NO741858L - - Google Patents
Info
- Publication number
- NO741858L NO741858L NO741858A NO741858A NO741858L NO 741858 L NO741858 L NO 741858L NO 741858 A NO741858 A NO 741858A NO 741858 A NO741858 A NO 741858A NO 741858 L NO741858 L NO 741858L
- Authority
- NO
- Norway
- Prior art keywords
- substituted
- salts
- dioxide
- thiadiazinone
- benzo
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 21
- 230000002363 herbicidal effect Effects 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000004009 herbicide Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000000304 alkynyl group Chemical group 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- -1 for example Chemical class 0.000 description 21
- 239000013543 active substance Substances 0.000 description 20
- 241000196324 Embryophyta Species 0.000 description 17
- 150000002148 esters Chemical class 0.000 description 16
- 150000001408 amides Chemical class 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 12
- 239000003921 oil Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002790 naphthalenes Chemical class 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- UOCUSOBVEHOMMB-UHFFFAOYSA-N 2h-1$l^{6},2,3-benzothiadiazine 1,1-dioxide Chemical class C1=CC=C2S(=O)(=O)NN=CC2=C1 UOCUSOBVEHOMMB-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000000729 antidote Substances 0.000 description 2
- 229940075522 antidotes Drugs 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 230000001069 nematicidal effect Effects 0.000 description 2
- 239000005645 nematicide Substances 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical class OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- FTDGDIFUDKDKAW-UHFFFAOYSA-N 1,1a,5,5a,6,6a-hexahydrocyclopropa[a]indene Chemical class C12C(CC3CC=CC=C13)C2 FTDGDIFUDKDKAW-UHFFFAOYSA-N 0.000 description 1
- FNQJDLTXOVEEFB-UHFFFAOYSA-N 1,2,3-benzothiadiazole Chemical class C1=CC=C2SN=NC2=C1 FNQJDLTXOVEEFB-UHFFFAOYSA-N 0.000 description 1
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical class C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- MFVFDTCSVFBOTL-UHFFFAOYSA-N 1,3-diazetidine Chemical class C1NCN1 MFVFDTCSVFBOTL-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- JCRNSBKSAQHNIN-UHFFFAOYSA-N 2,4-dibutylnaphthalene-1-sulfonic acid Chemical class C1=CC=CC2=C(S(O)(=O)=O)C(CCCC)=CC(CCCC)=C21 JCRNSBKSAQHNIN-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical class CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 1
- HQQTZCPKNZVLFF-UHFFFAOYSA-N 4h-1,2-benzoxazin-3-one Chemical class C1=CC=C2ONC(=O)CC2=C1 HQQTZCPKNZVLFF-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 241000551547 Dione <red algae> Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000209510 Liliopsida Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical class CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical class C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 125000002490 anilino group Chemical class [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- BUSBFZWLPXDYIC-UHFFFAOYSA-N arsonic acid Chemical class O[AsH](O)=O BUSBFZWLPXDYIC-UHFFFAOYSA-N 0.000 description 1
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- 150000005130 benzoxazines Chemical class 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- QQSGDKKFXBGYON-UHFFFAOYSA-N ethoxy-methylperoxy-(6-methyl-2-propan-2-ylpyrimidin-4-yl)oxy-sulfanylidene-$l^{5}-phosphane Chemical class CCOP(=S)(OOC)OC1=CC(C)=NC(C(C)C)=N1 QQSGDKKFXBGYON-UHFFFAOYSA-N 0.000 description 1
- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 description 1
- 241001233957 eudicotyledons Species 0.000 description 1
- 239000000194 fatty acid Chemical class 0.000 description 1
- 229930195729 fatty acid Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical class CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 150000001469 hydantoins Chemical class 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- QNMLMAVEXUCXRG-UHFFFAOYSA-N oxadiazinane-4,5-dione Chemical class O=C1CONNC1=O QNMLMAVEXUCXRG-UHFFFAOYSA-N 0.000 description 1
