NO179236C - Sammensetning for bruk i omdannelse av syntesegass, fremgangsmåte for fremstilling av sammensetningen samt anvendelse derav - Google Patents

Sammensetning for bruk i omdannelse av syntesegass, fremgangsmåte for fremstilling av sammensetningen samt anvendelse derav

Info

Publication number
NO179236C
NO179236C NO873958A NO873958A NO179236C NO 179236 C NO179236 C NO 179236C NO 873958 A NO873958 A NO 873958A NO 873958 A NO873958 A NO 873958A NO 179236 C NO179236 C NO 179236C
Authority
NO
Norway
Prior art keywords
composition
preparing
synthesis gas
gas conversion
conversion
Prior art date
Application number
NO873958A
Other languages
English (en)
Other versions
NO873958D0 (no
NO179236B (no
NO873958L (no
Inventor
Colin Hugh Mcateer
Original Assignee
British Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Petroleum Co filed Critical British Petroleum Co
Publication of NO873958D0 publication Critical patent/NO873958D0/no
Publication of NO873958L publication Critical patent/NO873958L/no
Publication of NO179236B publication Critical patent/NO179236B/no
Publication of NO179236C publication Critical patent/NO179236C/no

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8953Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425Catalysts; their physical properties
    • C07C1/043Catalysts; their physical properties characterised by the composition
    • C07C1/0435Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/30Tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42Platinum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44Palladium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46Ruthenium, rhodium, osmium or iridium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/745Iron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/75Cobalt
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/755Nickel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
NO873958A 1986-09-26 1987-09-22 Sammensetning for bruk i omdannelse av syntesegass, fremgangsmåte for fremstilling av sammensetningen samt anvendelse derav NO179236C (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB868623233A GB8623233D0 (en) 1986-09-26 1986-09-26 Syngas conversion catalyst

Publications (4)

Publication Number Publication Date
NO873958D0 NO873958D0 (no) 1987-09-22
NO873958L NO873958L (no) 1988-03-28
NO179236B NO179236B (no) 1996-05-28
NO179236C true NO179236C (no) 1996-09-04

Family

ID=10604863

Family Applications (1)

Application Number Title Priority Date Filing Date
NO873958A NO179236C (no) 1986-09-26 1987-09-22 Sammensetning for bruk i omdannelse av syntesegass, fremgangsmåte for fremstilling av sammensetningen samt anvendelse derav

Country Status (11)

Country Link
US (2) US4826800A (no)
EP (1) EP0261870B1 (no)
JP (1) JP2573965B2 (no)
CN (2) CN1013645B (no)
AU (1) AU605506B2 (no)
CA (1) CA1307782C (no)
DE (1) DE3764754D1 (no)
GB (1) GB8623233D0 (no)
NO (1) NO179236C (no)
NZ (1) NZ221823A (no)
ZA (1) ZA877162B (no)

