NO305820B1 - Anordning ved brenselcelle - Google Patents
Anordning ved brenselcelle Download PDFInfo
- Publication number
- NO305820B1 NO305820B1 NO923650A NO923650A NO305820B1 NO 305820 B1 NO305820 B1 NO 305820B1 NO 923650 A NO923650 A NO 923650A NO 923650 A NO923650 A NO 923650A NO 305820 B1 NO305820 B1 NO 305820B1
- Authority
- NO
- Norway
- Prior art keywords
- fuel
- plate
- oxygen
- fuel cell
- gas
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 121
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 44
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000001301 oxygen Substances 0.000 claims abstract description 43
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010410 layer Substances 0.000 claims abstract description 9
- 239000002344 surface layer Substances 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 3
- 239000007789 gas Substances 0.000 claims description 16
- 239000000919 ceramic Substances 0.000 claims description 14
- 125000006850 spacer group Chemical group 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- 239000007784 solid electrolyte Substances 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000011229 interlayer Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010763 heavy fuel oil Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(iii) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims 2
- 229910000640 Fe alloy Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 230000002093 peripheral effect Effects 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 239000011195 cermet Substances 0.000 abstract 1
- 210000004027 cell Anatomy 0.000 description 50
- 238000005192 partition Methods 0.000 description 22
- 239000003570 air Substances 0.000 description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910001098 inconels 690 Inorganic materials 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910002060 Fe-Cr-Al alloy Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0206—Metals or alloys
- H01M8/0208—Alloys
- H01M8/021—Alloys based on iron
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0236—Glass; Ceramics; Cermets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0241—Composites
- H01M8/0245—Composites in the form of layered or coated products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2432—Grouping of unit cells of planar configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
- H01M2300/0074—Ion conductive at high temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/249—Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Composite Materials (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Fuel-Injection Apparatus (AREA)
- Hybrid Cells (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH654/91A CH682270A5 (fr) | 1991-03-05 | 1991-03-05 | |
| PCT/EP1992/000384 WO1992016029A1 (fr) | 1991-03-05 | 1992-02-24 | Dispositif pour la transformation d'energie chimique d'un combustible en energie electrique au moyen d'un ensemble de cellules combustibles a haute temperature |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO923650D0 NO923650D0 (no) | 1992-09-21 |
| NO923650L NO923650L (no) | 1992-09-21 |
| NO305820B1 true NO305820B1 (no) | 1999-07-26 |
Family
ID=4192045
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO923650A NO305820B1 (no) | 1991-03-05 | 1992-09-21 | Anordning ved brenselcelle |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5338621A (fr) |
| EP (1) | EP0527990B1 (fr) |
| JP (1) | JPH05507384A (fr) |
| AT (1) | ATE127962T1 (fr) |
| AU (1) | AU643371B2 (fr) |
| CA (1) | CA2081779C (fr) |
| CH (1) | CH682270A5 (fr) |
| DE (1) | DE59203656D1 (fr) |
| DK (1) | DK0527990T3 (fr) |
| ES (1) | ES2077402T3 (fr) |
| NO (1) | NO305820B1 (fr) |
| WO (1) | WO1992016029A1 (fr) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4237602A1 (de) * | 1992-11-06 | 1994-05-11 | Siemens Ag | Hochtemperatur-Brennstoffzellen-Stapel und Verfahren zu seiner Herstellung |
| DE4431510C1 (de) * | 1994-09-03 | 1996-01-18 | Forschungszentrum Juelich Gmbh | Festelektrolyt-Hochtemperatur-Brennstoffzellenanordnung |
| US5952116A (en) * | 1995-02-16 | 1999-09-14 | Siemens Aktiengesellschaft | Solid electrolyte high temperature fuel cell module and method for its operation |
| DE19505274C2 (de) * | 1995-02-16 | 1997-02-13 | Siemens Ag | Verfahren zum Betrieb eines Festelektrolyt-Hochtemperatur-Brennstoffzellenmoduls und dazu geeignetes Festelektrolyt-Hochtemperatur-Brennstoffzellenmodul |
| US5858314A (en) | 1996-04-12 | 1999-01-12 | Ztek Corporation | Thermally enhanced compact reformer |
| ATE303001T1 (de) * | 1996-10-30 | 2005-09-15 | Sulzer Hexis Ag | Batterie mit planaren hochtemperatur- brennstoffzellen |
