NO300489B1 - Katalysatorsammensetning og anvendelse av sammensetningen i en fremgangsmåte til dehydrogenering og/eller dehydrocyklisering av organiske forbindelser - Google Patents
Katalysatorsammensetning og anvendelse av sammensetningen i en fremgangsmåte til dehydrogenering og/eller dehydrocyklisering av organiske forbindelser Download PDFInfo
- Publication number
- NO300489B1 NO300489B1 NO911576A NO911576A NO300489B1 NO 300489 B1 NO300489 B1 NO 300489B1 NO 911576 A NO911576 A NO 911576A NO 911576 A NO911576 A NO 911576A NO 300489 B1 NO300489 B1 NO 300489B1
- Authority
- NO
- Norway
- Prior art keywords
- catalyst
- composition
- stated
- metal
- dehydrogenation
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 90
- 239000000203 mixture Substances 0.000 title claims description 58
- 238000000034 method Methods 0.000 title claims description 38
- 238000006356 dehydrogenation reaction Methods 0.000 title claims description 28
- 230000008569 process Effects 0.000 title claims description 18
- 150000002894 organic compounds Chemical class 0.000 title description 4
- -1 zinc aluminate Chemical class 0.000 claims description 38
- 229910052751 metal Inorganic materials 0.000 claims description 35
- 239000002184 metal Substances 0.000 claims description 35
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims description 33
- 229930195733 hydrocarbon Natural products 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 25
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 25
- 229910052725 zinc Inorganic materials 0.000 claims description 22
- 239000011701 zinc Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 15
- 229910052697 platinum Inorganic materials 0.000 claims description 15
- 229910052718 tin Inorganic materials 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 6
- 229910052732 germanium Inorganic materials 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000004215 Carbon black (E152) Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 150000002739 metals Chemical class 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 239000001294 propane Substances 0.000 description 8
- 230000007306 turnover Effects 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 7
- 239000007858 starting material Substances 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000012876 carrier material Substances 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 3
- 150000001242 acetic acid derivatives Chemical class 0.000 description 3
- 229940045985 antineoplastic platinum compound Drugs 0.000 description 3
- 235000013844 butane Nutrition 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 150000004679 hydroxides Chemical class 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 150000003058 platinum compounds Chemical class 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000011143 downstream manufacturing Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 150000003891 oxalate salts Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- HFABJRIXDJWNLA-UHFFFAOYSA-L 2-aminoacetate;platinum(2+) Chemical compound [Pt+2].NCC([O-])=O.NCC([O-])=O HFABJRIXDJWNLA-UHFFFAOYSA-L 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 1
- 229910003771 Gold(I) chloride Inorganic materials 0.000 description 1
- 229910003803 Gold(III) chloride Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- VEFOGWVXEBSPOE-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.O.O Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.O.O VEFOGWVXEBSPOE-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 1
- RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical compound Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 description 1
- OIZJPMOIAMYNJL-UHFFFAOYSA-H gold(3+);trisulfate Chemical compound [Au+3].[Au+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OIZJPMOIAMYNJL-UHFFFAOYSA-H 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000006263 metalation reaction Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- NFOHLBHARAZXFQ-UHFFFAOYSA-L platinum(2+);dihydroxide Chemical compound O[Pt]O NFOHLBHARAZXFQ-UHFFFAOYSA-L 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- LFAGQMCIGQNPJG-UHFFFAOYSA-N silver cyanide Chemical compound [Ag+].N#[C-] LFAGQMCIGQNPJG-UHFFFAOYSA-N 0.000 description 1
- 229940098221 silver cyanide Drugs 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 229960001516 silver nitrate Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000013179 statistical model Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
- C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
- C07C5/41—Catalytic processes
- C07C5/415—Catalytic processes with metals
