NO310876B1 - Fremgangsmåte for innföring av en fast katalysator i en gassfase-olefinpolymerisasjonsreaktor - Google Patents
Fremgangsmåte for innföring av en fast katalysator i en gassfase-olefinpolymerisasjonsreaktor Download PDFInfo
- Publication number
- NO310876B1 NO310876B1 NO19965076A NO965076A NO310876B1 NO 310876 B1 NO310876 B1 NO 310876B1 NO 19965076 A NO19965076 A NO 19965076A NO 965076 A NO965076 A NO 965076A NO 310876 B1 NO310876 B1 NO 310876B1
- Authority
- NO
- Norway
- Prior art keywords
- catalyst
- liquid hydrocarbon
- liquid
- chamber
- reactor
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 56
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 45
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 39
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 239000011949 solid catalyst Substances 0.000 title claims abstract description 28
- 230000008569 process Effects 0.000 title claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 167
- 239000007788 liquid Substances 0.000 claims abstract description 156
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 86
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 86
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 85
- 239000000725 suspension Substances 0.000 claims abstract description 42
- 239000000843 powder Substances 0.000 claims abstract description 39
- 238000002156 mixing Methods 0.000 claims abstract description 38
- 239000011541 reaction mixture Substances 0.000 claims description 24
- 239000012298 atmosphere Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 238000003860 storage Methods 0.000 claims description 14
- 150000001993 dienes Chemical class 0.000 claims description 11
- 230000000737 periodic effect Effects 0.000 claims description 8
- 229910052723 transition metal Inorganic materials 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- 238000012685 gas phase polymerization Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 description 19
- 239000012071 phase Substances 0.000 description 15
- 238000009434 installation Methods 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 6
- 238000005243 fluidization Methods 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 6
- 238000004891 communication Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- -1 alkyl aluminum compound Chemical class 0.000 description 4
- 150000001924 cycloalkanes Chemical class 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- JBVMSEMQJGGOFR-FNORWQNLSA-N (4e)-4-methylhexa-1,4-diene Chemical compound C\C=C(/C)CC=C JBVMSEMQJGGOFR-FNORWQNLSA-N 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 2
- SLQMKNPIYMOEGB-UHFFFAOYSA-N 2-methylhexa-1,5-diene Chemical compound CC(=C)CCC=C SLQMKNPIYMOEGB-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical class B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
- B01J8/0035—Periodical feeding or evacuation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00743—Feeding or discharging of solids
- B01J2208/00752—Feeding
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/523—Miscellaneous specific techniques of general applicability
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9514720A FR2741549B1 (fr) | 1995-11-29 | 1995-11-29 | Procede d'introduction d'un catalyseur dans un reacteur de polymerisation d'olefine en phase gazeuse |
Publications (3)
Publication Number | Publication Date |
---|---|
NO965076D0 NO965076D0 (no) | 1996-11-28 |
NO965076L NO965076L (no) | 1997-05-30 |
NO310876B1 true NO310876B1 (no) | 2001-09-10 |
Family
ID=9485418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19965076A NO310876B1 (no) | 1995-11-29 | 1996-11-28 | Fremgangsmåte for innföring av en fast katalysator i en gassfase-olefinpolymerisasjonsreaktor |
Country Status (7)
Country | Link |
---|---|
US (1) | US5922818A (fr) |
EP (1) | EP0776691B1 (fr) |
AT (1) | ATE205418T1 (fr) |
DE (1) | DE69615125T2 (fr) |
FR (1) | FR2741549B1 (fr) |
MY (1) | MY113820A (fr) |
NO (1) | NO310876B1 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0763546B1 (fr) * | 1995-09-13 | 1997-05-28 | Witco GmbH | Procédé de préparation de systèmes catalytiques à base de métallocène sur supports utilisant des réacteurs à phase gazeuse inertes |
