NZ209216A

NZ209216A - Manufacture alcohol-free base wine and apparatus therefor

Info

Publication number: NZ209216A
Application number: NZ209216A
Authority: NZ
Inventors: A R Boucher
Original assignee: Seagram & Sons Inc
Priority date: 1983-08-16
Filing date: 1984-08-14
Publication date: 1988-02-12
Also published as: GB2145110A; GB8420792D0; SE8404098L; PT79073A; NL8402456A; DE3429777A1; LU85497A1; NO161153B; JPH0571225B2; CA1215262A; BE900359A; BR8404073A; ES8602375A1; JPS60145074A; SE8404098D0; MX7687E; DK391484D0; NO843247L; ES535171A0; GB2145110B

Description

<div class="application article clearfix" id="description"> 209216 I Pr'orhy Complete Specific^ Filed- ' Cf3S5: .C.VaG;^ hft • Publication Date: ./),? FEB 1988 Jou™l, No: 1-cQLj* "' N.Z.No. NEW ZEALAND Patents Act 1953 COMPLETE SPECIFICATION ft "ALCOHOL-FREE WINE AND ITS MANUFACTURE" § We, JOSEPH E SEAGRAM & SONS, INC., a corporation of Indiana, having a place of business at 800 Third Avenue, New York, New York, United States of America, do hereby declare the invention, for which we pray that a t Patent may be granted to us» an(3 the method by which it is to be performed, to be particularly described in and by the following statement ; - 209216 BACKGROUND OF THE INVENTION There is a continuing consumer demand for low calorie foods and beverages. Market growth and penetration of low calorie soft drinks and light beers have risen dramatically. The wine industry has recently introduced several low calorie wines which appear to be gaining consumer appeal. In keeping with this trend, several alcohol free wines have been introduced but with questionable and varying degrees of acceptance because of quality. However, of far greater importance is the ever increasing requirement for an alcohol free beverage for those who elect not to partake in alcohol for diverse reasons and for those who may have a drinking problem. Thus, there remains a need for a consumer acceptable alcohol free wine of improved quality. In the past, efforts have been made to produce non-alcohol wine using methodology of distillation and/or evaporation. Reports on such efforts, generally indicate poor quality. These processes involved either high temperatures or long holding time due to the nature of the equipment involved. As would be expected, a large reduction of the original water and consequent concentration of non-volatile acids would take place. 209216 C , W SUMMARY OF THE INVENTION A principal object of the invention is to provide an alcohol free wine that responds to the identified consumer requirement and/or need that is not filled by any other wine now sold in the United States or abroad, namely, a wine with substantially fewer calories, appealing taste and, above all, substantially no alcohol. Another object is an alcohol free wine production process that may be installed and deployed year round without limitation to times of harvest or seasons of the year. Still another object is to utilize a finished table wine and convert it into a low calorie, alcohol free wine. A further object is to provide an improved process for converting a finished table wine to an alcohol free wine in which essentially all of the feed wine without the alcohol and highly volatile ingredients appears in the finished product. A still further object is to produce a high proof vapor by-product from the alcohol free wine production process that is a superior quality brandy alcohol. 18 DECI987n,'i "3~ j 209216 The term "alcohol-free" as used herein is a wine derived beverage having less than 0.5% alcohol content considered by the Bureau of Alcohol, Tobacco Products and Firearms Division of the U.S. Treasury Department as not being a wine for tax purposes. It should be understood that if this limit varies it is intended that the term "alcohol-free" as used herein will vary accordingly. BRIEF DESCRIPTION OF THE DRAWINGS The Figure is a schematic view of the flow diagram of the alcohol free wine production process incorporating the teachings of the present invention. DETAILED DESCRIPTION In the Figure, an embodiment of the invention is illustrated on which a wine preblend is processed and converted into an alcohol free wine and a superior brandy alcohol by-product. Thus, an original finished table feed wine from tank 10 normally having 11-12% alcohol content and demineralized and/or distilled -4- 209216 water from tank 12 are fed into a mixing tank 14 within which a wine preblend is formed. Any type of mixing system may be employed including pump or mechanical agitator. A ratio of approximately 58% feed wine to 42% water will produce a workable preblend. In any event, the preblend will have an alcohol content of 6-7% and according to a successful embodiment of the invention possess an alcohol content of approximately 6.8%. As will be apparent shortly, the addition of water protects and preserves the essential character and organoleptic properties of the original table wine without degradation or scorching during the subsequent processing steps. Enough water is added to the feed r reduced wine for the preblend to arrive at an alcohol base wine that will permit final cutting by water of alcohol to below 0.5% and to keep the original feed wine content about 50% in the final product (whether final water content is derived from this feed wine or added water). The wine preblend is then fed into a centrifugal film evaporator 16 which operates in reducing the preblend into a liquid phase which is an alcohol reduced base wine fed therefrom into receiver 18 and a vapor phase which is condensed. The centrifugal film evaporator 16 is disclosed in detail in the aSove> referenced patent applications. Towards this end, the evaporator 16 may be obtained commercially from Alfa-Laval AB, Lund, Sweden under its tradenames CMF6 and CMF 