NO300642B1 - Krystallinske propylenpolymerer med forbedret bearbeidbarhet i smeltet tilstand - Google Patents
Krystallinske propylenpolymerer med forbedret bearbeidbarhet i smeltet tilstand Download PDFInfo
- Publication number
- NO300642B1 NO300642B1 NO931933A NO931933A NO300642B1 NO 300642 B1 NO300642 B1 NO 300642B1 NO 931933 A NO931933 A NO 931933A NO 931933 A NO931933 A NO 931933A NO 300642 B1 NO300642 B1 NO 300642B1
- Authority
- NO
- Norway
- Prior art keywords
- polymers
- weight
- values
- copolymers
- fraction
- Prior art date
Links
- 229920001155 polypropylene Polymers 0.000 title claims description 16
- 229920000642 polymer Polymers 0.000 claims description 48
- 229920001577 copolymer Polymers 0.000 claims description 22
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 11
- 239000008096 xylene Substances 0.000 claims description 11
- 239000002667 nucleating agent Substances 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 4
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- 229920006285 olefinic elastomer Polymers 0.000 claims description 2
- 229920001384 propylene homopolymer Polymers 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 description 33
- 238000006116 polymerization reaction Methods 0.000 description 23
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 22
- -1 magnesium halides Chemical class 0.000 description 19
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 13
- 239000011777 magnesium Substances 0.000 description 13
- 229910052749 magnesium Inorganic materials 0.000 description 13
- 239000007789 gas Substances 0.000 description 11
- 239000012071 phase Substances 0.000 description 11
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 10
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical class [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 9
- 229910003074 TiCl4 Inorganic materials 0.000 description 9
- 239000000155 melt Substances 0.000 description 9
- 239000011949 solid catalyst Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 239000000806 elastomer Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical group C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 150000003609 titanium compounds Chemical class 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229910010062 TiCl3 Inorganic materials 0.000 description 3
- 238000002083 X-ray spectrum Methods 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000003856 thermoforming Methods 0.000 description 3
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- OJOWICOBYCXEKR-UHFFFAOYSA-N 5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=CC)CC1C=C2 OJOWICOBYCXEKR-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical group [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- UXXXZMDJQLPQPH-UHFFFAOYSA-N bis(2-methylpropyl) carbonate Chemical compound CC(C)COC(=O)OCC(C)C UXXXZMDJQLPQPH-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI921337A IT1260497B (it) | 1992-05-29 | 1992-05-29 | Polimeri cristallini del propilene aventi migliorata processabilita' allo stato e processo per la loro preparazione |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO931933D0 NO931933D0 (no) | 1993-05-27 |
| NO931933L NO931933L (no) | 1993-11-30 |
| NO300642B1 true NO300642B1 (no) | 1997-06-30 |
Family
