NO329347B1 - Anvendelse av alkoksylerte polyglyceroler som demulgeringsmidler - Google Patents
Anvendelse av alkoksylerte polyglyceroler som demulgeringsmidler Download PDFInfo
- Publication number
- NO329347B1 NO329347B1 NO20033415A NO20033415A NO329347B1 NO 329347 B1 NO329347 B1 NO 329347B1 NO 20033415 A NO20033415 A NO 20033415A NO 20033415 A NO20033415 A NO 20033415A NO 329347 B1 NO329347 B1 NO 329347B1
- Authority
- NO
- Norway
- Prior art keywords
- polyglycerols
- units
- alkoxylated
- alkylated
- water
- Prior art date
Links
- 229920000223 polyglycerol Polymers 0.000 title claims description 33
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000839 emulsion Substances 0.000 claims description 19
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 13
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
- 125000002947 alkylene group Chemical group 0.000 claims description 9
- 230000029936 alkylation Effects 0.000 claims description 4
- 238000005804 alkylation reaction Methods 0.000 claims description 4
- 230000021523 carboxylation Effects 0.000 claims description 3
- 238000006473 carboxylation reaction Methods 0.000 claims description 3
- 150000002314 glycerols Chemical class 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims 1
- 239000010779 crude oil Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000003921 oil Substances 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- 235000019198 oils Nutrition 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000005336 cracking Methods 0.000 description 7
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- WOKDXPHSIQRTJF-UHFFFAOYSA-N 3-[3-[3-[3-[3-[3-[3-[3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]propane-1,2-diol Chemical compound OCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)CO WOKDXPHSIQRTJF-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229920005628 alkoxylated polyol Polymers 0.000 description 1
- 229940100198 alkylating agent Drugs 0.000 description 1
- 239000002168 alkylating agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/04—Dewatering or demulsification of hydrocarbon oils with chemical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
- B01D17/047—Breaking emulsions with separation aids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyethers (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10107880A DE10107880B4 (de) | 2001-02-20 | 2001-02-20 | Alkoxylierte Polyglycerine und ihre Verwendung als Emulsionsspalter |
PCT/EP2002/001376 WO2002066136A2 (fr) | 2001-02-20 | 2002-02-09 | Polyglycerines alkoxylees et leur utilisation en tant que separateurs d'emulsion |
Publications (3)
Publication Number | Publication Date |
---|---|
NO20033415L NO20033415L (no) | 2003-07-30 |
NO20033415D0 NO20033415D0 (no) | 2003-07-30 |
NO329347B1 true NO329347B1 (no) | 2010-10-04 |
Family
ID=7674686
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO20033415A NO329347B1 (no) | 2001-02-20 | 2003-07-30 | Anvendelse av alkoksylerte polyglyceroler som demulgeringsmidler |
Country Status (5)
Country | Link |
---|---|
US (1) | US7026363B2 (fr) |
EP (1) | EP1363715B1 (fr) |
DE (2) | DE10107880B4 (fr) |
NO (1) | NO329347B1 (fr) |
WO (1) | WO2002066136A2 (fr) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10211801B4 (de) * | 2002-03-16 | 2004-09-30 | Clariant Gmbh | Kosmetische und pharmazeutische Zubereitungen enthaltend einen oxalkylierten Polyglycerinester |
DE10325198B4 (de) * | 2003-06-04 | 2007-10-25 | Clariant Produkte (Deutschland) Gmbh | Verwendung von alkoxylierten vernetzten Polyglycerinen als biologisch abbaubare Emulsionsspalter |
DE10342870A1 (de) * | 2003-09-15 | 2005-05-12 | Clariant Gmbh | Flüssige Zusammensetzungen enthaltend oxalkylierte Polyglycerinester |