| DE19646579C2 (de) * | 1996-11-12 | 2002-01-24 | Forschungszentrum Juelich Gmbh | Brennstoffzellenstapel mit integriertem Reformer |
| WO1998035398A1 (fr) | 1997-02-11 | 1998-08-13 | Bossel Ulf G | Pile de cellules a combustible a electrolytes solides et son agencement |
| DE19705874C2 (de) | 1997-02-15 | 2000-01-20 | Forschungszentrum Juelich Gmbh | Stromkollektor für SOFC-Brennstoffzellenstapel |
| US6296963B1 (en) * | 1997-11-14 | 2001-10-02 | Mitsubishi Heavy Industries, Ltd. | Solid oxide electrolyte fuel cell |
| US6040076A (en) * | 1998-03-03 | 2000-03-21 | M-C Power Corporation | One piece fuel cell separator plate |
| DE19835759A1 (de) * | 1998-08-07 | 2000-02-17 | Opel Adam Ag | Brennstoffzelle |
| US6432567B1 (en) * | 1999-03-17 | 2002-08-13 | Sulzer Hexis Ag | Fuel cell battery with afterburning at the periphery of a cell stack |
| US6613470B1 (en) * | 1999-09-01 | 2003-09-02 | Honda Giken Kogyo Kabushiki Kaisha | Solid polymer electrolyte fuel cell stack |
| WO2002019451A2 (fr) * | 2000-08-18 | 2002-03-07 | Franklin Jerrold E | Plaques de collecteurs bsp/mea intégrés modulaires et contacts flexibles pour piles à combustible |
| US20020022170A1 (en) * | 2000-08-18 | 2002-02-21 | Franklin Jerrold E. | Integrated and modular BSP/MEA/manifold plates for fuel cells |
| WO2002054519A1 (fr) * | 2000-12-28 | 2002-07-11 | Mitsubishi Materials Corporation | Module de pile a combustible et structure pour l'alimentation en gaz de cette pile a combustible |
| US20040023090A1 (en) * | 2002-03-30 | 2004-02-05 | Pearson Kenneth E. | Fuel cell system |
| US7294424B2 (en) * | 2002-06-24 | 2007-11-13 | Delphi Technologies, Inc. | Solid-oxide fuel cell assembly having simplified arrangement of current collectors |
| US7670707B2 (en) * | 2003-07-30 | 2010-03-02 | Altergy Systems, Inc. | Electrical contacts for fuel cells |
| DE102005022894A1 (de) * | 2005-05-18 | 2006-11-23 | Staxera Gmbh | SOFC-Stapel |
| WO2006137585A2 (fr) * | 2005-06-24 | 2006-12-28 | Honda Motor Co., Ltd. | Pile a combustible |
| DE102020207603A1 (de) * | 2020-06-19 | 2021-12-23 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur Herstellung einer Bipolarplatte und Brennstoffzelle |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH444243A (de) * | 1965-04-08 | 1967-09-30 | Bbc Brown Boveri & Cie | Brennstoffbatterie |
| US3400054A (en) * | 1966-03-15 | 1968-09-03 | Westinghouse Electric Corp | Electrochemical method for separating o2 from a gas; generating electricity; measuring o2 partial pressure; and fuel cell |
| EP0068522B1 (fr) * | 1981-05-11 | 1984-10-24 | BBC Aktiengesellschaft Brown, Boveri & Cie. | Procédé et installation pour la préparation synthétique d'ozone par electrolyse et son application |
| JPS6124170A (ja) * | 1984-07-13 | 1986-02-01 | Mitsubishi Electric Corp | 溶融炭酸塩形燃料電池 |
| JPH01267963A (ja) * | 1988-04-20 | 1989-10-25 | Mitsui Eng & Shipbuild Co Ltd | 固体電解質型燃料電池 |
| US5049458A (en) * | 1988-08-31 | 1991-09-17 | Nkk Corporation | Fuel cell |
| US4937152A (en) * | 1988-09-26 | 1990-06-26 | Nkk Corporation | Fuel cell |
| US4997726A (en) * | 1989-02-15 | 1991-03-05 | Sanyo Electric Co., Ltd. | Solid oxide electrolyte fuel cell |
| EP0406523A1 (fr) * | 1989-07-07 | 1991-01-09 | Osaka Gas Co., Ltd. | Pile à combustible |
-
1991
- 1991-03-05 CH CH654/91A patent/CH682270A5/de not_active IP Right Cessation
-
1992
- 1992-02-24 AT AT92905478T patent/ATE127962T1/de not_active IP Right Cessation
- 1992-02-24 ES ES92905478T patent/ES2077402T3/es not_active Expired - Lifetime
- 1992-02-24 CA CA002081779A patent/CA2081779C/fr not_active Expired - Fee Related
- 1992-02-24 DK DK92905478.1T patent/DK0527990T3/da not_active Application Discontinuation
- 1992-02-24 DE DE59203656T patent/DE59203656D1/de not_active Expired - Fee Related
- 1992-02-24 AU AU12721/92A patent/AU643371B2/en not_active Ceased
- 1992-02-24 US US07/941,045 patent/US5338621A/en not_active Expired - Fee Related
- 1992-02-24 JP JP92504920A patent/JPH05507384A/ja active Pending
- 1992-02-24 WO PCT/EP1992/000384 patent/WO1992016029A1/fr active IP Right Grant
- 1992-02-24 EP EP92905478A patent/EP0527990B1/fr not_active Expired - Lifetime
- 1992-09-21 NO NO923650A patent/NO305820B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US5338621A (en) | 1994-08-16 |
| CH682270A5 (fr) | 1993-08-13 |
| NO923650D0 (no) | 1992-09-21 |
| ATE127962T1 (de) | 1995-09-15 |
| NO923650L (no) | 1992-09-21 |
| DE59203656D1 (de) | 1995-10-19 |
| DK0527990T3 (da) | 1996-01-22 |
| EP0527990B1 (fr) | 1995-09-13 |
| ES2077402T3 (es) | 1995-11-16 |
| AU643371B2 (en) | 1993-11-11 |
| EP0527990A1 (fr) | 1993-02-24 |
| WO1992016029A1 (fr) | 1992-09-17 |
| JPH05507384A (ja) | 1993-10-21 |
| CA2081779C (fr) | 1997-10-14 |
| AU1272192A (en) | 1992-10-06 |
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