ID=11363423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO931933A NO300642B1 (no) | 1992-05-29 | 1993-05-27 | Krystallinske propylenpolymerer med forbedret bearbeidbarhet i smeltet tilstand |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7332556B2 (de) |
| EP (1) | EP0573862B1 (de) |
| JP (1) | JPH0693034A (de) |
| KR (1) | KR100272480B1 (de) |
| CN (1) | CN1037182C (de) |
| AT (1) | ATE164380T1 (de) |
| AU (1) | AU658478B2 (de) |
| CA (1) | CA2092639C (de) |
| DE (1) | DE69317599T2 (de) |
| ES (1) | ES2114967T3 (de) |
| FI (1) | FI106384B (de) |
| IT (1) | IT1260497B (de) |
| MX (1) | MX9301698A (de) |
| NO (1) | NO300642B1 (de) |
| RU (1) | RU2081132C1 (de) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1264679B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori per la (co)polimerizzazione di etilene |
| BR9402947A (pt) * | 1994-05-12 | 1999-06-01 | Showa Denko Kk | Processo para a producao de um componente catalisador lido para a polimerizacao de propileno, processo para a producao de um polimero em base de propileno e processo para a producao de uma composicao polimerica |
| US6184328B1 (en) | 1994-09-07 | 2001-02-06 | Showa Denko Kabushiki Kaisha | Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production |
| EP0821012B1 (de) * | 1994-05-12 | 1999-01-13 | Showa Denko Kabushiki Kaisha | Polymer auf Propylenbasis, Verfahren zu seiner Herstellung und Zusammensetzungen davon |
| FI944761A0 (fi) * | 1994-10-11 | 1994-10-11 | Borealis Holding As | Ny polypropylenkomposition med vid molekylvikt distribution |
| US5641848A (en) * | 1995-07-24 | 1997-06-24 | Montell North America Inc. | Polypropylene blown film |
| US5670595A (en) * | 1995-08-28 | 1997-09-23 | Exxon Chemical Patents Inc. | Diene modified polymers |
| DE19543292A1 (de) * | 1995-11-21 | 1997-05-22 | Basf Ag | Copolymerisate des Propylens mit anderen C¶2¶-C¶1¶¶0¶-Alk-1-enen |
| DE19543293A1 (de) * | 1995-11-21 | 1997-05-22 | Basf Ag | Copolymerisate des Propylens |
| DE19605217C2 (de) | 1996-02-13 | 1998-02-19 | Filtertek Bv | Infusionsbesteck mit Behältern für Flüssigmedikamente |
| DE19606510A1 (de) | 1996-02-22 | 1997-08-28 | Hoechst Ag | Hochmolekulares Polypropylen mit breiter Molmassenverteilung |
| DE19621022B4 (de) * | 1996-05-24 | 2014-12-31 | Basell Polyolefine Gmbh | Hochmolekulares Ethylen/Propylen-Reaktorblend mit breiter Molmassenverteilung |
| CN1154670C (zh) * | 1996-05-27 | 2004-06-23 | 三井化学株式会社 | 结晶聚丙烯,其制备方法,聚丙烯组合物和热成型的产品 |
| US6403708B2 (en) * | 1996-05-27 | 2002-06-11 | Mitsui Chemicals Inc | Crystalline polypropylenes, process for preparing thereof, polypropylene compositions, and thermoformed products |
| KR100444618B1 (ko) * | 1997-05-30 | 2004-08-18 | 미쓰이 가가쿠 가부시키가이샤 | 폴리프로필렌 수지조성물 및 사출성형품 |
| WO1999007752A1 (fr) * | 1997-08-05 | 1999-02-18 | Grand Polymer Co., Ltd. | Composition de resine de polypropylene et utilisation de celle-ci |
| FI973816A0 (fi) * | 1997-09-26 | 1997-09-26 | Borealis As | Polypropen med hoeg smaeltstyrka |
| SG71878A1 (en) * | 1997-12-11 | 2000-04-18 | Sumitomo Chemical Co | Propylene-based polymer composition and foamed article thereof |
| DE19813399A1 (de) | 1998-03-26 | 1999-09-30 | Basf Ag | Statistische Propylencopolymerisate |
| DE19829246A1 (de) | 1998-06-30 | 2000-01-05 | Targor Gmbh | Polymermischungen |
| EP1058718B1 (de) | 1998-12-24 | 2009-01-21 | Basell Poliolefine Italia S.r.l. | Flaschenverschlüsse aus polyolefinen |