- SDRLFDJOSQLRPB-UHFFFAOYSA-N oxadiazine-4,5-dione Chemical class O=C1CON=NC1=O SDRLFDJOSQLRPB-UHFFFAOYSA-N 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- DTHHUAXKOMWYBI-UHFFFAOYSA-N oxadiazolidine Chemical class C1CONN1 DTHHUAXKOMWYBI-UHFFFAOYSA-N 0.000 description 1
- YDCVQGAUCOROHB-UHFFFAOYSA-N oxadiazolidine-4,5-dione Chemical class O=C1NNOC1=O YDCVQGAUCOROHB-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical class P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- BFZYLUGEHGYJKJ-UHFFFAOYSA-N pyrazolidine-3-thione Chemical class S=C1CCNN1 BFZYLUGEHGYJKJ-UHFFFAOYSA-N 0.000 description 1
- 150000004892 pyridazines Chemical class 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000005299 pyridinones Chemical class 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 150000008318 pyrimidones Chemical class 0.000 description 1
- NYCVCXMSZNOGDH-UHFFFAOYSA-N pyrrolidine-1-carboxylic acid Chemical class OC(=O)N1CCCC1 NYCVCXMSZNOGDH-UHFFFAOYSA-N 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 150000003246 quinazolines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- OLPRIZQBWZMBAS-UHFFFAOYSA-N thiadiazolidine 1,1-dioxide Chemical class O=S1(=O)CCNN1 OLPRIZQBWZMBAS-UHFFFAOYSA-N 0.000 description 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 1
- 150000003582 thiophosphoric acids Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 244000045561 useful plants Species 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
"Herbicide midler"
^ jj^ pen foreliggende oppfinnelse angår nye verdifulle herbicide^ som inneholder blandinger av virksomme stoffer.
Det er kjent at benzotiadiazinondioksyder (DT-OS 1 542 836) og fosforsyreester har en herbicid virkning. Denne er , imidlertid ikke alltid tilstrekkelig.
Det ble funnet at en blanding av
a) en forbindelse med formelen
hvor R betyr et lavere alkyl med opp til 4 karbonatomer, betyr hydrogen og saltene, eksempelvis ammonium-, natrium-, kalium-, litium-, kalsium-, magnesium-, etyl-amin-, dimetylamin-, etanolamin-, dietanolamin-, dimetyl-etanolamin-saltene, og
b) en forbindelse med formelen
hvor R og R^betyr lavere alkyl, alkenyl, alkinyl, z betyr
metyl, n har verdier fra 0 til 3, Y betyr oksygen eller svovel, X betyr - CH^ i 0 eller N,
har en bedre herbicid virkning enn de virksomme enkeltstoffer.
Blandingene kan inneholde en eller flere forbindelser med formelen a) og formelen b).
Blandingsforholdene kan velges etter ønske. Blandingsfor-holdet mellom de virksomme stoffer a) og b) er fortrinnsvis 10 : 1 til 1 • 3 på vektsbasis.
De mengder! som anvendes av midlene ifølge oppfinnelsen, kan variere. Den mengde som anvendes, avhenger hovedsakelig av arten av den ønskede virkning. Mengden ligger vanligvis mellom 0,1 og 30 eller mer, fortrinnsvis 0,2-6, kg virksomt stoff pr. hektar. Midlene ifølge oppfinnelsen kan blant annet anvendes ved metoder hvor de påføres før plantingen, etter plantingen, før såingen, før plantene kommer opp av jorden, etter at plantene kommer opp av jorden eller mens kulturplantene eller de uønskede planter er i ferd med å komme opp av jord-n, og midlene kan anvendes en eller flere ganger.
Blandingene er egnet til bekjempelse av uønskede planter i kulturer av nytteplanter, som for eksempel
Videre kan blandingene anvendes som totalmiddel ved graver, langs elver og bekker, langs jernbaneskinner, på øde flater etc.
Midlene oppviser en sterk herbicid virkning og kan derfor anvendes som ugrasdrepende midler eller til bekjempelse av uønsket plantevekst. Om midlene virker som totale eller selektive midler, avhenger hovedsakelig av den mengde virksomt stoff som anvendes pr. flateenhet.
Med ugras eller uønsket plantevekst menes alle enfrøbladede og tofrøbladede planter som vokser på steder hvor de ikke er ønsket.