9. Unlike those specific applications the feed rate of the preblend is reduced enough to obtain a base wine having less an 1% alcohol. In some instances, the rate is reduced to one-third to assure contact of the liquid as a thin film on the steamheated cones of the evaporator. Moreover, operation of the process of this invention is at very high vacuum conditions. The contact time of the preblend with the heat transfer surfaces of the evaporator is very short and less than a second; and, therefore, no molecular decomposition or transformation takes place due to chemical reaction. The alcohol reduced base wine leaving the evaporator 16 will range in alcohol content from 0.5% to 1% and in accordance with successful applications of this invention will normally be approximately 0.70 - 0.8% and preferably 0.75% alcohol. In addition, the yield has ranged from 60-65% of the feed wine. Referring now to the vapor phase system, the vapor phase from the evaporator 16 may be processed according U.S. Potfcw#' speaficairbrt AJo. to Application Serial No.—3 41,363 or may be exposed to 209216 a rectifying action within the column 20 which may be of the type disclosed in ^ '445, 0G4« .Similarly, the higher proof vapor product is condensed and cooled within condenser 22, fed into receiver 23 and then transferred to a storage tank 24 by pump 26 through back pressure control valve 28. A vacuum for system is provided by vacuum pump 29 which is connected to the receiver 23 as shown. A reflux return line 30 having rotometer 32 feeds the higher proof by-product back to the top of the column 20 through the reflux control valve 33 to facilitate and enhance the distillation process. Pump 34 draws the alcohol reduced base wine from evaporator 16 into the receiver 18. This base wine is then cooled by heat exchange 36 and then fed into storage tank 37. The essential character and organoleptic properties of the original feed wine including the ph level is retained by the alcohol free base wine in tank 37. However, some of the original bouquet is lost with the removal of the higher alcohols by the evaporator 16. Accordingly, the present invention contemplates adding grape juice concentrate to restore flavor and bouquet. The concentrate is produced in the Alfa-Laval evaporator and therefore such a concentrate has no molecular decomposition or transformation due to chemical reaction. This addition 209216 may be done directly into tank 37 from juice concentrate tank 38 or perhaps at some other location in the process if desired or found more practical. p-alcohol This mixture will normally have approximately 0.6%hand may be filtered at ( this time by filter 39 which, may be of the millipore type. The remaining processing steps may be performed shortly thereafter or at a later period of time at the same plant, wine making facility or at a removed bottling plant. Towards this end, if the bottling plant is at a different location, the alcohol base wine and grape juice concentrate mixture will be appropriately transferred to tank 40. Further demineralized water from tank 41 will be added together with citric acid from source 42 as well as further grape juice concentrate from source 43. The citric acid contributes to mouth feel and desired level of tartness. The added grape juice concentrate finally .adjusts the organoleptic level of taste. The alcohol content of the mixture is now lowered to a level below 0.5%. Thereafter, the mixture is filtered at station 44 by a millipore filter. Carbonization (COis then introduced at station 48. Normally, 350-400 -8- DEC 1987 209216 grams/100/ml will be sufficient for such purposes to attain a prescribed level of effervescence for improvement of tactual properties. Then the mixture may have sulphur dioxide (SC^) added as a preservative. At bottling station 52, the mixture is discharged into bottles by means of a conventional counter pressure filler and thereafter capped. In order to complete the preservation of the bottled mixture, a pasteurization step 54 is employed if desired or necessary. Suitable grape juice concentrate usable with the present invention for producing an alcohol free white wine using a chablis feed wine are the Muscat and blends thereof, with the main volume being Thompson or French Columbard seedless grape juice in the proportion of about 20% - 10% to 80% to 90%, In blending an ✓ alcohol free rose wine, a Malvasia Bianco or Muscat concentrate would be substituted for the Muscat in the same proportions. In addition, Red Concord grape juice concentrate for coloring could be added to the alcohol free white wine beverage along with enough Muscat to impart a rose character. Similarly, in producing an alcohol free red wine, enough Red Concord grape juice concentrate may be added to the alcohol free white wine beverage for obtaining the desired red wine color. It is also contemplated that the alcohol free drinkable white wine beverage may be utilized to 20921 manufacture a champagne. In this connection, a yeast-type of character is sought; and either an additive may be introduced for such purpose or the beverage may be subjected to further fermentation which would have the same effect. In view of adding sulphur dioxide as a preservative or in conjunction therewith, the finished and bottled alcohol free wine beverage may be pasteurized according to conventional techniques to eliminate any possible bacteria, yeast or other organism and/or spores. In addition, the CMF equipment could be deployed for flash pasteurization by exposing the thin film of base wine with demineralized water from tank 37 to cone temperatures of about 170% F. with no vaporization vacuum applied. The following examples describe the manner and process of making and using the invention and sets forth the best mode contemplated by the inventor of carrying out the invention but are not to be construed as limiting. In carrying out these and other examples the chemical analysis results reported were determined by gas chromatograph. 