NO142531B - WATER-FREE HANDWASH WASTE. - Google Patents

WATER-FREE HANDWASH WASTE. Download PDF

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Publication number
NO142531B
NO142531B NO753437A NO753437A NO142531B NO 142531 B NO142531 B NO 142531B NO 753437 A NO753437 A NO 753437A NO 753437 A NO753437 A NO 753437A NO 142531 B NO142531 B NO 142531B
Authority
NO
Norway
Prior art keywords
mixture
water
paste
silicone oil
free
Prior art date
Application number
NO753437A
Other languages
Norwegian (no)
Other versions
NO753437L (en
NO142531C (en
Inventor
Hans Wallrath
Original Assignee
Thomae Gmbh Dr K
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19742448716 external-priority patent/DE2448716C3/en
Application filed by Thomae Gmbh Dr K filed Critical Thomae Gmbh Dr K
Publication of NO753437L publication Critical patent/NO753437L/no
Publication of NO142531B publication Critical patent/NO142531B/en
Publication of NO142531C publication Critical patent/NO142531C/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11Encapsulated compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22Peroxides; Oxygen; Ozone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039Coated compositions or coated components in the compositions, (micro)capsules
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0042Reducing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/14Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3942Inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3947Liquid compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41Particular ingredients further characterized by their size
    • A61K2800/412Microsized, i.e. having sizes between 0.1 and 100 microns

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Devices For Medical Bathing And Washing (AREA)

Description

Oppfinnelsen vedrører en ny håndvaskepasta som fortrinnsvis er egnet til fjerning av farveflekker. Håndvaskepastaen i henhold til oppfinnelsen er vannfri og inneholder fuktemidler, reduserende midler og et vannfritt oksydasjonsmiddel, og den er karakterisert ved at pastaen som oksydasjonsmiddel inneholder 5-15 vekt% av et natriumperborat som er overtrukket med silikonolje i et vektforhold mellom perborat og silikonolje lik 2:1 The invention relates to a new hand washing paste which is preferably suitable for removing color stains. The hand washing paste according to the invention is water-free and contains wetting agents, reducing agents and an anhydrous oxidizing agent, and it is characterized in that the paste as oxidizing agent contains 5-15% by weight of a sodium perborate which is coated with silicone oil in a weight ratio between perborate and silicone oil equal to 2 :1

til 4:1. to 4:1.

I det tyske patentskrift 1 031 450 beskrives for første gang en håndvaskepasta ved hvilken fuktemidlet dannes først i an-vendelsesøyeblikket. Ved denne innarbeides den syre som ligger til grunn for den vaskeaktive substans, på enkel måte i en oljefase på grunn av dens oljeløselighet. Eksempelvis lar den syre som opp-nås på grunn av en kondensasjon av fettsyre med sarkosin, seg innarbeide i en naturlig planteolje, f.eks. ricinusolje, hvorved det også kan tilsettes metallsåper for konsistensforbedring. I denne grunnmasse lar det seg så innarbeide en blanding av soda, natriumditionitt og pimpstenpulver. Disse uorganiske grunnstoffer om- German patent document 1 031 450 describes for the first time a hand washing paste in which the wetting agent is only formed at the moment of use. With this, the acid which forms the basis of the detergent active substance is simply incorporated into an oil phase due to its oil solubility. For example, the acid obtained due to a condensation of fatty acid with sarcosine can be incorporated into a natural plant oil, e.g. castor oil, whereby metal soaps can also be added to improve consistency. A mixture of soda, sodium dithionite and pumice powder can then be incorporated into this base material. These inorganic elements re-

gis av oljefasen på en slik måte at det ikke er mulig med en reak-sjon med syren under saltdannelse. Selv små vannmengder emulge-res på en slik måte at heller ikke de bevirker noen for tidlig inntreden av reaksjonen. Når denne pasta smøres på hendene og vann tilsettes, så setter først nøytralisasjonsprosessen inn under dannelse av det virksomme fuktemiddel og også utvikling av svoveldioksyd. is given by the oil phase in such a way that a reaction with the acid during salt formation is not possible. Even small amounts of water are emulsified in such a way that they also do not cause any premature onset of the reaction. When this paste is smeared on the hands and water is added, the neutralization process first sets in with the formation of the effective moisturizer and also the evolution of sulfur dioxide.

Det ble nå overraskende funnet at den blekende og således den rensende virkning av en vaskepasta av lignende sammensett ning som beskrevet i det tyske patentskrift 1 031 460, som eksempelvis inneholder butylglykol, lauriditt, emulan, heksylenglykol, furunålsolje, lanolin, trietanolamin, talkum, aerosil, pimpstenmel og et vannfritt reduksjonsmiddel, f.eks. natriumditionitt, vesentlig økes ved at det samtidig blandes inn granulert, med silikonolje overtrukket natriumperborat som oksydasjonsmiddel. It was now surprisingly found that the bleaching and thus the cleansing effect of a washing paste of a similar composition as described in German patent document 1 031 460, which for example contains butyl glycol, lauridite, emulan, hexylene glycol, pine needle oil, lanolin, triethanolamine, talc, aerosil , pumice stone flour and an anhydrous reducing agent, e.g. sodium dithionite, is significantly increased by simultaneously mixing in granulated sodium perborate coated with silicone oil as an oxidizing agent.

