-26 | Basf Se | Herbicidal uracilpyrid |
| EP3472621A4 (en) | 2016-06-21 | 2020-03-04 | Waters Technologies Corporation | Methods of electrospray ionization of glycans modified with amphipathic, strongly basic moieties |
| EP3472132A4 (en) | 2016-06-21 | 2020-01-15 | Waters Technologies Corporation | FLUORESCENCE LABELING OF GLYCANS AND OTHER BIOMOLECULES BY REDUCING AMINATION FOR IMPROVED MASS SPECTROMETRY SIGNALS |
| CN114839302A (zh) | 2016-07-01 | 2022-08-02 | 沃特世科技公司 | 使用分子量截留过滤和过滤器上去糖基化从复杂基质快速制备标记的葡基胺的方法 |
| EP3587396A1 (en) | 2018-06-27 | 2020-01-01 | Basf Se | A method of isolating a n-(3-nitrobenzoyl)sulfamide |
| US20240217915A1 (en) | 2021-03-26 | 2024-07-04 | Adama Agan Ltd. | Preparation of 2-chloro-4-fluoro-5-nitrobenzoic acid |
| IL319021A (en) | 2022-08-31 | 2025-04-01 | Adama Agan Ltd | Preparation of 2-chloro-4-fluoro-5-nitrobenzoic acid |
| WO2025124942A1 (en) | 2023-12-12 | 2025-06-19 | BASF Agro B.V. | Process for preparing a saflufenacil intermediate |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4309209A (en) | 1977-08-15 | 1982-01-05 | Chevron Research | Herbicidal method and composition |
| DK156573C (da) | 1981-06-16 | 1990-01-29 | Sumitomo Chemical Co | 2-(2-fluor-4-halogen-5-substitueret-phenyl)-hydantoinderivater, et herbicidt praeparat indeholdende disse, en fremgangsmaade til bekaempelse af ukrudt under anvendelse af disse samt anvendelse af disse som herbicid |
| EP0075267B1 (en) | 1981-09-19 | 1986-01-15 | Sumitomo Chemical Company, Limited | 4-(2-fluoro-4-halo-5-substituted phenyl)urazols, and their production and use |
| DE3433391A1 (de) | 1984-09-12 | 1986-03-20 | Bayer Ag, 5090 Leverkusen | Acylierte saccharin-derivate |
| DE3924052A1 (de) | 1989-07-21 | 1991-01-24 | Bayer Ag | N- (indol-6-yl)-heterocyclen |
| US5238908A (en) | 1989-08-31 | 1993-08-24 | Rohm And Haas Company | Herbicidal glutaramic acids and derivatives |
| DE59309922D1 (de) | 1992-02-20 | 2000-02-17 | Clariant Gmbh | Verfahren zur Herstellung von substituierten 2,3-Difluorpyridinen |
| DE19610786A1 (de) * | 1996-03-14 | 1997-09-18 | Bayer Ag | Verfahren zur Herstellung von substituierten aromatischen Thiocarbonsäureamiden |
| DE19627901A1 (de) * | 1996-07-11 | 1998-01-15 | Bayer Ag | Substituierte aromatische Carbonylverbindungen und ihre Derivate |
| DE19632005A1 (de) * | 1996-08-08 | 1998-02-12 | Bayer Ag | Substituierte p-Trifluormethylphenyluracile |
| DE19731784A1 (de) * | 1997-07-24 | 1999-02-04 | Bayer Ag | Substituierte N-Aryl-N-thioxocarbonyl-sulfonamide |
| IL125947A0 (en) | 1997-09-17 | 1999-04-11 | American Cyanamid Co | 3-(1,2-benzisothiazol- and isoxazol-5-yl)-2,4(1h,3h)-pyrimidinedione or thione and 3-(1,2-benzisothiazol- and isoxazol-5-yl)-4(3)-pyrimidinone or thione herbicidal agents |
| US6251829B1 (en) | 2000-04-18 | 2001-06-26 | Rohm And Haas Company | Herbicidal benzoyloxy carboxylates and carboxamides |
| NZ517562A (en) | 2000-05-04 | 2004-09-24 | Basf Ag | Uracil substituted phenyl sulfamoyl carboxamides |
| EP1284972A1 (en) | 2000-05-17 | 2003-02-26 | Cor Therapeutics, Inc. | Methods for producing amino substituted chromanes and intermediates therefor |