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US4801573A (en) * 1987-10-23 1989-01-31 501 Den Norske Stats Oljeslenskap A.S. Catalyst for production of hydrocarbons
US5109027A (en) * 1989-06-13 1992-04-28 Amoco Corporation Catalytic process for producing olefins or higher alcohols from synthesis gas
EP0554348B1 (en) * 1990-10-15 1998-06-03 Exxon Research And Engineering Company Method for preparing cobalt-containing hydrocarbon synthesis catalyst
US5168091A (en) * 1990-10-15 1992-12-01 Exxon Research And Engineering Company Activation conditions to maximize the HSC activity of supported cobalt catalysts
GB9114314D0 (en) * 1991-07-02 1991-08-21 British Petroleum Co Plc Catalyst treatment for fisher-tropsch process
GB9225372D0 (en) * 1992-12-04 1993-01-27 British Petroleum Co Plc Oxide compositions
US5811365A (en) * 1992-12-04 1998-09-22 The British Petroleum Company, P.L.C. Zinc oxide composition for use in catalysts
US5939350A (en) * 1997-02-10 1999-08-17 Energy International Corporation Processes and catalysts for conducting fischer-tropsch synthesis in a slurry bubble column reactor
US6191066B1 (en) 1998-05-27 2001-02-20 Energy International Corporation Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts
US6262132B1 (en) * 1999-05-21 2001-07-17 Energy International Corporation Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems
US6100304A (en) * 1999-05-26 2000-08-08 Energy International Corportion Processes and palladium-promoted catalysts for conducting Fischer-Tropsch synthesis
US6184176B1 (en) * 1999-08-25 2001-02-06 Phillips Petroleum Company Process for the production of a sulfur sorbent
US6313062B1 (en) * 1999-10-29 2001-11-06 Exxon Reserach And Engineering Company Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst composition, use of the catalysts for conducting such reactions, and the products of such reactions
US6573413B2 (en) 2000-04-19 2003-06-03 Solutia Inc. Process for activating catalyst for the hydroxylation of aromatics
GB0023781D0 (en) * 2000-09-28 2000-11-08 Kvaerner Process Tech Ltd Process
GB0112796D0 (en) * 2001-05-25 2001-07-18 Bp Exploration Operating Process
GB0112791D0 (en) 2001-05-25 2001-07-18 Bp Exploration Operating Process
GB0126643D0 (en) 2001-11-06 2002-01-02 Bp Exploration Operating Composition and process
GB0203058D0 (en) 2002-02-09 2002-03-27 Bp Chem Int Ltd Production of olefins
US6713657B2 (en) * 2002-04-04 2004-03-30 Chevron U.S.A. Inc. Condensation of olefins in fischer tropsch tail gas
EP1358934A1 (en) * 2002-04-25 2003-11-05 Engelhard Corporation Fischer-Tropsch catalyst
US7422995B2 (en) * 2004-04-30 2008-09-09 Basf Catalysts Llc Process for the preparation of a supported catalyst
US7361626B2 (en) 2004-04-30 2008-04-22 Engelhard Corporation Supported catalyst
US7846977B2 (en) * 2004-04-30 2010-12-07 Basf Corporation Processes using a supported catalyst
GB0409901D0 (en) * 2004-05-04 2004-06-09 Johnson Matthey Plc Catalysts
TWI294413B (en) * 2004-11-19 2008-03-11 Ind Tech Res Inst Method for converting co and hydrogen into methane and water
CN100374200C (zh) * 2005-07-27 2008-03-12 新奥新能(北京)科技有限公司 一种合成气转化催化剂及其制备方法
ES2374573T3 (es) * 2005-10-25 2012-02-20 Bp Exploration Operating Company Limited Procedimiento de fischer-tropsch.
ES2344752T3 (es) * 2005-12-19 2010-09-06 Bp Exploration Operating Company Limited Proceso para producir producto de fase condensada a partir de uno o mas reactivos de fase de gas.
EP1852182A1 (en) * 2006-05-01 2007-11-07 Engelhard Corporation Fischer-Tropsch Catalyst comprising cobalt and zinc oxide
EP1946835A1 (en) * 2006-12-19 2008-07-23 Bp Exploration Operating Company Limited Fischer-Tropsch catalyst
EP1935964A1 (en) * 2006-12-19 2008-06-25 Bp Exploration Operating Company Limited Fischer-Tropsch catalyst
EP2008714A1 (en) * 2007-06-19 2008-12-31 BASF Catalysts LLC Process for the preparation of a cobalt-zinc oxide Fischer-Tropsch catalyst
US20090156393A1 (en) * 2007-12-14 2009-06-18 Range Fuels, Inc. Catalyst compositions and methods for alcohol production from synthesis gas
EP2090363A1 (en) * 2008-02-05 2009-08-19 Basf Se Fischer-Tropsch catalyst containing cobalt on Zinc oxide support doped with either Alumina or Zirconia
EP2530125A1 (en) 2011-05-30 2012-12-05 Total SA Core-shell particles with catalytic activity
FR2984347B1 (fr) 2011-12-14 2015-03-20 IFP Energies Nouvelles Procede de fabrication d'hydrocarbures avec conditionnement du catalyseur
US9006297B2 (en) 2012-06-16 2015-04-14 Robert P. Herrmann Fischer tropsch method for offshore production risers for oil and gas wells
WO2016091694A1 (en) 2014-12-12 2016-06-16 Bp P.L.C. Process for producing a supported, partially reductively activated fischer-tropsch synthesis catalyst, and process for producing hydrocarbons using the same
WO2016091692A1 (en) 2014-12-12 2016-06-16 Bp P.L.C. Process for producing a supported reductively activated fischer-tropsch synthesis catalyst, and process for producing hydrocarbons using the same
WO2016091691A1 (en) 2014-12-12 2016-06-16 Bp P.L.C. Fischer-tropsch process using supported reduced cobalt catalyst
GB201702248D0 (en) 2017-02-10 2017-03-29 Bp Plc Start-up procedure for a fischer-tropsch process
WO2021139898A1 (en) 2020-01-10 2021-07-15 Bp P.L.C. Process for producing a fischer-tropsch synthesis catalyst and fischer-tropsch start-up process

