NO303677B1 - Zeolitt-katalysator, fremgangsmÕte for fremstilling derav og fremgangsmÕte for anvendelse derav - Google Patents
Zeolitt-katalysator, fremgangsmÕte for fremstilling derav og fremgangsmÕte for anvendelse derav Download PDFInfo
- Publication number
- NO303677B1 NO303677B1 NO895175A NO895175A NO303677B1 NO 303677 B1 NO303677 B1 NO 303677B1 NO 895175 A NO895175 A NO 895175A NO 895175 A NO895175 A NO 895175A NO 303677 B1 NO303677 B1 NO 303677B1
- Authority
- NO
- Norway
- Prior art keywords
- catalyst
- zeolite
- hydrogen
- catalyst according
- hours
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 119
- 239000010457 zeolite Substances 0.000 title claims abstract description 100
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 92
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 91
- 238000000034 method Methods 0.000 title claims description 38
- 230000008569 process Effects 0.000 title claims description 13
- 238000002360 preparation method Methods 0.000 title description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 22
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 21
- 238000006317 isomerization reaction Methods 0.000 claims abstract description 21
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 11
- 238000005804 alkylation reaction Methods 0.000 claims abstract description 9
- 230000029936 alkylation Effects 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 110
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 60
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 60
- 239000001257 hydrogen Substances 0.000 claims description 42
- 229910052739 hydrogen Inorganic materials 0.000 claims description 42
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 31
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 30
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 27
- 229910052782 aluminium Inorganic materials 0.000 claims description 22
- 238000005342 ion exchange Methods 0.000 claims description 22
- 239000008096 xylene Substances 0.000 claims description 19
- 229910052710 silicon Inorganic materials 0.000 claims description 18
- 239000011230 binding agent Substances 0.000 claims description 17
- 150000001768 cations Chemical class 0.000 claims description 17
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 13
- 238000002441 X-ray diffraction Methods 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 11
- 150000002431 hydrogen Chemical class 0.000 claims description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 150000001336 alkenes Chemical class 0.000 claims description 10
- 238000007323 disproportionation reaction Methods 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 150000001491 aromatic compounds Chemical class 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 7
- 238000005470 impregnation Methods 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 6
- 238000005899 aromatization reaction Methods 0.000 claims description 6
- 229910052733 gallium Inorganic materials 0.000 claims description 6
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 5
- 239000002808 molecular sieve Substances 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 5
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 150000002736 metal compounds Chemical class 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052732 germanium Chemical group 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011572 manganese Substances 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 238000006384 oligomerization reaction Methods 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- 238000006900 dealkylation reaction Methods 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- 229910021645 metal ion Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 238000010555 transalkylation reaction Methods 0.000 abstract description 7
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- 238000006243 chemical reaction Methods 0.000 description 45
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 36
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 27
- 239000011734 sodium Substances 0.000 description 27
- 238000004458 analytical method Methods 0.000 description 22
- 229910052708 sodium Inorganic materials 0.000 description 20
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 19
- 239000011541 reaction mixture Substances 0.000 description 19
- -1 alkali metal cation Chemical class 0.000 description 18
- 229910001220 stainless steel Inorganic materials 0.000 description 17
- 239000010935 stainless steel Substances 0.000 description 17
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 16
- 239000007789 gas Substances 0.000 description 16
- 239000007788 liquid Substances 0.000 description 16
- 229910052757 nitrogen Inorganic materials 0.000 description 16
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 16
- 238000006356 dehydrogenation reaction Methods 0.000 description 15
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 14
- 239000008367 deionised water Substances 0.000 description 14