| JP3832129B2 (ja) * | 1999-02-05 | 2006-10-11 | 株式会社プライムポリマー | ポリプロピレン樹脂組成物および射出成形品 |
| FI990284A0 (fi) * | 1999-02-12 | 1999-02-12 | Borealis As | Monivaiheinen prosessi erittäin stereosäännöllisen sulakäsiteltävän alfa-olefiinipolymeerituotteen valmistamiseksi |
| FI990282A0 (fi) * | 1999-02-12 | 1999-02-12 | Borealis As | Monivaiheinen prosessi sellaisten alfa-olefiinipolymeerien valmistamiseksi, joilla on kontrolloitu stereosäännöllisyys, sekä niistä valmistetut tuotteet |
| FI990283A (fi) | 1999-02-12 | 2000-08-13 | Borealis As | alfa-olefiinin polymerointikatalysattorisysteemi ja sen käyttö alfa -olefiinien polymerointiin |
| FI990285A0 (fi) * | 1999-02-12 | 1999-02-12 | Borealis As | Menetelmä vedylle herkän alfa-olefiinin polymerointikatalysaattorijärjestelmän valmistamiseksi, prosessissa syntynyt polymerointikatalysaattorijärjestelmä ja sen käyttö alfa-olefiinien polymeroinnissa |
| SE518553C2 (sv) * | 1999-06-09 | 2002-10-22 | Borealis As | Profil för fönster och dörrar av propensegmentsampolymer med kärnbildande medel och fyllmedel |
| JP3921951B2 (ja) * | 2001-02-27 | 2007-05-30 | 住友化学株式会社 | ポリプロピレン樹脂組成物およびその製造方法 |
| KR100435328B1 (ko) * | 2001-08-07 | 2004-06-10 | 현대자동차주식회사 | 도장성이 우수한 폴리프로필렌 수지 조성물 |
| EP1300239A1 (de) * | 2001-10-04 | 2003-04-09 | Borealis Technology OY | Nicht-orientierter Polypropylenfilm |
| JP2005507444A (ja) | 2001-10-30 | 2005-03-17 | バセル ポリオレフィン イタリア エス．ピー．エー． | ポリプロピレン組成物についての管システム |
| ATE324387T1 (de) | 2001-11-27 | 2006-05-15 | Basell Poliolefine Srl | Durchsichtige und flexible polypropenzusammensetzungen |
| US7572859B2 (en) | 2002-06-26 | 2009-08-11 | Basell Polyolefine Italia S.R.L. | Impact-resistant polyolefin compositions |
| MXPA04012699A (es) | 2002-06-26 | 2005-03-23 | Basell Poliolefine Spa | Composiciones de poliolefina resistentes a impactos. |
| BR0306195B1 (pt) | 2002-08-01 | 2012-12-25 | processo para a preparaÇço de polÍmeros, polÍmeros obtidos pelo mesmo, filmes ou folhas e artigos laminados multicamadas. | |
| EP1680468B1 (de) | 2003-11-06 | 2011-08-17 | Basell Poliolefine Italia S.r.l. | Polypropylenzusammensetzung |
| JP4920587B2 (ja) | 2004-06-08 | 2012-04-18 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 剛性、衝撃強さおよび破断点伸び率の良好なバランスならびに低い熱収縮を有するポリオレフィン組成物 |
| ES2306188T3 (es) | 2004-06-25 | 2008-11-01 | Basell Poliolefine Italia S.R.L. | Sistemas de tuberias fabricados a partir de copolimeros de propileno y alfa-olefinas (retipificados). |
| EP1674530A1 (de) * | 2004-12-24 | 2006-06-28 | Kraton Polymers Research B.V. | Thermoplastische Elastomerzusammensetzung mit hoher Schmelzefestigkeit |
| JP2008528779A (ja) | 2005-02-03 | 2008-07-31 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 射出成形用プロピレンポリマー組成物 |
| KR20080022101A (ko) | 2005-05-12 | 2008-03-10 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌-에틸렌 공중합체 및 그 제조 방법 |
| JP5178512B2 (ja) * | 2005-07-01 | 2013-04-10 | サンアロマー株式会社 | 広い分子量分布を示すプロピレンポリマー |
| WO2008074713A1 (en) * | 2006-12-20 | 2008-06-26 | Basell Poliolefine Italia S.R.L. | Filled polyolefin compositions |
| US8309659B2 (en) | 2006-12-20 | 2012-11-13 | Basell Poliolefine Italia S.R.L. | Filled polyolefin compositions |
| US8227550B2 (en) | 2006-12-20 | 2012-07-24 | Basell Poliolefine Italia S.R.L. | Filled polyolefin compositions |
| US8716394B2 (en) | 2006-12-20 | 2014-05-06 | Basell Poliolefine Italia S.R.L. | Polypropylene compositions containing fillers and/or pigments |