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US3997582A (en) * 1975-12-08 1976-12-14 Battelle Development Corporation Process and catalyst for synthesizing a gaseous hydrocarbon mixture having a high methane content from carbon monoxide and hydrogen
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DE2625541A1 (de) * 1976-06-05 1977-12-22 Basf Ag Verfahren zur herstellung einer zink und nickel oder kobalt enthaltenden kontaktmasse
NL7612460A (nl) * 1976-11-10 1978-05-12 Shell Int Research Werkwijze voor de bereiding van koolwater- stoffen.
NL7805494A (nl) * 1978-05-22 1979-11-26 Shell Int Research Kwaliteitsverbetering van fischer-tropsch produkten.
FR2496095B1 (fr) * 1980-12-15 1985-11-15 Shell Int Research Procede de preparation d'un melange hydrocarbone a partir d'un melange h2/co
US4301077A (en) * 1980-12-22 1981-11-17 Standard Oil Company Process for the manufacture of 1-4-butanediol and tetrahydrofuran
DE3365659D1 (en) * 1982-08-02 1986-10-02 Shell Int Research Process for the preparation of hydrocarbons
US4423265A (en) * 1982-12-01 1983-12-27 Mobil Oil Corporation Process for snygas conversions to liquid hydrocarbon products
US4500417A (en) * 1982-12-28 1985-02-19 Mobil Oil Corporation Conversion of Fischer-Tropsch products
IN161735B (no) * 1983-09-12 1988-01-30 Shell Int Research
NL8400609A (nl) * 1984-02-28 1985-09-16 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
US4520215A (en) * 1984-04-16 1985-05-28 Mobil Oil Corporation Catalytic conversion of olefinic Fischer-Tropsch light oil to heavier hydrocarbons
US4595703A (en) * 1984-06-29 1986-06-17 Exxon Research And Engineering Co. Preparation of hydrocarbons from synthesis gas
US4599481A (en) * 1984-09-13 1986-07-08 Shell Oil Company Process for the preparation of hydrocarbons
US4544792A (en) * 1984-12-13 1985-10-01 Mobil Oil Corporation Upgrading Fischer-Tropsch olefins

Also Published As

Publication number Publication date
CN1052844A (zh) 1991-07-10
US4826800A (en) 1989-05-02
NO873958D0 (no) 1987-09-22
CN1026098C (zh) 1994-10-05
AU7848887A (en) 1988-03-31
GB8623233D0 (en) 1986-10-29
US5023277A (en) 1991-06-11
NO179236B (no) 1996-05-28
NO873958L (no) 1988-03-28
CA1307782C (en) 1992-09-22
ZA877162B (en) 1989-05-30
JPS63141644A (ja) 1988-06-14
JP2573965B2 (ja) 1997-01-22
EP0261870A1 (en) 1988-03-30
AU605506B2 (en) 1991-01-17
NZ221823A (en) 1990-08-28
CN1013645B (zh) 1991-08-28
CN87106596A (zh) 1988-04-13
DE3764754D1 (de) 1990-10-11
EP0261870B1 (en) 1990-09-05

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