Natriumperborat-granulatet har fortrinnsvis en partik-kelstørrelse som tilsvarer den anvendte pimpsten og ligger i stør-relsesområdet 30-60^,um (DIN-norm ca. G 1/2) . Det er nødvendig å blande dette natriumperborat-granulat først med silikonolje, hvorved vekt-forholdet mellom natriumperborat og silikonolje kan svinge mellom 2:1 og 4:1. Denne blanding blandes så godt med den annen blanding som består av et vannfritt fuktemiddel, et reduksjonsmiddel og de øvrige, ovenfor angitte bestanddeler. Som reduksjonsmiddel egner seg f.eks. brenzkatekin, natriumsulfitt eller- bisulfitt, men sær-lig natriumditionitt. The sodium perborate granules preferably have a particle size that corresponds to the pumice stone used and is in the size range 30-60 µm (DIN standard approx. G 1/2). It is necessary to mix this sodium perborate granulate first with silicone oil, whereby the weight ratio between sodium perborate and silicone oil can fluctuate between 2:1 and 4:1. This mixture is then mixed well with the other mixture which consists of an anhydrous wetting agent, a reducing agent and the other, above stated components. As a reducing agent, e.g. brenzcatechin, sodium sulphite or bisulphite, but especially sodium dithionite.

I den således fremstilte pasta kan reduksjonsmidlet ikke reagere med oksydasjonsmidlet natriumperborat, denne pasta kan lag-res ubegrenset, og den taper heller ikke etter lang lagringstid sine reduserende og oksyderende egenskaper. Hvis denne pasta benyttes til vask, så trer først den reduserende og, forsinket i tid i for-hold til denne, den oksyderende virkning i forgrunnen. In the paste thus prepared, the reducing agent cannot react with the oxidizing agent sodium perborate, this paste can be stored indefinitely, and it does not lose its reducing and oxidizing properties after a long storage period either. If this paste is used for washing, first the reducing and, delayed in time in relation to this, the oxidizing effect come to the fore.

Det var å vente at reduksjonsmidlet ved vaskeprosessen, på grunn av vannets oppløsende virkning, forsterket av fuktemidlets virkning, i første linje ville reagere med oksydasjonsmidlet, hvorved begge stoffer da gjensidig ville nøytralisere seg og dermed bortfalle for den rensende, respektive blekende virkning på hudet eller vevet. Det har imidlertid faktisk vist seg at ved vaskeprosessen innvirker reduksjonsmidlet først på gjenstanden som skal renses og at først senere, f.eks. etter 2 til 5 minutter, også oksy-das jonsmidlet blir helt virksomt. It was to be expected that the reducing agent during the washing process, due to the water's dissolving effect, reinforced by the moisturizing agent's effect, would primarily react with the oxidizing agent, whereby both substances would then mutually neutralize each other and thus lose their cleansing, respective whitening effect on the skin or the tissue. However, it has actually been shown that during the washing process the reducing agent first acts on the object to be cleaned and that only later, e.g. after 2 to 5 minutes, the oxidizing agent also becomes fully effective.

Denne dobbelte renseeffekt ved vaskepastaen i henhold This double cleaning effect of the washing paste according to

til oppfinnelsen er av stor betydning, f.eks. ved fjerning av smuss-flekker som samtidig inneholder farvestoffer som bare kan blekes reduktivt eller oksydativt. until the invention is of great importance, e.g. when removing dirt stains that also contain dyes that can only be bleached reductively or oxidatively.

Eksempel 1 Example 1

72,0 kg granulert natriumperborat innrøres i 25,0 kg silikonolje 2000 (blanding I). 28,48 kg butylglykol, 128,55 kg lauriditt VD, 31,0 kg emulan, 8,02 kg furunålsolje, 40,41 kg heksylenglykol, 196,84 kg talkum, 5,0 kg aerosil, 15,04 kg lanolin, 72.0 kg of granulated sodium perborate is stirred into 25.0 kg of silicone oil 2000 (mixture I). 28.48 kg butyl glycol, 128.55 kg lauridite VD, 31.0 kg emulan, 8.02 kg pine needle oil, 40.41 kg hexylene glycol, 196.84 kg talc, 5.0 kg aerosil, 15.04 kg lanolin,

27,5 kg trietanolamin, 94,0 kg natriumditionitt og 158,07 kg pimpstenmel G 1/2 blandes intenst med hverandre (blanding II). 27.5 kg of triethanolamine, 94.0 kg of sodium dithionite and 158.07 kg of pumice stone flour G 1/2 are intensively mixed with each other (mixture II).