- C07C5/417—Catalytic processes with metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/60—Platinum group metals with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/324—Catalytic processes with metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/513,407 US5073662A (en) | 1990-04-23 | 1990-04-23 | Catalyst and process for dehydrogenation and dehydrocyclization |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO911576D0 NO911576D0 (no) | 1991-04-22 |
| NO911576L NO911576L (no) | 1991-10-24 |
| NO300489B1 true NO300489B1 (no) | 1997-06-09 |
Family
ID=24043134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO911576A NO300489B1 (no) | 1990-04-23 | 1991-04-22 | Katalysatorsammensetning og anvendelse av sammensetningen i en fremgangsmåte til dehydrogenering og/eller dehydrocyklisering av organiske forbindelser |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5073662A (da) |
| EP (1) | EP0454022B1 (da) |
| JP (1) | JP2577830B2 (da) |
| KR (1) | KR960006925B1 (da) |
| AR (1) | AR247348A1 (da) |
| AT (1) | ATE118471T1 (da) |
| AU (1) | AU632677B2 (da) |
| BR (1) | BR9101540A (da) |
| CA (1) | CA2033715C (da) |
| DE (1) | DE69107325T2 (da) |
| DK (1) | DK0454022T3 (da) |
| ES (1) | ES2068419T3 (da) |
| FI (1) | FI116290B (da) |
| GR (1) | GR3015729T3 (da) |
| MX (1) | MX167017B (da) |
| NO (1) | NO300489B1 (da) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5220091A (en) * | 1992-02-26 | 1993-06-15 | Phillips Petroleum Company | Alkane dehydrogenation |
| US5482615A (en) * | 1993-03-11 | 1996-01-09 | Exxon Research And Engineering Company | Noble metal/ZN-A1203 reforming catalysts with enhanced reforming performance (C-2714) |
| US5344805A (en) * | 1993-05-03 | 1994-09-06 | Phillips Petroleum Company | Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation |
| US5877369A (en) * | 1997-10-23 | 1999-03-02 | Phillips Petroleum Company | Hydrocarbon conversion catalyst composition and processes therefor and therewith |
| AU2001278449A1 (en) * | 2000-06-14 | 2001-12-24 | Basf Aktiengesellschaft | Method for producing acrolein and/or acrylic acid |
| UY28921A1 (es) * | 2004-05-28 | 2005-06-30 | Mintek | Catalizador y produccion y uso del mismo |
| WO2010069548A1 (de) * | 2008-12-18 | 2010-06-24 | Uhde Gmbh | Variation der zinnimprägnierung eines katalysators zur alkandehydrierung |
| AU2011258422C1 (en) | 2010-05-24 | 2017-03-30 | Lummus Technology Llc | Nanowire catalysts |
| EA029867B1 (ru) | 2011-05-24 | 2018-05-31 | Силурия Текнолоджиз, Инк. | Катализаторы для нефтехимического катализа |
| HK1202275A1 (en) | 2011-11-29 | 2015-09-25 | Siluria Technologies, Inc. | Nanowire catalysts and methods for their use and preparation |
| US9446397B2 (en) | 2012-02-03 | 2016-09-20 | Siluria Technologies, Inc. | Method for isolation of nanomaterials |
| US20140121433A1 (en) * | 2012-05-24 | 2014-05-01 | Siluria Technologies, Inc. | Catalytic forms and formulations |
| EP2712674A1 (en) * | 2012-09-27 | 2014-04-02 | Saudi Basic Industries Corporation | Catalyst composition for the dehydrogenation of alkanes |
| CA2902192C (en) | 2013-03-15 | 2021-12-07 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
| CA2947483C (en) | 2014-05-02 | 2023-08-01 | Siluria Technologies, Inc. | Heterogeneous catalysts |
| HUE054014T2 (hu) | 2014-09-17 | 2021-08-30 | Lummus Technology Inc | Katalizátorok metán oxidatív csatolására és etán oxidatív dehidrogenálására |
| WO2018053145A1 (en) * | 2016-09-16 | 2018-03-22 | Lummus Technology Inc. | Integrated propane dehydrogenation process |
| US11040338B2 (en) | 2016-12-06 | 2021-06-22 | Sabic Global Technologies B.V. | Process of preparing catalyst; platinum-tin on zinc aluminate-calcium aluminate-zeolite catalyst for selective light alkane dehydrogenation |
| AU2020215051B2 (en) | 2019-01-30 | 2026-02-05 | Lummus Technology Llc | Catalysts for oxidative coupling of methane |
| US11654420B2 (en) | 2020-07-03 | 2023-05-23 | Council Of Scientific & Industrial Research | Process and catalyst for low temperature non-oxidative dehydrogenation of propane to propylene |
| WO2022138746A1 (ja) * | 2020-12-24 | 2022-06-30 | Ｅｎｅｏｓ株式会社 | シクロペンタジエンの製造方法 |
| BR112023025118A2 (pt) | 2021-06-02 | 2024-02-20 | Exxonmobil Chemical Patents Inc | Processos para regeneração de catalisadores e para aperfeiçoamento de alcanos e/ou hidrocarbonetos alquil aromáticos |
| KR20260030166A (ko) | 2023-07-10 | 2026-03-05 | 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 | 촉매를 재생 및 환원하고 알칸 및/또는 알킬 방향족 탄화수소를 고도화하기 위한 공정 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3461183A (en) * | 1967-11-08 | 1969-08-12 | Phillips Petroleum Co | Catalytic dehydrogenation process |
| US3880776A (en) * | 1971-06-10 | 1975-04-29 | Phillips Petroleum Co | Highly calcined support for catalytic dehydrogenation |