209216 EXAMPLE 1 Employing the apparatus and system described above and depicted in the Figure, a matured California white chablis feed wine at 11.2% alcohol was processed as follows utilizing an Alfa-Laval CMF6 and the following parameters. First a preblend was produced in mixing tank 14 having an alcohol content of 6.35% by mixing 1166 gallons of the feed wine with 870 gallons of demineralized water. Preblend Feed Rate 284 g.p.h. CMF Vacuum . 27.5" hg CMF Steam Temperature 58° C. CMF Steam Controller -.88 Bar CMF Vapor Temperature 40° C. The mixture balance was as follows: Entering CMF Preblend Feed -2036 w.g. at 6.35% = 129.29 absolute gallons alcohol Leaving CMF Wine Base -1297 w.g. at 0.75% = 9.7 absolute gallons alcohol Leaving CMF Vapor - 717 w.g. at 15.9% = 114.0 absolute Condensator gallons alcohol Total Recovery 2014 w.g. = 123.7 absolute gallons alcohol Recovery based on diluted wine feed: Wine Base 1297 gal Diluted Wine Feed 2036 gal ~ 63.7% Recovery based on original' wine in process: Wine based product 1297 gal _ -^2% Original wine at 1160 gal The base wine thus produced was blended with about 185 gallons white grape juice, concentrate (at 62° Brix) in tank 37. After transfer to tank 40, final blending was performed utilizing the mixture of 64% base wine (with concentrate), 9.5% white grape juice concentrate (at 62° Brix) and 26.5% demineralized water. About 3.5 lbs of citric acid were added and thereafter the mixture was filtered. In addition 1/2 lb of SO2/IOOO gal of liquid was added as a preservative. The beverage was carbonated by introducing 370+20 milligram/100 ml of C02. The finished product was bottled possessing the desirable character of the original chablis feed wine as an alcohol free white wine beverage with an alcohol content of .45%. 209216 EXAMPLE 2 Employing the apparatus and system described and depicted in the Figure, 966 gallons of a matured / California Rose feed wine was blended with 574 gallons of demineralized water to produce a preblend having an alcohol content of 7.42%. The parameters of the system were set as follows: Preblend Feed Rate 310 gph CMF Vacuum 27.5" hg CMF Steam Temperature 59° C. CMF Steam Controller -.85 Bar CMF Vapor Temperature 40° C. Entering CMF Preblend Feed 1540 gals at 7.42% = 114 gallons absolute alcohol Leaving CMF Wine Base 990 gals at 0.93% =9.2 gallons absolute alcohol Leaving CMF Vapor Condensate 539 gals at 18% = 97 gallons absolute alcohol Total Recovery 1529 gals 106.2 Recovery based on diluted wine feed Recovery based on original wine process^ 64.3% 103% 209216 The base wine thus produced was blended with about 185 gallons of white grape juice concentrate in tank 37. After transfer to tank 40, final blending was performed utilizing 64% base wine (with concentrate), 1.5% red grape juice concentrate for color, 8% white grape juice concentrate and 26.5% gallons of demineralized water. About 3 1/2 lbs/1000 gal. of citric acid/1000 gallons of liquid were added and the mixture was then filtered. In addition, 1/2 lb of SO2/IOOO gal of liquid was added as a preservative. The beverage was carbonated by introducing 370+20 milligram/100 ml of CC^. The finished product was bottled possessing the x desirable character of the original rose feed wine as ✓ an alcohol free rose wine beverage having .43% alcohol content. 209216 r • EXAMPLE 3 The procedure of employing the apparatus of the Figure and Example 1, a California white chablis feed wine was treated in arriving at an alcohol free wine beverage. Chemical analysis'of the original chablis feed wine, the preblend, the alcohol free wine base, the base with concentrate in tank 37, and finished bottled alcohol free white wine beverage is given in Table 1 below. TABLE 1 Feedwine Preblend Alcohol Base Plus Concentrate Alcohol Free White (Chablis) Plus Free Water Wine Feedwine Base Beverage Finished and Bottled Hydroxymethyl Furfural 0.01 0. 03 0.02 Furfural 0.14 0. 06 0.11 0.15 0. 05 Tannin, mg/liter 398 160 285 420 228 EXAMPLE 4 Employing the apparatus of the Figure and the s procedure of Example 2, a California rose feed wine was treated in arriving at an alcohol free wine beverage. Chemical analysis of the finished bottled alcohol free / rose wine beverage is given in Table 2 below: TABLE 2 Alcohol Free Rose Beverage Finished Bottle Hydroxymethyl furfural 0.09 Furfural 0.06 Tannin, mg/liter 338 209216 209216 Of particular significance in obtaining an acceptable alcohol free wine beverage by the present invention having desirable organoleptic properties while possessing the desirable character of the original matured feed wine are the following results based on chemical data and analysis comparable to the foregoing tables: i. the hydroxymethyl furfural level is reduced to a level below 1/10 gram/100 liters. This ingredient contributes to a cooked character. ii. the furfural level is reduced by approximately 1/3 to 1/2. iii. The tannins are reduced by about 1/2. Tannins provide an astringent character. Bottled alcohol free white, rose and red wines of this invention possessed the following ingredients: Dealcoholized wine 57.0% Reconstituted grape juice concentrate 4 2.6% (concentrate and water) Carbon dioxide (370 mg/100 ml) Citric acid (3.5 lbs/1000 gal) 0.37% 0.042% Sulfur Dioxide (170 ppm total) 0.017% 209216 Thus the several aforenoted objects and advantages are most effectively attained. Although several somewhat preferred embodiments have been disclosed and described in detail herein, it should be understood that this inventionis in no sense limited thereby and its scope is to be determined by that of the appended claims. </div>

