NO763757L - - Google Patents
Info
- Publication number
- NO763757L NO763757L NO763757A NO763757A NO763757L NO 763757 L NO763757 L NO 763757L NO 763757 A NO763757 A NO 763757A NO 763757 A NO763757 A NO 763757A NO 763757 L NO763757 L NO 763757L
- Authority
- NO
- Norway
- Prior art keywords
- mixture
- block copolymer
- stated
- polymer
- unhydrogenated
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 claims description 36
- 229920001400 block copolymer Polymers 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 31
- 229920000058 polyacrylate Polymers 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 239000004793 Polystyrene Substances 0.000 claims description 11
- -1 diene hydrocarbon Chemical class 0.000 claims description 11
- 229920002223 polystyrene Polymers 0.000 claims description 11
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 9
- 230000001070 adhesive effect Effects 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 239000010985 leather Substances 0.000 claims description 8
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 7
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 6
- 125000005907 alkyl ester group Chemical group 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000004753 textile Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
- 239000004926 polymethyl methacrylate Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- QZWKEPYTBWZJJA-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine-4,4'-diisocyanate Chemical compound C1=C(N=C=O)C(OC)=CC(C=2C=C(OC)C(N=C=O)=CC=2)=C1 QZWKEPYTBWZJJA-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 229920000307 polymer substrate Polymers 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WOGVOIWHWZWYOZ-UHFFFAOYSA-N 1,1-diisocyanatoethane Chemical compound O=C=NC(C)N=C=O WOGVOIWHWZWYOZ-UHFFFAOYSA-N 0.000 description 1
- VNMOIBZLSJDQEO-UHFFFAOYSA-N 1,10-diisocyanatodecane Chemical compound O=C=NCCCCCCCCCCN=C=O VNMOIBZLSJDQEO-UHFFFAOYSA-N 0.000 description 1
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- ICLCCFKUSALICQ-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanato-3-methylphenyl)-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(C=2C=C(C)C(N=C=O)=CC=2)=C1 ICLCCFKUSALICQ-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- VBIAXKVXACZQFW-OWOJBTEDSA-N bis(2-isocyanatoethyl) (e)-but-2-enedioate Chemical compound O=C=NCCOC(=O)\C=C\C(=O)OCCN=C=O VBIAXKVXACZQFW-OWOJBTEDSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000011953 free-radical catalyst Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J111/00—Adhesives based on homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/006—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
- B32B2437/02—Gloves, shoes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31645—Next to addition polymer from unsaturated monomers
- Y10T428/31649—Ester, halide or nitrile of addition polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y10T428/31696—Including polyene monomers [e.g., butadiene, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y10T428/31699—Ester, halide or nitrile of addition polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31931—Polyene monomer-containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2738—Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Description
Oppfinnelsen vedrører en klebemiddelblanding på basis
av polyuretan, polykloropren, polystyren, en uhydrogenert blokk-kopolymer med minst 2 polymerblokker av et monoalkenyl- eller monoalkenyliden-aromatisk hydrokarbon og minst én polymerblokk av et alifatisk konjugert dien-hydrokarbon, et hydrogenert derivat av en slik blokk-kopolymer eller en blanding av slike polymerer. Oppfinnelsen vedrører også et laminat som omfatter et første substrat oppnådd av en uhydrogenert eller hydrogenert blokk-kopolymer som har minst to polymerblokker av et monoalkenyl- eller monoalkenyliden-atomatisk hydrokarbon og minst én polymerblokk av et alifatisk konjusgert dien-hydrokarbon, et annet substrat oppnådd av tekstil, polyvinylklorid, lær, metall eller glass, og som en binding mellom disse en klebemiddelblanding.
Blokk-kopolymerer av den type som her er beskrevet, er kjente. De kan være uhydrogenert eller delvis eller fullstendig hydrogenert og kan ha lineær, forgrenet eller stjerneformet kon-figurasjon .
De kjente blokk-kopolymerer som har ikke-polar karakter, viser manglende klebeevne overfor slike substanser som metaller, tre, lær, polyvinylklorid og andre polymerer som inkluderer polyuretaner og polykloropren, spesielt under våte betingelser under anvendelse av kommersielle klebemidler. Disse mangler kommer f.eks. til syne ved fremstilling av sko, hvor sålematerialet kan være festet til overlæret som kan være laget av stoff, lær eller polyvinylklorid.