Blanding I has ned i blanding II og alt blandes godt. Eksempel 2 Mixture I is poured into mixture II and everything is mixed well. Example 2

6,1 kg natriumperborat granuleres koldt med 2,9 kg silikonolje 2000 (blanding I). 21,0 kg ricinusolje, 8,5 kg fettsyre/- sarkosin-kondensasjonsprodukt, 4,0 kg aluminiumpalmitat og 2,0 kg heksylenglykol blandes med hverandre (blanding II). Samtidig frem-stilles en blanding av 6,9 kg kalsinert soda, 15,0 kg natriumditionitt og 33,5 kg pimpstenmel (blanding III). 6.1 kg of sodium perborate is granulated cold with 2.9 kg of silicone oil 2000 (mixture I). 21.0 kg of castor oil, 8.5 kg of fatty acid/sarcosine condensation product, 4.0 kg of aluminum palmitate and 2.0 kg of hexylene glycol are mixed together (mixture II). At the same time, a mixture of 6.9 kg of soda ash, 15.0 kg of sodium dithionite and 33.5 kg of pumice stone flour is prepared (mixture III).

Blanding III blandes koldt med blanding II, og der-etter has blanding I inn i blanding II + III. Mixture III is mixed cold with mixture II, and then mixture I is mixed into mixture II + III.

Claims (1)

Vannfri håndvaskepasta som inneholder fuktemidler, reduserende midler og et vannfritt oksydasjonsmiddel, karakterisert ved at pastaen som oksydasjonsmiddel inneholder 5-15 vekt% av et natriumperborat som er overtrukket med silikonolje i et vektforhold mellom perborat og silikonolje lik 2:1 til 4:1.Water-free hand washing paste containing wetting agents, reducing agents and an anhydrous oxidizing agent, characterized in that the paste as oxidizing agent contains 5-15% by weight of a sodium perborate which is coated with silicone oil in a weight ratio between perborate and silicone oil equal to 2:1 to 4:1.
NO753437A 1974-10-12 1975-10-10 WATER-FREE HANDWASH WASTE. NO142531C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19742448716 DE2448716C3 (en) 1974-10-12 Hand washing paste

Publications (3)

Publication Number Publication Date
NO753437L NO753437L (en) 1976-04-13
NO142531B true NO142531B (en) 1980-05-27
NO142531C NO142531C (en) 1980-09-03

Family

ID=5928167

Family Applications (1)

Application Number Title Priority Date Filing Date
NO753437A NO142531C (en) 1974-10-12 1975-10-10 WATER-FREE HANDWASH WASTE.

Country Status (14)

Country Link
AT (1) AT342173B (en)
BE (1) BE834410A (en)
CH (1) CH616702A5 (en)
DK (1) DK152377C (en)
ES (1) ES441719A1 (en)
FI (1) FI58512C (en)
FR (1) FR2287506A1 (en)
GB (1) GB1501942A (en)
IE (1) IE43304B1 (en)
IT (1) IT1047535B (en)
LU (1) LU73570A1 (en)
NL (1) NL180851B (en)
NO (1) NO142531C (en)
SE (1) SE417980B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6087310A (en) * 1998-09-23 2000-07-11 Castrol Limited Skin cleaning compositions and uses comprising a polymer latex emulsion
DE19918265A1 (en) * 1999-04-22 2000-10-26 Henkel Kgaa Abrasive-containing aqueous liquid cleaning or scouring agent for hard surfaces contains microcapsules containing an ingredient to be protected e.g. a perfume
FR2843540A1 (en) * 2002-11-06 2004-02-20 Oreal Transparent composition for external application comprising a volatile hydrocarbon, non-ionic surfactant and hexylene glycol, useful for skin cleansing or make-up removal
MX2007007305A (en) 2005-03-04 2007-07-09 Procter & Gamble Rinse-off or wipe-off skin cleansing compositions.
DE102018221598A1 (en) 2018-12-13 2020-06-18 Henkel Ag & Co. Kgaa Means for the reductive color proofing of colored keratin fibers

Also Published As

Publication number Publication date
FI752827A (en) 1976-04-13
FI58512C (en) 1981-02-10
IE43304B1 (en) 1981-01-28
LU73570A1 (en) 1977-02-09
NL7511930A (en) 1976-04-14
SE7511412L (en) 1976-04-13
ES441719A1 (en) 1977-11-01
GB1501942A (en) 1978-02-22
ATA736275A (en) 1977-07-15
FI58512B (en) 1980-10-31
FR2287506A1 (en) 1976-05-07
FR2287506B1 (en) 1979-01-05
DE2448716B2 (en) 1977-01-13
DE2448716A1 (en) 1976-04-22
CH616702A5 (en) 1980-04-15
NO753437L (en) 1976-04-13
SE417980B (en) 1981-04-27
IT1047535B (en) 1980-10-20
NO142531C (en) 1980-09-03
IE43304L (en) 1976-04-12
DK451775A (en) 1976-04-13
DK152377C (en) 1988-07-25
DK152377B (en) 1988-02-22
BE834410A (en) 1976-04-12
AT342173B (en) 1978-03-28
NL180851B (en) 1986-12-01

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