Således kan eksempelvis følgende planter bekjempes med midlene ifølge oppfinnelsen* ;
Midlene kan eksempelvis anvendes i form av direkte sprøyt-bare løsninger, pulvere, suspensjoner eller dispersjoner, emulsjoner, oljedispersjoner, pastaer, støvformige midler, strømidler eller granulater, ved sprøyting, forstøvning, utstrøing eller uthelling. Bruksformene retter seg helt etter anvendelsesformålet; man tar alltid sikte på å oppnå en mest mulig fin fordeling av de virksomme stoffer ifølge oppfinnelsen. ;For fremstilling av direkte sprføytbare løsninger, emulsjoner, pastaer eller oljedispersjoner kan man bruke mineraloljefraksjoner med midlere til høyt kokepunkt, så som kerosin eller dieselolje, enn-videre kulltjæreoljer etc. samt oljer av vegetabilsk eller animalsk opprinnelse, alifatiske, cykliske og aromatiske hydrokarboner, som for eksempel benzen, toluen, xylen, paraffin, tetrahydronaftalin, alkylerte naftaliner eller deres derivater, for eksempel metanol, etanol, propanol, butanol, kloroform, karbontetraklorid, cyklohek-sanol, cykloheksanon, klorbenzen, isoforon etc, sterkt polare løs-ningsmidler, så som dimetylformamid, dimetylsulfoksyd, N-metyl-pyr-rolidon, vann etc. ;Vandige bruksformer kan fremstilles av emulsjonskonsentrater, pastaer eller fuktbare pulvere (sprøytepulvere) eller oljedispersjoner ved tilsetning av vann. Ved fremstilling av emulsjoner, pastaer eller oljedispersjoner kan stoffene som sådanne eller løst i olje eller løsningsmiddel homogeniseres i vann ved hjelp av fukte-, klebe-, dispergerings- eller emulgeringsmidler. Det kan imidlertid også fremstilles konsentrater bestående av virksomt stoff, fukte-, klebe-, dispergerings- eller emulgeringsmiddel og eventuelt løsnings-middel eller olje, hvilke konsentrater er egnet til å fortynnes med vann. ;Blant overflateaktive stoffer kan nevnes: alkali-, jord-alkali- og ammoniumsalter av ligninsulfonsyre, naftalinsulfonsyre, fenolsulfonsyrer, alkylarylsulfonater, alkylsulfater, alkylsulfonater, alkali- og jordalkalisalter av dibutylnaftalinsulfonsyre, lauryl-etersulfat, fettalkoholsulfater, fettsure alkali- og jordalkalisalter, salter av sulfaterte heksadekanoler, heptadekanoler, oktadekanoler, salter av sulfatert fettalkoholglykoleter, kondensasjonsprodukter av sulfonert naftalin og naftalinderivater med formaldehyd, konden-sas jonsprodukter av naftalin eller naftalinsulfonsyrer/ med fenol og formaldehyd, polyoksyetylen-okstylfenoleter, etoksylert isookstyl-fenol, -oktylfenol, -nonylfenol, alkylfenolpolyglykoleter, tributyl-fenylpolyglykoleter, alkylarylpolyeteralkoholer, isotridecylalkohol, fettalkoholetylenoksyd-kondensater, etoksylert riciriusolje, poly-oksyetylenalkyleter, etoksylert polyoksypropylen, laurylalkohol-polyglykoleteracetal, sorbitolester, lignin, sulfittavluter og metylcellulose. ;Pulver, strø- og støvformige midler kan fremstilles ved blanding eller sammaling av de virksomme stoffer med et fast bære-materiale. ;Granulater, for eksempel omhyllings-, impregnerings-pog homogengranulater, kan fremstilles ved binding av de virksomme stoffer på faste bærematerialer. Faste bærematerialer er for eksempel mineralmaterialer så som silikagel, kiselsyrer, kiselgeler, sili-kater, talkum, kaolin, attaclay, kalkstein, kalk, kritt, bolus, ;løss, leire, dolomitt, diatoméjord, kalsium- og magnesiumsulfat, magnesiumoksyd, malte harpikser, gjødningsstoffer, som for eksempel ammoniumsulfat, ammoniumfosfat, ammoniumnitrat, urinstoffer