US20090082483A1 (en) * | 2007-09-20 | 2009-03-26 | Petrovic Zoran S | Polyglycerol based polyols and polyurethanes and methods for producing polyols and polyurethanes |
RU2539897C2 (ru) | 2009-07-30 | 2015-01-27 | Басф Се | Композиция для нанесения металлического покрытия, содержащая подавляющий агент, для беспустотного заполнения субмикронных элементов поверхности |
US20120059088A1 (en) * | 2010-09-02 | 2012-03-08 | Baker Hughes Incorporated | Novel Copolymers for Use as Oilfield Demulsifiers |
WO2015009485A1 (fr) * | 2013-07-18 | 2015-01-22 | Croda, Inc. | Procédé de séparation entre une huile et un jus de distillation |
CN103666539B (zh) * | 2013-11-22 | 2015-03-11 | 江苏汉光实业股份有限公司 | 一种原油破乳剂的生产系统 |
CA2969767C (fr) * | 2015-01-16 | 2022-10-18 | Croda, Inc. | Procede de separation d'huile |
Family Cites Families (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE229006C (fr) | ||||
US2499365A (en) | 1947-03-07 | 1950-03-07 | Petrolite Corp | Chemical manufacture |
US2552528A (en) * | 1949-07-14 | 1951-05-15 | Petrolite Corp | Process for breaking petroleum emulsions |
US2944982A (en) | 1954-06-10 | 1960-07-12 | Petrolite Corp | Process for breaking petroleum emulsions employing certain oxyalkylated acyclic diglycerols |
US3110737A (en) * | 1958-09-15 | 1963-11-12 | Petrolite Corp | Certain oxyalkylated polyols |
US3110736A (en) * | 1958-09-15 | 1963-11-12 | Petrolite Corp | Certain oxyalkylated polyols |
US3752657A (en) | 1971-04-26 | 1973-08-14 | Chevron Res | Nonionic surfactant as a demulsifier for amine containing fuel detergents |
GB1446435A (en) | 1972-11-02 | 1976-08-18 | Cooper Ltd Ethyl | Lubricant additives |
DE2360020C2 (de) | 1973-12-01 | 1982-08-19 | Henkel KGaA, 4000 Düsseldorf | Schaumarmes Wasch-, Spül- und Reinigungsmittel |
US4265774A (en) * | 1976-10-29 | 1981-05-05 | Basf Wyandotte Corporation | Oxyalkylated polyglycerols and water-based lubricants prepared therefrom |
US4061684A (en) | 1976-10-29 | 1977-12-06 | Basf Wyandotte Corporation | Highly branched polyether polyols of high molecular weight |
DE2719978C3 (de) | 1977-05-04 | 1980-09-25 | Basf Ag, 6700 Ludwigshafen | Erdölemulsionsspalter |
DD229006A1 (de) * | 1979-04-02 | 1985-10-30 | Petrolchemisches Kombinat | Schmieroele mit demulgierender wirkung |
US4414035A (en) | 1979-05-21 | 1983-11-08 | Petrolite Corporation | Method for the removal of asphaltenic deposits |
US4342657A (en) | 1979-10-05 | 1982-08-03 | Magna Corporation | Method for breaking petroleum emulsions and the like using thin film spreading agents comprising a polyether polyol |
US4263178A (en) | 1979-11-26 | 1981-04-21 | The Gillette Company | Hair shampoo composition |
US4321146A (en) * | 1980-05-22 | 1982-03-23 | Texaco Inc. | Demulsification of bitumen emulsions with a high molecular weight mixed alkylene oxide polyol |
CA1184865A (fr) | 1981-07-08 | 1985-04-02 | William B. Walton | Methode de rupture des emulsions de petrole |
DE3142955A1 (de) | 1981-10-29 | 1983-05-11 | Hoechst Ag, 6230 Frankfurt | "neue grenzflaechenaktive verbindungen, verfahren zu ihrer herstellung und ihre verwendung" |
GB2118937A (en) | 1982-03-24 | 1983-11-09 | Ciba Geigy Ag | Alkoxylated alkyl phenol derivatives used as emulsion breakers for crude oil |
US4921898A (en) | 1985-08-02 | 1990-05-01 | Air Products And Chemicals, Inc. | Vinyl acetate-ethylene copolymer emulsions prepared in the presence of a stabilizing system of a low molecular weight polyvinyl alcohol and a surfactant |
US5021498A (en) | 1989-11-08 | 1991-06-04 | Nalco Chemical Company | Asphaltene dispersants - inhibitors |
FR2661913B1 (fr) | 1990-05-11 | 1992-08-28 | Distugil | Procede de production de polychloroprene. |
CA2075749C (fr) | 1991-08-12 | 2004-11-02 | William K. Stephenson | Adjuvant de dessalage et traitement chimique |