- 229910021641 deionized water Inorganic materials 0.000 description 14
- 238000005984 hydrogenation reaction Methods 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 13
- 238000012546 transfer Methods 0.000 description 13
- 239000002253 acid Substances 0.000 description 12
- 229910052697 platinum Inorganic materials 0.000 description 12
- 238000000634 powder X-ray diffraction Methods 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 239000013078 crystal Substances 0.000 description 11
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 229910052759 nickel Inorganic materials 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 150000003738 xylenes Chemical class 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000003776 cleavage reaction Methods 0.000 description 8
- 239000012535 impurity Substances 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 8
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- 229910052814 silicon oxide Inorganic materials 0.000 description 8
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- 238000003786 synthesis reaction Methods 0.000 description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- 239000003085 diluting agent Substances 0.000 description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 7
- 239000002243 precursor Substances 0.000 description 7
- 230000007017 scission Effects 0.000 description 7
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 235000019270 ammonium chloride Nutrition 0.000 description 6
- 238000001354 calcination Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000006297 dehydration reaction Methods 0.000 description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 6
- 229910052763 palladium Inorganic materials 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 229910052702 rhenium Inorganic materials 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 6
- MTCUAOILFDZKCO-UHFFFAOYSA-N Decamethonium Chemical group C[N+](C)(C)CCCCCCCCCC[N+](C)(C)C MTCUAOILFDZKCO-UHFFFAOYSA-N 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
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- 230000000996 additive effect Effects 0.000 description 5
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
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- 125000003118 aryl group Chemical group 0.000 description 3
- 238000004523 catalytic cracking Methods 0.000 description 3
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- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
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- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical class [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- AGMNAIOLVWYHRE-UHFFFAOYSA-N [O-2].[Th+4].[Si+2]=O.[O-2].[O-2] Chemical compound [O-2].[Th+4].[Si+2]=O.[O-2].[O-2] AGMNAIOLVWYHRE-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
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- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
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- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
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- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
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Classifications
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- C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
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- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
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- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
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- C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB888829923A GB8829923D0 (en) | 1988-12-22 | 1988-12-22 | Zeolites |
Publications (3)
Publication Number | Publication Date |
---|---|
NO895175D0 NO895175D0 (no) | 1989-12-21 |
NO895175L NO895175L (no) | 1990-06-25 |
NO303677B1 true NO303677B1 (no) | 1998-08-17 |
Family
ID=10648937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO895175A NO303677B1 (no) | 1988-12-22 | 1989-12-21 | Zeolitt-katalysator, fremgangsmÕte for fremstilling derav og fremgangsmÕte for anvendelse derav |
Country Status (17)
Country | Link |
---|---|
US (2) | US5041402A (ja) |
EP (1) | EP0378916B1 (ja) |
JP (1) | JP2924911B2 (ja) |
KR (1) | KR0144466B1 (ja) |
CN (1) | CN1027048C (ja) |
AT (1) | ATE82526T1 (ja) |
AU (1) | AU622964B2 (ja) |
CA (1) | CA2006542C (ja) |
DE (1) | DE68903560T2 (ja) |
DK (1) | DK173894B1 (ja) |
ES (1) | ES2044151T3 (ja) |
GB (1) | GB8829923D0 (ja) |
GR (1) | GR3006777T3 (ja) |
IN (1) | IN178832B (ja) |
NO (1) | NO303677B1 (ja) |
RU (1) | RU2067024C1 (ja) |
ZA (1) | ZA899697B (ja) |
Families Citing this family (91)
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DE19630670A1 (de) * | 1996-07-30 | 1998-02-05 | Basf Ag | Verfahren zur Herstellung von Aminen aus Olefinen an Zeolithen mit NES-Struktur |