og vege-tabilske produkter så som mel av korn, bark, tre og nøtteskall, cellulosepulver og andre faste bærematerialer. ;Preparatene Inneholder mellom 0,1 og 95 vekt% virksomt stoff, fortrinnsvis mellom 0,5 og 90 vekt%. ;Til blandingene eller de enkelte virksomme stoffer kan man, eventuelt først umiddelbart før anvendelsen (tankblanding), tilsette oljer av forskjellige typer, herbicider, fungicider, nematocider, insekticider, baktericider, sporelementer, gjødningsstoffer, skum-hindrende midler (for eksempel silikoner) , vektetregulatorer, motgiftmidler og andre herbicid virksomme forbindelser, som for eksempel ;substituerte aniliner;substituerte aryloksykarboksylsyrer og deres salter, estere og ;amider;substituerte etere;substituerte arsonsyrer og deres salter, estere og amider substituerte benzimidazoler ;substituerte benzisotiazoler;substituerte benztiadiazinondioksyder;substituerte benzoksaziner;substiuerte benzoksazinoner;substituerte benztiadiazoler;substituerte biureter;substituerte kinoliner;substituerte karbamater;substituerte a11fatiske karboksylsyrer og deres salter, estere og amider ;substituerte aromatiske karboksylsyrer og deres salter, estere og amider ;substituerte karbamoylalkyl-tiol- eller ditiofosfater substituerte kinazoliner ;substituerte cykloalkylamidokarboksyltiolsyrer og deres salter, ;estere og amider;substituerte cykloalkylkarbonamido-tiazoler;substituerte dikarboksylsyrer og deres salter, estere og amider substituerte dihydrobenzofuranylsulfonater ;substiuerte disulfider;substituerte dipyridyliumsalter;substituerte ditiokarbamater;substituerte ditiofosforsyrer og deres salter, estere og amider substituerte urinstoffer ;substituerte heksahydro-l-H-karbotioater;substituerte hydantoiner;substituerte hydrazider i;substituerte hydrazoniumsalter;substituerte isooksazolpyrimidoner;substituerte imidazoler;substituerte isotiazolpyrimidoner;substituerte ketoner;substituerte naftokinoner;substituerte alifatiske nitriler;substituerte aromatiske nitriler;substi^tuerte oksadiazoler;substituerte oksadiazinoner;substituerte oksadiazolidindioner;substituerte oksadiazindioner;substituerte fenoler og deres salter og estere substituerte fosfonsyrer og deres salter, estere og amider substituerte fosfoniumklorider ;substituerte fosfonalkylglyciner;substituerte fosfitter;substituerte fosforsyrer og deres salter, estere og amider substituerte piperidiner ;substituerte pyrazoler;substituerte pyrazolalkylkarboksylsyrer og deres salter, estere og amid er ;substituerte pyrazoliumsalter;substituerte pyrazoliumalkylsulfater;substituerte pyridaziner;substituerte pyridazoner substituerte pyridinkarboksylsyrer og deres salter, estere og amider substituerte pyridiner ;substituerte pyridinkarboksylater;substituerte pyridinoner;substituerte pyrimidiner;substituerte pyrimidoner;substituerte pyrrolidinkarboksylsyre og dennes salter, estere og ;amider;substituerte pyrrolidiner;substituerte pyrrolidoner;substituerte arylsulfonsyrer og deres salter, estere og amider substituerte styrener ;substituerte tetrahydro-oksadiazindioner;substituerte tetrahydro-oksadiazoldiorier;substituerte tetrahydrometanoindener;substituerte tetrahydro-diazol-tioner;substituerte tetrahydro-tiadiazin-tioner;substituerte tetrahydro-tiadiazoldioner;substituerte aromatiske tiokarboksylsyreamider;substituerte tiokarboksylsyrer og deres salter, estere og amider substituerte tiolkarbamater ;substituerte tiourinstoffer;substituerte tiofosforsyrer og deres salter, estere og amider substituerte triaziner ;substituerte triazoler;substituerte uraciler;substituerte uretidindioner.;De sistnevnte^héTb"i<r>c^"del-lE6rbih^els1erJkan etter ønske anvendes før eller etter de virksomme enkeltstoffer eller blandinger ifølge oppfinnelsen. ;Tilblandingen av disse midler til herbicidene ifølge oppfinnelsen kan skje i vektforholdet 1:10 til 10\: 1. Det samme gjelder olje, fungicider, nematocider, insekticider, baktericider, motgiftmidler og vekstregulatorer. ;De følgende forbindelser ble i drivhus og på friland ut-prøvet i forskjellige blandinger overfor de ovennevnte planter: 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd, 3-diopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-natriumsalt, 3-idopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-dimetyl-
aminsalt, ;3-siopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-dietanol-aminsalt, ;3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-kaliumsalt, 3-isopropyl-2, 1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-ammoniumsalt, 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-litiumsalt, 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-magnesium-salt, ;3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-etylaminsalt, 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-etanolamin-salt, ;3-isopropyl-2,1, 3-benzo-tiadiazinon-jL(4-)-y2 , 2-dioksyd-trietanol-aminsalt og andre salter, ;3-metyl-2,1, 3,-benzo-tiadiazinon-(4) -2, 2-dioksyd, ;3-etyl-2,'T7j3-benzo-tiadiazinon-(4) -2, 2-dioksyd, ;3-n-propyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd, 3-sek.-butyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd, S-(2-metyl-l-piperidyl-karbonylmetyl)-0,O-di-n-propylditio-fosfat, ;S-(2,5-dimetyl-l-morfolinyl-karbonylmetyl)-0,0-dietyl-ditiofosfat, ;S-(3,5-dimetyl-l-morfolinyl-karbonylmetyl)-0,0-dietyl-ditiofosfat, og andre. ;De anførte midler har en tilsvarende biologisk virkning som de i eksemplene 1-4 anførte blandinger. ;Eksempel 1;I et drivhus ble forsøkskasser fyllt med leirholdig sand-jord. Deretter ble jorden behandlet med de følgende virksomme enkeltstoffer og deres blandinger i form av løsninger i et organisk løsningsmiddel: ;I 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd;II S-(2-metyl-l-piperidyl-karbonyl-metyl)-0,0-di-n-propyl-ditiofosfat ;i hvert tilfelle 0,25 - 0,5 -0,75 - 1 - 1,25 - 1,5 og;2 kg/ha aktivt stoff.;I + II 0,25 + 1,25?1,25+0,25*0,75 + 0,75; 1,5 + 0,5;
0,5+1,5; 1+1 kg/ha aktivt stoff.
Deretter ble frø av de uønskede planter sådd og Oryza sativa plantet (plantestørrelse 10-40 cm). Det hele ble så satt under 10 cm vann.
Etter 3-4 uker ble det slått fast at blandingen I + II viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene I og II.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 2
I et drivhus ble forsøkskasser fyllt med leirholdig sand-jord, og forskjellige frø ble sådd. Jorden ble deretter behandlet med de følgende virksomme enkeltstoffer og deres blandinger i form av granulat:
I 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd,
II S-(2-metyl-l-piperidyl-carbonylmetyl)-0,0-di-n-propyl-ditiofosfat
i hvert tilfelle 1, 2, 3 og 4 kg/ha aktivt stoff.
I + II 3 + 1; 1+3; 2 + 2 kg ha aktivt stoff.
Til sammenligning:
III 0,0-dietyl-S-(N-fenyl-N-propargyl)-karbamoylmetyl-ditiofosfat
3 og 4 kg/ha aktivt stoff.
Iin(l\ 3 + 1 kg/ha aktivt stoff.
