NO319083B1 - Tverrbindbare polyolefinblandinger, og fremgangsmate for fremstilling og anvendelse derav - Google Patents
Tverrbindbare polyolefinblandinger, og fremgangsmate for fremstilling og anvendelse derav Download PDFInfo
- Publication number
- NO319083B1 NO319083B1 NO19981493A NO981493A NO319083B1 NO 319083 B1 NO319083 B1 NO 319083B1 NO 19981493 A NO19981493 A NO 19981493A NO 981493 A NO981493 A NO 981493A NO 319083 B1 NO319083 B1 NO 319083B1
- Authority
- NO
- Norway
- Prior art keywords
- mixture
- polymer
- molecular weight
- mixture according
- log
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 153
- 229920000098 polyolefin Polymers 0.000 title claims description 73
- 238000000034 method Methods 0.000 title claims description 51
- 230000008569 process Effects 0.000 title description 10
- 238000002360 preparation method Methods 0.000 title description 9
- 229920000573 polyethylene Polymers 0.000 claims description 60
- 238000009826 distribution Methods 0.000 claims description 32
- 238000005227 gel permeation chromatography Methods 0.000 claims description 31
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 26
- 238000001125 extrusion Methods 0.000 claims description 25
- 238000002156 mixing Methods 0.000 claims description 23
- 239000005977 Ethylene Substances 0.000 claims description 20
- 239000000155 melt Substances 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 230000004044 response Effects 0.000 claims description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 239000004711 α-olefin Substances 0.000 claims description 10
- 150000004756 silanes Chemical class 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 238000005315 distribution function Methods 0.000 claims description 6
- 239000011888 foil Substances 0.000 claims description 6
- 238000012417 linear regression Methods 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 5
- 239000012190 activator Substances 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 210000001699 lower leg Anatomy 0.000 claims description 4
- 238000003490 calendering Methods 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000000962 organic group Chemical group 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- 230000036541 health Effects 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000004423 acyloxy group Chemical group 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 72
- -1 polyethylene Polymers 0.000 description 30
- 239000004698 Polyethylene Substances 0.000 description 29
- 229920000092 linear low density polyethylene Polymers 0.000 description 20
- 238000004132 cross linking Methods 0.000 description 17
- 239000003054 catalyst Substances 0.000 description 15
- 239000004707 linear low-density polyethylene Substances 0.000 description 15
- 229910000077 silane Inorganic materials 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 229920002959 polymer blend Polymers 0.000 description 10
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 9
- 239000003999 initiator Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229920001684 low density polyethylene Polymers 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 7
- 239000004702 low-density polyethylene Substances 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 229920001866 very low density polyethylene Polymers 0.000 description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- 239000004708 Very-low-density polyethylene Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000009795 derivation Methods 0.000 description 6
- 238000009998 heat setting Methods 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 239000006057 Non-nutritive feed additive Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000000518 rheometry Methods 0.000 description 5
- 239000013077 target material Substances 0.000 description 5
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 description 3