| CN101319070B (zh) | 2007-06-06 | 2012-10-03 | 住友化学株式会社 | 聚丙烯树脂组合物及其拉伸膜 |
| RU2010139855A (ru) | 2008-02-29 | 2012-04-10 | Базелль Полиолефин Италия С.Р.Л. (It) | Полиолефиновые композиции |
| EP2358810B1 (de) | 2008-12-19 | 2013-02-27 | Basell Poliolefine Italia S.r.l. | Gefüllte polyolefinzusammensetzungen |
| ES2370689T3 (es) | 2009-02-25 | 2011-12-21 | Borealis Ag | Polímero multimodal de polipropileno, composición que comprende el mismo y un procedimiento para producir el mismo. |
| US8282906B2 (en) * | 2009-12-23 | 2012-10-09 | 3M Innovative Properties Company | Remote plasma synthesis of metal oxide nanoparticles |
| EP2781548A1 (de) | 2013-03-19 | 2014-09-24 | Basell Poliolefine Italia S.r.l. | Mineralgefüllte Polypropylen-Zusammensetzung |
| US9550844B2 (en) | 2013-06-19 | 2017-01-24 | Borealis Ag | Polypropylene with broad molecular weight distribution |
| US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
| US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
| US9611341B2 (en) | 2014-02-07 | 2017-04-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE792607A (nl) * | 1971-12-20 | 1973-06-12 | Shell Int Research | Titaanchloride-bevattende composities geschikt voor polymerisatie |
| JPS5883016A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | プロピレンブロツク共重合体の製法 |
| JPS58219207A (ja) | 1982-06-15 | 1983-12-20 | Chisso Corp | 高剛性高溶融粘弾性ポリプロピレンとその製造法 |
| JPS59172507A (ja) | 1983-03-23 | 1984-09-29 | Mitsui Petrochem Ind Ltd | ポリプロピレンの製造方法 |
| DE3331877A1 (de) * | 1983-09-03 | 1985-03-21 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung einer polypropylen-formmasse |
| JPS62116618A (ja) * | 1985-11-15 | 1987-05-28 | Chisso Corp | プロピレン−エチレンブロツク共重合体の連続製造法 |
| US4970280A (en) * | 1987-04-01 | 1990-11-13 | Chisso Corporation | Continuous process for producing high molten viscoelastic polypropylene or ethylene-propylene copolymer |
| EP0350170B2 (de) * | 1988-06-17 | 2001-09-12 | Mitsui Chemicals, Inc. | Olefinpolymerisationsverfahren und dabei anwendbarer Polymerisationskatalysator |
| EP0385765B1 (de) * | 1989-03-02 | 1995-05-03 | Mitsui Petrochemical Industries, Ltd. | Verfahren zur Polymerisation von Olefinen und Katalysator für Olefinpolymerisation |
| DE4009169A1 (de) * | 1990-03-22 | 1991-09-26 | Hoechst Ag | Verfahren zur herstellung einer polypropylen-formmasse |
| JPH0436350A (ja) * | 1990-06-01 | 1992-02-06 | Nippon Unicar Co Ltd | 光崩壊性耐熱性樹脂組成物及び該樹脂組成物で作った成形品 |
| US5218052A (en) * | 1991-02-04 | 1993-06-08 | Amoco Corporation | Olefin polymerization and copolymerization process |
| US5147936A (en) * | 1991-04-08 | 1992-09-15 | Mobil Oil Corporation | LLDPE films by blending with specific polypropylenes |
-
1992
- 1992-05-29 IT ITMI921337A patent/IT1260497B/it active IP Right Grant
-
1993
- 1993-02-17 AU AU33115/93A patent/AU658478B2/en not_active Ceased
- 1993-03-12 CA CA002092639A patent/CA2092639C/en not_active Expired - Fee Related
- 1993-03-26 MX MX9301698A patent/MX9301698A/es not_active IP Right Cessation
- 1993-03-31 KR KR1019930005381A patent/KR100272480B1/ko not_active IP Right Cessation
- 1993-05-25 RU RU9393005229A patent/RU2081132C1/ru not_active IP Right Cessation
- 1993-05-26 CN CN93106771A patent/CN1037182C/zh not_active Expired - Lifetime
- 1993-05-27 NO NO931933A patent/NO300642B1/no not_active IP Right Cessation