EP0882497A1 (fr) * | 1997-06-06 | 1998-12-09 | Engelhard Corporation | Procédé pour réaliser une réaction catalytique avec un catalyseur à base de nickel en l'absence d'oxygène |
US6245868B1 (en) * | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
US7141630B2 (en) | 2002-10-09 | 2006-11-28 | Exxonmobil Chemical Patents Inc. | Methods of feed purification for olefin polymerization |
US7235614B2 (en) | 2002-10-09 | 2007-06-26 | Exxonmobil Chemical Patents Inc. | Methods for injecting catalyst into a polymerization reactor |
EP1556422B1 (fr) | 2002-10-09 | 2006-03-29 | Exxonmobil Chemical Patents Inc. | Procedes de fourniture de systemes catalyseurs destines a une polymerisation de propylene |
AU2004232695A1 (en) * | 2003-03-28 | 2004-11-04 | Union Carbide Chemicals & Plastics Technology Corporation | Chromium-based catalysts in mineral oil for production of polyethylene |
US6982304B2 (en) * | 2003-12-22 | 2006-01-03 | Union Carbide Chemicals & Plastics Technology Corporation | Blow molding resins with improved ESCR |
BRPI0821808A2 (pt) * | 2007-12-27 | 2015-06-16 | Univation Tech Llc | Sistemas e métodos para remover particulados carregados de fluxos de gás, e sistemas reatores que implementam os mesmos |
EP2370201B1 (fr) * | 2008-12-29 | 2017-10-04 | Basell Poliolefine Italia S.r.l. | Procédé d'introduction de catalyseur dans un réacteur de polymérisation |
CA2749835C (fr) | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Approvisionnement de catalyseurs de phosphinimine tres actifs dans un reacteur en phase gazeuse |
US11512150B2 (en) * | 2020-11-17 | 2022-11-29 | Ineos Usa Llc | Polymerization process |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1084370B (it) * | 1977-07-08 | 1985-05-25 | Montedison Spa | Procedimento e dispositivo per dosare e alimentare in un reattore chiuso, piccole quantita' di catalizzatore o di reagente allo stato solido, in polvere. |
US4200715A (en) * | 1977-09-21 | 1980-04-29 | Gulf Oil Corporation | Vapor phase processes for the polymerization of olefins |
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
US4610574A (en) * | 1984-05-30 | 1986-09-09 | Amoco Corporation | Catalyst feeding system |
CA1268754A (fr) | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Catalyseur de polymerisation sur support |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US5098667A (en) * | 1989-05-05 | 1992-03-24 | Phillips Petroleum Company | Particulate flow control |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
FR2670399B1 (fr) * | 1990-12-14 | 1994-08-05 | Bp Chemicals Snc | Procede et dispositif d'introduction d'une suspension dans un reacteur. |
FR2706467B1 (fr) | 1992-10-26 | 1995-09-15 | Bp Chemicals Snc | Procédé de préparation d'un catalyseur de type Ziegler-Natta et utilisation. |
FR2705252B1 (fr) * | 1993-05-19 | 1995-07-21 | Bp Chemicals Snc | Procédé d'introduction d'un solide dans un réacteur et appareillage. |
ZA943399B (en) * | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
-
1995
- 1995-11-29 FR FR9514720A patent/FR2741549B1/fr not_active Expired - Fee Related
-
1996
- 1996-11-22 EP EP96308479A patent/EP0776691B1/fr not_active Expired - Lifetime
- 1996-11-22 AT AT96308479T patent/ATE205418T1/de not_active IP Right Cessation
- 1996-11-22 DE DE69615125T patent/DE69615125T2/de not_active Expired - Lifetime
- 1996-11-26 US US08/755,825 patent/US5922818A/en not_active Expired - Lifetime
- 1996-11-28 NO NO19965076A patent/NO310876B1/no unknown
- 1996-11-28 MY MYPI96004994A patent/MY113820A/en unknown
Also Published As
Publication number | Publication date |
---|---|
FR2741549A1 (fr) | 1997-05-30 |
EP0776691B1 (fr) | 2001-09-12 |
DE69615125D1 (de) | 2001-10-18 |
US5922818A (en) | 1999-07-13 |
NO965076L (no) | 1997-05-30 |
DE69615125T2 (de) | 2002-06-20 |
FR2741549B1 (fr) | 1998-01-02 |
EP0776691A1 (fr) | 1997-06-04 |
ATE205418T1 (de) | 2001-09-15 |
MY113820A (en) | 2002-05-31 |
NO965076D0 (no) | 1996-11-28 |
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