- 238000010828 elution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 229920013716 polyethylene resin Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229920000034 Plastomer Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000004590 computer program Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 2
- 238000013213 extrapolation Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000010102 injection blow moulding Methods 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000010094 polymer processing Methods 0.000 description 2
- 229920006124 polyolefin elastomer Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000001175 rotational moulding Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000003856 thermoforming Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000251730 Chondrichthyes Species 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000004614 Process Aid Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000001769 aryl amino group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229940038553 attane Drugs 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012967 coordination catalyst Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- JQZRVMZHTADUSY-UHFFFAOYSA-L di(octanoyloxy)tin Chemical compound [Sn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O JQZRVMZHTADUSY-UHFFFAOYSA-L 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 239000011990 phillips catalyst Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Organic Insulating Materials (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/538,689 US5795941A (en) | 1995-10-03 | 1995-10-03 | Crosslinkable bimodal polyolefin compositions |
PCT/US1996/015863 WO1997012934A1 (en) | 1995-10-03 | 1996-10-02 | Crosslinkable polyolefin compositions |
Publications (3)
Publication Number | Publication Date |
---|---|
NO981493D0 NO981493D0 (no) | 1998-04-02 |
NO981493L NO981493L (no) | 1998-04-02 |
NO319083B1 true NO319083B1 (no) | 2005-06-13 |
Family
ID=24148001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19981493A NO319083B1 (no) | 1995-10-03 | 1998-04-02 | Tverrbindbare polyolefinblandinger, og fremgangsmate for fremstilling og anvendelse derav |
Country Status (17)
Country | Link |
---|---|
US (2) | US5795941A (zh) |
EP (1) | EP0853643B1 (zh) |
JP (1) | JP3782459B2 (zh) |
KR (1) | KR100445938B1 (zh) |
CN (1) | CN1117810C (zh) |
AR (1) | AR003770A1 (zh) |
AU (1) | AU704844B2 (zh) |
BR (1) | BR9611582A (zh) |
CA (1) | CA2227279C (zh) |
DE (1) | DE69612560T2 (zh) |
ES (1) | ES2155946T3 (zh) |
MY (1) | MY113524A (zh) |
NO (1) | NO319083B1 (zh) |
RU (1) | RU2173324C2 (zh) |
TW (1) | TW368512B (zh) |
WO (1) | WO1997012934A1 (zh) |
ZA (1) | ZA968278B (zh) |
Families Citing this family (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6399708B2 (en) * | 1993-07-19 | 2002-06-04 | Visteon Systemes Interieurs S.A.S. | Grafted and crosslinkable pulverulent thermoplastic polyolefin composition which has elasticity and flexibility properties |
HUP9900394A3 (en) * | 1996-01-22 | 2000-08-28 | Dow Chemical Co | Polyolefin elastomer blends exhibiting improved properties |
US6395839B2 (en) * | 1996-04-01 | 2002-05-28 | Visteon Systemes Interieurs S.A.S. | Grafted and crosslinkable pulverulent thermoplastic polyolefin composition which has elasticity and flexibility properties |
EP0870803A1 (en) * | 1997-04-07 | 1998-10-14 | Phillips Petroleum Company | A process to produce a crosslinked composition that comprises polymers that comprise ethylene and a crosslinked composition that comprises polymers that comprise ethylene |
US5986002A (en) * | 1997-12-05 | 1999-11-16 | Becton, Dickinson And Company | Medical article of improved sterilizability |
DE69918638T2 (de) * | 1998-10-30 | 2005-07-21 | Mitsui Chemicals, Inc. | Vernetzter Elastomerschaum auf Basis von Polyolefin und Zusammensetzung dafür |