Formålet med oppfinnelsen er å eliminere den manglende klebeevne hos de kjente blokk-kopolymerer overfor polare substanser.Klebemiddelblandingen i overensstemmelse med oppfinnelsen omfatter
i tillegg til basisingrediensen en polymerisert alkylester av en syre av akrylsyrerekken, idet denne esterpolymer kan være blandet med eller podet på en uhydrogenert eller hydrogenert blokk-kopolymer med minst to polymerblokker av et monoalkenyl- eller monoalkenyliden-
aromatisk hydrokarbon og minst én polymerblokk av et alifatisk konjugert dien-hydrokarbon.
De umodifiserte blokk-kopolymerer kan være enten line-ære eller forgrenet og kan ha minst to endestående polymerblokker
av styren eller a-metylstyren og minst én polymerblokk av butadien eller isopren, så vel som hydrogenerte derivater av disse. For formålene ved foreliggende oppfinnelse er den strukturelle konfi-gurasjon ikke av primær betydning.Blokkenes molekylvekt, uttrykt som antallsmidlere molekylvekt, bestemmes ved infrarød- eller tri-tiumtellemetoder. Polymerblokkene av det alkenyl- eller alkényliden-aromatiske hydrokarbon har normalt gjennomsnittlige molekylvekter på mellom 4.000 og 50.000, fortrinnsvis mellom 14.000 og 25.000.
De konjugerte dien-polymerblokker eller deres i alt vesentlig fullstendig hydrogenerte motparter har normalt gjennomsnittlige molekylvekter på mellom 30.000 og 200.000, fortrinnsvis mellom 40.000 og 125.000. To typiske familier er som følger: polystyren/polybuta-dien/polystyren og polystyren/polyisopren/polytyren.
I tillegg til disse uhydrogenerte familier kan visse hydrogenerte familier derav anvendes. Disse omfatter polymerer hvor minst de konjugerte dien-polymerblokker eller en hver ønsket frak-sjon derav er hydrogenert. Selektiv hydrogenering kan utføres for reduksjon av de olefiniske dobbeltbindinger.
Polymerer av estere av syrer av akrylserierekken inkluderer både akrylater og metakrylater. Disse polymerer kalles i det følgende polyakrylater. De estere som det spesielt er tenkt på her, er slike som stammer fra énverdige alifatiske alkoholer med 1-8 karbonatomer.Blandinger av disse estere er også inkludert. Typiske estere inkluderer metylakrylat, etylakrylat, butylakrylat
og de tilsvarende estere av metakrylsyre. Den foretrukne familie er metylmetakrylat. Polymerene av disse monomerer er kjent og trenger følgelig ikke å bli beskrevet ytterligere her. Den gjennomsnittlige molekylvekt for produktene som er spesielt nyttige i blandingen i henhold til oppfinnelsen, ligger mellom 25.000 og 250.000 eller fortrinnsvis mellom 50.000 og 150.000. Disse polymere estere kan så blandes fysisk med polyuretan, polykloropren, polystyren,
en hydrogenert blokk-kopolymer som beskrevet ovenfor eller et hydrogenert derivat derav. Alternativt kan de vært kjemisk podet på
blokk-kopolymerkjedene ved løsningspolymerisasjon i nærvær av blokkpolymeren. Dette gjøres ved dispergering av blokkpolymeren i hydro-karbonløsning og podning av de polymeriserte estere på blokkpolymer-
kjedene i nærvær av en friradikal katalysator, f.eks. et organisk peroksyd. Det foretrekkes at polymetyImetakrylatpodingene har gjennomsnittlige molekylvekter innen det område som er gjengitt ovenfor for homopolymerene.