| US4229602A (en) * | 1978-12-04 | 1980-10-21 | Phillips Petroleum Company | Dehydrocyclization process |
| US4902849A (en) * | 1989-02-06 | 1990-02-20 | Phillips Petroleum Company | Dehydrogenation process |
| US4926005A (en) * | 1989-05-17 | 1990-05-15 | Phillips Petroleum Company | Dehydrogenation process |
-
1990
- 1990-04-23 US US07/513,407 patent/US5073662A/en not_active Expired - Lifetime
-
1991
- 1991-01-07 CA CA002033715A patent/CA2033715C/en not_active Expired - Fee Related
- 1991-03-28 AU AU73917/91A patent/AU632677B2/en not_active Expired
- 1991-04-17 BR BR919101540A patent/BR9101540A/pt not_active IP Right Cessation
- 1991-04-17 KR KR1019910006157A patent/KR960006925B1/ko not_active Expired - Lifetime
- 1991-04-17 MX MX025391A patent/MX167017B/es unknown
- 1991-04-18 JP JP3086466A patent/JP2577830B2/ja not_active Expired - Lifetime
- 1991-04-19 AR AR91319497A patent/AR247348A1/es active
- 1991-04-22 FI FI911947A patent/FI116290B/fi not_active IP Right Cessation
- 1991-04-22 ES ES91106432T patent/ES2068419T3/es not_active Expired - Lifetime
- 1991-04-22 EP EP91106432A patent/EP0454022B1/en not_active Expired - Lifetime
- 1991-04-22 AT AT91106432T patent/ATE118471T1/de not_active IP Right Cessation
- 1991-04-22 NO NO911576A patent/NO300489B1/no not_active IP Right Cessation
- 1991-04-22 DK DK91106432.7T patent/DK0454022T3/da active
- 1991-04-22 DE DE69107325T patent/DE69107325T2/de not_active Expired - Lifetime
-
1995
- 1995-04-10 GR GR950400862T patent/GR3015729T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX167017B (es) | 1993-02-22 |
| KR910018077A (ko) | 1991-11-30 |
| AR247348A1 (es) | 1994-12-29 |
| DE69107325T2 (de) | 1995-06-14 |
| JPH04225835A (ja) | 1992-08-14 |
| EP0454022A1 (en) | 1991-10-30 |
| DK0454022T3 (da) | 1995-04-10 |
| CA2033715C (en) | 2000-08-08 |
| JP2577830B2 (ja) | 1997-02-05 |
| EP0454022B1 (en) | 1995-02-15 |
| NO911576L (no) | 1991-10-24 |
| KR960006925B1 (ko) | 1996-05-25 |
| US5073662A (en) | 1991-12-17 |
| FI911947A0 (fi) | 1991-04-22 |
| GR3015729T3 (en) | 1995-07-31 |
| AU7391791A (en) | 1992-01-02 |
| NO911576D0 (no) | 1991-04-22 |
| ATE118471T1 (de) | 1995-03-15 |
| FI116290B (fi) | 2005-10-31 |
| DE69107325D1 (de) | 1995-03-23 |
| FI911947L (fi) | 1991-10-24 |
| CA2033715A1 (en) | 1991-10-24 |
| AU632677B2 (en) | 1993-01-07 |
| BR9101540A (pt) | 1991-12-10 |
| ES2068419T3 (es) | 1995-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO300489B1 (no) | Katalysatorsammensetning og anvendelse av sammensetningen i en fremgangsmåte til dehydrogenering og/eller dehydrocyklisering av organiske forbindelser | |
| US10894752B2 (en) | Catalyst and method for aromatization of C3-C4 gases, light hydrocarbon fractions and aliphatic alcohols, as well as mixtures thereof | |
| US10486140B2 (en) | Catalytic composition and process for the dehydrogenation of butenes or mixtures of butanes and butenes to give 1,3-butadiene | |
| EP0345950B1 (en) | Hydrocarbon dehydrogenation process using a combination of isothermal and adiabatic dehydrogenation steps | |
| CN101511756A (zh) | 制备邻二甲苯的方法 | |
| EP0361767B1 (en) | Process for the conversion of a c2-c6 aliphatic hydrocarbon into naphthenic hydrocarbons | |
| US5143888A (en) | Group VIII catalyst supported on mixture of zinc aluminate and calcium aluminate | |
| US5436383A (en) | Process for the dehydrogenation of aliphatic hydrocarbons saturated into olefinic hydrocarbons | |
| CN101765576B (zh) | 用于烷烃脱氢的催化剂的再生 | |
| US4513162A (en) | Dehydrogenation process | |
| AU2003255444B2 (en) | Isothermal method for dehydrogenating alkanes | |
| CN113710634B (zh) | 通过催化部分氧化和裂化生产合成气和烯烃的集成间接热传递方法 | |
| US20050228204A1 (en) | Process for the preparation of xylene | |
| US20050228203A1 (en) | Process for the preparation of xylene | |
| CN101103095A (zh) | 通过自热裂化生产烯烃的方法 | |
| US20250129303A1 (en) | Process and Plant for Producing One or More Hydrocarbons | |
| US20140371503A1 (en) | Single stage reactor system with oxidative preheat for dehydrogenation of hydrocarbons | |
| US20250346545A1 (en) | Combining oxidative coupling of methane with adiabatic thermal cracking (pyrolysis) reactor | |
| US20180118638A1 (en) | Use of membrane for oxidative-dehydrogenation process | |
| US10221110B2 (en) | Dehydrogenation of olefin-rich hydrocarbon mixtures | |
| WO2025132459A1 (en) | Methyl tert-butyl ether synthesis method with integraged feed pre-processing | |
| WO2023287606A2 (en) | Method and system for light olefin generation with high yields and selectivity | |
| HK1237707B (en) | Process for the dehydrogenation of butenes or mixtures of butanes and butenes to give 1,3-butadiene |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK1K | Patent expired |