CA2033715A1 - Catalyst and Process for Dehydrogenation and Dehydrocyclization - Google Patents

Catalyst and Process for Dehydrogenation and Dehydrocyclization

Info

Publication number
CA2033715A1
CA2033715A1 CA2033715A CA2033715A CA2033715A1 CA 2033715 A1 CA2033715 A1 CA 2033715A1 CA 2033715 A CA2033715 A CA 2033715A CA 2033715 A CA2033715 A CA 2033715A CA 2033715 A1 CA2033715 A1 CA 2033715A1
Authority
CA
Canada
Prior art keywords
catalyst
dehydrogenation
dehydrocyclization
improving
catalyst composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2033715A
Other languages
French (fr)
Other versions
CA2033715C (en
Inventor
Michael E. Olbrich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Industrial Solutions AG
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of CA2033715A1 publication Critical patent/CA2033715A1/en
Application granted granted Critical
Publication of CA2033715C publication Critical patent/CA2033715C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C07C5/417—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

A method for improving the activity of a dehydrogenation and dehydrocyclization catalyst composition and a process for improving the conversion and selectivity of paraffin hydrocarbons to olefin and aromatic compounds. The novel processes comprise adding calcium aluminate to a catalyst composition comprising a zinc aluminate support and a catalyst metal, and optionally a promoter metal.
CA002033715A 1990-04-23 1991-01-07 Catalyst and process for dehydrogenation and dehydrocyclization Expired - Fee Related CA2033715C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/513,407 1990-04-23
US07/513,407 US5073662A (en) 1990-04-23 1990-04-23 Catalyst and process for dehydrogenation and dehydrocyclization

Publications (2)

Publication Number Publication Date
CA2033715A1 true CA2033715A1 (en) 1991-10-24
CA2033715C CA2033715C (en) 2000-08-08

Family

ID=24043134

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002033715A Expired - Fee Related CA2033715C (en) 1990-04-23 1991-01-07 Catalyst and process for dehydrogenation and dehydrocyclization

Country Status (16)

