NO315124B1 - Fremgangsmåte for oppgradering av bensin - Google Patents
Fremgangsmåte for oppgradering av bensin Download PDFInfo
- Publication number
- NO315124B1 NO315124B1 NO19971067A NO971067A NO315124B1 NO 315124 B1 NO315124 B1 NO 315124B1 NO 19971067 A NO19971067 A NO 19971067A NO 971067 A NO971067 A NO 971067A NO 315124 B1 NO315124 B1 NO 315124B1
- Authority
- NO
- Norway
- Prior art keywords
- catalyst
- zsm
- gasoline
- zeolite
- weight
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 38
- 239000003054 catalyst Substances 0.000 claims description 94
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 38
- 238000009835 boiling Methods 0.000 claims description 35
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 34
- 229910052717 sulfur Inorganic materials 0.000 claims description 34
- 239000011593 sulfur Substances 0.000 claims description 34
- 239000010457 zeolite Substances 0.000 claims description 33
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 28
- 229910021536 Zeolite Inorganic materials 0.000 claims description 26
- 239000007858 starting material Substances 0.000 claims description 26
- 239000000047 product Substances 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 21
- 229910052750 molybdenum Inorganic materials 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 15
- 239000011733 molybdenum Substances 0.000 claims description 15
- 239000011148 porous material Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000013067 intermediate product Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 238000005336 cracking Methods 0.000 description 9
- 238000006477 desulfuration reaction Methods 0.000 description 9
- 230000023556 desulfurization Effects 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- 229910003294 NiMo Inorganic materials 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000006872 improvement Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 239000000571 coke Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000004231 fluid catalytic cracking Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000006069 physical mixture Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000004763 sulfides Chemical group 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- -1 ZSM-5 Chemical compound 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical class 0.000 description 1
- 238000005899 aromatization reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/08—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of reforming naphtha
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Stereophonic System (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/303,908 US5500108A (en) | 1991-08-15 | 1994-09-09 | Gasoline upgrading process |
| PCT/US1995/010364 WO1996007714A1 (en) | 1994-09-09 | 1995-08-15 | Gasoline upgrading process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO971067D0 NO971067D0 (no) | 1997-03-07 |
| NO971067L NO971067L (no) | 1997-03-07 |
| NO315124B1 true NO315124B1 (no) | 2003-07-14 |
Family
ID=23174225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19971067A NO315124B1 (no) | 1994-09-09 | 1997-03-07 | Fremgangsmåte for oppgradering av bensin |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5500108A (ko) |
| EP (1) | EP0781315B1 (ko) |
| JP (1) | JP3573752B2 (ko) |
| KR (1) | KR970705622A (ko) |
| CA (1) | CA2198214C (ko) |
| DE (1) | DE69523612T2 (ko) |
| FI (1) | FI970973A (ko) |
| MX (1) | MX9701508A (ko) |
| NO (1) | NO315124B1 (ko) |
| WO (1) | WO1996007714A1 (ko) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5685972A (en) * | 1995-07-14 | 1997-11-11 | Timken; Hye Kyung C. | Production of benzene, toluene, and xylene (BTX) from FCC naphtha |
| US5876855A (en) * | 1995-12-22 | 1999-03-02 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive suitable for skin and method of preparing |
| US6051520A (en) * | 1998-05-19 | 2000-04-18 | Phillips Petroleum Company | Hydrotreating catalyst composition and processes therefor and therewith |
| EA001985B1 (ru) | 1998-07-09 | 2001-10-22 | Ги Негре | Способ управления камерой расширения двигателя, уменьшающего загрязнение окружающей среды, и камера расширения для его реализации |
| US6042719A (en) * | 1998-11-16 | 2000-03-28 | Mobil Oil Corporation | Deep desulfurization of FCC gasoline at low temperatures to maximize octane-barrel value |
| JP2002530468A (ja) * | 1998-11-16 | 2002-09-17 | モービル・オイル・コーポレイション | 低圧下にて二官能性触媒を用いるオレフィン性ガソリンの脱硫 |