DE4136661A1 (de) | 1991-11-07 | 1993-05-13 | Basf Ag | Erdoelemulsionsspalter |
DE4206429A1 (de) | 1992-02-29 | 1993-09-02 | Basf Ag | Waessrige polymerisatdispersionen |
US5399371A (en) | 1993-06-17 | 1995-03-21 | Henkel Corporation | Low calorie substitute for an edible oil |
US5525201A (en) | 1993-08-10 | 1996-06-11 | Nalco Chemical Company | Oxyalkylated phenol/formaldehyde resin for desalter applications in the refinery Industry |
US5460750A (en) | 1993-08-10 | 1995-10-24 | Nalco Chemical Company | Phenolic resins and method for breaking crude oil emulsions |
DE19503099A1 (de) | 1994-02-11 | 1995-08-17 | Basf Ag | Verfahren zur Herstellung wäßriger Polymerisatdispersionen nach der Methode der radikalischen wäßrigen Emulsionspolymerisation in Gegenwart eines nichtionischen Emulgators |
US5494607A (en) | 1994-04-29 | 1996-02-27 | Nalco Chemical Company | Alkyl substituted phenol-polyethylenepolyamine-formaldehyde resins as asphaltene dispersants |
DE4418800A1 (de) | 1994-05-30 | 1995-12-07 | Basf Ag | Verfahren zur Abtrennung vom Wasser aus Rohöl und hierbei verwendete Erdölemulsionsspalter |
RU2089593C1 (ru) * | 1994-08-18 | 1997-09-10 | Научно-исследовательский институт нефтепромысловой химии "НИИнефтепромхим" | Способ получения деэмульгатора для обезвоживания и обессоливания водонефтяных эмульсий |
US5667727A (en) * | 1995-06-26 | 1997-09-16 | Baker Hughes Incorporated | Polymer compositions for demulsifying crude oil |
DE19629038A1 (de) * | 1996-07-19 | 1998-01-22 | Henkel Kgaa | Verwendung von mit alpha-Olefinepoxiden umgesetzten Ethylenoxid/Propylenoxid-Anlagerungsverbindungen des Glycerins oder Polyglycerins als Entschäumer |
DE19733077A1 (de) | 1997-07-31 | 1999-02-04 | Clariant Gmbh | Neue Kolloiddispersions-Mischungen als Schutzkolloid für die wäßrige Emulsionspolymerisation, Verfahren zu ihrer Herstellung und ihre Verwendung |
RU2151780C1 (ru) * | 1999-02-02 | 2000-06-27 | Открытое акционерное общество "Нижнекамскнефтехим" | Способ получения деэмульгатора |
DE19916946C1 (de) | 1999-04-15 | 2000-07-27 | Clariant Gmbh | Aromatische Aldehydharze und ihre Verwendung als Emulsionsspalter |
RU2154090C1 (ru) * | 1999-07-08 | 2000-08-10 | Открытое акционерное общество "Научно-исследовательский институт по нефтепромысловой химии" | Способ получения деэмульгатора для обезвоживания и обессоливания нефти |
RU2152976C1 (ru) * | 1999-07-28 | 2000-07-20 | Открытое акционерное общество "Научно-исследовательский институт по нефтепромысловой химии" | Состав для обезвоживания и обессоливания нефти и ингибирования асфальтено-смолопарафиновых отложений |
DE10211801B4 (de) * | 2002-03-16 | 2004-09-30 | Clariant Gmbh | Kosmetische und pharmazeutische Zubereitungen enthaltend einen oxalkylierten Polyglycerinester |
-
2001
- 2001-02-20 DE DE10107880A patent/DE10107880B4/de not_active Expired - Fee Related
-
2002
- 2002-02-09 EP EP02716756A patent/EP1363715B1/fr not_active Expired - Lifetime
- 2002-02-09 WO PCT/EP2002/001376 patent/WO2002066136A2/fr active IP Right Grant
- 2002-02-09 DE DE50203753T patent/DE50203753D1/de not_active Expired - Lifetime
- 2002-02-09 US US10/467,395 patent/US7026363B2/en not_active Expired - Lifetime
-
2003
- 2003-07-30 NO NO20033415A patent/NO329347B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US7026363B2 (en) | 2006-04-11 |
WO2002066136A2 (fr) | 2002-08-29 |
EP1363715A2 (fr) | 2003-11-26 |
NO20033415L (no) | 2003-07-30 |
EP1363715B1 (fr) | 2005-07-27 |
US20040072916A1 (en) | 2004-04-15 |
NO20033415D0 (no) | 2003-07-30 |
DE50203753D1 (de) | 2005-09-01 |
DE10107880B4 (de) | 2007-12-06 |
DE10107880A1 (de) | 2002-09-05 |
WO2002066136A3 (fr) | 2002-11-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM1K | Lapsed by not paying the annual fees |