Claims

209216 WHAT WE CLAIM IS:

1. A method of producing an alcohol free base wine for making an alcohol free drinkable wine beverage comprising: feeding an original finished feed wine and a demineralized water preblend from a tank through an inlet line to a centrifugal film evaporator; dividng the preblend in the evaporator into a first part which is a liquid phase and another part which is a vapor phase, the liquid phase being the alcohol free base wine; removing the liquid phase from the evaporator.

2. A method according to claim 1 including: feeding the original finished feed wine from a first tank; feeding the demineralized water from a second tank; mixing the original finished feed wine, and the demineralized water prior to feeding the preblend into the evaporator. I

3. A method according to claim 7 including: feeding grape juice concentrate from a tank to the alcohol free base wine in a predetermined ratio.

4. A method according to claim 1 including: collecting the vapor phase as a high proof by-product.

5. A method of producing an alcohol free drinkable wine beverage comprising: feeding an original finished feed wine from a tank; feeding a demineralized water from a tank; mixing in a tank the original finished feed wine and demineralized water in a predetermined ratio to provide a feed wine, water preblend; 19 ^ OfC1987 I ■»>/; 209216 feeding the feed wine, water preblend through an inlet line from the mixing tank to a centrifugal film evaporator; dividing the preblend in the evaporator into a first part which is a liquid phase and another part which is a vapor phase, the liquid phase being an alcohol free base wine; removing the liquid phase alcohol free base wine from the evaporator; mixing a grape juice concentrate from a tank with the alcohol free base wine; finally blending the mixture to arrive at the finished alcohol free wine beverage; and bottling the finished alcohol free wine beverage.