- 1993-05-28 DE DE69317599T patent/DE69317599T2/de not_active Expired - Lifetime
- 1993-05-28 AT AT93108679T patent/ATE164380T1/de not_active IP Right Cessation
- 1993-05-28 FI FI932442A patent/FI106384B/fi active
- 1993-05-28 EP EP93108679A patent/EP0573862B1/de not_active Expired - Lifetime
- 1993-05-28 ES ES93108679T patent/ES2114967T3/es not_active Expired - Lifetime
- 1993-05-28 JP JP5127510A patent/JPH0693034A/ja active Pending
-
2006
- 2006-03-22 US US11/385,711 patent/US7332556B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0573862A3 (en) | 1994-05-11 |
| NO931933L (no) | 1993-11-30 |
| ATE164380T1 (de) | 1998-04-15 |
| US7332556B2 (en) | 2008-02-19 |
| FI106384B (fi) | 2001-01-31 |
| ITMI921337A1 (it) | 1993-11-30 |
| DE69317599D1 (de) | 1998-04-30 |
| CN1037182C (zh) | 1998-01-28 |
| AU3311593A (en) | 1993-12-02 |
| US20060160963A1 (en) | 2006-07-20 |
| NO931933D0 (no) | 1993-05-27 |
| EP0573862B1 (de) | 1998-03-25 |
| ES2114967T3 (es) | 1998-06-16 |
| EP0573862A2 (de) | 1993-12-15 |
| DE69317599T2 (de) | 1998-09-24 |
| JPH0693034A (ja) | 1994-04-05 |
| MX9301698A (es) | 1993-11-01 |
| FI932442A0 (fi) | 1993-05-28 |
| KR930023381A (ko) | 1993-12-18 |
| CA2092639A1 (en) | 1993-11-30 |
| CA2092639C (en) | 2004-02-24 |
| IT1260497B (it) | 1996-04-09 |
| CN1079968A (zh) | 1993-12-29 |
| KR100272480B1 (ko) | 2000-11-15 |
| FI932442A (fi) | 1993-11-30 |
| RU2081132C1 (ru) | 1997-06-10 |
| AU658478B2 (en) | 1995-04-13 |
| ITMI921337A0 (it) | 1992-05-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO300642B1 (no) | Krystallinske propylenpolymerer med forbedret bearbeidbarhet i smeltet tilstand | |
| AU2004226245B2 (en) | Impact resistant polyolefin compositions | |
| KR100217158B1 (ko) | 엘라스토플라스틱 폴리올레핀 조성물 | |
| KR100635888B1 (ko) | 내충격성 폴리올레핀 조성물 | |
| RU2459836C2 (ru) | Способ получения мягких композиций пропиленовых полимеров | |
| JP3065325B2 (ja) | 良好な透明性及び改良された耐衝撃性を有するプロピレン重合体組成物 | |
| SK280805B6 (sk) | Polypropylénová kompozícia a spôsob jej prípravy | |
| EP2931808B1 (de) | Polyolefinzusammensetzung | |
| HU210337B (en) | Process for producing thermoplastic olefin polymeric composition | |
| AU2005291326A1 (en) | Elastomeric polyolefin compositions | |
| US7074871B2 (en) | Crystalline polymers of propylene having improved processability in the molten state and process for their preparation | |
| RU2671201C2 (ru) | Состав полиэтилена и его использование в полиолефиновых композициях | |
| RU2679135C2 (ru) | Состав полиэтилена с улучшенными механическими свойствами при растяжении | |
| KR101453130B1 (ko) | 인장 특성이 개선된 헤테로상 폴리올레핀 조성물 | |
| HU181967B (en) | Process for producing propylene-ethylene aulk copolymeres | |
| US20020103302A1 (en) | Crystalline polymer of propylene having improved processability in the molten state and process for their preparation | |
| WO2013135653A1 (en) | Propylene polymer compositions | |
| RU2670985C2 (ru) | Состав полиэтилена и его использование в полиолефиновых композициях | |
| US20230383107A1 (en) | Polypropylene composition | |
| WO2023057054A1 (en) | Polypropylene composition | |
| WO2011144486A1 (en) | Polypropylene tub for washing machine | |
| MXPA01004822A (en) | Impact-resitant polyolefin compositions | |
| JPH05320249A (ja) | 高剛性ポリプロピレンの製造法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |
Free format text: LAPSED IN NOVEMBER 2002 |