Etter 3-4 uker ble det slått fast at blandingen I + II viste en bedre forenlighet med kulturplantene ved samme herbicide virkning enn de virksomme enkeltstoffer I, II, III og blandingen
III + I.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 3
I et drivhus ble forskjellige planter ved en veksthøyde på 2-18 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger i form av emulsjoner:
I 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd
II 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2, 2-dioksyd-natriumsalt
III 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)- 2, 2-dioksyd-dimetylaminsalt
IV 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)- 2,2-dioksyd-dietanolaminsalt
V S-(2-metyl-l-piperidyl-karbonylmetyl)-0,O-di-n-propyl-ditiofosfat
i hvert tilfelle 0,25 - 0,75 - 1,25 og 1,5 kg/ha
I + V, 11+ V, III + V, IV + V i hvert tilfelle 0,25+1,25; 0,75+0,75;
1,25+0,25 kg/ha aktivt stoff. []■ ~Tr^
Etter 10-14 dager ble det slått fast at blandingene viste
en bedre herbicid virkning ved samme forenlighet med kulturplantene enn de virksomme enkeltstoffer.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 4
På friland ble forskjellige planter ved en veksthøyde på 3-25 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger i form av emulsjoner eller støvs
I 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd
II 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd-natriumsalt
III 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)- 2, 2-dioksyd-dimetylaminsalt
IV 3-isopropyl-2,1, 3-benzo-tiadiazinon-(4)- 2, 2-dioksyd-dietanolaminsalt
V S-(2-metyl-l-piperidyl-karbonylmetyl)-0,O-di-n-propyl-ditiofosfat
i hvert tilfelle 1 - 1,5 - 2 og 3 kg/ha aktivt stoff.
I+V, II+V, III+V, IV+V, i. hvert tilfelle 2+1, 1+2, 1,5+1,5 kg/ha aktivt stoff.
Etter 12-16 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene.
Forsøksresultatet vil fremgå av den følgende tabell.
Claims (2)
1. Herbicid^ karakterisert ved at det inneholder en blanding ava) en forbindelse med formelen
hvor R betyr lavere alkyl med opp til 4 karbonatomer, R^ betyr hydrogen og saltene, og
b) en forbindelse med'formelen
hvor R og R^ betyr lavere alkyl, alkenyl, alkinyl, Z betyr metyl, n har verdier fra 0 til 3, Y betyr oksygen eller svovel, X betyr - CB^, 0 eller N.
2. Herbicid, karakterisert ved at det inneholder en blanding av 3-isopropyl-2,1,3-benzo-tiadiazinon-(4)-2,2-dioksyd og S-(2-metyl-l-piperidyl-karbonyl-metyl)-0,O-di-n-propyl-ditio-fosfat.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2329044A DE2329044A1 (de) | 1973-06-07 | 1973-06-07 | Herbizid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO741858L true NO741858L (no) | 1975-01-06 |
Family
ID=5883331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO741858A NO741858L (no) | 1973-06-07 | 1974-05-21 |
Country Status (27)
| Country | Link |
|---|---|
| US (1) | US3912494A (no) |
| JP (1) | JPS5019934A (no) |
| AT (1) | AT334130B (no) |
| AU (1) | AU6921274A (no) |
| BE (1) | BE815936A (no) |
| BG (1) | BG22784A3 (no) |
| BR (1) | BR7404668D0 (no) |
| DD (1) | DD111634A5 (no) |
| DE (1) | DE2329044A1 (no) |
| DK (1) | DK302674A (no) |
| ES (1) | ES427038A1 (no) |
| FI (1) | FI170074A (no) |
| FR (1) | FR2232270B3 (no) |
| GB (1) | GB1461797A (no) |
| HU (1) | HU168168B (no) |
| IL (1) | IL44861A0 (no) |
| IT (1) | IT1049290B (no) |
| LU (1) | LU70249A1 (no) |