Country Link
US (1) US5073662A (en)
EP (1) EP0454022B1 (en)
JP (1) JP2577830B2 (en)
KR (1) KR960006925B1 (en)
AR (1) AR247348A1 (en)
AT (1) ATE118471T1 (en)
AU (1) AU632677B2 (en)
BR (1) BR9101540A (en)
CA (1) CA2033715C (en)
DE (1) DE69107325T2 (en)
DK (1) DK0454022T3 (en)
ES (1) ES2068419T3 (en)
FI (1) FI116290B (en)
GR (1) GR3015729T3 (en)
MX (1) MX167017B (en)
NO (1) NO300489B1 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5220091A (en) * 1992-02-26 1993-06-15 Phillips Petroleum Company Alkane dehydrogenation
US5482615A (en) * 1993-03-11 1996-01-09 Exxon Research And Engineering Company Noble metal/ZN-A1203 reforming catalysts with enhanced reforming performance (C-2714)
US5344805A (en) * 1993-05-03 1994-09-06 Phillips Petroleum Company Platinum and tin-containing catalyst and use thereof in alkane dehydrogenation
US5877369A (en) * 1997-10-23 1999-03-02 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
JP5021140B2 (en) * 2000-06-14 2012-09-05 ビーエーエスエフ ソシエタス・ヨーロピア Method for producing acrolein and / or acrylic acid
AR051171A1 (en) * 2004-05-28 2006-12-27 Mintek A CATALYST THAT INCLUDES GOLD ON A VEHICLE AND METHOD TO PREPARE SUCH CATALYST
US20110301392A1 (en) * 2008-12-18 2011-12-08 Uhde Gmbh Variation of tin impregnation of a catalyst for alkane dehydrogenation
WO2011149996A2 (en) 2010-05-24 2011-12-01 Siluria Technologies, Inc. Nanowire catalysts
EP3702028A1 (en) 2011-05-24 2020-09-02 Siluria Technologies, Inc. Catalysts for petrochemical catalysis
US20130158322A1 (en) 2011-11-29 2013-06-20 Siluria Technologies, Inc. Polymer templated nanowire catalysts
US9446397B2 (en) 2012-02-03 2016-09-20 Siluria Technologies, Inc. Method for isolation of nanomaterials
EP2855011A2 (en) 2012-05-24 2015-04-08 Siluria Technologies, Inc. Catalytic forms and formulations
EP2712674A1 (en) * 2012-09-27 2014-04-02 Saudi Basic Industries Corporation Catalyst composition for the dehydrogenation of alkanes
WO2014143880A1 (en) 2013-03-15 2014-09-18 Siluria Technologies, Inc. Catalysts for petrochemical catalysis
EP3137211A2 (en) 2014-05-02 2017-03-08 Siluria Technologies, Inc. Heterogeneous catalysts
AU2015317805B2 (en) 2014-09-17 2019-11-14 Lummus Technology Llc Catalysts for oxidative coupling of methane and oxidative dehydrogenation of ethane
WO2018053145A1 (en) * 2016-09-16 2018-03-22 Lummus Technology Inc. Integrated propane dehydrogenation process
US11040338B2 (en) 2016-12-06 2021-06-22 Sabic Global Technologies B.V. Process of preparing catalyst; platinum-tin on zinc aluminate-calcium aluminate-zeolite catalyst for selective light alkane dehydrogenation
US11654420B2 (en) 2020-07-03 2023-05-23 Council Of Scientific & Industrial Research Process and catalyst for low temperature non-oxidative dehydrogenation of propane to propylene
JPWO2022138746A1 (en) * 2020-12-24 2022-06-30
BR112023025118A2 (en) 2021-06-02 2024-02-20 Exxonmobil Chemical Patents Inc PROCESSES FOR REGENERATION OF CATALYSTS AND FOR IMPROVEMENT OF ALKANES AND/OR AROMATIC ALKYL HYDROCARBONS
WO2025014577A1 (en) 2023-07-10 2025-01-16 ExxonMobil Technology and Engineering Company Processes for regenerating and reducing catalysts and for upgrading alkanes and/or alkyl aromatic hydrocarbons

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3461183A (en) * 1967-11-08 1969-08-12 Phillips Petroleum Co Catalytic dehydrogenation process
US3880776A (en) * 1971-06-10 1975-04-29 Phillips Petroleum Co Highly calcined support for catalytic dehydrogenation
US4229602A (en) * 1978-12-04 1980-10-21 Phillips Petroleum Company Dehydrocyclization process
US4902849A (en) * 1989-02-06 1990-02-20 Phillips Petroleum Company Dehydrogenation process
US4926005A (en) * 1989-05-17 1990-05-15 Phillips Petroleum Company Dehydrogenation process

Also Published As

Publication number Publication date
JP2577830B2 (en) 1997-02-05
FI911947A0 (en) 1991-04-22
ES2068419T3 (en) 1995-04-16
EP0454022B1 (en) 1995-02-15
GR3015729T3 (en) 1995-07-31
ATE118471T1 (en) 1995-03-15
AR247348A1 (en) 1994-12-29
JPH04225835A (en) 1992-08-14
NO911576L (en) 1991-10-24
CA2033715C (en) 2000-08-08
NO300489B1 (en) 1997-06-09
DK0454022T3 (en) 1995-04-10
NO911576D0 (en) 1991-04-22
AU632677B2 (en) 1993-01-07
DE69107325T2 (en) 1995-06-14
FI911947L (en) 1991-10-24
BR9101540A (en) 1991-12-10
US5073662A (en) 1991-12-17
DE69107325D1 (en) 1995-03-23
FI116290B (en) 2005-10-31
KR910018077A (en) 1991-11-30
EP0454022A1 (en) 1991-10-30
MX167017B (en) 1993-02-22
KR960006925B1 (en) 1996-05-25
AU7391791A (en) 1992-01-02

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Effective date: 20070108