JP3727010B2 (ja) * | 2000-07-14 | 2005-12-14 | 西川ゴム工業株式会社 | 自動車用ウエザーストリップ及びグラスランの製造方法 |
US6548600B2 (en) * | 2000-09-22 | 2003-04-15 | Dupont Dow Elastomers L.L.C. | Thermoplastic elastomer compositions rheology-modified using peroxides and free radical coagents |
US6455602B1 (en) * | 2000-10-24 | 2002-09-24 | Union Carbide Chemicals & Plastics Technology Corporation | High-speed processable cellular insulation material with enhanced foamability |
MY131000A (en) * | 2001-03-16 | 2007-07-31 | Dow Global Technologies Inc | High melt strength polymers and method of making same |
WO2004026949A2 (en) * | 2002-09-23 | 2004-04-01 | Toray Plastics (America), Inc. | Polyolefin isolation membrane |
EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
KR100469470B1 (ko) * | 2003-01-30 | 2005-02-02 | 엘지전자 주식회사 | 열변형을 이용한 댐퍼 및 이를 구비한 세탁기 |
JP2006528826A (ja) * | 2003-07-24 | 2006-12-21 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | 柔軟性、高温変形抵抗を有し、粘着性の度合いが減少したケーブル絶縁系 |
US6870010B1 (en) | 2003-12-01 | 2005-03-22 | Univation Technologies, Llc | Low haze high strength polyethylene compositions |
US7288596B2 (en) | 2003-12-22 | 2007-10-30 | Univation Technologies, Llc | Polyethylene compositions having improved tear properties |
US7193017B2 (en) * | 2004-08-13 | 2007-03-20 | Univation Technologies, Llc | High strength biomodal polyethylene compositions |
EP1634896A1 (en) * | 2004-09-10 | 2006-03-15 | Borealis Technology Oy | Polymer composition |
DE602004017458D1 (de) * | 2004-09-10 | 2008-12-11 | Borealis Tech Oy | Halbleitende Polymerzusammensetzung |
US7749024B2 (en) | 2004-09-28 | 2010-07-06 | Southwire Company | Method of manufacturing THHN electrical cable, and resulting product, with reduced required installation pulling force |
US7557301B2 (en) | 2004-09-28 | 2009-07-07 | Southwire Company | Method of manufacturing electrical cable having reduced required force for installation |
US10763008B2 (en) | 2004-09-28 | 2020-09-01 | Southwire Company, Llc | Method of manufacturing electrical cable, and resulting product, with reduced required installation pulling force |
US7312279B2 (en) * | 2005-02-07 | 2007-12-25 | Univation Technologies, Llc | Polyethylene blend compositions |
JP2006258122A (ja) * | 2005-03-15 | 2006-09-28 | Ntn Corp | 摺動式等速自在継手 |
EP1834987B1 (en) * | 2006-03-15 | 2015-08-12 | Borealis Technology Oy | Method for the production of a polypropylene composition with selective cross-linkable dispersed phase |
US20070264512A1 (en) * | 2006-05-11 | 2007-11-15 | Mehta Sameer D | Extrusion coating process for improved adhesion to metal(lized) substrates |
WO2008077830A2 (en) * | 2006-12-27 | 2008-07-03 | Ciba Holding Inc. | Multifilament, monofilament, non-woven or tape |
US8800967B2 (en) | 2009-03-23 | 2014-08-12 | Southwire Company, Llc | Integrated systems facilitating wire and cable installations |
US8138264B2 (en) * | 2007-05-04 | 2012-03-20 | Fina Technology, Inc. | Bimodal polyethylene resins that have high stiffness and high ESCR |
KR101152413B1 (ko) * | 2008-09-12 | 2012-06-05 | 에스케이이노베이션 주식회사 | 에틸렌 공중합체 및 이의 제조방법 |
US8986586B2 (en) * | 2009-03-18 | 2015-03-24 | Southwire Company, Llc | Electrical cable having crosslinked insulation with internal pulling lubricant |
DE102009002559A1 (de) * | 2009-04-22 | 2010-10-28 | Robert Bosch Gmbh | Sensoranordnung |
EP2256159A1 (en) * | 2009-05-26 | 2010-12-01 | Borealis AG | Polymer composition for crosslinked pipes |
US8658576B1 (en) | 2009-10-21 | 2014-02-25 | Encore Wire Corporation | System, composition and method of application of same for reducing the coefficient of friction and required pulling force during installation of wire or cable |
US10325696B2 (en) | 2010-06-02 | 2019-06-18 | Southwire Company, Llc | Flexible cable with structurally enhanced conductors |
US9126353B2 (en) * | 2010-11-03 | 2015-09-08 | Ineos Olefins & Polymers Usa | Method and apparatus for making polyolefin pellets |