| NL (1) | NL7407210A (no) |
| NO (1) | NO741858L (no) |
| OA (1) | OA04711A (no) |
| PL (1) | PL88546B1 (no) |
| RO (1) | RO67783A (no) |
| SE (1) | SE7407407L (no) |
| SU (1) | SU511831A3 (no) |
| TR (1) | TR17763A (no) |
| ZA (1) | ZA743576B (no) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5251028A (en) * | 1975-10-22 | 1977-04-23 | Nippon Tokushu Noyaku Seizo Kk | Herbicide |
| WO2007076028A2 (en) * | 2005-12-22 | 2007-07-05 | Fmc Corporation | Insecticidal and miticidal mixtures of bifenthrin and cyano-pyrethroids |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3708277A (en) * | 1966-08-30 | 1973-01-02 | Basf Ag | Herbicidal method |
| US3826642A (en) * | 1969-03-19 | 1974-07-30 | Basf Ag | Herbicide |
-
1973
- 1973-06-07 DE DE2329044A patent/DE2329044A1/de active Pending
-
1974
- 1974-05-20 IL IL44861A patent/IL44861A0/xx unknown
- 1974-05-21 NO NO741858A patent/NO741858L/no unknown
- 1974-05-21 AU AU69212/74A patent/AU6921274A/en not_active Expired
- 1974-05-24 US US473222A patent/US3912494A/en not_active Expired - Lifetime
- 1974-05-29 NL NL7407210A patent/NL7407210A/xx unknown
- 1974-05-31 OA OA55211A patent/OA04711A/xx unknown
- 1974-06-03 JP JP49061949A patent/JPS5019934A/ja active Pending
- 1974-06-04 FI FI1700/74A patent/FI170074A/fi unknown
- 1974-06-04 RO RO7479042A patent/RO67783A/ro unknown
- 1974-06-04 TR TR17763A patent/TR17763A/xx unknown
- 1974-06-05 SE SE7407407A patent/SE7407407L/xx not_active Application Discontinuation
- 1974-06-05 PL PL1974171665A patent/PL88546B1/pl unknown
- 1974-06-05 ZA ZA00743576A patent/ZA743576B/xx unknown
- 1974-06-05 LU LU70249A patent/LU70249A1/xx unknown
- 1974-06-05 SU SU2032795A patent/SU511831A3/ru active
- 1974-06-05 IT IT51400/74A patent/IT1049290B/it active
- 1974-06-05 BE BE145091A patent/BE815936A/xx unknown
- 1974-06-06 AT AT470374A patent/AT334130B/de not_active IP Right Cessation
- 1974-06-06 HU HUBA3082A patent/HU168168B/hu unknown
- 1974-06-06 ES ES427038A patent/ES427038A1/es not_active Expired
- 1974-06-06 GB GB2517474A patent/GB1461797A/en not_active Expired
- 1974-06-06 BG BG26887A patent/BG22784A3/xx unknown
- 1974-06-06 BR BR4668/74A patent/BR7404668D0/pt unknown
- 1974-06-06 DD DD178992A patent/DD111634A5/xx unknown
- 1974-06-06 DK DK302674A patent/DK302674A/da unknown
- 1974-06-06 FR FR7419548A patent/FR2232270B3/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SU511831A3 (ru) | 1976-04-25 |
| IT1049290B (it) | 1981-01-20 |
| OA04711A (fr) | 1980-08-31 |
| HU168168B (no) | 1976-03-28 |
| BG22784A3 (no) | 1977-04-20 |
| PL88546B1 (no) | 1976-09-30 |
| DK302674A (no) | 1974-12-08 |
| BR7404668D0 (pt) | 1975-09-23 |
| FI170074A (no) | 1974-12-08 |
| FR2232270A1 (no) | 1975-01-03 |
| AU6921274A (en) | 1975-11-27 |
| SE7407407L (no) | 1974-12-09 |
| BE815936A (fr) | 1974-12-05 |
| LU70249A1 (no) | 1974-10-17 |
| TR17763A (tr) | 1976-07-01 |
| ATA470374A (de) | 1976-04-15 |
| AT334130B (de) | 1976-12-27 |
| US3912494A (en) | 1975-10-14 |
| ES427038A1 (es) | 1976-09-01 |
| FR2232270B3 (no) | 1977-04-08 |
| NL7407210A (no) | 1974-12-10 |
| IL44861A0 (en) | 1974-07-31 |
| DD111634A5 (no) | 1975-03-05 |
| GB1461797A (en) | 1977-01-19 |
| ZA743576B (en) | 1975-06-25 |
| JPS5019934A (no) | 1975-03-03 |
| DE2329044A1 (de) | 1975-01-02 |
| RO67783A (ro) | 1981-08-30 |
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