| JP2004502795A (ja) * | 2000-07-05 | 2004-01-29 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | エチレンのホモポリマーおよびコポリマーの製造のための担持チタン化クロム触媒およびその使用 |
| DE10036653A1 (de) | 2000-07-26 | 2002-02-07 | Clariant Gmbh | Verfahren zur Herstellung von substituierten Benzoylchloriden |
| WO2002020531A2 (de) | 2000-09-08 | 2002-03-14 | Basf Aktiengesellschaft | Verfahren zur herstellung anellierter tetrahydro-[1h]-triazole |
-
2003
- 2003-10-29 HU HUE12174668A patent/HUE027607T2/en unknown
- 2003-10-29 JP JP2004547601A patent/JP4738812B2/ja not_active Expired - Lifetime
- 2003-10-29 BR BRPI0315932A patent/BRPI0315932B1/pt unknown
- 2003-10-29 PL PL376995A patent/PL214983B1/pl unknown
- 2003-10-29 KR KR1020057007661A patent/KR101055954B1/ko not_active Expired - Lifetime
- 2003-10-29 EP EP12174668.9A patent/EP2537829B1/de not_active Expired - Lifetime
- 2003-10-29 AR ARP030103955A patent/AR041861A1/es active IP Right Grant
- 2003-10-29 AU AU2003287972A patent/AU2003287972B2/en not_active Expired
- 2003-10-29 EA EA200500598A patent/EA010872B1/ru not_active IP Right Cessation
- 2003-10-29 MX MXPA05004546A patent/MXPA05004546A/es active IP Right Grant
- 2003-10-29 EP EP03779818A patent/EP1560810B1/de not_active Expired - Lifetime
- 2003-10-29 CN CNB2003801046055A patent/CN100368392C/zh not_active Expired - Lifetime
- 2003-10-29 BR BR0315932-9A patent/BR0315932A/pt active IP Right Grant
- 2003-10-29 CA CA2504410A patent/CA2504410C/en not_active Expired - Lifetime
- 2003-10-29 WO PCT/EP2003/012013 patent/WO2004039768A1/de not_active Ceased
- 2003-10-29 ES ES12174668.9T patent/ES2565961T3/es not_active Expired - Lifetime
- 2003-10-29 UA UAA200505013A patent/UA89941C2/ru unknown
- 2003-10-29 US US10/532,931 patent/US7820846B2/en active Active
-
2005
- 2005-04-12 IL IL167983A patent/IL167983A/en unknown
- 2005-05-27 ZA ZA200504331A patent/ZA200504331B/en unknown
-
2010
- 2010-09-21 US US12/886,986 patent/US8232421B2/en not_active Expired - Fee Related
-
2012
- 2012-06-28 US US13/535,544 patent/US8541611B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006504763A (ja) | 2006-02-09 |
| ZA200504331B (en) | 2006-07-26 |
| EP1560810A1 (de) | 2005-08-10 |
| UA89941C2 (ru) | 2010-03-25 |
| PL214983B1 (pl) | 2013-10-31 |
| MXPA05004546A (es) | 2005-10-18 |
| EA200500598A1 (ru) | 2006-06-30 |
| BR0315932A (pt) | 2005-09-13 |
| AR041861A1 (es) | 2005-06-01 |
| US8232421B2 (en) | 2012-07-31 |
| EA010872B1 (ru) | 2008-12-30 |
| US20120271049A1 (en) | 2012-10-25 |
| US20110009640A1 (en) | 2011-01-13 |
| US20060004220A1 (en) | 2006-01-05 |
| KR20050090380A (ko) | 2005-09-13 |
| EP1560810B1 (de) | 2012-08-01 |
| AU2003287972A1 (en) | 2004-05-25 |
| WO2004039768A1 (de) | 2004-05-13 |
| EP2537829A1 (de) | 2012-12-26 |
| CN100368392C (zh) | 2008-02-13 |
| HUE027607T2 (en) | 2016-10-28 |
| CA2504410A1 (en) | 2004-05-13 |
| BRPI0315932B1 (pt) | 2019-08-13 |
| US7820846B2 (en) | 2010-10-26 |
| JP4738812B2 (ja) | 2011-08-03 |
| CN1717388A (zh) | 2006-01-04 |
| IL167983A (en) | 2010-11-30 |
| ES2565961T3 (es) | 2016-04-07 |
| AU2003287972B2 (en) | 2010-04-22 |
| EP2537829B1 (de) | 2016-03-02 |
| KR101055954B1 (ko) | 2011-08-09 |
| CA2504410C (en) | 2012-03-20 |
| US8541611B2 (en) | 2013-09-24 |
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