EP2640757A4 (en) * | 2010-11-19 | 2014-07-30 | Exxonmobil Chem Patents Inc | METHODS FOR PRODUCING POLYOLEFINS HAVING MULTIMODAL MOLECULAR WEIGHT DISTRIBUTION |
CN103347936B (zh) * | 2011-02-04 | 2017-04-12 | 陶氏环球技术有限责任公司 | 用于成形花纹表皮应用的可交联聚烯烃组合物 |
US9352371B1 (en) | 2012-02-13 | 2016-05-31 | Encore Wire Corporation | Method of manufacture of electrical wire and cable having a reduced coefficient of friction and required pulling force |
EP2703528A1 (en) * | 2012-08-31 | 2014-03-05 | baumhueter extrusion GmbH | Cross-linked polyethylene fibre, its use and process for its manufacture |
US11328843B1 (en) | 2012-09-10 | 2022-05-10 | Encore Wire Corporation | Method of manufacture of electrical wire and cable having a reduced coefficient of friction and required pulling force |
US10056742B1 (en) | 2013-03-15 | 2018-08-21 | Encore Wire Corporation | System, method and apparatus for spray-on application of a wire pulling lubricant |
BR112015031594B1 (pt) | 2013-06-24 | 2021-12-21 | Dow Global Technologies Llc | Composição de polipropileno reforçada |
US10431350B1 (en) | 2015-02-12 | 2019-10-01 | Southwire Company, Llc | Non-circular electrical cable having a reduced pulling force |
JP6850862B2 (ja) | 2016-07-14 | 2021-03-31 | エクソンモービル・ケミカル・パテンツ・インク | 粘度調整剤として有用な、2元メタロセン触媒で重合されたバイモーダルのコポリマー組成物 |
EP3538571B1 (en) | 2016-11-08 | 2022-06-01 | Univation Technologies, LLC | Bimodal polyethylene |
US11299616B2 (en) * | 2017-06-29 | 2022-04-12 | Dow Global Technologies Llc | Moisture-cured wire and cable constructions |
US11302459B2 (en) | 2017-10-06 | 2022-04-12 | Exxonmobil Chemical Patents Inc. | Polyethylene extrudates and methods of making the same |
CN107624515A (zh) * | 2017-10-24 | 2018-01-26 | 建瓯市元润塑料有限公司 | 黑木耳户外栽培菌袋及其制备与使用方法 |
US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
WO2019209546A1 (en) | 2018-04-27 | 2019-10-31 | Dow Global Technologies Llc | Non-foam polyolefin compositions for wire and cable coating |
WO2020109870A2 (en) | 2018-06-28 | 2020-06-04 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions, wires and cables, and methods for making the same |
CN113412302A (zh) | 2018-12-17 | 2021-09-17 | 阿科玛法国公司 | 作为用于将热塑性聚合物交联的活性助剂的多(甲基)丙烯酸酯官能化树脂 |
CN109771722A (zh) * | 2019-01-22 | 2019-05-21 | 西安乐析医疗科技有限公司 | 一种新型腹膜透析管 |
CN114502602B (zh) | 2019-09-30 | 2024-02-06 | 埃克森美孚化学专利公司 | 用于改进的线材涂覆产品的高压聚乙烯管式反应器方法 |
EP3831590A1 (en) | 2019-12-05 | 2021-06-09 | Lapmaster Wolters GmbH | Press ram for a fine blanking press |
CN114163763B (zh) * | 2021-12-27 | 2023-12-22 | 复旦大学 | 一种可热塑性加工的聚乙烯复配物 |
Family Cites Families (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3280220A (en) * | 1963-04-29 | 1966-10-18 | Phillips Petroleum Co | Blend of high density polyethylene-1-butene copolymer |
CA849081A (en) * | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
BE794718Q (fr) * | 1968-12-20 | 1973-05-16 | Dow Corning Ltd | Procede de reticulation d'olefines |
US3914342A (en) * | 1971-07-13 | 1975-10-21 | Dow Chemical Co | Ethylene polymer blend and polymerization process for preparation thereof |
GB2007685B (en) * | 1977-10-11 | 1982-05-12 | Asahi Dow Ltd | Composition for drawn film cold drawn film made of said composition and process for manufacture of said film |
US4302565A (en) * | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization |
US4335034A (en) * | 1978-12-18 | 1982-06-15 | J. P. Stevens & Co., Inc. | Thermoplastic compositions and automotive carpeting backed therewith |
JPS5734145A (en) * | 1980-08-07 | 1982-02-24 | Mitsui Petrochem Ind Ltd | Ethylene-alpha-olefin copolymer composition |
US4403007A (en) * | 1980-08-11 | 1983-09-06 | E. I. Du Pont De Nemours & Co. | Filled thermoplastic compositions based on ethylene interpolymers and polyester, polyether and polyether ester plasticizers |