| US6034020A (en) * | 1998-12-29 | 2000-03-07 | Phillips Petroleum Company | Zeolite-based catalyst material, the preparation thereof and the use thereof |
| US6090274A (en) * | 1998-12-29 | 2000-07-18 | Phillips Petroleum Company | Hydrotreating catalyst composition and processes therefor and therewith |
| IT1311512B1 (it) | 1999-03-12 | 2002-03-13 | Agip Petroli | Composizione catalitica per l'upgrading di miscele idrocarburiche. |
| US6641714B2 (en) | 2000-07-21 | 2003-11-04 | Exxonmobil Research And Engineering Company | Hydrocarbon upgrading process |
| CA2376700A1 (en) * | 2002-03-13 | 2003-09-13 | Irving Oil Limited | Unleaded gasoline compositions |
| US7288181B2 (en) * | 2003-08-01 | 2007-10-30 | Exxonmobil Research And Engineering Company | Producing low sulfur naphtha products through improved olefin isomerization |
| US20050023191A1 (en) * | 2003-08-01 | 2005-02-03 | Shih Stuart S. | Process to manufacture low sulfur fuels |
| US7357856B2 (en) * | 2003-10-06 | 2008-04-15 | Exxonmobil Research And Engineering Company | Nitrogen removal from olefinic naphtha feedstreams to improve hydrodesulfurization versus olefin saturation selectivity |
| RU2446882C1 (ru) * | 2010-10-21 | 2012-04-10 | Российская Федерация, От Имени Которой Выступает Министерство Образования И Науки Российской Федерации | Цеолитсодержащий катализатор, способ его получения и способ конверсии прямогонной бензиновой фракции в высокооктановый компонент бензина с низким содержанием бензола |
| US10144883B2 (en) | 2013-11-14 | 2018-12-04 | Uop Llc | Apparatuses and methods for desulfurization of naphtha |
| GB2551118A (en) * | 2016-05-31 | 2017-12-13 | Univ Oxford Innovation Ltd | Process |
| WO2020219310A1 (en) * | 2019-04-26 | 2020-10-29 | Exxonmobil Research And Engineering Company | System for converting hydrocarbons in the presence of nitrogen |
| RU2753602C1 (ru) * | 2021-05-17 | 2021-08-18 | Роман Николаевич Демин | Способ каталитической переработки легких углеводородных фракций и установка для его осуществления |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3759821A (en) * | 1971-03-29 | 1973-09-18 | Mobil Oil Corp | Catalytic process for upgrading cracked gasolines |
| US3957625A (en) * | 1975-02-07 | 1976-05-18 | Mobil Oil Corporation | Method for reducing the sulfur level of gasoline product |
| US4211640A (en) * | 1979-05-24 | 1980-07-08 | Mobil Oil Corporation | Process for the treatment of olefinic gasoline |
| ZA861382B (en) * | 1986-02-24 | 1987-10-28 | Mobil Oil Corp | Process for improving the octane number of cracked gasolines |
| US4827076A (en) * | 1987-07-16 | 1989-05-02 | Union Oil Company Of California | Desulfurization and isomerization of N-paraffins |
| US4950387A (en) * | 1988-10-21 | 1990-08-21 | Mobil Oil Corp. | Upgrading of cracking gasoline |
| US4997543A (en) * | 1988-12-21 | 1991-03-05 | Mobil Oil Corporation | Reduction of benzene in gasoline |
| EP0641375B1 (en) * | 1991-08-15 | 1997-12-29 | Mobil Oil Corporation | Hydrocarbon upgrading process |
-
1994
- 1994-09-09 US US08/303,908 patent/US5500108A/en not_active Expired - Fee Related
-
1995
- 1995-08-15 CA CA002198214A patent/CA2198214C/en not_active Expired - Fee Related
- 1995-08-15 DE DE69523612T patent/DE69523612T2/de not_active Expired - Fee Related
- 1995-08-15 KR KR1019970701476A patent/KR970705622A/ko active IP Right Grant
- 1995-08-15 MX MX9701508A patent/MX9701508A/es unknown
- 1995-08-15 JP JP50950896A patent/JP3573752B2/ja not_active Expired - Fee Related
- 1995-08-15 EP EP95929542A patent/EP0781315B1/en not_active Expired - Lifetime
- 1995-08-15 WO PCT/US1995/010364 patent/WO1996007714A1/en active IP Right Grant
-
1997
- 1997-03-07 FI FI970973A patent/FI970973A/fi not_active IP Right Cessation
- 1997-03-07 NO NO19971067A patent/NO315124B1/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0781315A1 (en) | 1997-07-02 |
| NO971067D0 (no) | 1997-03-07 |
| NO971067L (no) | 1997-03-07 |
| DE69523612D1 (de) | 2001-12-06 |
| KR970705622A (ko) | 1997-10-09 |
| CA2198214A1 (en) | 1996-03-14 |
| JPH10505127A (ja) | 1998-05-19 |
| WO1996007714A1 (en) | 1996-03-14 |
| CA2198214C (en) | 2003-09-23 |
| US5500108A (en) | 1996-03-19 |
| MX9701508A (es) | 1997-05-31 |
| EP0781315A4 (en) | 1998-05-20 |
| FI970973A (fi) | 1997-05-06 |
| FI970973A0 (fi) | 1997-03-07 |
| EP0781315B1 (en) | 2001-10-31 |
| JP3573752B2 (ja) | 2004-10-06 |
| DE69523612T2 (de) | 2002-07-18 |
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