De polyuretaner som er tenkt å være det foretrukne bindemiddel, er reaksjonsprodukter av diisocyanater og polyestere. Egnede diisocyanater er følgende: difenylmetan-4,4'-diisocyanat,
difenylen-4,4'-diisocyanat,
2.4- toluylen-diisocyanat,
2,6-toluylen-diisocyanat,
3,3-dimetoksy-4,4'-difenylen-diisocyariat
(dianisidin-diisocyanat),
tetrametylen-diisocyanat,
heksametylen-diisocyanat,
dekametylen-diisocyanat,
etylen-diisocyanat,
etyliden-diisocyanat,
propylen-1,2-diisocyanat,
cykloheksylen-1,2-diisocyanat,
m-fenylen-diisocyanat,
p-fenylen-diisocyanat,
1.5- naftalen-diisocyanat,'
3,3'-dimetyl-4,4'-bifenylen-diisocyanat, 3,3'-dimetoksy-4,4'-bifenylen-diisocyanat, 3,3'-difenyl-4,4'-bifenylen-diisocyanat, 4,4'-bifenylen-diisocyanat,
3,3'-dikloro-4,4'-bifenylen-diisocyanat, furfuryliden-diisocyanat,
bis-(2-isocyanatoetyl)fumarat.
En blanding i henhold til oppfinnelsen inneholder fortrinnsvis fra 5 til 50 vekt% av et polyakrylat eller en uhydrogenert eller hydrogenert blokk-kopolymer og på denne podet et polyakrylat og fra 95 til 50 vekt% av basisingrediensen. Hvis basisingrediensen er en blokk-kopolymer, så drøyes blandingen fortrinnsvis med polyuretan i en mengde av 1 til 10vektdeler for hver vektdel av blandingen av polyakrylat eller blokk-kopolymer som er påpodet et polyakrylat med blokk-kopolymeren. Hvis polyakrylatet er podet på en blokk-kopolymer, så er polyakrylatet fortrinnsvis tilstede i en mengde av fra 10til 50vekt% av den podede blokk-kopolymer.
Blandingen i henhold til oppfinnelsen er spesielt
godt egnet for anvendelse som klebemidler i fottøyindustrien.
Mens polyakrylatet som tjener som adhesjonspromotor kan påføres overflatene separat fra basisingrediensen, f.eks. polyuretan, så utgjør det ekstra primingtrinn tillegg til omkostningene ved fremstilling av fottøyet. Følgelig eliminerer anvendelsen av blandingen i henhold til oppfinnelsen primingtrinnet og reduserer omkostningene ved produktsjonen mens det på samme tid blir forsterk-ning av bindingen mellom ikke-polart materiale som blokk-kopoly-merene som er beskrevet ovenfor som kan anvendes for såling, og polare materialer så som tekstil, polyvinylklorid og lær, som kan anvendes for fremstilling av overlæret i fottøyet.
Følgende eksempel illustrerer oppfinnelsen.
EKSEMPEL
Den anvendte blokk-kopolymer hadde strukturen polystyren/polybutadien/polystyen.Molekylvektene til blokkens ledd var 14.000, 65.000 og 14.000.Blokkpolymeren ble oppløst i toluen for dannelse av en 10% løsning som ble modifisert med metylmetakrylat (MMA) til hvilken det så ble tilsatt benzoylperoksy (BPO). Mengden av disse komponenter er gjengitt i nedenstående tabell,
så vel som reaksjonstiden og -temperaturen ved slutten av reaksjons-perioden. Hydrokinon ble tilsatt, og reaksjonsblandingen ble av-kjølt for avslutning av reaksjonen.
Fysiske blandinger av polymetylmetakrylat og blokk-kopolymeren som eir beskrevet ovenfor i dette eksempel, ble testet som bindemiddelblandinger mellom hydrokarbon-blokkpolymersubstrater og lær. For dette formål ble blandinger av 20 vektdeler polymetylmetakrylat som hadde en gjennomsnittlig molekylvekt på 100.000 blandet med 100 vektdeler blokk-kopolymer dispergert i toluen/metyletyl-ketonløsning. Løsningen ble påført som en primer på semskede og blokk-kopolymeroverflater, og løsningsmidlet ble så fordampet. En . kommersiell polyuretanløsning ble så påført på hver av de primede overflater, og løsningsmidlet fikk fordampe. De to belagte overflater ble oppvarmet og bundet sammen (i varm tilstand) ved pressing. Avrivningsstyrke ble målt i en Instron Tester ved en separasjons-hastighet på 5 cm pr. minutt. Avrivningsstyrken var 20-22 kg/2,5 cm. Uten metakrylatet i primeren var avrivningsstyrkene bare 3-4 kg/
2,5 cm.