US4339507A (en) * | 1980-11-26 | 1982-07-13 | Union Carbide Corporation | Linear low density ethylene hydrocarbon copolymer containing composition for extrusion coating |
US4438238A (en) * | 1981-01-30 | 1984-03-20 | Sumitomo Chemical Company, Limited | Low density copolymer composition of two ethylene-α-olefin copolymers |
US4461873A (en) * | 1982-06-22 | 1984-07-24 | Phillips Petroleum Company | Ethylene polymer blends |
US4525257A (en) * | 1982-12-27 | 1985-06-25 | Union Carbide Corporation | Low level irradiated linear low density ethylene/alpha-olefin copolymers and film extruded therefrom |
US4500648A (en) * | 1983-04-25 | 1985-02-19 | Exxon Research & Engineering Co. | Long chain branching in polyolefins from ziegler-natta catalysts |
US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
US4540753A (en) * | 1983-06-15 | 1985-09-10 | Exxon Research & Engineering Co. | Narrow MWD alpha-olefin copolymers |
US4786697A (en) * | 1983-06-15 | 1988-11-22 | Exxon Research & Engineering Co. | Molecular weight distribution modification in a tubular reactor |
IL75719A (en) * | 1984-07-18 | 1988-11-30 | Du Pont Canada | Polyolefin blends containing reactive agents |
US4614764A (en) * | 1985-03-06 | 1986-09-30 | Mobil Oil Corporation | Linear low density ethylene polymers blended with modified linear low density ethylene polymers |
US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4798081A (en) * | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
FR2592051B1 (fr) * | 1985-12-24 | 1988-10-14 | Charbonnages Ste Chimique | Compositions de polymeres de l'ethylene, un procede pour leur preparation et leur application a l'obtention d'articles industriels |
US4939217A (en) * | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
US5382631A (en) * | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions |
US5371143A (en) * | 1989-11-16 | 1994-12-06 | Minnesota Mining And Manufacturing Company | Polymer blend composition of fluorinated elastomers, thermoplastic polymers and thermoplastics elastomers |
GB8927174D0 (en) * | 1989-12-01 | 1990-01-31 | Exxon Chemical Patents Inc | Cross-linkable polymer blends |
US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
JP3045548B2 (ja) * | 1990-12-28 | 2000-05-29 | 日本石油化学株式会社 | ポリエチレン組成物 |
US5089321A (en) * | 1991-01-10 | 1992-02-18 | The Dow Chemical Company | Multilayer polyolefinic film structures having improved heat seal characteristics |
US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
EP0619827B1 (en) * | 1991-12-30 | 1996-06-12 | The Dow Chemical Company | Ethylene interpolymer polymerizations |
US5210142A (en) * | 1992-02-13 | 1993-05-11 | The Dow Chemical Company | Reduction of melt fracture in linear polyethylene |
GB9215821D0 (en) * | 1992-07-24 | 1992-09-09 | Exxon Chemical Patents Inc | Thermoplastic compositions and processes for cross-linking |
US5414040A (en) * | 1992-09-15 | 1995-05-09 | The Dow Chemical Company | Formulated ethylene/α-olefin elastomeric compounds |
CA2103380C (en) * | 1992-11-19 | 2002-07-02 | Mitsui Chemicals, Inc. | Ethylene/.alpha.-olefin copolymer composition, graft modified ethylene/.alpha.-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process |
KR100301978B1 (ko) * | 1993-01-29 | 2001-11-14 | 리챠드 지. 워터맨 | 에틸렌공중합법 |
US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
US5408004A (en) * | 1993-08-17 | 1995-04-18 | The Dow Chemical Company | Polyolefin blends and their solid state processing |
US5387630A (en) * | 1993-08-31 | 1995-02-07 | Eastman Chemical Company | Polyolefin-extrusion coating compositions having good coatability, good adhesion to the substrate, and good chill roll release |
JP3398451B2 (ja) * | 1994-01-14 | 2003-04-21 | 積水化学工業株式会社 | 架橋ポリオレフィン系樹脂発泡体 |
AU688500B2 (en) * | 1994-04-20 | 1998-03-12 | Dow Chemical Company, The | Silane-crosslinkable, substantially linear ethylene polymers and their uses |