FR2752568B1 (fr) * | 1996-08-23 | 1998-09-25 | Inst Francais Du Petrole | Zeolithe desaluminee de type structural nes, et son utilisation en dismutation et/ou transalkylation d'hydrocarbures alkylaromatiques |
FR2758566B1 (fr) * | 1997-01-20 | 1999-02-19 | Inst Francais Du Petrole | Procede de craquage de charges hydrocarbonees a l'aide d'un catalyseur comprenant une zeolithe de type structural nes desaluminee |
CN1067040C (zh) * | 1997-11-13 | 2001-06-13 | 中国石油化工集团公司 | 甲苯歧化与烷基转移工艺 |
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US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
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CN105772067B (zh) * | 2014-12-26 | 2019-10-11 | 中国科学院大连化学物理研究所 | 一种双孔道结晶铝硅酸盐分子筛催化剂及其制备方法 |
WO2017051260A1 (en) * | 2015-09-22 | 2017-03-30 | Hindustan Petroleum Corporation Limited | An additive and a catalyst composition comprising the additive for fcc process |
CN106000457A (zh) * | 2016-05-24 | 2016-10-12 | 山东成泰化工有限公司 | 一种用于汽油醚化的复合催化剂及其制备方法 |
CN107790172B (zh) * | 2016-08-30 | 2020-07-07 | 中国石油化工股份有限公司 | 烷基转移催化剂及其制备方法和用途 |
CN108238612B (zh) * | 2016-12-23 | 2019-11-15 | 中国石油化工股份有限公司 | 一种含硼nu-87分子筛的制备方法 |
CN108238615B (zh) * | 2016-12-23 | 2020-05-19 | 中国石油化工股份有限公司 | 一种含硼nu-87分子筛的制备方法 |
FR3074428B1 (fr) * | 2017-12-06 | 2022-01-21 | Ifp Energies Now | Procede de preparation d'un catalyseur a base d'izm-2 a partir d'une solution comprenant des precurseurs specifiques et utilisation pour l'isomerisation de charges paraffiniques |
CN109772447B (zh) * | 2019-01-18 | 2022-04-12 | 太原大成环能化工技术有限公司 | 一种碳八芳烃异构化复合分子筛催化剂及其制备方法 |
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Family Cites Families (10)
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SE364246B (ja) * | 1969-12-02 | 1974-02-18 | Shell Int Research | |
CA1051855A (en) * | 1974-10-07 | 1979-04-03 | David E.W. Vaughan | Zeolite vk-2 |
EP0055045B1 (en) * | 1980-12-19 | 1984-09-12 | Imperial Chemical Industries Plc | Production of ethers |
US4757041A (en) * | 1983-10-13 | 1988-07-12 | Mobil Oil Corporation | Catalysts for cracking and dewaxing hydrocarbon oils |
US4634686A (en) * | 1985-05-02 | 1987-01-06 | The Standard Oil Company | Yttrium silicate molecular sieves |
FR2634140B1 (fr) * | 1988-07-12 | 1990-09-14 | Inst Francais Du Petrole | Catalyseur du type aluminosilicate contenant du gallium et son utilisation en aromatisation des gaz legers c2-c4 |
GB8818452D0 (en) * | 1988-08-03 | 1988-09-07 | British Petroleum Co Plc | Process for preparation of crystalline(metallo)silicates & germanates |
GB8829924D0 (en) * | 1988-12-22 | 1989-02-15 | Ici Ltd | Zeolites |
GB8829923D0 (en) * | 1988-12-22 | 1989-02-15 | Ici Plc | Zeolites |
US5178748A (en) * | 1988-12-22 | 1993-01-12 | Imperial Chemical Industries | Catalytic reactions using zeolites |
-
1988
- 1988-12-22 GB GB888829923A patent/GB8829923D0/en active Pending
-
1989
- 1989-12-14 EP EP89313126A patent/EP0378916B1/en not_active Expired - Lifetime
- 1989-12-14 DE DE8989313126T patent/DE68903560T2/de not_active Expired - Fee Related
- 1989-12-14 ES ES89313126T patent/ES2044151T3/es not_active Expired - Lifetime
- 1989-12-14 AT AT89313126T patent/ATE82526T1/de not_active IP Right Cessation
- 1989-12-18 ZA ZA899697A patent/ZA899697B/xx unknown
- 1989-12-19 IN IN1211DE1989 patent/IN178832B/en unknown
- 1989-12-21 RU SU894742706A patent/RU2067024C1/ru active
- 1989-12-21 NO NO895175A patent/NO303677B1/no not_active IP Right Cessation
- 1989-12-21 AU AU47146/89A patent/AU622964B2/en not_active Ceased
- 1989-12-21 DK DK198906547A patent/DK173894B1/da not_active IP Right Cessation
- 1989-12-22 US US07/453,305 patent/US5041402A/en not_active Expired - Lifetime
- 1989-12-22 CN CN89109815A patent/CN1027048C/zh not_active Expired - Fee Related
- 1989-12-22 CA CA002006542A patent/CA2006542C/en not_active Expired - Fee Related
- 1989-12-22 JP JP1334686A patent/JP2924911B2/ja not_active Expired - Lifetime
- 1989-12-22 KR KR1019890019324A patent/KR0144466B1/ko not_active IP Right Cessation
-
1993
- 1993-01-11 US US08/002,800 patent/US5345021A/en not_active Expired - Lifetime
- 1993-01-14 GR GR920402594T patent/GR3006777T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
GR3006777T3 (ja) | 1993-06-30 |
KR900009135A (ko) | 1990-07-02 |
NO895175L (no) | 1990-06-25 |
CN1027048C (zh) | 1994-12-21 |
AU4714689A (en) | 1990-06-28 |
EP0378916B1 (en) | 1992-11-19 |
DK173894B1 (da) | 2002-02-04 |
US5345021A (en) | 1994-09-06 |
DK654789D0 (da) | 1989-12-21 |
ZA899697B (en) | 1991-03-27 |
NO895175D0 (no) | 1989-12-21 |
CN1044052A (zh) | 1990-07-25 |
KR0144466B1 (ko) | 1998-07-15 |
DK654789A (da) | 1990-06-23 |
GB8829923D0 (en) | 1989-02-15 |
RU2067024C1 (ru) | 1996-09-27 |
JPH02222727A (ja) | 1990-09-05 |
AU622964B2 (en) | 1992-04-30 |
JP2924911B2 (ja) | 1999-07-26 |
CA2006542A1 (en) | 1990-06-22 |
EP0378916A1 (en) | 1990-07-25 |
US5041402A (en) | 1991-08-20 |
DE68903560T2 (de) | 1993-06-17 |
IN178832B (ja) | 1997-07-05 |
DE68903560D1 (de) | 1992-12-24 |
ATE82526T1 (de) | 1992-12-15 |
CA2006542C (en) | 2000-03-14 |
ES2044151T3 (es) | 1994-01-01 |
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