En podet kopolymer som omfattet polystyren/polybutadien/ polystyren podet med polymetylmetakrylat som beskrevet ovenfor i dette eksempel, og som inneholdt 74 vekt% podet metakrylat, ble blandet med et polyuretan-klebemiddel kommersielt tilgjengelig som "USM-322", i en mengde av 10% av det podede produkt og 90% av klebe-midlet. Denne blanding viste seg å være et helt ut tilfredsstil-lende bindemiddel for sammenbinding av et polyvinylkloridsubstrat med et hydrokarbon-blokkpolymersubstrat.
Claims (14)
1.B indemiddelblanding på basis av polyuretan, polykloropren, polystyren, en uhydrogenert blokk-kopolymer med minst to polymerblokker av et monoalkenyl- eller monoalkenyliden-aromatisk hydrokarbon og minst én polymerblokk av et alifatisk konjugert dien-hydrokarbon, et hydrogenert derivat av en slik blokk-kopolymer eller en blanding av slike polymerer, karakterisert ved at blandingen omfatter en polymerisert alkylester av en syre av akrylsyrerekken, idet denne esterpolymer kan være blandet med eller podet på en uhydrogenert eller hydrogenert blokk-kopolymer som har minst to polymerblokker av et monoalkenyl- eller monoalkenyliden-aromatisk hydrokarbon og minst én polymerblokk av et alifatisk konjugert dien-hydrokarbon.
2.K lebemiddelblanding som angitt i krav 1, karakterisert ved at den uhydrogenerte eller hydrogenerte blokk-kopolymer har minst to endestående polymerblokker av styren eller a-metylatyren og minst én polymerblokk av butadien eller isopren.
3. Klebemiddelblanding som angitt i krav 1 eller 2, karakterisert ved at blokk-kopolymeren har minst to polymerblokker av et monoalkenyl- eller monoalkenyliden-aromatisk hydrokarbon med gjennomsnittlige molekylvekter mellom 4.000 og 50.000 og minst én polymerblokk av et alifatisk konjugert dien-hydrokarbon med en gjennomsnittlig molékylvekt på mellom 30.000 og 200.000.
o
4.K lebemiddelblanding som angitt i krav 3, karakterisert ved at polymerblokkene i det monoalkenyl- eller monoalkenyliden-aromatiske hydrokarbon har gjennomsnittlige molekylvekter på mellom 14.000 og 25.00 0, og at polymerblokken i det alifatiske konjugerte dien-hydrokarbon har en gjennomsnittlig molekylvekt på mellom 40.000 og 125.000.
5. Klebemiddelblanding som angitt i hvilket som helst av kravene 1 til 4, karakterisert ved at den polymeriserte alkylester er polymerisert metylmetakrylat.
6.K lebemiddelblanding som angitt i hvilket som helst av kravene 1 til 5, karakterisert ved at den polymeri serte alkylester har en gjennomsnittlig molekylvekt på fra 25.000 til 250.000.
7.K lebemiddelblanding som angitt i krav 6, karakterisert ved at den polymeriserte alkylester har en gjennomsnittlig molekylvekt på fra 50.000 til 150.000.
8.K lebemiddelblanding som angitt i hvilket som helst av kravene 1 til 7, karakterisert ved at blandingen omfatter fra 5 til 50 vekt% av et polyakrylat eller en uhydrogenert eller hydrogenert blokk-kopolymer hvorpå det er podet et polyakrylat og fra 95 til 50 vekt% av basisingrediensen.
9.K lebemiddelblanding som angitt i krav 8, karakterisert ved at blandingen av et polyakrylat eller en uhydrogenert eller hydrogenert blokk-kopolymer som er påpodet et polyakrylat med en blokk-kopolymer drøyes med polyuretan i en mengde av fra 1 til 10 vektdeler for hver vektdel av blandingen.
10.K lebemiddelblanding som angitt i krav 8 eller 9, karakterisert ved at den podede blokk-kopolymer inneholder polyakrylat i en mengde av fra 10 til 50 vekt%.
11.K lebemiddelblanding som angitt i hvilket som helst av kravene 1 til 10, vesentlig som her beskrevet med spesiell henvis-ning til eksemplet.