US5773106A (en) * | 1994-10-21 | 1998-06-30 | The Dow Chemical Company | Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus |
US5589539A (en) * | 1994-11-23 | 1996-12-31 | Union Carbide Chemicals & Plastics Technology Corporation | Process for preparing an in situ polyethylene blend |
US5492760A (en) * | 1994-12-05 | 1996-02-20 | At Plastics Inc. | Water tree resistant, moisture curable insulation composition for power cables |
US5578682A (en) * | 1995-05-25 | 1996-11-26 | Exxon Chemical Patents Inc. | Bimodalization of polymer molecular weight distribution |
ID17196A (id) * | 1996-03-14 | 1997-12-11 | Dow Chemical Co | Bahan-bahan perekat yang mengandung polimer-polimer olefin |
-
1995
- 1995-10-03 US US08/538,689 patent/US5795941A/en not_active Expired - Lifetime
-
1996
- 1996-08-26 US US08/703,263 patent/US5852116A/en not_active Expired - Lifetime
- 1996-10-02 RU RU98108397/04A patent/RU2173324C2/ru not_active IP Right Cessation
- 1996-10-02 ZA ZA9608278A patent/ZA968278B/xx unknown
- 1996-10-02 AR ARP960104575A patent/AR003770A1/es unknown
- 1996-10-02 ES ES96937652T patent/ES2155946T3/es not_active Expired - Lifetime
- 1996-10-02 AU AU75141/96A patent/AU704844B2/en not_active Ceased
- 1996-10-02 WO PCT/US1996/015863 patent/WO1997012934A1/en active IP Right Grant
- 1996-10-02 CA CA002227279A patent/CA2227279C/en not_active Expired - Lifetime
- 1996-10-02 CN CN96197436A patent/CN1117810C/zh not_active Expired - Lifetime
- 1996-10-02 KR KR10-1998-0702042A patent/KR100445938B1/ko not_active IP Right Cessation
- 1996-10-02 JP JP51441997A patent/JP3782459B2/ja not_active Expired - Lifetime
- 1996-10-02 EP EP96937652A patent/EP0853643B1/en not_active Expired - Lifetime
- 1996-10-02 DE DE69612560T patent/DE69612560T2/de not_active Expired - Lifetime
- 1996-10-02 MY MYPI96004071A patent/MY113524A/en unknown
- 1996-10-02 BR BR9611582A patent/BR9611582A/pt not_active IP Right Cessation
- 1996-12-09 TW TW085115216A patent/TW368512B/zh active
-
1998
- 1998-04-02 NO NO19981493A patent/NO319083B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2227279C (en) | 2006-09-05 |
NO981493D0 (no) | 1998-04-02 |
RU2173324C2 (ru) | 2001-09-10 |
DE69612560T2 (de) | 2001-09-13 |
AR003770A1 (es) | 1998-09-09 |
EP0853643B1 (en) | 2001-04-18 |
ES2155946T3 (es) | 2001-06-01 |
EP0853643A1 (en) | 1998-07-22 |
BR9611582A (pt) | 1999-03-30 |
JPH11513427A (ja) | 1999-11-16 |
US5852116A (en) | 1998-12-22 |
ZA968278B (en) | 1998-04-02 |
KR100445938B1 (ko) | 2004-10-14 |
TW368512B (en) | 1999-09-01 |
CN1117810C (zh) | 2003-08-13 |
DE69612560D1 (de) | 2001-05-23 |
US5795941A (en) | 1998-08-18 |
CN1198762A (zh) | 1998-11-11 |
NO981493L (no) | 1998-04-02 |
AU7514196A (en) | 1997-04-28 |
JP3782459B2 (ja) | 2006-06-07 |
KR19990063599A (ko) | 1999-07-26 |
MY113524A (en) | 2002-03-30 |
AU704844B2 (en) | 1999-05-06 |
WO1997012934A1 (en) | 1997-04-10 |
CA2227279A1 (en) | 1997-04-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
NO319083B1 (no) | Tverrbindbare polyolefinblandinger, og fremgangsmate for fremstilling og anvendelse derav | |
KR100562616B1 (ko) | 엘라스토머의 유동성을 개질시키는 방법 | |
EP1527112B1 (en) | Silane crosslinkable polyethylene | |
US5827916A (en) | Formulated ethylene α-olefin elastomeric compounds | |
US6005053A (en) | Polyolefin elastomer blends exhibiting improved properties | |
EP2448757B1 (en) | Ethylenic polymer and its use | |
NO319607B1 (no) | Reologi-modifisert polyetylen | |
CN1174438C (zh) | 电源电缆的绝缘组合物 | |
WO2017074707A1 (en) | Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation | |
US8183328B2 (en) | Compositions comprising grafted and crosslinked LLDPE's, Methods for making same, and articles made therefrom | |
US8211985B2 (en) | Silicon-containing ethylene-based polymer blends, methods for making same, and articles made therefrom | |
MXPA98002561A (en) | Compositions poliolefi |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM1K | Lapsed by not paying the annual fees |