6. A method according to claim 5, including the step of: introducing further demineralized water to the alcohol free base wine prior to bottling to reduce the alcohol level below a prescribed value defining an alcohol free wine beverage.

7. A method according to claim 5 including the step of: introducing carbon dioxide to the alcohol free base wine prior to bottling to provide carbonization to the beverage.

8. A method according to claim 5 including the step of: introducing sulphur dioxide to the alcohol free base wine prior to bottling to serve as a preservative.

9. A method according to claim 5 including the step of: introducing citric acid to the alcohol free base wine prior to bottling to provide tartness.

10. A method according to claim 5 including the step of: pasteurizing the bottled beverage. 20 209216

11. A method according to claim 5 including the step of: filtering the alcohol free base wine, juice mixture prior to bottling.

12. A method according to claim 5 including the steps of: lowering the alcohol content of the original feed wine by the addition of demineralized water in forming the preblend from a level of substantially 11-12% to 6-8%; lowering the alcohol content of the preblend from substantially 6-8% to a level of substantially 0.5-1% by the centrifugal evaporator; lowering the alcohol content of the alcohol free wine base, concentrated grape juice mixture by the addition of a further demineralized water as part of the final blending step prior to bottling to a level below 0.5%.

13. A method according to claim 12 including the step of adding further grape juice concentrate, citric acid and carbon dioxide as part of the final blending step.

14. A method according to claim 5, wherein the quantity of base wine extracted from the evaporator is about the same as the quantity of original feed wine.

15. Apparatus to perform the method of any one of the preceding claims for producing an alcohol free base wine for making an alcohol free drinkable wine beverage comprising: a tank of an original finished feed wine and a demineralized water preblend; a feed wine, water preblend inlet line coupled with the preblend tank; a feed wine, water preblend feeding means for feeding the feed wine, water preblend from the preblend tank through the 21 209216 inlet line; a centrifugal film evaporator coupled with the inlet line for elevating the temperature of the feed wine, water preblend while being centrifuged to a temperature at which a predetermined part thereof is divided into a liquid phase and another part into a vapor phase, the liquid phase being the alcohol free base wine, the centrifugal film evaporator having means which removes the liquid phase by centrifugation from the evaporator.

16. Apparatus according to claim 15, wherein a first tank of the original finished feed wine, a second tank of the demineralized water and means which couples the first and second tanks to the preblend tank are provided.

17. Apparatus according to claim 15, wherein a tank of grape juice concentrate is provided, and means which feeds the grape juice concentrate into the alcohol free base wine in a predetermined ratio.

18. Apparatus to perform the method of any one of the preceding claims 1-14 for producing an alcohol free drinkable wine beverage comprising: original finished feed wine and demineralized water in a predetermined ratio to provide a tank of a feed wine, water preblend; a feed wine, water preblend feeding means whic the feed wine, water preblend from the preblend tank through the a first tank of an original finished feed wine; a second tank of demineralized water; mixing means coupled with a tank which mixes the a feed wine, water preblend inlet line coupled with the preblend tank; 22 209216 inlet line; a centrifugal film evaporator coupled with the inlet line for elevating the temperature of the feed wine, water preblend while being centrifuged to a temperature at which a predetermined part thereof is divided into a liquid phase and another part into a vapor phase, the liquid phase being the alcohol free base wine, the centrifugal film evaporator having means which removes the liquid phase by centrifugation from the evaporator; a tank of grape juice concentrate; means which mixes the grape juice concentrate into the alcohol free base wine in a predetermined ratio; a second tank of demineralized water, the water from the second tank being mixed into the base wine, juice concentrate mixture to reduce the alcohol content thereof to a further lower amount; and a bottling station for bottling the mixture having a further reduced alcohol content.

19. Apparatus according to claim 18, wherein a filter filters the mixture having a further reduced alcohol content prior to bottling.

20. Apparatus according to claim 18, including means which introduces carbon dioxide gas into the mixture having a further reduced alcohol content prior to bottling.

21. Apparatus in accordance with claim 18, including means which introduces sulphur dioxide gas into the mixture having a further reduced alcohol content prior to bottling.

22. Apparatus in accordance with claim 18. including means f-ooa which introduces citric I into the mixture having a further reduced 23 r v ■f/yf ■ f is ofci ms 209216 alcohol content, prior to bottling.

23. A substantially alcohol free wine beverage produced, according to the method of claim 1. JOSEPH E SEAGRAM & SONS, INC.. By Their Attorneys