12. Laminat som omfatter:
(a) et første substrat av en uhydrogenert eller hydrogenert blokk-kopolymer som har minst to polymerblokker av et monoalkenyl- eller monoalkenyliden-aromatisk hydrokarbon og minst én polymerblokk av et alifatisk konjugert dien-hydrokarbon;
(b) et annet substrat av et tekstil, polyvinylklorid, lær, metall, glass eller et annet polart materiale;
(c) og som binding mellom disse en blanding som angitt i hvilket som helst av kravene 1 til 11.
13. Artikkel, spesielt fottøy, inneholdende et laminat som angitt i krav 12.
14. Artikler ialt vesentlig som her beskrevet.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/629,455 US4007311A (en) | 1975-11-06 | 1975-11-06 | Polyacrylate-grafted block copolymer adhesive compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO763757L true NO763757L (no) | 1977-05-09 |
Family
ID=24523062
Family Applications (1)
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| NO763757A NO763757L (no) | 1975-11-06 | 1976-11-04 |
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|---|---|
| US (1) | US4007311A (no) |
| JP (1) | JPS5258739A (no) |
| AT (1) | AT352846B (no) |
| AU (1) | AU512216B2 (no) |
| BE (1) | BE847892A (no) |
| BR (1) | BR7607371A (no) |
| CA (1) | CA1086885A (no) |
| DE (1) | DE2650573A1 (no) |
| DK (1) | DK498376A (no) |
| FR (1) | FR2330750A1 (no) |
| GB (1) | GB1563905A (no) |
| HK (1) | HK54380A (no) |
| NL (1) | NL7612224A (no) |
| NO (1) | NO763757L (no) |
| SE (1) | SE7612333L (no) |
| ZA (1) | ZA766613B (no) |
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-
1975
- 1975-11-06 US US05/629,455 patent/US4007311A/en not_active Expired - Lifetime
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1976
- 1976-10-25 CA CA264,030A patent/CA1086885A/en not_active Expired
- 1976-11-03 BE BE1007737A patent/BE847892A/xx unknown
- 1976-11-04 NL NL7612224A patent/NL7612224A/xx not_active Application Discontinuation
- 1976-11-04 GB GB45943/76A patent/GB1563905A/en not_active Expired
- 1976-11-04 SE SE7612333A patent/SE7612333L/xx unknown
- 1976-11-04 DE DE19762650573 patent/DE2650573A1/de not_active Withdrawn
- 1976-11-04 AU AU19313/76A patent/AU512216B2/en not_active Expired
- 1976-11-04 JP JP51131833A patent/JPS5258739A/ja active Pending
- 1976-11-04 DK DK498376A patent/DK498376A/da unknown
- 1976-11-04 AT AT819576A patent/AT352846B/de not_active IP Right Cessation
- 1976-11-04 ZA ZA766613A patent/ZA766613B/xx unknown
- 1976-11-04 NO NO763757A patent/NO763757L/no unknown
- 1976-11-04 FR FR7633245A patent/FR2330750A1/fr active Granted
- 1976-11-04 BR BR7607371A patent/BR7607371A/pt unknown
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1980
- 1980-09-25 HK HK543/80A patent/HK54380A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2330750A1 (fr) | 1977-06-03 |
| HK54380A (en) | 1980-10-03 |
| NL7612224A (nl) | 1977-05-10 |
| ATA819576A (de) | 1979-03-15 |
| BR7607371A (pt) | 1977-09-20 |
| AT352846B (de) | 1979-10-10 |
| JPS5258739A (en) | 1977-05-14 |
| ZA766613B (en) | 1977-10-26 |
| BE847892A (nl) | 1977-05-03 |
| SE7612333L (sv) | 1977-05-07 |
| AU512216B2 (en) | 1980-10-02 |
| CA1086885A (en) | 1980-09-30 |
| GB1563905A (en) | 1980-04-02 |
| DK498376A (da) | 1977-05-07 |
| US4007311A (en) | 1977-02-08 |
| FR2330750B1 (no) | 1979-04-06 |
| DE2650573A1 (de) | 1977-05-18 |
| AU1931376A (en) | 1978-05-11 |
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